{"id":"https://openalex.org/W7225800414","doi":"https://doi.org/10.1021/acscatal.6c05543","title":"Halogen Fluorine Unlocks Ru Activity for Olefins Production from Syngas","display_name":"Halogen Fluorine Unlocks Ru Activity for Olefins Production from Syngas","publication_year":2026,"publication_date":"2026-11-11","ids":{"openalex":"https://openalex.org/W7225800414","doi":"https://doi.org/10.1021/acscatal.6c05543"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.6c05543","doi":"https://doi.org/10.1021/acscatal.6c05543","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.6c05543","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101934825","display_name":"Yang Xiao","orcid":"https://orcid.org/0000-0001-6513-0533","observed_orcids":["https://orcid.org/0000-0001-6513-0533"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiao Yang","raw_affiliation_strings":["Chinese Academy of Sciences , , ,","University of Chinese Academy of Sciences , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]},{"raw_affiliation_string":"University of Chinese Academy of Sciences , ,","institution_ids":["https://openalex.org/I4210165038"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020854177","display_name":"Zezhong Miao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I30809798","display_name":"ShanghaiTech University","ror":"https://ror.org/030bhh786","country_code":"CN","type":"education","lineage":["https://openalex.org/I30809798"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zezhong Miao","raw_affiliation_strings":["Chinese Academy of Sciences , , ,","ShanghaiTech University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]},{"raw_affiliation_string":"ShanghaiTech University , , ,","institution_ids":["https://openalex.org/I30809798"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112610954","display_name":"Kun Gong","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Kun Gong","raw_affiliation_strings":["Chinese Academy of Sciences , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5128727849","display_name":"Ding Du","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ding Du","raw_affiliation_strings":["Chinese Academy of Sciences , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161481224","display_name":"Chixi Zhou","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chixi Zhou","raw_affiliation_strings":["Chinese Academy of Sciences , , ,","University of Chinese Academy of Sciences , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]},{"raw_affiliation_string":"University of Chinese Academy of Sciences , ,","institution_ids":["https://openalex.org/I4210165038"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103954819","display_name":"Yunlei An","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yunlei An","raw_affiliation_strings":["Chinese Academy of Sciences , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5115595350","display_name":"Xinxing Wang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xinxing Wang","raw_affiliation_strings":["Chinese Academy of Sciences , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100298159","display_name":"Dong Lv","orcid":"https://orcid.org/0009-0003-5555-6487","observed_orcids":["https://orcid.org/0009-0003-5555-6487"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Dong Lv","raw_affiliation_strings":["Chinese Academy of Sciences , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111733963","display_name":"Shenggang Li","orcid":"https://orcid.org/0000-0002-5173-0025","observed_orcids":["https://orcid.org/0000-0002-5173-0025"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I30809798","display_name":"ShanghaiTech University","ror":"https://ror.org/030bhh786","country_code":"CN","type":"education","lineage":["https://openalex.org/I30809798"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shenggang Li","raw_affiliation_strings":["Chinese Academy of Sciences , , ,","ShanghaiTech University , , ,","University of Chinese Academy of Sciences , ,"],"raw_orcid":"https://orcid.org/0000-0002-5173-0025","affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]},{"raw_affiliation_string":"ShanghaiTech University , , ,","institution_ids":["https://openalex.org/I30809798"]},{"raw_affiliation_string":"University of Chinese Academy of Sciences , ,","institution_ids":["https://openalex.org/I4210165038"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161462540","display_name":"Tiejun Lin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tiejun Lin","raw_affiliation_strings":["Chinese Academy of Sciences , , ,","University of Chinese Academy of Sciences , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]},{"raw_affiliation_string":"University of Chinese Academy of Sciences , ,","institution_ids":["https://openalex.org/I4210165038"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5022840101","display_name":"Liangshu Zhong","orcid":"https://orcid.org/0000-0002-4167-8630","observed_orcids":["https://orcid.org/0000-0002-4167-8630"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Liangshu Zhong","raw_affiliation_strings":["Chinese Academy of Sciences , , ,","University of Chinese Academy of Sciences , ,"],"raw_orcid":"https://orcid.org/0000-0002-4167-8630","affiliations":[{"raw_affiliation_string":"Chinese Academy of Sciences , , ,","institution_ids":["https://openalex.org/I19820366"]},{"raw_affiliation_string":"University of Chinese Academy of Sciences , ,","institution_ids":["https://openalex.org/I4210165038"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10495","display_name":"Catalysts for Methane Reforming","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10495","display_name":"Catalysts for Methane