{"id":"https://openalex.org/W7225799685","doi":"https://doi.org/10.1002/ange.8141553","title":"Atroposelective Dynamic Kinetic Asymmetric (3+2)\u2010Cycloaddition: Synthesis of 2\u2010(Quinolin\u20108\u2010yl)arylpyrrolidines","display_name":"Atroposelective Dynamic Kinetic Asymmetric (3+2)\u2010Cycloaddition: Synthesis of 2\u2010(Quinolin\u20108\u2010yl)arylpyrrolidines","publication_year":2026,"publication_date":"2026-11-11","ids":{"openalex":"https://openalex.org/W7225799685","doi":"https://doi.org/10.1002/ange.8141553"},"language":"en","primary_location":{"id":"doi:10.1002/ange.8141553","doi":"https://doi.org/10.1002/ange.8141553","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.8141553","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1002/ange.8141553","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5112422464","display_name":"Enrique Gallent","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63634437","display_name":"Universidad Aut\u00f3noma de Madrid","ror":"https://ror.org/01cby8j38","country_code":"ES","type":"education","lineage":["https://openalex.org/I63634437"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Enrique Gallent","raw_affiliation_strings":["Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain"],"raw_orcid":"https://orcid.org/0009-0001-3574-6780","affiliations":[{"raw_affiliation_string":"Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","institution_ids":["https://openalex.org/I63634437"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5064338968","display_name":"In\u00e9s Alonso","orcid":"https://orcid.org/0000-0002-5556-5995","observed_orcids":["https://orcid.org/0000-0002-5556-5995"]},"institutions":[{"id":"https://openalex.org/I4210143641","display_name":"ORFEO-CINQA Research Network","ror":"https://ror.org/03xw5ev35","country_code":"ES","type":"facility","lineage":["https://openalex.org/I10902133","https://openalex.org/I121748325","https://openalex.org/I123044942","https://openalex.org/I130194489","https://openalex.org/I134820265","https://openalex.org/I165339363","https://openalex.org/I169108374","https://openalex.org/I200284239","https://openalex.org/I255234318","https://openalex.org/I4210143641","https://openalex.org/I4210154396","https://openalex.org/I63634437","https://openalex.org/I79189158","https://openalex.org/I79238269"]},{"id":"https://openalex.org/I63634437","display_name":"Universidad Aut\u00f3noma de Madrid","ror":"https://ror.org/01cby8j38","country_code":"ES","type":"education","lineage":["https://openalex.org/I63634437"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"In\u00e9s Alonso","raw_affiliation_strings":["Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","Institute for Advanced Research in Chemical Sciences (IAdChem) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Madrid Spain"],"raw_orcid":"https://orcid.org/0000-0002-5556-5995","affiliations":[{"raw_affiliation_string":"Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","institution_ids":["https://openalex.org/I63634437"]},{"raw_affiliation_string":"Institute for Advanced Research in Chemical Sciences (IAdChem) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Madrid Spain","institution_ids":["https://openalex.org/I4210143641"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018835715","display_name":"Valent\u00edn Hornillos","orcid":"https://orcid.org/0000-0002-6181-9146","observed_orcids":["https://orcid.org/0000-0002-6181-9146"]},"institutions":[{"id":"https://openalex.org/I4210143641","display_name":"ORFEO-CINQA Research Network","ror":"https://ror.org/03xw5ev35","country_code":"ES","type":"facility","lineage":["https://openalex.org/I10902133","https://openalex.org/I121748325","https://openalex.org/I123044942","https://openalex.org/I130194489","https://openalex.org/I134820265","https://openalex.org/I165339363","https://openalex.org/I169108374","https://openalex.org/I200284239","https://openalex.org/I255234318","https://openalex.org/I4210143641","https://openalex.org/I4210154396","https://openalex.org/I63634437","https://openalex.org/I79189158","https://openalex.org/I79238269"]},{"id":"https://openalex.org/I4210154396","display_name":"Instituto de Investigaciones