{"id":"https://openalex.org/W7225824994","doi":"https://doi.org/10.1021/acsami.6c12581","title":"Photoelectrochemical CO2 Reduction to CO by a Molecular Catalyst Attached to Pyrene-Terminated Silicon through Noncovalent Interactions","display_name":"Photoelectrochemical CO2 Reduction to CO by a Molecular Catalyst Attached to Pyrene-Terminated Silicon through Noncovalent Interactions","publication_year":2026,"publication_date":"2026-11-12","ids":{"openalex":"https://openalex.org/W7225824994","doi":"https://doi.org/10.1021/acsami.6c12581"},"language":"en","primary_location":{"id":"doi:10.1021/acsami.6c12581","doi":"https://doi.org/10.1021/acsami.6c12581","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsami.6c12581","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials & Interfaces","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111147957","display_name":"Rebecca E. Powers","orcid":"https://orcid.org/0009-0007-6189-4131","observed_orcids":["https://orcid.org/0009-0007-6189-4131"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Rebecca E. Powers","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0009-0007-6189-4131","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071231028","display_name":"Aldo Jordan","orcid":"https://orcid.org/0000-0002-4386-1295","observed_orcids":["https://orcid.org/0000-0002-4386-1295"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Aldo M. Jordan","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024041888","display_name":"Eric A. Assaf","orcid":"https://orcid.org/0000-0001-5507-7791","observed_orcids":["https://orcid.org/0000-0001-5507-7791"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Eric A. Assaf","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0001-5507-7791","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5138010051","display_name":"Genevieve Holliday","orcid":"https://orcid.org/0009-0000-3426-7502","observed_orcids":["https://orcid.org/0009-0000-3426-7502"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Genevieve A. Holliday","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071524611","display_name":"Xiaofan Jia","orcid":"https://orcid.org/0000-0003-0425-5089","observed_orcids":["https://orcid.org/0000-0003-0425-5089"]},"institutions":[{"id":"https://openalex.org/I32971472","display_name":"Yale University","ror":"https://ror.org/03v76x132","country_code":"US","type":"education","lineage":["https://openalex.org/I32971472"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xiaofan Jia","raw_affiliation_strings":["Yale University , , , ,"],"raw_orcid":"https://orcid.org/0000-0003-0425-5089","affiliations":[{"raw_affiliation_string":"Yale University , , , ,","institution_ids":["https://openalex.org/I32971472"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090014711","display_name":"Benjamin R. Travis","orcid":"https://orcid.org/0009-0008-1835-548X","observed_orcids":["https://orcid.org/0009-0008-1835-548X"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Benjamin D. Travis","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0009-0008-1835-548X","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006673161","display_name":"Stephen J. Tereniak","orcid":"https://orcid.org/0000-0003-4978-0020","observed_orcids":["https://orcid.org/0000-0003-4978-0020"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Stephen J. Tereniak","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0003-4978-0020","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059663466","display_name":"John C. Dickenson","orcid":"https://orcid.org/0000-0002-7788-6810","observed_orcids":["https://orcid.org/0000-0002-7788-6810"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"John C. Dickenson","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-7788-6810","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037039521","display_name":"Pierpaolo Vecchi","orcid":"https://orcid.org/0000-0003-4853-1540","observed_orcids":["https://orcid.org/0000-0003-4853-1540"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Pierpaolo Vecchi","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023394477","display_name":"Christian Y. Dones Lassalle","orcid":"https://orcid.org/0009-0005-0317-457X","observed_orcids":["https://orcid.org/0009-0005-0317-457X"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christian Y. Dones Lassalle","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0009-0005-0317-457X","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072247799","display_name":"James D. Sappington","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James D. Sappington","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078884026","display_name":"Carrie L. Donley","orcid":"https://orcid.org/0000-0003-0906-306X","observed_orcids":["https://orcid.org/0000-0003-0906-306X"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Carrie L. Donley","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0003-0906-306X","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034407539","display_name":"Brittany L. Huffman","orcid":"https://orcid.org/0000-0002-4620-1081","observed_orcids":["https://orcid.org/0000-0002-4620-1081"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Brittany