{"id":"https://openalex.org/W856842348","doi":null,"title":"Catalyzed additions to alkene double bonds: (I) Fumarase-catalyzed hydration of alkene double bonds (II) Alumina-catalyzed hydrochlorination of alkene double bonds","display_name":"Catalyzed additions to alkene double bonds: (I) Fumarase-catalyzed hydration of alkene double bonds (II) Alumina-catalyzed hydrochlorination of alkene double bonds","publication_year":1996,"publication_date":"1996-01-01","ids":{"openalex":"https://openalex.org/W856842348","mag":"856842348"},"language":"en","primary_location":{"id":"pmh:oai:scholarworks.rit.edu:theses-6991","doi":null,"is_oa":true,"landing_page_url":"https://scholarworks.rit.edu/theses/5986","pdf_url":"https://repository.rit.edu/cgi/viewcontent.cgi?article=6991&context=theses","source":{"id":"https://openalex.org/S4306402456","display_name":"RIT Scholar Works (Rochester Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I155173764","host_organization_name":"Rochester Institute of Technology","host_organization_lineage":["https://openalex.org/I155173764"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Theses","raw_type":"text"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://repository.rit.edu/cgi/viewcontent.cgi?article=6991&context=theses","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5076793775","display_name":"Charles Francavilla","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Charles Francavilla","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5076793775"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.5770999789237976,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.5770999789237976,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.2207999974489212,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.04740000143647194,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/fumarase","display_name":"fumarase","score":0.8740000128746033},{"id":"https://openalex.org/keywords/alkene-hydration","display_name":"alkene hydration","score":0.8289999961853027},{"id":"https://openalex.org/keywords/mesaconate","display_name":"mesaconate","score":0.6899999976158142},{"id":"https://openalex.org/keywords/norbornadiene","display_name":"norbornadiene","score":0.8650000095367432},{"id":"https://openalex.org/keywords/hydrochlorination","display_name":"hydrochlorination","score":0.8930000066757202},{"id":"https://openalex.org/keywords/alumina-catalysis","display_name":"alumina catalysis","score":0.8650000095367432},{"id":"https://openalex.org/keywords/thionyl-chloride","display_name":"thionyl chloride","score":0.9459999799728394},{"id":"https://openalex.org/keywords/oxalyl-chloride","display_name":"oxalyl chloride","score":0.9169999957084656},{"id":"https://openalex.org/keywords/heavy-water","display_name":"heavy water","score":0.6190000176429749},{"id":"https://openalex.org/keywords/stereospecific-addition","display_name":"stereospecific addition","score":0.722000002861023},{"id":"https://openalex.org/keywords/1-2-addition","display_name":"1,2-addition","score":0.8450000286102295},{"id":"https://openalex.org/keywords/exo-selectivity","display_name":"exo selectivity","score":0.5580000281333923},{"id":"https://openalex.org/keywords/kinetic-and-thermodynamic-products","display_name":"kinetic and thermodynamic products","score":0.6190000176429749}],"concepts":[{"id":"https://openalex.org/C2776254738","wikidata":"https://www.wikidata.org/wiki/Q81406","display_name":"Alkene","level":3,"score":0.9405333995819092},{"id":"https://openalex.org/C68381374","wikidata":"https://www.wikidata.org/wiki/Q258652","display_name":"Double bond","level":2,"score":0.9167079925537109},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6436495780944824},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6056261658668518},{"id":"https://openalex.org/C106302636","wikidata":"https://www.wikidata.org/wiki/Q21107515","display_name":"Fumarase","level":3,"score":0.4258493483066559},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.36484628915786743},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28022903203964233},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.08748385310173035}],"mesh":[],"locations_count":3,"locations":[{"id":"pmh:oai:scholarworks.rit.edu:theses-6991","doi":null,"is_oa":true,"landing_page_url":"https://scholarworks.rit.edu/theses/5986","pdf_url":"https://repository.rit.edu/cgi/viewcontent.cgi?article=6991&context=theses","source":{"id":"https://openalex.org/S4306402456","display_name":"RIT Scholar Works (Rochester Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I155173764","host_organization_name":"Rochester Institute of Technology","host_organization_lineage":["https://openalex.org/I155173764"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Theses","raw_type":"text"},{"id":"pmh:oai:repository.rit.edu:theses-6991","doi":null,"is_oa":false,"landing_page_url":"https://repository.rit.edu/theses/5986","pdf_url":null,"source":{"id":"https://openalex.org/S4306402456","display_name":"RIT Scholar Works (Rochester Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I155173764","host_organization_name":"Rochester Institute of Technology","host_organization_lineage":["https://openalex.org/I155173764"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Theses","raw_type":"text"},{"id":"mag:856842348","doi":null,"is_oa":false,"landing_page_url":"https://scholarworks.rit.edu/cgi/viewcontent.cgi?article=6991&context=theses","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:scholarworks.rit.edu:theses-6991","doi":null,"is_oa":true,"landing_page_url":"https://scholarworks.rit.edu/theses/5986","pdf_url":"https://repository.rit.edu/cgi/viewcontent.cgi?article=6991&context=theses","source":{"id":"https://openalex.org/S4306402456","display_name":"RIT Scholar Works (Rochester Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I155173764","host_organization_name":"Rochester Institute of Technology","host_organization_lineage":["https://openalex.org/I155173764"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Theses","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W856842348.pdf","grobid_xml":"https://content.openalex.org/works/W856842348.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2084282870","https://openalex.org/W2950818179","https://openalex.org/W3158203854","https://openalex.org/W2963694540","https://openalex.org/W4235201801","https://openalex.org/W2036381499","https://openalex.org/W2086225955","https://openalex.org/W1978823560","https://openalex.org/W2950216280","https://openalex.org/W2136843076"],"abstract_inverted_index":{"The":[0,15],"stereospecific":[1],"hydration":[2,38,66],"of":[3,59,81,109,136,147,184,209],"(5)-malate":[4],"to":[5,67,77,83,130,143,149,156],"fumarate,":[6],"catalyzed":[7,188],"by":[8,13],"fumarase,":[9],"was":[10,43,75,141],"extensively":[11],"analyzed":[12],"NMR.":[14],"NMR":[16],"techniques":[17],"employed":[18],"were":[19,34],"one":[20],"dimensional":[21,28],"2H":[22],"and":[23,26,71,94,116,121,178],"NOE":[24],"Difference,":[25],"two":[27],"^^H":[29],"COSY.":[30],"Various":[31],"potentional":[32],"substrates":[33],"tried":[35],"for":[36,65,186,192],"fumarase-promoted":[37],"with":[39,138,153],"no":[40],"sucesss.":[41],"It":[42],"concluded":[44],"that":[45,52,197],"mesaconate":[46],"is":[47],"possibly":[48],"the":[49,56,62,79,107,110,124,131,145,187,193,198],"largest":[50],"molecule":[51],"can":[53],"fit":[54],"into":[55],"active":[57],"site":[58],"fumarase":[60],"in":[61],"correct":[63],"orientation":[64],"occur.":[68],"Thionyl":[69],"chloride":[70,115],"appropriately":[72],"prepared":[73],"alumina":[74,117,137],"found":[76,142],"promote":[78,144],"addition":[80,146,190],"HC1":[82],"norbornadiene":[84],"(":[85,91,97,161,166,173],"I":[86],"),":[87,163,168,175],"resulting":[88],"in71%(+l%)":[89],"exo-5-chloronorbornene":[90],"II":[92,120],")":[93,99],"29%":[95],"3-chloronortricyclene":[96],"HI":[98],"at":[100],"room":[101],"temperature,":[102],"while":[103],"lower":[104],"temperatures":[105],"favor":[106],"synthesis":[108],"kinetic":[111],"product,":[112,133],"HI.":[113,134,180],"Oxalyl":[114],"also":[118],"produces":[119],"HI,":[122],"but":[123],"product":[125],"composition":[126],"slowly":[127],"equilbrates":[128],"mostly":[129],"thermodynamic":[132],"Treatment":[135],"deuterium":[139],"oxide":[140],"DC1":[148,189],"norbornadiene,":[150],"when":[151,201],"used":[152],"thionyl":[154],"chloride,":[155],"give":[157],"1":[158,171,199],"8%":[159,179],"exo,aft'-5-chlorobicyclo[2.2.1]hept-2-ene-7-d":[160],"VHIa":[162],"33%":[164],"exo,exo-6-chlorobicyclo[2.2.1]hept-2-ene-5-d":[165],"VHIb":[167],"21%":[169],"5-chlorotricyclo[2.2.":[170],".0^2,6]heptane-3-d":[172],"VEHc":[174],"20%":[176],"H,":[177],"A":[181],"higher":[182,207],"ratio":[183],"Vmb/Vma":[185],"than":[191],"uncatalyzed":[194],"addition1":[195],"suggests":[196],",2-addition,":[200],"using":[202],"alumina,":[203],"gives":[204],"a":[205],"somwhat":[206],"proportion":[208],"syn-addition.":[210]},"counts_by_year":[],"updated_date":"2026-09-04T10:56:28.161419","created_date":"2016-06-24T00:00:00"}
