{"id":"https://openalex.org/W7225826477","doi":"https://doi.org/10.3389/frsfm.2026.1964016","title":"Structure-property relationships in bifunctional benzoxazines and their basalt-fiber-reinforced composites: curing behavior, thermal stability, antimicrobial activity, and corrosion protection","display_name":"Structure-property relationships in bifunctional benzoxazines and their basalt-fiber-reinforced composites: curing behavior, thermal stability, antimicrobial activity, and corrosion protection","publication_year":2026,"publication_date":"2026-11-11","ids":{"openalex":"https://openalex.org/W7225826477","doi":"https://doi.org/10.3389/frsfm.2026.1964016"},"language":"en","primary_location":{"id":"doi:10.3389/frsfm.2026.1964016","doi":"https://doi.org/10.3389/frsfm.2026.1964016","is_oa":true,"landing_page_url":"https://doi.org/10.3389/frsfm.2026.1964016","pdf_url":"https://www.frontiersin.org/journals/soft-matter/articles/10.3389/frsfm.2026.1964016/pdf","source":{"id":"https://openalex.org/S4386622059","display_name":"Frontiers in Soft Matter","issn_l":"2813-0499","issn":["2813-0499"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320527","host_organization_name":"Frontiers Media","host_organization_lineage":["https://openalex.org/P4310320527"],"host_organization_lineage_names":["Frontiers Media"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in Soft Matter","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://www.frontiersin.org/journals/soft-matter/articles/10.3389/frsfm.2026.1964016/pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5133013940","display_name":"Mythili Settu","orcid":"https://orcid.org/0009-0000-7736-9728","observed_orcids":["https://orcid.org/0009-0000-7736-9728"]},"institutions":[{"id":"https://openalex.org/I4210109528","display_name":"PSG INSTITUTE OF TECHNOLOGY AND APPLIED RESEARCH","ror":"https://ror.org/01sa9ng67","country_code":"IN","type":"education","lineage":["https://openalex.org/I4210109528"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Mythili Settu","raw_affiliation_strings":["Sustainable Materials Research Lab, Department of Chemistry, PSG Institute of Technology and Applied Research"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sustainable Materials Research Lab, Department of Chemistry, PSG Institute of Technology and Applied Research","institution_ids":["https://openalex.org/I4210109528"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5013790860","display_name":"Balaji Krishnasamy","orcid":"https://orcid.org/0000-0003-0004-3863","observed_orcids":["https://orcid.org/0000-0003-0004-3863"]},"institutions":[{"id":"https://openalex.org/I4210109528","display_name":"PSG INSTITUTE OF TECHNOLOGY AND APPLIED RESEARCH","ror":"https://ror.org/01sa9ng67","country_code":"IN","type":"education","lineage":["https://openalex.org/I4210109528"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Balaji Krishnasamy","raw_affiliation_strings":["Sustainable Materials Research Lab, Department of Chemistry, PSG Institute of Technology and Applied Research"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sustainable Materials Research Lab, Department of Chemistry, PSG Institute of Technology and Applied Research","institution_ids":["https://openalex.org/I4210109528"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5070939066","display_name":"Kailasam Saravana Mani","orcid":"https://orcid.org/0000-0001-5795-3652","observed_orcids":["https://orcid.org/0000-0001-5795-3652"]},"institutions":[{"id":"https://openalex.org/I65220239","display_name":"Karpagam Academy of Higher Education","ror":"https://ror.org/00ssvzv66","country_code":"IN","type":"education","lineage":["https://openalex.org/I65220239"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Kailasam Saravana Mani","raw_affiliation_strings":["Centre for Material Chemistry, Department of Chemistry, Karpagam Academy of Higher Education"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Material Chemistry, Department of Chemistry, Karpagam Academy of Higher Education","institution_ids":["https://openalex.org/I65220239"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5013790860"],"corresponding_institution_ids":["https://openalex.org/I4210109528"],"apc_list":{"value":1950,"currency":"CHF","value_usd":2353},"apc_paid":{"value":1950,"currency":"CHF","value_usd":2353},"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"6","issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11145","display_name":"Epoxy