{"id":"https://openalex.org/W87701686","doi":"https://doi.org/10.7907/4qz8-cs23","title":"Applications and Extensions of Living Ring-Opening Metathesis Polymerization","display_name":"Applications and Extensions of Living Ring-Opening Metathesis Polymerization","publication_year":2009,"publication_date":"2009-09-15","ids":{"openalex":"https://openalex.org/W87701686","doi":"https://doi.org/10.7907/4qz8-cs23","mag":"87701686"},"language":"en","primary_location":{"id":"pmh:oai:thesis.library.caltech.edu:3416","doi":null,"is_oa":true,"landing_page_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","pdf_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","source":{"id":"https://openalex.org/S4306402402","display_name":"CaltechTHESIS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Thesis"},"volume":null,"type":"dissertation","indexed_in":["datacite"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5051929521","display_name":"John B. Matson","orcid":"https://orcid.org/0000-0001-7984-5396","observed_orcids":["https://orcid.org/0000-0001-7984-5396"]},"institutions":[{"id":"https://openalex.org/I122411786","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055","country_code":"US","type":"education","lineage":["https://openalex.org/I122411786"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Matson, John B.","raw_affiliation_strings":["California Institute of Technology"],"raw_orcid":"https://orcid.org/0000-0001-7984-5396","affiliations":[{"raw_affiliation_string":"California Institute of Technology","institution_ids":["https://openalex.org/I122411786"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5051929521"],"corresponding_institution_ids":["https://openalex.org/I122411786"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.6610999703407288,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.6610999703407288,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11549","display_name":"Synthetic Organic Chemistry Methods","score":0.3319999873638153,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.0017999999690800905,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/living-ring-opening-metathesis-polymerization","display_name":"living ring-opening metathesis polymerization","score":0.9869999885559082},{"id":"https://openalex.org/keywords/polynorbornene","display_name":"polynorbornene","score":0.8140000104904175},{"id":"https://openalex.org/keywords/janus-nanoparticles","display_name":"Janus nanoparticles","score":0.6909999847412109},{"id":"https://openalex.org/keywords/radiofluorination","display_name":"radiofluorination","score":0.7170000076293945},{"id":"https://openalex.org/keywords/fluorine-18","display_name":"fluorine-18","score":0.906000018119812},{"id":"https://openalex.org/keywords/photocrosslinkable-polymers","display_name":"photocrosslinkable polymers","score":0.7960000038146973},{"id":"https://openalex.org/keywords/end-capping","display_name":"end-capping","score":0.6970000267028809},{"id":"https://openalex.org/keywords/atom-transfer-radical-polymerization","display_name":"atom transfer radical polymerization","score":0.9890000224113464},{"id":"https://openalex.org/keywords/functionalized-polymers","display_name":"functionalized polymers","score":0.6019999980926514},{"id":"https://openalex.org/keywords/nanostructure-assembly","display_name":"nanostructure assembly","score":0.6010000109672546}],"concepts":[{"id":"https://openalex.org/C2780227895","wikidata":"https://www.wikidata.org/wiki/Q2660966","display_name":"ROMP","level":5,"score":0.9831358194351196},{"id":"https://openalex.org/C2780547246","wikidata":"https://www.wikidata.org/wiki/Q420176","display_name":"Norbornene","level":4,"score":0.831727147102356},{"id":"https://openalex.org/C174499055","wikidata":"https://www.wikidata.org/wiki/Q4250538","display_name":"Ring-opening metathesis polymerisation","level":5,"score":0.7042266726493835},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.6174912452697754},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.6089579463005066},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5613763928413391},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5185292959213257},{"id":"https://openalex.org/C150539798","wikidata":"https://www.wikidata.org/wiki/Q757561","display_name":"Atom-transfer radical-polymerization","level":4,"score":0.47201746702194214},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.46371176838874817},{"id":"https://openalex.org/C48396125","wikidata":"https://www.wikidata.org/wiki/Q903447","display_name":"Living polymerization","level":5,"score":0.43619397282600403},{"id":"https://openalex.org/C153914509","wikidata":"https://www.wikidata.org/wiki/Q191090","display_name":"Metathesis","level":4,"score":0.43340831995010376},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.2927044630050659},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.058437615633010864}],"mesh":[],"locations_count":3,"locations":[{"id":"pmh:oai:thesis.library.caltech.edu:3416","doi":null,"is_oa":true,"landing_page_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","pdf_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","source":{"id":"https://openalex.org/S4306402402","display_name":"CaltechTHESIS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Thesis"},{"id":"mag:87701686","doi":null,"is_oa":false,"landing_page_url":"https://oatd.org/oatd/record?record=oai%5C%3Athesis.library.caltech.edu%5C%3A3416","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},{"id":"doi:10.7907/4qz8-cs23","doi":"https://doi.org/10.7907/4qz8-cs23","is_oa":true,"landing_page_url":"https://doi.org/10.7907/4qz8-cs23","pdf_url":null,"source":{"id":"https://openalex.org/S7407050848","display_name":"Caltech