{"id":"https://openalex.org/W7225824586","doi":"https://doi.org/10.1021/acselectrochem.6c00426","title":"Electrochemical Dicarboxylation of Non-Activated Olefins with CO2","display_name":"Electrochemical Dicarboxylation of Non-Activated Olefins with CO2","publication_year":2026,"publication_date":"2026-11-11","ids":{"openalex":"https://openalex.org/W7225824586","doi":"https://doi.org/10.1021/acselectrochem.6c00426"},"language":"en","primary_location":{"id":"doi:10.1021/acselectrochem.6c00426","doi":"https://doi.org/10.1021/acselectrochem.6c00426","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acselectrochem.6c00426","pdf_url":null,"source":{"id":"https://openalex.org/S4404674019","display_name":"ACS electrochemistry.","issn_l":"2997-0571","issn":["2997-0571"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Electrochemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1021/acselectrochem.6c00426","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5161471952","display_name":"Mihailo Stjepanovi\u0107","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I4210110444","display_name":"Max Planck Institute for Chemical Energy Conversion","ror":"https://ror.org/01y9arx16","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210110444"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Mihailo Stjepanovi\u0107","raw_affiliation_strings":["Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u201336 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u201336 , ,","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210110444"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043646844","display_name":"Darryl F. Nater","orcid":"https://orcid.org/0000-0001-5800-3982","observed_orcids":["https://orcid.org/0000-0001-5800-3982"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I4210110444","display_name":"Max Planck Institute for Chemical Energy Conversion","ror":"https://ror.org/01y9arx16","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210110444"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Darryl F. Nater","raw_affiliation_strings":["Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u201336 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u201336 , ,","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210110444"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004134551","display_name":"Carl\u2010Friedrich Hoppe","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Carl-Friedrich Hoppe","raw_affiliation_strings":["EVONIK Operations GmbH , Rodenbacher Chaussee 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EVONIK Operations GmbH , Rodenbacher Chaussee 4 , ,","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039827585","display_name":"Sebastian Arndt","orcid":"https://orcid.org/0000-0003-0823-1543","observed_orcids":["https://orcid.org/0000-0003-0823-1543"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Sebastian Arndt","raw_affiliation_strings":["EVONIK Operations GmbH , Rodenbacher Chaussee 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EVONIK Operations GmbH , Rodenbacher Chaussee 4 , ,","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039002519","display_name":"Patrik Stenner","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Patrik Stenner","raw_affiliation_strings":["EVONIK Operations GmbH , Rodenbacher Chaussee 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"EVONIK Operations GmbH , Rodenbacher Chaussee 4 , ,","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057186122","display_name":"Siegfried R. Waldvogel","orcid":"https://orcid.org/0000-0002-7949-9638","observed_orcids":["https://orcid.org/0000-0002-7949-9638"]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]},{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I4210110444","display_name":"Max Planck Institute for Chemical Energy Conversion","ror":"https://ror.org/01y9arx16","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210110444"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Siegfried R. Waldvogel","raw_affiliation_strings":["Karlsruhe Institute of Technology (KIT) , , Kaiserstra\u00dfe 12 , ,","Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u201336 , ,"],"raw_orcid":"https://orcid.org/0000-0002-7949-9638","affiliations":[{"raw_affiliation_string":"Karlsruhe Institute of Technology (KIT) , , Kaiserstra\u00dfe 12 , ,","institution_ids":["https://openalex.org/I102335020"]},{"raw_affiliation_string":"Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u201336 , ,","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210110444"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5057186122"],"corresponding_institution_ids":["https://openalex.org/I102335020","https://openalex.org/I149899117","https://openalex.org/I4210110444"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":{"value":4500,"currency":"USD","value_usd":4500},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.8895999789237976,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.8895999789237976,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":0.10509999841451645,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.0013000000035390258,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C40869318","wikidata":"https://www.wikidata.org/wiki/Q899050","display_name":"Synthon","level":2,"score":0.7260000109672546},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.7214000225067139},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.6960999965667725},{"id":"https://openalex.org/C49110097","wikidata":"https://www.wikidata.org/wiki/Q175233","display_name":"Cathode","level":2,"score":0.5964000225067139},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.5819000005722046},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5134999752044678},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.4352000057697296},{"id":"https://openalex.org/C51886252","wikidata":"https://www.wikidata.org/wiki/Q4118667","display_name":"Olefin