Resin Curing Processes","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11145","display_name":"Epoxy Resin Curing Processes","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.000699999975040555,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12084","display_name":"Synthesis and properties of polymers","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C60100273","wikidata":"https://www.wikidata.org/wiki/Q902806","display_name":"Thermogravimetric analysis","level":2,"score":0.891700029373169},{"id":"https://openalex.org/C132976073","wikidata":"https://www.wikidata.org/wiki/Q2991861","display_name":"Curing (chemistry)","level":2,"score":0.8090000152587891},{"id":"https://openalex.org/C2780443040","wikidata":"https://www.wikidata.org/wiki/Q3737863","display_name":"Bifunctional","level":3,"score":0.7096999883651733},{"id":"https://openalex.org/C39519442","wikidata":"https://www.wikidata.org/wiki/Q904893","display_name":"Differential scanning calorimetry","level":2,"score":0.6625000238418579},{"id":"https://openalex.org/C95121573","wikidata":"https://www.wikidata.org/wiki/Q190474","display_name":"Activation energy","level":2,"score":0.5685999989509583},{"id":"https://openalex.org/C20625102","wikidata":"https://www.wikidata.org/wiki/Q137056","display_name":"Corrosion","level":2,"score":0.5490000247955322},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.4876999855041504},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4713999927043915},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.43059998750686646},{"id":"https://openalex.org/C2779970684","wikidata":"https://www.wikidata.org/wiki/Q11567121","display_name":"Char","level":3,"score":0.4262000024318695},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.42089998722076416},{"id":"https://openalex.org/C129446986","wikidata":"https://www.wikidata.org/wiki/Q542419","display_name":"Thermal analysis","level":3,"score":0.4115999937057495},{"id":"https://openalex.org/C4937899","wikidata":"https://www.wikidata.org/wiki/Q68541106","display_name":"Antimicrobial","level":2,"score":0.3831000030040741},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3801000118255615},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.37959998846054077},{"id":"https://openalex.org/C135502975","wikidata":"https://www.wikidata.org/wiki/Q904041","display_name":"Order of reaction","level":4,"score":0.37209999561309814},{"id":"https://openalex.org/C2780104969","wikidata":"https://www.wikidata.org/wiki/Q4774530","display_name":"Antibacterial activity","level":3,"score":0.2800000011920929},{"id":"https://openalex.org/C2780640045","wikidata":"https://www.wikidata.org/wiki/Q183055","display_name":"Mannich reaction","level":3,"score":0.25440001487731934}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.3389/frsfm.2026.1964016","doi":"https://doi.org/10.3389/frsfm.2026.1964016","is_oa":true,"landing_page_url":"https://doi.org/10.3389/frsfm.2026.1964016","pdf_url":"https://www.frontiersin.org/journals/soft-matter/articles/10.3389/frsfm.2026.1964016/pdf","source":{"id":"https://openalex.org/S4386622059","display_name":"Frontiers in Soft Matter","issn_l":"2813-0499","issn":["2813-0499"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320527","host_organization_name":"Frontiers Media","host_organization_lineage":["https://openalex.org/P4310320527"],"host_organization_lineage_names":["Frontiers Media"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in Soft Matter","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.3389/frsfm.2026.1964016","doi":"https://doi.org/10.3389/frsfm.2026.1964016","is_oa":true,"landing_page_url":"https://doi.org/10.3389/frsfm.2026.1964016","pdf_url":"https://www.frontiersin.org/journals/soft-matter/articles/10.3389/frsfm.2026.1964016/pdf","source":{"id":"https://openalex.org/S4386622059","display_name":"Frontiers in Soft Matter","issn_l":"2813-0499","issn":["2813-0499"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj"],"host_organization":"https://openalex.org/P4310320527","host_organization_name":"Frontiers Media","host_organization_lineage":["https://openalex.org/P4310320527"],"host_organization_lineage_names":["Frontiers