Library","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"thesis"}],"best_oa_location":{"id":"pmh:oai:thesis.library.caltech.edu:3416","doi":null,"is_oa":true,"landing_page_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","pdf_url":"https://thesis.library.caltech.edu/3416/1/Full_Thesis_final_version.pdf","source":{"id":"https://openalex.org/S4306402402","display_name":"CaltechTHESIS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Thesis"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W87701686.pdf","grobid_xml":"https://content.openalex.org/works/W87701686.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W7097767378","https://openalex.org/W2725278238","https://openalex.org/W4310289610","https://openalex.org/W2088780699","https://openalex.org/W2007252698","https://openalex.org/W150607283","https://openalex.org/W1763503507","https://openalex.org/W165344238","https://openalex.org/W2117418550","https://openalex.org/W2071744350"],"abstract_inverted_index":{"Living":[0],"ring-opening":[1],"metathesis":[2,25],"polymerization":[3,7,184],"(ROMP)":[4],"is":[5,175,236],"a":[6,40,51,94,122,128,135,140,169,232,260,306],"method":[8,163],"that":[9,266,310,319],"has":[10],"recently":[11],"become":[12],"popular":[13],"in":[14,23,54,64,73,93,151,177,238,246,289,314],"the":[15,36,55,74,81,101,187,242,252,290,297,315],"synthesis":[16,102,253,291,298],"of":[17,31,35,43,57,76,83,105,148,226,254,276,292,301],"complex":[18,58,77],"polymers":[19,88,91,167,329],"due":[20],"to":[21,86,90,197,210,251,259],"advances":[22],"olefin":[24],"catalyst":[26,95,283],"design.":[27],"The":[28,118,279],"unrivaled":[29],"degree":[30],"functional":[32,61,212,327],"group":[33],"tolerance":[34],"method,":[37],"coupled":[38],"with":[39],"high":[41],"level":[42],"control":[44],"and":[45,60,79,89,103,194,221,249,262,299,330],"synthetic":[46],"ease,":[47],"make":[48],"living":[49,71,84,116],"ROMP":[50,72,85,166,228,300,328],"valuable":[52],"tool":[53],"assembly":[56,75],"nanostructures":[59,78],"polymers.":[62],"Work":[63],"this":[65,206],"thesis":[66],"details":[67,337],"methods":[68],"for":[69,164,323],"applying":[70],"extending":[80],"uses":[82],"end-functionalized":[87],"synthesized":[92,114],"economical":[96],"manner.":[97],"Chapter":[98,143,178,203,239],"2":[99,333],"describes":[100,296],"radiofluorination":[104],"fluorine-18":[106],"functionalized":[107,188],"nanoparticles":[108,150],"assembled":[109,157],"from":[110,127,139,186],"polynorbornene":[111,153],"block":[112,119,125,137,154,201,263],"copolymers":[113,120,155],"via":[115],"ROMP.":[117],"include":[121],"hydrophobic":[123],"photo-crosslinkable":[124],"made":[126,138],"novel":[129],"cinnamate-containing":[130],"norbornene,":[131,309],"as":[132,134,285,287],"well":[133],"hydrophilic":[136],"PEGylated":[141],"norbornene.":[142],"3":[144],"illustrates":[145],"another":[146],"application":[147],"ROMP-based":[149],"which":[152],"are":[156],"into":[158],"Janus":[159],"(hemispherical)":[160],"nanoparticles.":[161],"A":[162,223],"end-capping":[165,243],"using":[168,231],"symmetrical":[170],"alpha\u2013bromoester-containing":[171],"cis-olefin":[172],"terminating":[173],"agent":[174],"described":[176,245],"4.":[179],"Subsequent":[180],"atom":[181],"transfer":[182],"radical":[183],"(ATRP)":[185],"chain":[189,273],"end":[190],"confirms":[191],"complete":[192],"end-functionalization":[193,208],"was":[195],"used":[196],"synthesize":[198],"mechanistically":[199],"incompatible":[200],"copolymers.":[202],"5":[204,250],"extends":[205],"polymer":[207,256,272],"approach":[209],"additional":[211,255,335],"groups,":[213],"including":[214,305],"alcohols,":[215],"bromides,":[216],"thioacetates,":[217],"fluorescent":[218],"compounds,":[219],"biotin,":[220],"others.":[222],"thorough":[224],"study":[225],"pulsed-addition":[227],"(PA-ROMP)":[229],"performed":[230],"Symyx":[233],"robotic":[234],"system":[235],"presented":[237],"6.":[240],"Extending":[241],"methodology":[244],"Chapters":[247],"4":[248],"chains":[257],"led":[258],"homo-":[261],"copolymerization":[264],"strategy":[265,281],"can":[267],"produce":[268],"more":[269],"than":[270],"one":[271],"per":[274],"molecule":[275],"metal":[277],"initiatior.":[278],"PA-ROMP":[280],"reduces":[282],"consumption":[284],"much":[286],"sevenfold":[288],"polynorbornenes.":[293],"Appendix":[294,332],"1":[295],"several":[302],"norbornene":[303],"monomers,":[304],"copper-64":[307],"chelating":[308],"were":[311],"not":[312],"addressed":[313],"previous":[316],"chapters":[317],"but":[318],"may":[320],"be":[321],"useful":[322],"future":[324],"studies":[325],"on":[326,338],"nanostructures.":[331],"contains":[334],"mathematical":[336],"PA-ROMP.":[339]},"counts_by_year":[],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2016-06-24T00:00:00"}