L. Huffman","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062709693","display_name":"Nilay Hazari","orcid":"https://orcid.org/0000-0001-8337-198X","observed_orcids":["https://orcid.org/0000-0001-8337-198X"]},"institutions":[{"id":"https://openalex.org/I32971472","display_name":"Yale University","ror":"https://ror.org/03v76x132","country_code":"US","type":"education","lineage":["https://openalex.org/I32971472"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nilay Hazari","raw_affiliation_strings":["Yale University , , , ,"],"raw_orcid":"https://orcid.org/0000-0001-8337-198X","affiliations":[{"raw_affiliation_string":"Yale University , , , ,","institution_ids":["https://openalex.org/I32971472"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006832213","display_name":"Renato Nevia Sampaio","orcid":"https://orcid.org/0000-0002-7158-6470","observed_orcids":["https://orcid.org/0000-0002-7158-6470"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Renato N. Sampaio","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-7158-6470","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074259020","display_name":"Alexander J. M. Miller","orcid":"https://orcid.org/0000-0001-9390-3951","observed_orcids":["https://orcid.org/0000-0001-9390-3951"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alexander J. M. Miller","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0001-9390-3951","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5086938567","display_name":"Jillian Lee Dempsey","orcid":"https://orcid.org/0000-0002-9459-4166","observed_orcids":["https://orcid.org/0000-0002-9459-4166"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jillian L. Dempsey","raw_affiliation_strings":["University of North Carolina at Chapel Hill , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-9459-4166","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill , , , ,","institution_ids":["https://openalex.org/I114027177"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.5077999830245972,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.5077999830245972,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":0.4878000020980835,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.0012000000569969416,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7699000239372253},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6365000009536743},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6295999884605408},{"id":"https://openalex.org/C2778951431","wikidata":"https://www.wikidata.org/wiki/Q415723","display_name":"Pyrene","level":2,"score":0.6193000078201294},{"id":"https://openalex.org/C130349721","wikidata":"https://www.wikidata.org/wiki/Q5434705","display_name":"Faraday efficiency","level":4,"score":0.4733000099658966},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.4616999924182892},{"id":"https://openalex.org/C544956773","wikidata":"https://www.wikidata.org/wiki/Q670","display_name":"Silicon","level":2,"score":0.460999995470047},{"id":"https://openalex.org/C33347731","wikidata":"https://www.wikidata.org/wiki/Q285210","display_name":"Stacking","level":2,"score":0.4471000134944916},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.4429999887943268},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.41929998993873596},{"id":"https://openalex.org/C137277065","wikidata":"https://www.wikidata.org/wiki/Q2915446","display_name":"Non-covalent interactions","level":4,"score":0.3815999925136566},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.3734000027179718},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.3610999882221222},{"id":"https://openalex.org/C2781350956","wikidata":"https://www.wikidata.org/wiki/Q408228","display_name":"Terpyridine","level":3,"score":0.35339999198913574},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.34529998898506165},{"id":"https://openalex.org/C15752686","wikidata":"https://www.wikidata.org/wiki/Q901171","display_name":"Selective catalytic reduction","level":3,"score":0.3441999852657318},{"id":"https://openalex.org/C13115443","wikidata":"https://www.wikidata.org/wiki/Q1891923","display_name":"Photocathode","level":3,"score":0.34279999136924744},{"id":"https://openalex.org/C2779845233","wikidata":"https://www.wikidata.org/wiki/Q3381567","display_name":"Photocurrent","level":2,"score":0.3393999934196472},{"id":"https://openalex.org/C129396577","wikidata":"https://www.wikidata.org/wiki/Q7646006","display_name":"Surface photovoltage","level":3,"score":0.32519999146461487},{"id":"https://openalex.org/C7214806","wikidata":"https://www.wikidata.org/wiki/Q2957735","display_name":"Mulliken population analysis","level":3,"score":0.3190000057220459},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.31709998846054077},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.28130000829696655},{"id":"https://openalex.org/C2777413220","wikidata":"https://www.wikidata.org/wiki/Q3153583","display_name":"Selective reduction","level":3,"score":0.2671000063419342},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.262800008058548},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.2619999945163727},{"id":"https://openalex.org/C205507967","wikidata":"https://www.wikidata.org/wiki/Q900625","display_name":"Quantum