{"id":"https://openalex.org/W93455268","doi":null,"title":"[The role of halogenation in the electro-oxidation of halogenated anilines in acetonitrile as the solvent].","display_name":"[The role of halogenation in the electro-oxidation of halogenated anilines in acetonitrile as the solvent].","publication_year":2000,"publication_date":"2000-07-01","ids":{"openalex":"https://openalex.org/W93455268","mag":"93455268","pmid":"https://pubmed.ncbi.nlm.nih.gov/11379031"},"language":"hu","primary_location":{"id":"pmid:11379031","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11379031","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta pharmaceutica Hungarica","raw_type":"English Abstract"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5071625731","display_name":"Szabolcs Pusztai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I106118109","display_name":"E\u00f6tv\u00f6s Lor\u00e1nd University","ror":"https://ror.org/01jsq2704","country_code":"HU","type":"education","lineage":["https://openalex.org/I106118109"]}],"countries":["HU"],"is_corresponding":false,"raw_author_name":"S Pusztai","raw_affiliation_strings":["ELTE Szervetlen \u00e9s Analitikai K\u00e9miai Tansz\u00e9k, 1117 Budapest, P\u00e1zm\u00e1ny P. s\u00e9t\u00e1ny 1/A"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"ELTE Szervetlen \u00e9s Analitikai K\u00e9miai Tansz\u00e9k, 1117 Budapest, P\u00e1zm\u00e1ny P. s\u00e9t\u00e1ny 1/A","institution_ids":["https://openalex.org/I106118109"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059620472","display_name":"Tibor Dankh\u00e1zi","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"T Dankh\u00e1zi","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5113720737","display_name":"G. Farsang","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"G Farsang","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.00472261,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"70","issue":"3-6","first_page":"239","last_page":"43"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.3386000096797943,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.3386000096797943,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.2863999903202057,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.22419999539852142,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/electrochemical-oxidation","display_name":"electrochemical oxidation","score":0.7929999828338623},{"id":"https://openalex.org/keywords/halogenated-anilines","display_name":"halogenated anilines","score":0.9580000042915344},{"id":"https://openalex.org/keywords/acetonitrile","display_name":"acetonitrile","score":0.8500000238418579},{"id":"https://openalex.org/keywords/chloroanilines","display_name":"chloroanilines","score":0.9509999752044678},{"id":"https://openalex.org/keywords/bromoanilines","display_name":"bromoanilines","score":1.0},{"id":"https://openalex.org/keywords/protonation","display_name":"protonation","score":0.6629999876022339},{"id":"https://openalex.org/keywords/primary-amines","display_name":"primary amines","score":0.5870000123977661},{"id":"https://openalex.org/keywords/aprotic-solvents","display_name":"aprotic solvents","score":0.6299999952316284}],"concepts":[{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.8466323614120483},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.8258506059646606},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8027967214584351},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.7721246480941772},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.7472755312919617},{"id":"https://openalex.org/C65973085","wikidata":"https://www.wikidata.org/wiki/Q888529","display_name":"Halogenation","level":2,"score":0.732285737991333},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.7163757681846619},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.6443599462509155},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4316122531890869},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.4277316927909851},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.42322683334350586},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4082862138748169},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4069954752922058},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.13942012190818787},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D000097","descriptor_name":"Acetonitriles","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D000814","descriptor_name":"Aniline Compounds","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D000814","descriptor_name":"Aniline Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D004563","descriptor_name":"Electrochemistry","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":false},{"descriptor_ui":"D006219","descriptor_name":"Halogens","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D006846","descriptor_name":"Hydrocarbons, Halogenated","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D006846","descriptor_name":"Hydrocarbons, Halogenated","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012997","descriptor_name":"Solvents","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"pmid:11379031","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11379031","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta pharmaceutica Hungarica","raw_type":"English Abstract"},{"id":"mag:93455268","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11379031","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"PubMed","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2015121109","https://openalex.org/W2016784261","https://openalex.org/W2076601630","https://openalex.org/W1972593569","https://openalex.org/W2286564123","https://openalex.org/W1998597697","https://openalex.org/W7216808164","https://openalex.org/W2011709557","https://openalex.org/W2521733024","https://openalex.org/W4317103788"],"abstract_inverted_index":{"The":[0,24,31,42,67],"4-halogeno-,":[1],"2,4-dihalogeno-":[2],"and":[3,29,40,62,98],"2,4,6-trihalogenoanilines":[4],"were":[5,27],"the":[6,10,17,52,55,60,63,71,75,99,106],"model":[7],"substances":[8],"of":[9,16,82],"research":[11],"described.":[12],"Acetonitrile":[13],"being":[14],"one":[15],"most":[18],"popular":[19],"aprotic":[20],"solvent":[21],"was":[22],"used.":[23],"halogeno":[25],"monomers":[26],"chloro":[28],"bromoanilines.":[30],"electrodimerised":[32],"substrate":[33,53],"is":[34],"stabilised":[35],"by":[36,74],"rejecting":[37],"halogenide":[38,44],"ion":[39],"protons.":[41],"rejected":[43],"ions":[45],"are":[46,103],"oxidisable":[47],"more":[48],"easier":[49],"compared":[50],"to":[51],"therefore":[54],"halogene":[56],"formed":[57,69,104],"substitutes":[58],"both":[59],"substrate,":[61],"dimer":[64,101],"as":[65],"well.":[66],"protons":[68],"during":[70],"oxidation":[72],"bind":[73],"strong":[76],"base":[77],"monomer":[78],"primary":[79],"amine.":[80],"Because":[81],"these":[83],"not":[84],"only":[85],"a":[86],"simple":[87],"electrodimerisation":[88],"will":[89],"take":[90],"place,":[91],"but":[92],"protonised":[93],"monomers,":[94,97],"higher":[95],"halogenated":[96],"corresponding":[100],"molecules":[102],"in":[105],"solution.":[107]},"counts_by_year":[],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}