{"id":"https://openalex.org/W4410518512","doi":"https://doi.org/10.3390/sym17050791","title":"Synthesis, Structural Characterization, EPR Analysis and Antimicrobial Activity of a Copper(II) Thiocyanate Complex Based on 3,7-Di(3-pyridyl)-1,5-dioxa-3,7-diazacyclooctane","display_name":"Synthesis, Structural Characterization, EPR Analysis and Antimicrobial Activity of a Copper(II) Thiocyanate Complex Based on 3,7-Di(3-pyridyl)-1,5-dioxa-3,7-diazacyclooctane","publication_year":2025,"publication_date":"2025-05-20","ids":{"openalex":"https://openalex.org/W4410518512","doi":"https://doi.org/10.3390/sym17050791"},"language":"en","primary_location":{"id":"doi:10.3390/sym17050791","is_oa":true,"landing_page_url":"https://doi.org/10.3390/sym17050791","pdf_url":"https://www.mdpi.com/2073-8994/17/5/791/pdf?version=1747728848","source":{"id":"https://openalex.org/S190787756","display_name":"Symmetry","issn_l":"2073-8994","issn":["2073-8994"],"is_oa":true,"is_in_doaj":false,"is_core":true,"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Symmetry","raw_type":"journal-article"},"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://www.mdpi.com/2073-8994/17/5/791/pdf?version=1747728848","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100374757","display_name":"Wei Qian","orcid":"https://orcid.org/0000-0002-9563-721X"},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Wei Qian","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081883145","display_name":"Zibo Wang","orcid":"https://orcid.org/0000-0001-5213-7867"},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zibo Wang","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Jingfeng Xia","orcid":null},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jingfeng Xia","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100373288","display_name":"Hongxia Wang","orcid":"https://orcid.org/0000-0003-0720-3305"},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hongxia Wang","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050813524","display_name":"Shuling Dong","orcid":null},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shuling Dong","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029634331","display_name":"Shuai Lou","orcid":"https://orcid.org/0000-0001-8797-7516"},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shuai Lou","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100568823","display_name":"Ping Ding","orcid":null},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ping Ding","raw_affiliation_strings":["School of Material Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Material Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100361280","display_name":"Li Li","orcid":"https://orcid.org/0000-0002-9559-5806"},"institutions":[{"id":"https://openalex.org/I308837","display_name":"Suzhou University of Science and Technology","ror":"https://ror.org/04en8wb91","country_code":"CN","type":"education","lineage":["https://openalex.org/I308837"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Li Li","raw_affiliation_strings":["School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China","institution_ids":["https://openalex.org/I308837"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5100361280"],"corresponding_institution_ids":["https://openalex.org/I308837"],"apc_list":{"value":2000,"currency":"CHF","value_usd":2227},"apc_paid":{"value":2000,"currency":"CHF","value_usd":2227},"fwci":0.4672,"has_fulltext":true,"cited_by_count":2,"citation_normalized_percentile":{"value":0.53481912,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":95,"max":96},"biblio":{"volume":"17","issue":"5","first_page":"791","last_page":"791"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.9998000264167786,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.9998000264167786,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9997000098228455,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T12458","display_name":"Organometallic Compounds Synthesis and Characterization","score":0.9994000196456909,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/thiocyanate","display_name":"Thiocyanate","score":0.8229517340660095},{"id":"https://openalex.org/keywords/copper","display_name":"Copper","score":0.7844172716140747},{"id":"https://openalex.org/keywords/electron-paramagnetic-resonance","display_name":"Electron paramagnetic resonance","score":0.7715864181518555},{"id":"https://openalex.org/keywords/antimicrobial","display_name":"Antimicrobial","score":0.6866776943206787},{"id":"https://openalex.org/keywords/characterization","display_name":"Characterization (materials science)","score":0.6400900483131409},{"id":"https://openalex.org/keywords/chemistry","display_name":"Chemistry","score":0.47873470187187195},{"id":"https://openalex.org/keywords/nuclear-chemistry","display_name":"Nuclear chemistry","score":0.4459128677845001},{"id":"https://openalex.org/keywords/materials-science","display_name":"Materials science","score":0.2981001138687134},{"id":"https://openalex.org/keywords/inorganic-chemistry","display_name":"Inorganic chemistry","score":0.268852174282074},{"id":"https://openalex.org/keywords/nuclear-magnetic-resonance","display_name":"Nuclear magnetic resonance","score":0.19013434648513794},{"id":"https://openalex.org/keywords/nanotechnology","display_name":"Nanotechnology","score":0.1883312463760376},{"id":"https://openalex.org/keywords/organic-chemistry","display_name":"Organic