{"id":"https://openalex.org/W7225816608","doi":"https://doi.org/10.1038/s43246-026-01425-1","title":"\u201cRivet\u201d cations enhance mechanical stability of Ni-rich layered cathode materials for Li-ion batteries","display_name":"\u201cRivet\u201d cations enhance mechanical stability of Ni-rich layered cathode materials for Li-ion batteries","publication_year":2026,"publication_date":"2026-11-11","ids":{"openalex":"https://openalex.org/W7225816608","doi":"https://doi.org/10.1038/s43246-026-01425-1"},"language":"en","primary_location":{"id":"doi:10.1038/s43246-026-01425-1","doi":"https://doi.org/10.1038/s43246-026-01425-1","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s43246-026-01425-1","pdf_url":null,"source":{"id":"https://openalex.org/S4210233566","display_name":"Communications Materials","issn_l":"2662-4443","issn":["2662-4443"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-1","norway-1","oarl","poland-20","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Communications Materials","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.1038/s43246-026-01425-1","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011856557","display_name":"Yu. A. Klychevskikh","orcid":"https://orcid.org/0009-0004-0104-5056","observed_orcids":["https://orcid.org/0009-0004-0104-5056"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"Yuliya A. Klychevskikh","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":"https://orcid.org/0009-0004-0104-5056","affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036385681","display_name":"Ivan A. Moiseev","orcid":"https://orcid.org/0000-0002-5988-3640","observed_orcids":["https://orcid.org/0000-0002-5988-3640"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Ivan A. Moiseev","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":"https://orcid.org/0000-0002-5988-3640","affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021482417","display_name":"Eugene S. Statnik","orcid":"https://orcid.org/0000-0002-1105-9206","observed_orcids":["https://orcid.org/0000-0002-1105-9206"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Eugene S. Statnik","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019907417","display_name":"Arseniy S. Burov","orcid":"https://orcid.org/0009-0002-5677-987X","observed_orcids":["https://orcid.org/0009-0002-5677-987X"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Arseniy S. Burov","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":"https://orcid.org/0009-0002-5677-987X","affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073152897","display_name":"Dmitry A. Aksyonov","orcid":"https://orcid.org/0000-0002-3692-4809","observed_orcids":["https://orcid.org/0000-0002-3692-4809"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Dmitry A. Aksyonov","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":"https://orcid.org/0000-0002-3692-4809","affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051093327","display_name":"Alexander M. Korsunsky","orcid":"https://orcid.org/0000-0002-3558-5198","observed_orcids":["https://orcid.org/0000-0002-3558-5198"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Alexander M. Korsunsky","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5040689411","display_name":"Artem M. Abakumov","orcid":"https://orcid.org/0000-0002-7135-4629","observed_orcids":["https://orcid.org/0000-0002-7135-4629"]},"institutions":[{"id":"https://openalex.org/I125989756","display_name":"Skolkovo Institute of Science and Technology","ror":"https://ror.org/03f9nc143","country_code":"RU","type":"education","lineage":["https://openalex.org/I125989756"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Artem M. Abakumov","raw_affiliation_strings":["Skolkovo Institute of Science and Technology, Moscow, Russia"],"raw_orcid":"https://orcid.org/0000-0002-7135-4629","affiliations":[{"raw_affiliation_string":"Skolkovo Institute of Science and Technology, Moscow, Russia","institution_ids":["https://openalex.org/I125989756"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5011856557"],"corresponding_institution_ids":["https://openalex.org/I125989756"],"apc_list":{"value":3690,"currency":"USD","value_usd":3690},"apc_paid":{"value":3690,"currency":"USD","value_usd":3690},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10663","display_name":"Battery Modeling and Management","score":0.0015999999595806003,"subfield":{"id":"https://openalex.org/subfields/2203","display_name":"Automotive Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.000699999975040555,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.8245999813079834},{"id":"https://openalex.org/C49326732","wikidata":"https://www.wikidata.org/wiki/Q1549892","display_name":"Nanoindentation","level":2,"score":0.7422000169754028},{"id":"https://openalex.org/C49110097","wikidata":"https://www.wikidata.org/wiki/Q175233","display_name":"Cathode","level":2,"score":0.6075000166893005},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.5715000033378601},{"id":"https://openalex.org/C99595764","wikidata":"https://www.wikidata.org/wiki/Q486802","display_name":"Toughness","level":2,"score":0.5672000050544739},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.5552999973297119},{"id":"https://openalex.org/C97549433","wikidata":"https://www.wikidata.org/wiki/Q911969","display_name":"Fracture toughness","level":2,"score":0.49799999594688416},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.44209998846054077},{"id":"https://openalex.org/C26771246","wikidata":"https://www.wikidata.org/wiki/Q321095","display_name":"Scanning