efficiency","level":2,"score":0.25279998779296875}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acsami.6c12581","doi":"https://doi.org/10.1021/acsami.6c12581","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsami.6c12581","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials & Interfaces","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":68,"referenced_works":["https://openalex.org/W649432273","https://openalex.org/W1490876928","https://openalex.org/W1532684710","https://openalex.org/W1971113415","https://openalex.org/W1973752745","https://openalex.org/W1973902558","https://openalex.org/W1973955349","https://openalex.org/W1982685288","https://openalex.org/W2005874465","https://openalex.org/W2009184234","https://openalex.org/W2014779352","https://openalex.org/W2015186152","https://openalex.org/W2017476696","https://openalex.org/W2022844698","https://openalex.org/W2035974690","https://openalex.org/W2046182857","https://openalex.org/W2051857963","https://openalex.org/W2061680435","https://openalex.org/W2067494672","https://openalex.org/W2068196933","https://openalex.org/W2092562792","https://openalex.org/W2095579818","https://openalex.org/W2116357184","https://openalex.org/W2121564503","https://openalex.org/W2159444984","https://openalex.org/W2266610430","https://openalex.org/W2296182851","https://openalex.org/W2296190717","https://openalex.org/W2319606005","https://openalex.org/W2577366206","https://openalex.org/W2795512199","https://openalex.org/W2885377221","https://openalex.org/W2933592337","https://openalex.org/W2936769114","https://openalex.org/W2941803205","https://openalex.org/W2949190509","https://openalex.org/W2951651740","https://openalex.org/W3012026512","https://openalex.org/W3015932733","https://openalex.org/W3017181399","https://openalex.org/W3023747257","https://openalex.org/W3024117197","https://openalex.org/W3039708065","https://openalex.org/W3121654864","https://openalex.org/W3128773657","https://openalex.org/W3169642805","https://openalex.org/W4214560898","https://openalex.org/W4220747843","https://openalex.org/W4243302577","https://openalex.org/W4310289590","https://openalex.org/W4312114896","https://openalex.org/W4317851257","https://openalex.org/W4376108619","https://openalex.org/W4385856185","https://openalex.org/W4390732205","https://openalex.org/W4392855659","https://openalex.org/W4393235656","https://openalex.org/W4400577315","https://openalex.org/W4405185976","https://openalex.org/W4408225755","https://openalex.org/W4410973864","https://openalex.org/W4411542056","https://openalex.org/W4415802139","https://openalex.org/W4416876474","https://openalex.org/W7134112512","https://openalex.org/W7155035093","https://openalex.org/W7159683572","https://openalex.org/W7212770964"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"A":[1,67,130],"ruthenium-based":[2],"CO2":[3,22,70],"reduction":[4,71],"catalyst":[5,96],"immobilized":[6],"on":[7],"a":[8,64,84,103,119],"Si":[9,56,99,162],"photocathode":[10],"through":[11,147],"noncovalent":[12],"\u03c0\u2013\u03c0":[13,92],"interactions":[14],"is":[15],"active":[16],"for":[17,137,177,192],"the":[18,88,95,98,138,161,166,169,183,186],"photochemical":[19],"conversion":[20],"of":[21,34,94,106,118,142,155,168,185,195],"to":[23,82,101,116,181],"CO,":[24],"with":[25,31,60],"34%":[26],"\u00b1":[27,38,108],"20%":[28],"Faradaic":[29],"efficiency":[30],"current":[32],"densities":[33],"j":[35],"=":[36,75,78],"\u2013(0.3":[37],"0.1)":[39],"mA":[40],"cm\u20132":[41,113],"at":[42,160],"\u20131.9":[43],"V":[44],"vs":[45],"Fc+/0":[46],"in":[47,87],"an":[48,189],"acetonitrile/water":[49],"electrolyte":[50],"solution":[51],"under":[52],"1":[53],"sun":[54],"illumination.":[55],"photocathodes":[57],"were":[58],"functionalized":[59],"pyrene":[61,85,156],"(p-Si\u2013Py)":[62],"using":[63],"Grignard":[65],"methodology.":[66],"previously":[68],"reported":[69],"catalyst,":[72],"[Ru(tpy)(Mebim-py)(NCCH3)][PF6]2":[73],"(tpy":[74],"2,2\u2032:6\u2032,2\u2033-terpyridine,":[76],"Mebim-py":[77],"1-methylbenzimidazol-2-ylidene-3-(2\u2032-pyridine))":[79],"was":[80,135],"modified":[81],"include":[83],"moiety":[86],"terpyridine":[89],"backbone,":[90],"enabling":[91],"stacking":[93],"onto":[97],"surface":[100,104,153],"achieve":[102],"coverage":[105],"(1.85":[107],"0.28)":[109],"x":[110],"10\u201312":[111],"mol":[112],"(ca.":[114],"2%":[115],"5%":[117],"monolayer)":[120],"as":[121],"quantified":[122,136],"via":[123],"inductively":[124],"coupled":[125],"plasma":[126],"mass":[127],"spectroscopy":[128,150],"(ICP-MS).":[129],"420":[131],"mV":[132],"photovoltage":[133],"(Vph)":[134],"p-Si\u2013Py":[139],"photocathode.":[140],"Measurements":[141],"charge":[143],"carrier":[144],"recombination":[145],"kinetics":[146],"time-resolved":[148],"infrared":[149],"indicate":[151],"that":[152],"attachment":[154],"moieties":[157],"introduces":[158],"defects":[159,172],"interface,":[163],"even":[164],"without":[165],"presence":[167],"catalyst.":[170],"These":[171],"provide":[173],"competing":[174],"kinetic":[175],"pathways":[176],"photogenerated":[178],"carriers,":[179],"hypothesized":[180],"influence":[182],"selectivity":[184],"hybrid":[187,196],"photoelectrode,":[188],"important":[190],"implication":[191],"future":[193],"designs":[194],"photoelectrodes.":[197]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}