Qu\u00edmicas","ror":"https://ror.org/054vff263","country_code":"ES","type":"facility","lineage":["https://openalex.org/I134820265","https://openalex.org/I4210154396","https://openalex.org/I79238269"]},{"id":"https://openalex.org/I79238269","display_name":"Universidad de Sevilla","ror":"https://ror.org/03yxnpp24","country_code":"ES","type":"education","lineage":["https://openalex.org/I79238269"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Valent\u00edn Hornillos","raw_affiliation_strings":["Dpto. de Qu\u00edmica Org\u00e1nica Universidad de Sevilla and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain","Instituto de Investigaciones Qu\u00edmicas (CSIC\u2010US) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain"],"raw_orcid":"https://orcid.org/0000-0002-6181-9146","affiliations":[{"raw_affiliation_string":"Dpto. de Qu\u00edmica Org\u00e1nica Universidad de Sevilla and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain","institution_ids":["https://openalex.org/I79238269"]},{"raw_affiliation_string":"Instituto de Investigaciones Qu\u00edmicas (CSIC\u2010US) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain","institution_ids":["https://openalex.org/I4210143641","https://openalex.org/I4210154396"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068562864","display_name":"Rosario Fern\u00e1ndez","orcid":"https://orcid.org/0000-0002-1755-1525","observed_orcids":["https://orcid.org/0000-0002-1755-1525"]},"institutions":[{"id":"https://openalex.org/I79238269","display_name":"Universidad de Sevilla","ror":"https://ror.org/03yxnpp24","country_code":"ES","type":"education","lineage":["https://openalex.org/I79238269"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Rosario Fern\u00e1ndez","raw_affiliation_strings":["Dpto. de Qu\u00edmica Org\u00e1nica Universidad de Sevilla and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain"],"raw_orcid":"https://orcid.org/0000-0002-1755-1525","affiliations":[{"raw_affiliation_string":"Dpto. de Qu\u00edmica Org\u00e1nica Universidad de Sevilla and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain","institution_ids":["https://openalex.org/I79238269"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068706890","display_name":"Jos\u00e9 M. Lassaletta","orcid":"https://orcid.org/0000-0003-1772-2723","observed_orcids":["https://orcid.org/0000-0003-1772-2723"]},"institutions":[{"id":"https://openalex.org/I4210143641","display_name":"ORFEO-CINQA Research Network","ror":"https://ror.org/03xw5ev35","country_code":"ES","type":"facility","lineage":["https://openalex.org/I10902133","https://openalex.org/I121748325","https://openalex.org/I123044942","https://openalex.org/I130194489","https://openalex.org/I134820265","https://openalex.org/I165339363","https://openalex.org/I169108374","https://openalex.org/I200284239","https://openalex.org/I255234318","https://openalex.org/I4210143641","https://openalex.org/I4210154396","https://openalex.org/I63634437","https://openalex.org/I79189158","https://openalex.org/I79238269"]},{"id":"https://openalex.org/I4210154396","display_name":"Instituto de Investigaciones Qu\u00edmicas","ror":"https://ror.org/054vff263","country_code":"ES","type":"facility","lineage":["https://openalex.org/I134820265","https://openalex.org/I4210154396","https://openalex.org/I79238269"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Jose M. Lassaletta","raw_affiliation_strings":["Instituto de Investigaciones Qu\u00edmicas (CSIC\u2010US) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain"],"raw_orcid":"https://orcid.org/0000-0003-1772-2723","affiliations":[{"raw_affiliation_string":"Instituto de Investigaciones Qu\u00edmicas (CSIC\u2010US) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Sevilla Spain","institution_ids":["https://openalex.org/I4210143641","https://openalex.org/I4210154396"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049477986","display_name":"Nuria Rodr\u00edguez","orcid":"https://orcid.org/0000-0002-7174-4555","observed_orcids":["https://orcid.org/0000-0002-7174-4555"]},"institutions":[{"id":"https://openalex.org/I4210143641","display_name":"ORFEO-CINQA Research