{"id":"https://openalex.org/W7225809378","doi":"https://doi.org/10.1063/5.0315134","title":"Understanding electrolyte chemistry under extreme battery operating conditions","display_name":"Understanding electrolyte chemistry under extreme battery operating conditions","publication_year":2026,"publication_date":"2026-11-11","ids":{"openalex":"https://openalex.org/W7225809378","doi":"https://doi.org/10.1063/5.0315134"},"language":"en","primary_location":{"id":"doi:10.1063/5.0315134","doi":"https://doi.org/10.1063/5.0315134","is_oa":false,"landing_page_url":"https://doi.org/10.1063/5.0315134","pdf_url":null,"source":{"id":"https://openalex.org/S4210229136","display_name":"Applied Physics Reviews","issn_l":"1931-9401","issn":["1931-9401"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","norway-1","poland-200","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied Physics Reviews","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5161418977","display_name":"Younsang Cho","orcid":"https://orcid.org/0009-0007-3248-2744","observed_orcids":["https://orcid.org/0009-0007-3248-2744"]},"institutions":[{"id":"https://openalex.org/I148751991","display_name":"Sogang University","ror":"https://ror.org/056tn4839","country_code":"KR","type":"education","lineage":["https://openalex.org/I148751991"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Younsang Cho","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering, Sogang University , 35 Baekbeom-ro, Mapo-gu, Seoul 04107,"],"raw_orcid":"https://orcid.org/0009-0007-3248-2744","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, Sogang University , 35 Baekbeom-ro, Mapo-gu, Seoul 04107,","institution_ids":["https://openalex.org/I148751991"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020713992","display_name":"\ud55c\uc7ac\ud76c","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I148751991","display_name":"Sogang University","ror":"https://ror.org/056tn4839","country_code":"KR","type":"education","lineage":["https://openalex.org/I148751991"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jaehee Han","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering, Sogang University , 35 Baekbeom-ro, Mapo-gu, Seoul 04107,"],"raw_orcid":"https://orcid.org/0009-0000-0407-4216","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, Sogang University , 35 Baekbeom-ro, Mapo-gu, Seoul 04107,","institution_ids":["https://openalex.org/I148751991"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5005394364","display_name":"Jaegeon Ryu","orcid":"https://orcid.org/0000-0002-5290-6192","observed_orcids":["https://orcid.org/0000-0002-5290-6192"]},"institutions":[{"id":"https://openalex.org/I148751991","display_name":"Sogang University","ror":"https://ror.org/056tn4839","country_code":"KR","type":"education","lineage":["https://openalex.org/I148751991"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jaegeon Ryu","raw_affiliation_strings":["Department of Chemical and Biomolecular Engineering, Sogang University , 35 Baekbeom-ro, Mapo-gu, Seoul 04107,"],"raw_orcid":"https://orcid.org/0000-0002-5290-6192","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, Sogang University , 35 Baekbeom-ro, Mapo-gu, Seoul 04107,","institution_ids":["https://openalex.org/I148751991"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I148751991"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"13","issue":"4","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.5590999722480774,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.5590999722480774,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.4088999927043915,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10663","display_name":"Battery Modeling and Management","score":0.02459999918937683,"subfield":{"id":"https://openalex.org/subfields/2203","display_name":"Automotive Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.8809999823570251},{"id":"https://openalex.org/C148093993","wikidata":"https://www.wikidata.org/wiki/Q739398","display_name":"Solvation","level":3,"score":0.7218999862670898},{"id":"https://openalex.org/C49110097","wikidata":"https://www.wikidata.org/wiki/Q175233","display_name":"Cathode","level":2,"score":0.5777999758720398},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5752000212669373},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5633000135421753},{"id":"https://openalex.org/C205049153","wikidata":"https://www.wikidata.org/wiki/Q2698605","display_name":"Polarization (electrochemistry)","level":2,"score":0.5160999894142151},{"id":"https://openalex.org/C555008776","wikidata":"https://www.wikidata.org/wiki/Q267298","display_name":"Battery (electricity)","level":3,"score":0.4909999966621399},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.4392000138759613},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.430400013923645},{"id":"https://openalex.org/C74859849","wikidata":"https://www.wikidata.org/wiki/Q2466686","display_name":"Non-equilibrium thermodynamics","level":2,"score":0.423799991607666},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3652999997138977},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.36250001192092896},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.34459999203681946},{"id":"https://openalex.org/C68709404","wikidata":"https://www.wikidata.org/wiki/Q1134475","display_name":"Flux (metallurgy)","level":2,"score":0.34290000796318054},{"id":"https://openalex.org/C89395315","wikidata":"https://www.wikidata.org/wiki/Q181232","display_name":"Anode","level":3,"score":0.3418000042438507},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.32749998569488525},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.3059000074863434},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.29679998755455017},{"id":"https://openalex.org/C38115104","wikidata":"https://www.wikidata.org/wiki/Q582852","display_name":"Concentration polarization","level":3,"score":0.29649999737739563},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.28459998965263367},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.2711000144481659},{"id":"https://openalex.org/C7040849","wikidata":"https://www.wikidata.org/wiki/Q899580","display_name":"Dielectric spectroscopy","level":4,"score":0.2696000039577484},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2694999873638153},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2637999951839447}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/5.0315134","doi":"https://doi.org/10.1063/5.0315134","is_oa":false,"landing_page_url":"https://doi.org/10.1063/5.0315134","pdf_url":null,"source":{"id":"https://openalex.org/S4210229136","display_name":"Applied Physics Reviews","issn_l":"1931-9401","issn":["1931-9401"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","norway-1","poland-200","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied Physics Reviews","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":221,"referenced_works":["https://openalex.org/W2021172010","https://openalex.org/W2037697403","https://openalex.org/W2038807397","https://openalex.org/W2047775546","https://openalex.org/W2092944857","https://openalex.org/W2145196846","https://openalex.org/W2155489103","https://openalex.org/W2280898683","https://openalex.org/W2323634399","https://openalex.org/W2329122517","https://openalex.org/W2342831563","https://openalex.org/W2469089667","https://openalex.org/W2482923500","https://openalex.org/W2514054135","https://openalex.org/W2516657016","https://openalex.org/W2561429929","https://openalex.org/W2568888877","https://openalex.org/W2608000686","https://openalex.org/W2611622996","https://openalex.org/W2622203992","https://openalex.org/W2740598477","https://openalex.org/W2754816434","https://openalex.org/W2774731903","https://openalex.org/W2790076382","https://openalex.org/W2792697810","https://openalex.org/W2795886417","https://openalex.org/W2808438592","https://openalex.org/W2898726979","https://openalex.org/W2898845120","https://openalex.org/W2899927586","https://openalex.org/W2922443589","https://openalex.org/W2942798502","https://openalex.org/W2943266146","https://openalex.org/W2948650589","https://openalex.org/W2963743648","https://openalex.org/W2963775826","https://openalex.org/W2981885472","https://openalex.org/W2990919469","https://openalex.org/W3005112572","https://openalex.org/W3005157773","https://openalex.org/W3007729177","https://openalex.org/W3017294427","https://openalex.org/W3021821197","https://openalex.org/W3028225905","https://openalex.org/W3037006938","https://openalex.org/W3041376378","https://openalex.org/W3042633680","https://openalex.org/W3067387014","https://openalex.org/W3082040878","https://openalex.org/W3087435797","https://openalex.org/W3089077108","https://openalex.org/W3090557484","https://openalex.org/W3097207591","https://openalex.org/W3114534037","https://openalex.org/W3120110447","https://openalex.org/W3131227006","https://openalex.org/W3137527723","https://openalex.org/W3139008635","https://openalex.org/W3139505294","https://openalex.org/W3164681617","https://openalex.org/W3165320499","https://openalex.org/W3188626832","https://openalex.org/W3193044426","https://openalex.org/W3198279697","https://openalex.org/W3199117575","https://openalex.org/W3200327973","https://openalex.org/W3201369469","https://openalex.org/W3209770929","https://openalex.org/W3213328656","https://openalex.org/W4205320316","https://openalex.org/W4206522497","https://openalex.org/W4220842132","https://openalex.org/W4220954729","https://openalex.org/W4225918206","https://openalex.org/W4229079925","https://openalex.org/W4229460005","https://openalex.org/W4280553674","https://openalex.org/W4280581407","https://openalex.org/W4280610848","https://openalex.org/W4281630554","https://openalex.org/W4285283202","https://openalex.org/W4289766485","https://openalex.org/W4294771560","https://openalex.org/W4296670752","https://openalex.org/W4296698879","https://openalex.org/W4297324421","https://openalex.org/W4297325250","https://openalex.org/W4304588729","https://openalex.org/W4304698197","https://openalex.org/W4308248304","https://openalex.org/W4309161020","https://openalex.org/W4312193125","https://openalex.org/W4312193361","https://openalex.org/W4312195595","https://openalex.org/W4315487532","https://openalex.org/W4316468850","https://openalex.org/W4317234390","https://openalex.org/W4318049711","https://openalex.org/W4319986673","https://openalex.org/W4321100528","https://openalex.org/W4321178954","https://openalex.org/W4321200081","https://openalex.org/W4322009338","https://openalex.org/W4322101865","https://openalex.org/W4323812943","https://openalex.org/W4362663164","https://openalex.org/W4362736353","https://openalex.org/W4379260031","https://openalex.org/W4381612551","https://openalex.org/W4382344574","https://openalex.org/W4385348084","https://openalex.org/W4385406470","https://openalex.org/W4385708223","https://openalex.org/W4385955193","https://openalex.org/W4386126826","https://openalex.org/W4386316270","https://openalex.org/W4386705288","https://openalex.org/W4386945441","https://openalex.org/W4388418935","https://openalex.org/W4388425011","https://openalex.org/W4389386931","https://openalex.org/W4389431170","https://openalex.org/W4389726555","https://openalex.org/W4390533377","https://openalex.org/W4390563542","https://openalex.org/W4390606426","https://openalex.org/W4390769270","https://openalex.org/W4390886053","https://openalex.org/W4391386485","https://openalex.org/W4391931856","https://openalex.org/W4392242379","https://openalex.org/W4392499461","https://openalex.org/W4392565826","https://openalex.org/W4392657570","https://openalex.org/W4393256834","https://openalex.org/W4394689158","https://openalex.org/W4396674547","https://openalex.org/W4398250156","https://openalex.org/W4399081637","https://openalex.org/W4399458996","https://openalex.org/W4399495419","https://openalex.org/W4399498376","https://openalex.org/W4399504434","https://openalex.org/W4399678201","https://openalex.org/W4400200855","https://openalex.org/W4400530297","https://openalex.org/W4400657610","https://openalex.org/W4401049177","https://openalex.org/W4401632306","https://openalex.org/W4401653124","https://openalex.org/W4402162659","https://openalex.org/W4402634308","https://openalex.org/W4402695700","https://openalex.org/W4402948374","https://openalex.org/W4403132059","https://openalex.org/W4403216478","https://openalex.org/W4404699297","https://openalex.org/W4404824287","https://openalex.org/W4404866679","https://openalex.org/W4405242394","https://openalex.org/W4405317599","https://openalex.org/W4406093320","https://openalex.org/W4406739016","https://openalex.org/W4407086686","https://openalex.org/W4407199403","https://openalex.org/W4407868820","https://openalex.org/W4408123964","https://openalex.org/W4408313012","https://openalex.org/W4408344447","https://openalex.org/W4408362168","https://openalex.org/W4408945342","https://openalex.org/W4408954801","https://openalex.org/W4408956414","https://openalex.org/W4409021394","https://openalex.org/W4409733461