Reforming","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C194439259","wikidata":"https://www.wikidata.org/wiki/Q3273339","display_name":"Syngas","level":3,"score":0.9118000268936157},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.8529000282287598},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.8167999982833862},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.7674999833106995},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.7354000210762024},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.728600025177002},{"id":"https://openalex.org/C506198293","wikidata":"https://www.wikidata.org/wiki/Q650","display_name":"Fluorine","level":2,"score":0.7141000032424927},{"id":"https://openalex.org/C46062151","wikidata":"https://www.wikidata.org/wiki/Q19605","display_name":"Halogen","level":3,"score":0.6877999901771545},{"id":"https://openalex.org/C17112743","wikidata":"https://www.wikidata.org/wiki/Q7247759","display_name":"Product distribution","level":3,"score":0.44760000705718994},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.43959999084472656},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3305000066757202},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.32589998841285706},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3061000108718872},{"id":"https://openalex.org/C2776254738","wikidata":"https://www.wikidata.org/wiki/Q81406","display_name":"Alkene","level":3,"score":0.29190000891685486},{"id":"https://openalex.org/C129652920","wikidata":"https://www.wikidata.org/wiki/Q17152746","display_name":"Synergistic catalysis","level":3,"score":0.28369998931884766},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.27970001101493835},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.2791000008583069},{"id":"https://openalex.org/C51886252","wikidata":"https://www.wikidata.org/wiki/Q4118667","display_name":"Olefin fiber","level":3,"score":0.2718000113964081},{"id":"https://openalex.org/C66114498","wikidata":"https://www.wikidata.org/wiki/Q1466348","display_name":"Water-gas shift reaction","level":3,"score":0.26429998874664307},{"id":"https://openalex.org/C512735826","wikidata":"https://www.wikidata.org/wiki/Q2025","display_name":"Carbon monoxide","level":3,"score":0.2606000006198883}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acscatal.6c05543","doi":"https://doi.org/10.1021/acscatal.6c05543","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.6c05543","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W396325250","https://openalex.org/W1989421746","https://openalex.org/W2004751437","https://openalex.org/W2007395042","https://openalex.org/W2019973477","https://openalex.org/W2022298832","https://openalex.org/W2028056984","https://openalex.org/W2031430816","https://openalex.org/W2036113194","https://openalex.org/W2069904095","https://openalex.org/W2083222334","https://openalex.org/W2119611880","https://openalex.org/W2126778238","https://openalex.org/W2277399429","https://openalex.org/W2346683226","https://openalex.org/W2527978589","https://openalex.org/W2528925652","https://openalex.org/W2754741824","https://openalex.org/W2790622744","https://openalex.org/W2909663005","https://openalex.org/W2911689623","https://openalex.org/W2931840464","https://openalex.org/W3009549163","https://openalex.org/W3022778005","https://openalex.org/W3103984428","https://openalex.org/W3204152707","https://openalex.org/W3206606417","https://openalex.org/W3216831125","https://openalex.org/W3217138740","https://openalex.org/W4207006969","https://openalex.org/W4223585563","https://openalex.org/W4225277732","https://openalex.org/W4283799295","https://openalex.org/W4292833746","https://openalex.org/W4293239793","https://openalex.org/W4304099293","https://openalex.org/W4323353305","https://openalex.org/W4323806350","https://openalex.org/W4377014048","https://openalex.org/W4387172680","https://openalex.org/W4389048485","https://openalex.org/W4391963034","https://openalex.org/W4394959125","https://openalex.org/W4399747121","https://openalex.org/W4402827651","https://openalex.org/W4410292320","https://openalex.org/W4415707425","https://openalex.org/W4415707518","https://openalex.org/W7134990414","https://openalex.org/W7147438053"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"Olefins":[1],"production":[2],"from":[3],"syngas":[4,149],"via":[5],"Fischer\u2013Tropsch":[6],"synthesis":[7],"requires":[8],"catalysts":[9,53],"that":[10,46,112,128],"favor":[11],"olefins":[12,89,134],"formation,":[13],"maintain":[14],"intrinsic":[15],"activity,":[16],"and":[17,20,62,68,88,106,124,132],"suppress":[18,33,133],"CO2":[19,67],"CH4":[21],"formation.":[22],"Sodium-promoted":[23],"ruthenium":[24],"nanoparticles":[25],"shift":[26],"the":[27,78,118,144],"product":[28],"distribution":[29],"toward":[30],"\u03b1-olefins":[31,60],"but":[32],"Ru":[34,42,52,72,82],"activity":[35,55,103],"by":[36],"more":[37],"than":[38],"90%,":[39],"necessitating":[40],"higher":[41],"loadings.":[43],"We":[44],"show":[45],"incorporating":[47],"inorganic":[48],"fluorine":[49],"into":[50],"Na-promoted":[51],"increases":[54],"2.5-fold":[56],"while":[57],"maintaining":[58],"72.1%":[59],"selectivity":[61,65],"\u223c5.0%":[63],"combined":[64],"to":[66,142],"CH4.":[69],"At":[70],"a":[71,81,139],"loading":[73],"of":[74,85,92],"1.26":[75],"wt":[76],"%,":[77],"catalyst":[79],"achieves":[80],"time":[83],"yield":[84,91],"1.14":[86],"molCO\u00b7gRu\u20131\u00b7h\u20131":[87],"space-time":[90],"1516.1":[93],"g\u00b7molRu\u20131\u00b7h\u20131,":[94],"outperforming":[95],"most":[96],"reported":[97],"Ru-based":[98],"catalysts.":[99],"Fluorine":[100],"also":[101],"restores":[102],"in":[104,147],"Fe-":[105],"Co-based":[107],"systems.":[108],"Mechanistic":[109],"studies":[110],"indicate":[111],"surface":[113],"Na\u2013F":[114],"cation\u2013anion":[115],"pairs":[116],"modulate":[117],"electronic":[119],"structure,":[120],"weaken":[121],"Ru-CO":[122],"binding,":[123],"generate":[125],"hydrogen":[126],"species":[127],"accelerate":[129],"CO":[130],"activation":[131],"hydrogenation.":[135],"This":[136],"work":[137],"established":[138],"halogen-mediated":[140],"strategy":[141],"address":[143],"activity\u2013selectivity":[145],"trade-off":[146],"sodium-promoted":[148],"conversion.":[150]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}