fiber","level":3,"score":0.39649999141693115},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3935999870300293},{"id":"https://openalex.org/C2991944050","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Reaction conditions","level":3,"score":0.36230000853538513},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.34599998593330383},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.33320000767707825},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.32199999690055847},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3107999861240387},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.28790000081062317},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.28380000591278076},{"id":"https://openalex.org/C105768512","wikidata":"https://www.wikidata.org/wiki/Q7458208","display_name":"Reaction intermediate","level":3,"score":0.2793000042438507},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.2703000009059906},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.26969999074935913},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.2680000066757202},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.25279998779296875},{"id":"https://openalex.org/C2776799497","wikidata":"https://www.wikidata.org/wiki/Q484298","display_name":"Surface (topology)","level":2,"score":0.25270000100135803},{"id":"https://openalex.org/C177801218","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Chemical reaction","level":2,"score":0.2517000138759613},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.2515000104904175}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acselectrochem.6c00426","doi":"https://doi.org/10.1021/acselectrochem.6c00426","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acselectrochem.6c00426","pdf_url":null,"source":{"id":"https://openalex.org/S4404674019","display_name":"ACS electrochemistry.","issn_l":"2997-0571","issn":["2997-0571"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Electrochemistry","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1021/acselectrochem.6c00426","doi":"https://doi.org/10.1021/acselectrochem.6c00426","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acselectrochem.6c00426","pdf_url":null,"source":{"id":"https://openalex.org/S4404674019","display_name":"ACS electrochemistry.","issn_l":"2997-0571","issn":["2997-0571"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Electrochemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":42,"referenced_works":["https://openalex.org/W1979969053","https://openalex.org/W1984268129","https://openalex.org/W1994907036","https://openalex.org/W2046891790","https://openalex.org/W2063508472","https://openalex.org/W2093344318","https://openalex.org/W2111039825","https://openalex.org/W2133470200","https://openalex.org/W2135657785","https://openalex.org/W2339206657","https://openalex.org/W2340939917","https://openalex.org/W2793967588","https://openalex.org/W2801305065","https://openalex.org/W2916442064","https://openalex.org/W2947264857","https://openalex.org/W2951491799","https://openalex.org/W2966637237","https://openalex.org/W2996066499","https://openalex.org/W3003004440","https://openalex.org/W3027965069","https://openalex.org/W3042899046","https://openalex.org/W3085022108","https://openalex.org/W3096318052","https://openalex.org/W3120196531","https://openalex.org/W3194519141","https://openalex.org/W3196457189","https://openalex.org/W4281788379","https://openalex.org/W4303629836","https://openalex.org/W4311738269","https://openalex.org/W4362506806","https://openalex.org/W4366237772","https://openalex.org/W4384468457","https://openalex.org/W4390616491","https://openalex.org/W4400612469","https://openalex.org/W4402284470","https://openalex.org/W4406307963","https://openalex.org/W4406863583","https://openalex.org/W4409227097","https://openalex.org/W4411661118","https://openalex.org/W7117164883","https://openalex.org/W7154841694","https://openalex.org/W7203926146"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"Dicarboxylation":[1],"reactions":[2],"of":[3,64,78],"olefins":[4,55],"using":[5,22],"CO2":[6,89],"as":[7],"a":[8,16,28,40,62],"synthon":[9],"are":[10],"highly":[11],"desirable":[12],"transformations.":[13],"We":[14],"present":[15],"novel":[17],"approach":[18],"to":[19,58,80],"this":[20],"pathway":[21],"non-activated":[23,54],"olefins.":[24],"This":[25],"method":[26],"features":[27],"simple,":[29],"undivided":[30],"galvanostatic":[31],"setup":[32],"and":[33,94],"relies":[34],"on":[35],"carbonaceous":[36],"cathode":[37],"materials":[38],"with":[39,76,96],"high":[41,73],"surface":[42,87],"area.":[43],"Under":[44],"these":[45],"conditions,":[46],"valuable":[47],"diacids":[48],"can":[49,69],"be":[50,70],"generated":[51],"from":[52],"simple":[53],"in":[56],"up":[57,79],"50%":[59],"yield":[60],"for":[61],"variety":[63],"substrates.":[65],"Furthermore,":[66],"the":[67],"reaction":[68,84],"performed":[71],"at":[72],"substrate":[74],"concentrations":[75],"productivities":[77],"0.69":[81],"mmol/h.":[82],"A":[83],"mechanism":[85],"involving":[86],"bound":[88],"radical":[90],"anions":[91],"is":[92],"proposed":[93],"aligns":[95],"experimental":[97],"observations.":[98]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}