","https://openalex.org/W4410059779","https://openalex.org/W4410550339","https://openalex.org/W4410587957","https://openalex.org/W4410627670","https://openalex.org/W4410892270","https://openalex.org/W4410921093","https://openalex.org/W4411210778","https://openalex.org/W4411459978","https://openalex.org/W4412193406","https://openalex.org/W4412372695","https://openalex.org/W4412761228","https://openalex.org/W4412913293","https://openalex.org/W4412996670","https://openalex.org/W4413614409","https://openalex.org/W4413769434","https://openalex.org/W4413857609","https://openalex.org/W4413941235","https://openalex.org/W4414030264","https://openalex.org/W4414791554","https://openalex.org/W4414845441","https://openalex.org/W4415197103","https://openalex.org/W4416392047","https://openalex.org/W4416744368","https://openalex.org/W7077051714","https://openalex.org/W7118277096","https://openalex.org/W7118572127","https://openalex.org/W7119140727","https://openalex.org/W7122396339","https://openalex.org/W7125485802","https://openalex.org/W7125530401","https://openalex.org/W7125773650","https://openalex.org/W7128158624","https://openalex.org/W7128490906","https://openalex.org/W7131125560","https://openalex.org/W7131425888","https://openalex.org/W7135369809","https://openalex.org/W7135420541","https://openalex.org/W7139067899","https://openalex.org/W7153447948","https://openalex.org/W7154706464","https://openalex.org/W7154952469","https://openalex.org/W7155093389","https://openalex.org/W7159944691","https://openalex.org/W7163548351","https://openalex.org/W7167673250","https://openalex.org/W7167916577"],"related_works":[],"abstract_inverted_index":{"Simultaneous":[0],"high-voltage":[1,184],"(\u22654.5":[2],"V":[3],"vs":[4],"Li+/Li)":[5],"and":[6,25,50,74,97,104,116,139,150,169,182],"fast-charging":[7,185],"(\u22654C,":[8],"sub-15":[9],"min)":[10],"operation":[11],"drives":[12],"liquid":[13],"electrolytes":[14],"into":[15],"a":[16,60],"nonequilibrium":[17],"state":[18],"in":[19],"which":[20],"cathode":[21],"reactivity,":[22],"Li+":[23,48,86],"redistribution,":[24],"interfacial":[26,95],"polarization":[27],"evolve":[28],"on":[29],"comparable":[30],"timescales.":[31],"The":[32],"local":[33,175],"electrolyte":[34,80,176],"environment":[35],"established":[36],"during":[37],"charging":[38],"consequently":[39],"differs":[40],"substantially":[41],"from":[42],"its":[43],"bulk-averaged":[44],"state,":[45],"altering":[46],"both":[47],"transfer":[49],"oxidative":[51],"decomposition":[52,98],"near":[53],"the":[54,68,94,117,131],"electrode":[55],"surfaces.":[56],"This":[57],"review":[58],"presents":[59],"mechanistic":[61],"perspective":[62],"that":[63,144,172],"connects":[64],"these":[65],"processes":[66],"through":[67,88],"dynamic":[69,159],"evolution":[70,133],"of":[71,99,119,134],"solvation":[72,146],"structures":[73],"electrode\u2013electrolyte":[75],"interphases.":[76],"Within":[77],"this":[78,158],"framework,":[79],"design":[81,163],"is":[82],"directed":[83],"toward":[84],"sustaining":[85],"flux":[87],"exchangeable":[89],"coordination":[90],"environments":[91,147],"while":[92],"controlling":[93],"availability":[96],"reactive":[100],"species.":[101],"Molecular":[102],"structure":[103],"composition":[105],"influence":[106],"performance":[107],"by":[108],"changing":[109],"solvent":[110],"activity,":[111],"ion":[112],"association,":[113],"coordination-shell":[114],"reorganization,":[115],"selectivity":[118],"interphase-forming":[120],"reactions.":[121],"These":[122],"molecular":[123,149],"mechanisms":[124],"must":[125],"persist":[126],"throughout":[127],"charge":[128],"cycles,":[129],"accommodating":[130],"concurrent":[132],"concentration":[135],"gradients,":[136],"surface":[137],"reconstruction,":[138],"impedance":[140],"growth.":[141],"Emerging":[142],"approaches":[143],"organize":[145],"across":[148],"spatial":[151],"scales":[152],"offer":[153],"new":[154],"opportunities":[155],"to":[156],"regulate":[157],"response.":[160],"Establishing":[161],"transferable":[162],"principles":[164],"will":[165],"require":[166],"operando":[167],"characterization":[168],"practical-cell":[170],"evaluation":[171],"directly":[173],"connect":[174],"chemistry":[177],"with":[178],"charge-transfer":[179],"kinetics,":[180],"degradation,":[181],"long-term":[183],"performance.":[186]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}