chemistry","score":0.17998498678207397},{"id":"https://openalex.org/keywords/physics","display_name":"Physics","score":0.12683048844337463}],"concepts":[{"id":"https://openalex.org/C2776294642","wikidata":"https://www.wikidata.org/wiki/Q77747995","display_name":"Thiocyanate","level":2,"score":0.8229517340660095},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.7844172716140747},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.7715864181518555},{"id":"https://openalex.org/C4937899","wikidata":"https://www.wikidata.org/wiki/Q68541106","display_name":"Antimicrobial","level":2,"score":0.6866776943206787},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.6400900483131409},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.47873470187187195},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.4459128677845001},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2981001138687134},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.268852174282074},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.19013434648513794},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.1883312463760376},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17998498678207397},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.12683048844337463}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.3390/sym17050791","is_oa":true,"landing_page_url":"https://doi.org/10.3390/sym17050791","pdf_url":"https://www.mdpi.com/2073-8994/17/5/791/pdf?version=1747728848","source":{"id":"https://openalex.org/S190787756","display_name":"Symmetry","issn_l":"2073-8994","issn":["2073-8994"],"is_oa":true,"is_in_doaj":false,"is_core":true,"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Symmetry","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.3390/sym17050791","is_oa":true,"landing_page_url":"https://doi.org/10.3390/sym17050791","pdf_url":"https://www.mdpi.com/2073-8994/17/5/791/pdf?version=1747728848","source":{"id":"https://openalex.org/S190787756","display_name":"Symmetry","issn_l":"2073-8994","issn":["2073-8994"],"is_oa":true,"is_in_doaj":false,"is_core":true,"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Symmetry","raw_type":"journal-article"},"sustainable_development_goals":[],"awards":[{"id":"https://openalex.org/G8102964735","display_name":"\u7c7b\u82bd\u5b62\u6746\u83ccsp.LLZ1\u7ea4\u7ef4\u7d20\u9176\u591a\u6837\u6027\u53ca\u5176\u5728\u79bb\u5b50\u6db2\u4f53\u4e2d\u7684\u5931\u6d3b\u4e0e\u5f3a\u5316\u673a\u5236","funder_award_id":"21676173","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320321605","display_name":"Government of Jiangsu Province","ror":"https://ror.org/004svx814"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4410518512.pdf","grobid_xml":"https://content.openalex.org/works/W4410518512.grobid-xml"},"referenced_works_count":19,"referenced_works":["https://openalex.org/W2011748569","https://openalex.org/W2013845380","https://openalex.org/W2075391906","https://openalex.org/W2093001905","https://openalex.org/W2131350133","https://openalex.org/W2364947408","https://openalex.org/W2544648880","https://openalex.org/W2804484912","https://openalex.org/W3141246379","https://openalex.org/W3204794927","https://openalex.org/W4286751847","https://openalex.org/W4307392422","https://openalex.org/W4312071433","https://openalex.org/W4313417447","https://openalex.org/W4360827644","https://openalex.org/W4381384172","https://openalex.org/W4387730306","https://openalex.org/W6707847833","https://openalex.org/W6846298677"],"related_works":["https://openalex.org/W1981011544","https://openalex.org/W2082337540","https://openalex.org/W2084916282","https://openalex.org/W1994875143","https://openalex.org/W1974704866","https://openalex.org/W4295266695","https://openalex.org/W2116469879","https://openalex.org/W142503734","https://openalex.org/W2103988939","https://openalex.org/W1987482693"],"abstract_inverted_index":{"The":[0,72,108],"reaction":[1],"of":[2,79,89,138],"bipyridine":[3],"3,7-di(3-pyridyl)-1,5-dioxa-3,7-diazacyclooctane":[4],"(L)":[5],"with":[6,22,37],"copper":[7,24,33],"thiocyanate":[8],"produces":[9],"a":[10,83,131],"discrete":[11],"metallamacrocycle":[12],"[Cu(L)(SCN)2(DMF)]2":[13],"(1).":[14],"In":[15,91],"complex":[16,80,99,118,129],"1,":[17],"two":[18,23,38,43,125],"cis-coordinated":[19],"ligands":[20],"combine":[21],"ions":[25],"to":[26,105,136],"form":[27],"an":[28,121],"unabridged":[29],"24-membered":[30],"macrocycle.":[31],"Each":[32],"ion":[34],"is":[35,100],"five-coordinated":[36],"nitrogens":[39,44],"from":[40,45,50],"separate":[41],"ligands,":[42],"thiocyanates":[46],"and":[47,65,68,117],"one":[48],"oxygen":[49],"the":[51,93,98,115,128,139],"dimethylformamide":[52],"(DMF)":[53],"solvent.":[54],"Complex":[55],"1":[56,81,119],"has":[57],"been":[58],"characterized":[59],"using":[60],"single-crystal":[61],"X-ray":[62],"diffraction,":[63],"optical":[64],"thermal":[66,94],"analyses":[67],"antimicrobial":[69,109],"activity":[70,110],"measurements.":[71],"solid":[73],"electron":[74],"paramagnetic":[75],"resonance":[76],"(EPR)":[77],"analysis":[78,95],"yielded":[82],"characteristic":[84],"structural":[85],"g":[86],"factor":[87],"value":[88],"2.147.":[90],"addition,":[92],"established":[96],"that":[97,113,137],"thermally":[101],"stable":[102],"at":[103],"up":[104],"176":[106],"\u00b0C.":[107],"measurements":[111],"demonstrated":[112],"both":[114],"ligand":[116,141],"exhibit":[120],"inhibitory":[122],"effect":[123],"on":[124],"strains,":[126],"where":[127],"exhibits":[130],"significantly":[132],"greater":[133],"inhibition":[134],"relative":[135],"free":[140],"(p":[142],"<":[143],"0.05).":[144]},"counts_by_year":[{"year":2025,"cited_by_count":2}],"updated_date":"2026-07-22T07:51:19.307946","created_date":"2025-10-10T00:00:00"}