Media"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Frontiers in Soft Matter","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7225826477.pdf","grobid_xml":"https://content.openalex.org/works/W7225826477.grobid-xml"},"referenced_works_count":41,"referenced_works":["https://openalex.org/W48364762","https://openalex.org/W1975281499","https://openalex.org/W2039523741","https://openalex.org/W2898303536","https://openalex.org/W2946397740","https://openalex.org/W3039395053","https://openalex.org/W3094627895","https://openalex.org/W3116814633","https://openalex.org/W3129879005","https://openalex.org/W4210327540","https://openalex.org/W4210857056","https://openalex.org/W4214896474","https://openalex.org/W4293225080","https://openalex.org/W4306290771","https://openalex.org/W4313319495","https://openalex.org/W4320889486","https://openalex.org/W4320889696","https://openalex.org/W4322769440","https://openalex.org/W4323543469","https://openalex.org/W4328122263","https://openalex.org/W4362601625","https://openalex.org/W4385279847","https://openalex.org/W4386480946","https://openalex.org/W4387379533","https://openalex.org/W4387716411","https://openalex.org/W4387903069","https://openalex.org/W4389226070","https://openalex.org/W4389279407","https://openalex.org/W4389586704","https://openalex.org/W4392369187","https://openalex.org/W4393053597","https://openalex.org/W4399051194","https://openalex.org/W4399142640","https://openalex.org/W4403594840","https://openalex.org/W4404148940","https://openalex.org/W4407902471","https://openalex.org/W4410353013","https://openalex.org/W4413129826","https://openalex.org/W4414001903","https://openalex.org/W7148494961","https://openalex.org/W7153504471"],"related_works":[],"abstract_inverted_index":{"This":[0],"study":[1],"synthesized":[2],"bifunctional":[3],"benzoxazine":[4],"monomers":[5],"via":[6],"Mannich":[7],"condensation":[8],"of":[9,26,122,156,160,184,198],"4-tert-butylcatechol":[10],"(C)":[11],"with":[12,119,166],"five":[13],"structurally":[14],"varied":[15],"amines":[16],"to":[17],"tailor":[18],"curing":[19,54,61],"studies":[20],"and":[21,43,77,86,94,115,124,142],"multifunctional":[22],"performance.":[23,172],"Molecular":[24],"structures":[25],"benzoxazines":[27],"were":[28],"confirmed":[29],"through":[30],"spectral":[31],"techniques,":[32],"while":[33],"thermal":[34,171],"behavior":[35],"was":[36,201],"evaluated":[37],"using":[38],"differential":[39],"scanning":[40],"calorimetry":[41],"(DSC)":[42],"thermogravimetric":[44],"analysis":[45,132],"(TGA).":[46],"Among":[47,173],"the":[48,52,64,152,161,174,179],"benzoxazines,":[49],"C-ap":[50,76,93],"exhibited":[51,151,169],"lowest":[53],"temperature":[55],"(181":[56],"\u00b0C).":[57],"In":[58,146,163],"this":[59],"DSC":[60],"kinetic":[62],"study,":[63],"activation":[65],"energy":[66],"value":[67,183],"E":[68],"a":[69,194],"=":[70],"124.71":[71],"kJ":[72,79,88,96],"mol":[73,80,89,97],"-1":[74],"for":[75,83,92,100],"174.59":[78],"\u2212":[81,90,98],"1":[82,91,99],"C-at":[84,101],"(Kissinger)":[85],"118.54":[87],"173.86":[95],"(Ozawa)":[102],"at":[103],"different":[104],"heating":[105],"rates.":[106],"C-aa":[107,135],"possessed":[108],"good":[109],"antimicrobial":[110],"property":[111],"against":[112,138],"Escherichia":[113],"coli":[114,141],"Staphylococcus":[116],"aureus":[117,144],",":[118],"inhibition":[120,137,196],"zones":[121],"20":[123],"15":[125],"mm,":[126],"respectively.":[127],"Minimum":[128],"inhibitory":[129],"concentration":[130],"(MIC)":[131],"showed":[133,178],"that":[134],"exhibit":[136],"both":[139],"E.":[140],"S.":[143],".":[145],"TGA":[147],"analysis,":[148],"poly":[149,167,176,187],"(C-ap)":[150,177],"highest":[153,180],"char":[154],"yield":[155],"58%":[157],"than":[158],"rest":[159],"polybenzoxazines.":[162],"addition,":[164],"basalt-fiber-reinforced":[165],"(C-at)":[168],"improved":[170],"polybenzoxazines,":[175],"water":[181],"contact":[182],"148\u00b0.":[185],"All":[186],"(C-bz)":[188],"demonstrated":[189],"outstanding":[190],"corrosion":[191,195],"protection,":[192],"achieving":[193],"efficiency":[197],"99%,":[199],"which":[200],"further":[202],"rationalized":[203],"by":[204],"density":[205],"functional":[206],"theory":[207],"(DFT)":[208],"calculations.":[209]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}