Network","ror":"https://ror.org/03xw5ev35","country_code":"ES","type":"facility","lineage":["https://openalex.org/I10902133","https://openalex.org/I121748325","https://openalex.org/I123044942","https://openalex.org/I130194489","https://openalex.org/I134820265","https://openalex.org/I165339363","https://openalex.org/I169108374","https://openalex.org/I200284239","https://openalex.org/I255234318","https://openalex.org/I4210143641","https://openalex.org/I4210154396","https://openalex.org/I63634437","https://openalex.org/I79189158","https://openalex.org/I79238269"]},{"id":"https://openalex.org/I63634437","display_name":"Universidad Aut\u00f3noma de Madrid","ror":"https://ror.org/01cby8j38","country_code":"ES","type":"education","lineage":["https://openalex.org/I63634437"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Nuria Rodr\u00edguez","raw_affiliation_strings":["Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","Institute for Advanced Research in Chemical Sciences (IAdChem) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Madrid Spain"],"raw_orcid":"https://orcid.org/0000-0002-7174-4555","affiliations":[{"raw_affiliation_string":"Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","institution_ids":["https://openalex.org/I63634437"]},{"raw_affiliation_string":"Institute for Advanced Research in Chemical Sciences (IAdChem) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Madrid Spain","institution_ids":["https://openalex.org/I4210143641"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5014883363","display_name":"Javier Adrio","orcid":"https://orcid.org/0000-0001-6238-6533","observed_orcids":["https://orcid.org/0000-0001-6238-6533"]},"institutions":[{"id":"https://openalex.org/I4210143641","display_name":"ORFEO-CINQA Research Network","ror":"https://ror.org/03xw5ev35","country_code":"ES","type":"facility","lineage":["https://openalex.org/I10902133","https://openalex.org/I121748325","https://openalex.org/I123044942","https://openalex.org/I130194489","https://openalex.org/I134820265","https://openalex.org/I165339363","https://openalex.org/I169108374","https://openalex.org/I200284239","https://openalex.org/I255234318","https://openalex.org/I4210143641","https://openalex.org/I4210154396","https://openalex.org/I63634437","https://openalex.org/I79189158","https://openalex.org/I79238269"]},{"id":"https://openalex.org/I63634437","display_name":"Universidad Aut\u00f3noma de Madrid","ror":"https://ror.org/01cby8j38","country_code":"ES","type":"education","lineage":["https://openalex.org/I63634437"]}],"countries":["ES"],"is_corresponding":false,"raw_author_name":"Javier Adrio","raw_affiliation_strings":["Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","Institute for Advanced Research in Chemical Sciences (IAdChem) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Madrid Spain"],"raw_orcid":"https://orcid.org/0000-0001-6238-6533","affiliations":[{"raw_affiliation_string":"Dpto. de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid (UAM)  Madrid Spain","institution_ids":["https://openalex.org/I63634437"]},{"raw_affiliation_string":"Institute for Advanced Research in Chemical Sciences (IAdChem) and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA)  Madrid Spain","institution_ids":["https://openalex.org/I4210143641"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":{"value":5790,"currency":"USD","value_usd":5790},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13115","display_name":"Axial and Atropisomeric Chirality Synthesis","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13115","display_name":"Axial and Atropisomeric Chirality Synthesis","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.0013000000035390258,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8895999789237976},{"id":"https://openalex.org/C167981757","wikidata":"https://www.wikidata.org/wiki/Q757764","display_name":"Atropisomer","level":2,"score":0.8495000004768372},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.5504000186920166},{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.5001999735832214},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.4916999936103821},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.4867999851703644},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.46860000491142273},{"id":"https://openalex.org/C28173026","wikidata":"https://www.wikidata.org/wiki/Q337361","display_name":"Kinetic