{"id":"https://openalex.org/W8932795","doi":null,"title":"M\u00e9canismes de dissolution du quartz dans les solutions naturelles : \u00e9tude exp\u00e9rimentale et mod\u00e9lisation","display_name":"M\u00e9canismes de dissolution du quartz dans les solutions naturelles : \u00e9tude exp\u00e9rimentale et mod\u00e9lisation","publication_year":1995,"publication_date":"1995-01-01","ids":{"openalex":"https://openalex.org/W8932795","mag":"8932795"},"language":"fr","primary_location":{"id":"mag:8932795","doi":null,"is_oa":false,"landing_page_url":"http://www.theses.fr/1995TOU30251","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5024317462","display_name":"Eric Cador\u00e9","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Eric Cador\u00e9","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5024317462"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":12,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11073","display_name":"Metal Extraction and Bioleaching","score":0.27250000834465027,"subfield":{"id":"https://openalex.org/subfields/2506","display_name":"Metals and Alloys"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11073","display_name":"Metal Extraction and Bioleaching","score":0.27250000834465027,"subfield":{"id":"https://openalex.org/subfields/2506","display_name":"Metals and Alloys"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11302","display_name":"CO2 Sequestration and Geologic Interactions","score":0.24539999663829803,"subfield":{"id":"https://openalex.org/subfields/2305","display_name":"Environmental Engineering"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11740","display_name":"Geochemistry and Elemental Analysis","score":0.11050000041723251,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/quartz-dissolution","display_name":"quartz dissolution","score":0.9660000205039978},{"id":"https://openalex.org/keywords/dissolution-kinetics","display_name":"dissolution kinetics","score":0.9049999713897705},{"id":"https://openalex.org/keywords/surface-complexation","display_name":"surface complexation","score":0.6669999957084656},{"id":"https://openalex.org/keywords/surface-titration","display_name":"surface titration","score":0.40700000524520874},{"id":"https://openalex.org/keywords/electrokinetic-measurements","display_name":"electrokinetic measurements","score":0.6729999780654907},{"id":"https://openalex.org/keywords/ph-dependence","display_name":"pH dependence","score":0.46399998664855957},{"id":"https://openalex.org/keywords/sodium-adsorption","display_name":"sodium adsorption","score":0.6690000295639038},{"id":"https://openalex.org/keywords/sodium-catalysis","display_name":"sodium catalysis","score":0.5329999923706055},{"id":"https://openalex.org/keywords/lead-adsorption","display_name":"lead adsorption","score":0.7459999918937683},{"id":"https://openalex.org/keywords/grinding-effects","display_name":"grinding effects","score":0.4830000102519989},{"id":"https://openalex.org/keywords/reaction-stoichiometry","display_name":"reaction stoichiometry","score":0.5600000023841858},{"id":"https://openalex.org/keywords/protonation-enthalpy","display_name":"protonation enthalpy","score":0.8700000047683716},{"id":"https://openalex.org/keywords/dissolution-modeling","display_name":"dissolution modeling","score":0.4779999852180481},{"id":"https://openalex.org/keywords/mineral-weathering","display_name":"mineral weathering","score":0.46700000762939453},{"id":"https://openalex.org/keywords/acidic-media","display_name":"acidic media","score":0.4180000126361847}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6490780711174011},{"id":"https://openalex.org/C88380143","wikidata":"https://www.wikidata.org/wiki/Q416674","display_name":"Dissolution","level":2,"score":0.44453132152557373},{"id":"https://openalex.org/C2779870107","wikidata":"https://www.wikidata.org/wiki/Q43010","display_name":"Quartz","level":2,"score":0.4355050325393677},{"id":"https://openalex.org/C15708023","wikidata":"https://www.wikidata.org/wiki/Q80083","display_name":"Humanities","level":1,"score":0.4273309111595154},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.3127632439136505},{"id":"https://openalex.org/C138885662","wikidata":"https://www.wikidata.org/wiki/Q5891","display_name":"Philosophy","level":0,"score":0.2045024335384369},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.14817652106285095},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"mag:8932795","doi":null,"is_oa":false,"landing_page_url":"http://www.theses.fr/1995TOU30251","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W118445305","https://openalex.org/W7097208684","https://openalex.org/W2332356198","https://openalex.org/W56630048","https://openalex.org/W364263