electron microscope","level":2,"score":0.43950000405311584},{"id":"https://openalex.org/C155673373","wikidata":"https://www.wikidata.org/wiki/Q1648886","display_name":"Structural stability","level":2,"score":0.42669999599456787},{"id":"https://openalex.org/C195268267","wikidata":"https://www.wikidata.org/wiki/Q1928883","display_name":"Slip (aerodynamics)","level":2,"score":0.38679999113082886},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.3763999938964844},{"id":"https://openalex.org/C96035792","wikidata":"https://www.wikidata.org/wiki/Q43606218","display_name":"Shear (geology)","level":2,"score":0.3262999951839447},{"id":"https://openalex.org/C159122135","wikidata":"https://www.wikidata.org/wiki/Q737571","display_name":"Dislocation","level":2,"score":0.32600000500679016},{"id":"https://openalex.org/C133267278","wikidata":"https://www.wikidata.org/wiki/Q4120515","display_name":"Nanomechanics","level":3,"score":0.30550000071525574},{"id":"https://openalex.org/C30407753","wikidata":"https://www.wikidata.org/wiki/Q186191","display_name":"Compressive strength","level":2,"score":0.2987000048160553},{"id":"https://openalex.org/C2779679103","wikidata":"https://www.wikidata.org/wiki/Q5251805","display_name":"Degradation (telecommunications)","level":2,"score":0.295199990272522},{"id":"https://openalex.org/C87976508","wikidata":"https://www.wikidata.org/wiki/Q1498213","display_name":"Microstructure","level":2,"score":0.2858999967575073},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.2806999981403351},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.27390000224113464},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.27300000190734863},{"id":"https://openalex.org/C127893833","wikidata":"https://www.wikidata.org/wiki/Q7492185","display_name":"Shear strength (soil)","level":3,"score":0.26669999957084656},{"id":"https://openalex.org/C138999460","wikidata":"https://www.wikidata.org/wiki/Q787619","display_name":"Solid solution","level":2,"score":0.2513999938964844}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1038/s43246-026-01425-1","doi":"https://doi.org/10.1038/s43246-026-01425-1","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s43246-026-01425-1","pdf_url":null,"source":{"id":"https://openalex.org/S4210233566","display_name":"Communications Materials","issn_l":"2662-4443","issn":["2662-4443"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-1","norway-1","oarl","poland-20","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Communications Materials","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1038/s43246-026-01425-1","doi":"https://doi.org/10.1038/s43246-026-01425-1","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s43246-026-01425-1","pdf_url":null,"source":{"id":"https://openalex.org/S4210233566","display_name":"Communications Materials","issn_l":"2662-4443","issn":["2662-4443"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-1","norway-1","oarl","poland-20","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Communications Materials","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":[],"abstract_inverted_index":{"The":[0],"Mg2+":[1,53],"and":[2,40,54,77,99,132,157,176,184,194],"Ni2+":[3,55],"ions":[4,56,159],"at":[5,101,160,186],"the":[6,37,46,49,52,58,62,89,95,102,105,114,120,141,149,179,191],"Li":[7,144,161,187],"site":[8],"(A-site)":[9],"in":[10,72,80,91,104,110,154],"Ni-rich":[11,164],"NMC":[12,165],"layered":[13,106],"cathode":[14],"materials":[15,66],"improve":[16],"their":[17,31],"cycling":[18],"stability":[19,166],"by":[20,167],"reducing":[21],"intragranular":[22],"cracking.":[23,177],"These":[24],"cations":[25,97],"act":[26],"as":[27,169],"\u201crivets\u201d":[28],"due":[29],"to":[30,33,148],"ability":[32],"suppress":[34,173],"gliding":[35,175],"of":[36,51,61,94,113,119,151,196],"close-packed":[38],"layers":[39],"associated":[41],"mechanically-destructive":[42],"phase":[43],"transitions.":[44],"In":[45],"present":[47],"study":[48],"impact":[50],"on":[57],"mechanical":[59,152,192],"properties":[60,153],"single-crystal":[63,197],"Mg-doped":[64],"NMC811":[65],"has":[67],"been":[68],"investigated":[69],"quantitatively":[70],"with":[71],"situ":[73],"micropillar":[74],"compression,":[75],"nanoindentation":[76],"pillar":[78],"splitting":[79],"a":[81],"scanning":[82],"electron":[83],"microscope.":[84],"Here":[85],"we":[86],"show":[87,181],"that":[88,140,172,182],"increase":[90,112],"cumulative":[92],"occupancy":[93],"\u201crivet\u201d":[96],"NiA":[98],"MgA":[100],"A-site":[103],"R$$\\bar{3}$$m":[107],"structure":[108],"results":[109],"an":[111],"critical":[115],"resolved":[116],"shear":[117],"stress":[118],"basal":[121],"{0001}":[122],"<":[123],"11$$\\bar{2}$$0>":[124],"slip":[125],"system":[126],"activation,":[127],"hardness,":[128],"fracture":[129],"toughness":[130,195],"K1c":[131],"Young\u2019s":[133],"modulus.":[134],"Density":[135],"functional":[136],"theory":[137],"calculations":[138],"demonstrate":[139],"Ni/Mg":[142],"for":[143],"substitution":[145],"contributes":[146],"synergistically":[147,189],"enhancement":[150],"NMC811.":[155,198],"Mg\u00b2\u207a":[156,183],"Ni\u00b2\u207a":[158,185],"sites":[162,188],"enhance":[163,190],"acting":[168],"structural":[170],"rivets":[171],"layer":[174],"Here,":[178],"authors":[180],"strength":[193]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}