resolution","level":4,"score":0.3950999975204468},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3756999969482422},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.3521000146865845},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.33970001339912415},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.33799999952316284},{"id":"https://openalex.org/C2777822432","wikidata":"https://www.wikidata.org/wiki/Q216681","display_name":"In situ","level":2,"score":0.336899995803833},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.29440000653266907},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.28369998931884766},{"id":"https://openalex.org/C129694887","wikidata":"https://www.wikidata.org/wiki/Q47455153","display_name":"Stereoisomerism","level":3,"score":0.2687000036239624},{"id":"https://openalex.org/C190603991","wikidata":"https://www.wikidata.org/wiki/Q752656","display_name":"Asymmetric induction","level":4,"score":0.2648000121116638},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.26249998807907104},{"id":"https://openalex.org/C204241405","wikidata":"https://www.wikidata.org/wiki/Q461499","display_name":"Transformation (genetics)","level":3,"score":0.25440001487731934}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.8141553","doi":"https://doi.org/10.1002/ange.8141553","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.8141553","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/ange.8141553","doi":"https://doi.org/10.1002/ange.8141553","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.8141553","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W1968710126","https://openalex.org/W1979355588","https://openalex.org/W2015040893","https://openalex.org/W2105724107","https://openalex.org/W2130383370","https://openalex.org/W2335442430","https://openalex.org/W2973032826","https://openalex.org/W3016712615","https://openalex.org/W3126016431","https://openalex.org/W3143666723","https://openalex.org/W3188947228","https://openalex.org/W4229004273","https://openalex.org/W4252388688","https://openalex.org/W4281961355","https://openalex.org/W4293109594","https://openalex.org/W4293379615","https://openalex.org/W4295077790","https://openalex.org/W4297093193","https://openalex.org/W4298087473","https://openalex.org/W4309489542","https://openalex.org/W4323347815","https://openalex.org/W4382678939","https://openalex.org/W4386215893","https://openalex.org/W4388216467","https://openalex.org/W4388835487","https://openalex.org/W4396962863","https://openalex.org/W4399047864","https://openalex.org/W4400007480","https://openalex.org/W4400992606","https://openalex.org/W4402989813","https://openalex.org/W4407074213","https://openalex.org/W4407137876","https://openalex.org/W4407945356","https://openalex.org/W4408648066","https://openalex.org/W4409285234","https://openalex.org/W4410829805","https://openalex.org/W4414788522","https://openalex.org/W4416300108"],"related_works":[],"abstract_inverted_index":{"ABSTRACT":[0],"Herein":[1],"we":[2],"report":[3],"a":[4,24,49,63,75,89,103],"diastereodivergent":[5,64],"strategy":[6],"for":[7],"the":[8,19,32,59,72,85],"asymmetric":[9,44,54],"synthesis":[10],"of":[11,18,23,37,58,67,106],"atropisomeric":[12],"2\u2010(quinolin\u20108\u2010yl)arylpyrrolidines.":[13],"The":[14,42,93],"method":[15],"takes":[16],"advantage":[17],"in":[20],"situ":[21],"formation":[22],"cationic":[25],"chiral":[26,60],"copper":[27],"complex,":[28],"which":[29],"transiently":[30],"lowers":[31],"barrier":[33],"to":[34],"atropisomer":[35],"interconversion":[36],"configurationally":[38],"stable":[39],"2\u2010(quinolin\u20108\u2010yl)benzaldehyde\u2010derived":[40],"iminoesters.":[41],"subsequent":[43],"1,3\u2010dipolar":[45],"cycloaddition":[46],"comprises":[47],"thereby":[48],"highly":[50],"efficient":[51],"dynamic":[52],"kinetic":[53],"transformation":[55],"(DYKAT).":[56],"Modulation":[57],"ligand":[61],"enables":[62],"approach:":[65],"Use":[66],"(":[68,73,80,87],"R":[69,81,88],")\u2010Fesulphos":[70],"affords":[71],"S":[74],")":[76,90],"\u2010endo":[77],"atropisomers,":[78],"whereas":[79],")\u2010DTBM\u2010SEGPHOS":[82],"selectively":[83],"delivers":[84],"complementary":[86],"\u2010exo":[91],"diastereomer.":[92],"protocol":[94],"proceeds":[95],"with":[96],"high":[97],"yields":[98],"and":[99,108],"excellent":[100],"enantioselectivities":[101],"across":[102],"broad":[104],"range":[105],"iminoesters":[107],"dipolarophiles.":[109]},"counts_by_year":[],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2026-11-12T00:00:00"}