259","https://openalex.org/W2077948890","https://openalex.org/W2089742776","https://openalex.org/W2070414498","https://openalex.org/W6990558933","https://openalex.org/W3008052446"],"abstract_inverted_index":{"Les":[0,401],"objectifs":[1],"de":[2,29,31,43,46,57,60,67,71,84,87,91,94,98,123,125,127,140,143,146,156,158,164,177,186,200,225,234,251,264,267,287,296,322,327,335,376,404,406,412,416,419,422],"ce":[3,32],"travail":[4],"sont":[5],"d'ameliorer":[6],"notre":[7],"connaissance":[8],"des":[9,20,27,63,102,121,132,154,162,175,184,213,219,270,372,374,396,409],"mecanismes":[10],"elementaires":[11],"qui":[12,105,300,338,432],"controlent":[13,106],"la":[14,44,58,68,79,85,88,92,95,99,107,111,144,190,198,223,232,249,283,310,384,399,420,434],"dissolution":[15,30,47,165,201,226,252,405,435],"du":[16,48,113,148,202,206,227,246,253,257,275,344,429,436],"quartz":[17,49,178,203,228,258,279,407,437],"et":[18,97,138,240,306,366,388,394],"d'etablir":[19],"lois":[21],"cinetiques":[22],"rendant":[23],"compte":[24],"avec":[25,65,282],"precision":[26],"vitesses":[28],"mineral":[33],"dans":[34,350,408,426],"les":[35,55,303],"solutions":[36,410],"naturelles.":[37],"En":[38],"premier":[39],"lieu,":[40],"l'expression":[41],"generale":[42],"vitesse":[45,124,199,224,250,328],"a":[50,77,110,116,130,169,183,259,342,363,367,383],"ete":[51,172,260],"etablie":[52],"en":[53,82,166,208,262],"combinant":[54],"concepts":[56],"chimie":[59],"coordination":[61],"surfacique":[62,101],"mineraux":[64],"ceux":[66],"theorie":[69],"cinetique":[70,346],"l'etat":[72],"transitoire.":[73],"Cette":[74],"double":[75],"approche":[76],"permis":[78,117],"determination":[80],"precise,":[81],"fonction":[83],"composition":[86],"solution":[89],"d'attaque,":[90],"stoechiometrie,":[93],"charge":[96],"concentration":[100],"complexes":[103,235,375],"reactionnels":[104],"reaction":[108,145],"chimique":[109],"surface":[112],"quartz.":[114,254],"Elle":[115],"egalement":[118],"le":[119,242,278,289,314,355,386,389,427],"calcul":[120],"constantes":[122],"decomposition":[126,233],"ces":[128],"precurseurs":[129],"partir":[131],"grandeurs":[133],"thermodynamiques":[134],"appropriees":[135],"(constante":[136],"d'equilibre":[137],"enthalpie":[139],"protonation":[141],"lors":[142],"formation":[147],"complexe":[149,295,321,430],"active).":[150],"Des":[151],"mesures":[152],"electrocinetiques,":[153],"essais":[155,163],"titration":[157],"surfaces":[159],"ainsi":[160,307],"que":[161,197,222,241,273],"reacteur":[167],"ferme":[168],"25c":[170,373],"ont":[171],"realises":[173],"sur":[174,248,277],"poudres":[176],"bien":[179],"cristallise":[180],"ou":[181,266],"soumis":[182],"broyages":[185],"differentes":[187],"durees.":[188],"Pour":[189],"premiere":[191],"fois":[192,385],"il":[193],"est":[194,229,330],"clairement":[195],"demontre":[196,221],"depend":[204],"fortement":[205,281,302],"ph":[207,247],"milieu":[209],"acide.":[210],"La":[211],"comparaison":[212],"resultats":[214,271,402],"experimentaux":[215],"aux":[216],"modeles":[217],"issus":[218],"theories":[220],"controlee":[230],"par":[231,391],"triplement":[236],"coordonnes":[237],"au":[238,348],"solide":[239],"broyage":[243],"modifie":[244],"l'influence":[245],"Le":[255],"comportement":[256],"etudie":[261],"presence":[263,421],"sodium":[265,276,290,315],"plomb.":[268],"L'analyse":[269],"montre":[272],"l'adsorption":[274],"varie":[280],"temperature.":[284],"Au":[285],"dessus":[286],"150c,":[288],"subit":[291,316],"une":[292,317],"adsorption":[293,392],"specifique,":[294],"type":[297,323,377],"sphere":[298,324,378],"interne,":[299],"polarise":[301],"liaisons":[304],"si-o":[305],"catalyse":[308],"pleinement":[309],"dissolution.":[311,400],"A":[312,380],"25c,":[313],"simple":[318,333],"attraction":[319],"electrostatique,":[320],"externe.":[325],"L'accroissement":[326],"observe":[329],"donc":[331],"un":[332,358],"effet":[334],"force":[336],"ionique":[337],"peut":[339],"etre":[340],"calcule":[341],"l'aide":[343],"modele":[345],"mis":[347],"point":[349],"cette":[351],"etude.":[352],"Par":[353],"contre":[354],"plomb":[356,387],"joue":[357],"role":[359],"tres":[360],"important":[361],"meme":[362],"temperature":[364],"ordinaire":[365],"faible":[368],"concentration.":[369],"Il":[370],"forme":[371],"interne.":[379],"haute":[381],"temperature,":[382],"sodium,":[390],"specifique":[393],"polarisation":[395],"liaisons,":[397],"catalysent":[398],"d'essais":[403],"d'activite":[411],"l'eau":[413],"connue":[414],"permettent":[415],"formuler":[417],"l'hypothese":[418],"quatre":[423],"molecules":[424],"d'eau":[425],"precurseur":[428],"active":[431],"controle":[433]},"counts_by_year":[{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-08-08T07:41:36.138363","created_date":"2016-06-24T00:00:00"}