{"id":"https://openalex.org/W86104079","doi":"https://doi.org/10.1107/s1600536812047812","title":"(4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene","display_name":"(4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene","publication_year":2012,"publication_date":"2012-11-24","ids":{"openalex":"https://openalex.org/W86104079","doi":"https://doi.org/10.1107/s1600536812047812","mag":"86104079","pmid":"https://pubmed.ncbi.nlm.nih.gov/23468743","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/3588778"},"language":"en","primary_location":{"id":"doi:10.1107/s1600536812047812","doi":"https://doi.org/10.1107/s1600536812047812","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s1600536812047812","pdf_url":"https://journals.iucr.org/e/issues/2012/12/00/hg5267/hg5267.pdf","source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://journals.iucr.org/e/issues/2012/12/00/hg5267/hg5267.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5089946974","display_name":"Vincent Onserio Nyamori","orcid":"https://orcid.org/0000-0002-8995-4593","observed_orcids":["https://orcid.org/0000-0002-8995-4593"]},"institutions":[{"id":"https://openalex.org/I95023434","display_name":"University of KwaZulu-Natal","ror":"https://ror.org/04qzfn040","country_code":"ZA","type":"education","lineage":["https://openalex.org/I95023434"]}],"countries":["ZA"],"is_corresponding":false,"raw_author_name":"Vincent O. Nyamori","raw_affiliation_strings":["School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa","School of Chemistry & Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000,  South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa","institution_ids":["https://openalex.org/I95023434"]},{"raw_affiliation_string":"School of Chemistry & Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000,  South Africa","institution_ids":["https://openalex.org/I95023434"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017253115","display_name":"Godfrey Keru","orcid":"https://orcid.org/0000-0002-4879-2196","observed_orcids":["https://orcid.org/0000-0002-4879-2196"]},"institutions":[{"id":"https://openalex.org/I95023434","display_name":"University of KwaZulu-Natal","ror":"https://ror.org/04qzfn040","country_code":"ZA","type":"education","lineage":["https://openalex.org/I95023434"]}],"countries":["ZA"],"is_corresponding":false,"raw_author_name":"Godfrey Keru","raw_affiliation_strings":["School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa","School of Chemistry & Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000,  South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa","institution_ids":["https://openalex.org/I95023434"]},{"raw_affiliation_string":"School of Chemistry & Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000,  South Africa","institution_ids":["https://openalex.org/I95023434"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5113687267","display_name":"Bernard O. Omondi","orcid":"https://orcid.org/0000-0002-3003-6712","observed_orcids":["https://orcid.org/0000-0002-3003-6712"]},"institutions":[{"id":"https://openalex.org/I95023434","display_name":"University of KwaZulu-Natal","ror":"https://ror.org/04qzfn040","country_code":"ZA","type":"education","lineage":["https://openalex.org/I95023434"]}],"countries":["ZA"],"is_corresponding":true,"raw_author_name":"Bernard Omondi","raw_affiliation_strings":["School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa","School of Chemistry & Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000,  South Africa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa","institution_ids":["https://openalex.org/I95023434"]},{"raw_affiliation_string":"School of Chemistry & Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000,  South Africa","institution_ids":["https://openalex.org/I95023434"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5113687267"],"corresponding_institution_ids":["https://openalex.org/I95023434"],"apc_list":{"value":500,"currency":"USD","value_usd":500},"apc_paid":{"value":500,"currency":"USD","value_usd":500},"fwci":0.1652,"has_fulltext":true,"cited_by_count":1,"citation_normalized_percentile":{"value":0.47153969,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"68","issue":"12","first_page":"m1535","last_page":"m1535"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13833","display_name":"Ferrocene Chemistry and Applications","score":0.009700000286102295,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ferrocene","display_name":"ferrocene","score":0.6830000281333923},{"id":"https://openalex.org/keywords/pyridine-schiff-base","display_name":"pyridine Schiff base","score":0.6349999904632568},{"id":"https://openalex.org/keywords/molecular-conformation","display_name":"molecular conformation","score":0.7770000100135803},{"id":"https://openalex.org/keywords/dihedral-angle","display_name":"dihedral angle","score":0.9610000252723694},{"id":"https://openalex.org/keywords/asymmetric-unit","display_name":"asymmetric unit","score":0.38100001215934753}],"concepts":[{"id":"https://openalex.org/C2777237805","wikidata":"https://www.wikidata.org/wiki/Q211972","display_name":"Ferrocene","level":4,"score":0.8714248538017273},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5398937463760376},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.40913018584251404},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.36921316385269165},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.048249006271362305},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0}],"mesh":[],"locations_count":6,"locations":[{"id":"doi:10.1107/s1600536812047812","doi":"https://doi.org/10.1107/s1600536812047812","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s1600536812047812","pdf_url":"https://journals.iucr.org/e/issues/2012/12/00/hg5267/hg5267.pdf","source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},{"id":"pmh:oai:europepmc.org:2589899","doi":null,"is_oa":true,"landing_page_url":"http://europepmc.org/articles/PMC3588778","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"","raw_type":"Text"},{"id":"pmid:23468743","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23468743","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta crystallographica. Section E, Structure reports online","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:3588778","doi":null,"is_oa":true,"landing_page_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC3588778/","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallogr Sect E Struct Rep Online","raw_type":"Text"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.691.2806","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.691.2806","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/pdf/e-68-m1535.pdf","raw_type":"text"},{"id":"pmh:oai:doaj.org/article:f273071456e340a59b3f1f246222e742","doi":null,"is_oa":true,"landing_page_url":"https://doaj.org/article/f273071456e340a59b3f1f246222e742","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-sa","license_id":"https://openalex.org/licenses/cc-by-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1535-m1535 (2012)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.1107/s1600536812047812","doi":"https://doi.org/10.1107/s1600536812047812","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s1600536812047812","pdf_url":"https://journals.iucr.org/e/issues/2012/12/00/hg5267/hg5267.pdf","source":{"id":"https://openalex.org/S146636433","display_name":"Acta Crystallographica Section E Structure Reports Online","issn_l":"1600-5368","issn":["1600-5368"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Structure Reports Online","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W86104079.pdf","grobid_xml":"https://content.openalex.org/works/W86104079.grobid-xml"},"referenced_works_count":6,"referenced_works":["https://openalex.org/W44983015","https://openalex.org/W1990170643","https://openalex.org/W2006365755","https://openalex.org/W2059700174","https://openalex.org/W2128179591","https://openalex.org/W2131350133"],"related_works":["https://openalex.org/W1995257028","https://openalex.org/W2065732076","https://openalex.org/W2005444507","https://openalex.org/W2081779732","https://openalex.org/W2011989941","https://openalex.org/W2039294396","https://openalex.org/W2010188683","https://openalex.org/W1993648669","https://openalex.org/W2014845335","https://openalex.org/W1624028502"],"abstract_inverted_index":{"The":[0,27,61,86],"asymetric":[1],"unit":[2,19,33],"of":[3,30,63,80,96,103],"the":[4,17,31,42,51,64,71,94,97,110],"title":[5],"compound,":[6],"[Fe(C5H5)(C17H13N2)],":[7],"contains":[8],"two":[9,111],"independent":[10],"mol-ecules":[11],"whose":[12],"conformations":[13],"differ,":[14],"especially":[15],"in":[16,39,50,74,109],"4-{(pyridin-4-yl)methyl-idene]amino}-phenyl":[18],"where":[20],"one":[21,40],"is":[22,44,67,89],"flipped":[23],"by":[24,46,53],"almost":[25],"180\u00b0.":[26],"cyclo-penta-dienyl":[28],"rings":[29],"ferrocene":[32,72],"also":[34,90],"exhibit":[35],"different":[36],"staggered":[37,45],"conformations:":[38],"mol-ecule":[41],"conformation":[43],"9.43":[47],"(2)\u00b0":[48,108],"and":[49,83,106],"other":[52],"24.46":[54],"(1)\u00b0":[55],"from":[56,70,93],"an":[57],"ideal":[58],"eclipsed":[59],"geometry.":[60],"plane":[62,95],"benzene":[65,87],"ring":[66,88],"tilted":[68],"away":[69],"group":[73],"both":[75],"mol-ecules,":[76],"with":[77,100],"dihedral":[78,101],"angles":[79,102],"6.97":[81],"(1)":[82],"10.30":[84],"(2)\u00b0.":[85],"slightly":[91],"twisted":[92],"pyridine":[98],"ring,":[99],"5.98":[104],"(2)":[105],"6.51":[107],"mol-ecules.":[112]},"counts_by_year":[{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2016-06-24T00:00:00"}