{"id":"https://openalex.org/W7225747594","doi":"https://doi.org/10.1016/j.nxmate.2026.104007","title":"Sequential electrodeposition of hierarchical ZIF-67@V2O5 on carbon cloth for binder-free supercapacitor electrodes","display_name":"Sequential electrodeposition of hierarchical ZIF-67@V2O5 on carbon cloth for binder-free supercapacitor electrodes","publication_year":2026,"publication_date":"2026-11-10","ids":{"openalex":"https://openalex.org/W7225747594","doi":"https://doi.org/10.1016/j.nxmate.2026.104007"},"language":"en","primary_location":{"id":"doi:10.1016/j.nxmate.2026.104007","doi":"https://doi.org/10.1016/j.nxmate.2026.104007","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.nxmate.2026.104007","pdf_url":null,"source":{"id":"https://openalex.org/S4387287712","display_name":"Next Materials","issn_l":"2949-8228","issn":["2949-8228"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-1","norway-1","oarl"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Next Materials","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.1016/j.nxmate.2026.104007","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5001087596","display_name":"Gift Rutavi","orcid":"https://orcid.org/0000-0002-2235-6361","observed_orcids":["https://orcid.org/0000-0002-2235-6361"]},"institutions":[{"id":"https://openalex.org/I165390105","display_name":"University of South Africa","ror":"https://ror.org/048cwvf49","country_code":"ZA","type":"education","lineage":["https://openalex.org/I165390105"]}],"countries":["ZA"],"is_corresponding":true,"raw_author_name":"Gift Rutavi","raw_affiliation_strings":["Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Florida Science Campus, Johannesburg 1710, South Africa"],"raw_orcid":"https://orcid.org/0000-0002-2235-6361","affiliations":[{"raw_affiliation_string":"Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Florida Science Campus, Johannesburg 1710, South Africa","institution_ids":["https://openalex.org/I165390105"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5067793429","display_name":"Mesfin Abayneh Kebede","orcid":"https://orcid.org/0000-0002-7764-0933","observed_orcids":["https://orcid.org/0000-0002-7764-0933"]},"institutions":[{"id":"https://openalex.org/I165390105","display_name":"University of South Africa","ror":"https://ror.org/048cwvf49","country_code":"ZA","type":"education","lineage":["https://openalex.org/I165390105"]}],"countries":["ZA"],"is_corresponding":false,"raw_author_name":"Mesfin Abayneh Kebede","raw_affiliation_strings":["Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Florida Science Campus, Johannesburg 1710, South Africa"],"raw_orcid":"https://orcid.org/0000-0002-7764-0933","affiliations":[{"raw_affiliation_string":"Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Florida Science Campus, Johannesburg 1710, South Africa","institution_ids":["https://openalex.org/I165390105"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5001087596"],"corresponding_institution_ids":["https://openalex.org/I165390105"],"apc_list":{"value":1280,"currency":"USD","value_usd":1280},"apc_paid":{"value":1280,"currency":"USD","value_usd":1280},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"14","issue":null,"first_page":"104007","last_page":"104007"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10179","display_name":"Supercapacitor Materials and Fabrication","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10179","display_name":"Supercapacitor Materials and Fabrication","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11690","display_name":"Aqueous and Flow Batteries","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C6585489","wikidata":"https://www.wikidata.org/wiki/Q754523","display_name":"Supercapacitor","level":4,"score":0.9010000228881836},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.8084999918937683},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.7461000084877014},{"id":"https://openalex.org/C130349721","wikidata":"https://www.wikidata.org/wiki/Q5434705","display_name":"Faraday efficiency","level":4,"score":0.7027000188827515},{"id":"https://openalex.org/C104779481","wikidata":"https://www.wikidata.org/wiki/Q50707","display_name":"Composite number","level":2,"score":0.6977999806404114},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.6373000144958496},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.506600022315979},{"id":"https://openalex.org/C6648577","wikidata":"https://www.wikidata.org/wiki/Q622669","display_name":"Porosity","level":2,"score":0.49079999327659607},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.48910000920295715},{"id":"https://openalex.org/C2779647737","wikidata":"https://www.wikidata.org/wiki/Q190878","display_name":"Activated carbon","level":3,"score":0.46459999680519104},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.39959999918937683},{"id":"https://openalex.org/C30066665","wikidata":"https://www.wikidata.org/wiki/Q164399","display_name":"Capacitance","level":3,"score":0.3305000066757202},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.32190001010894775},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.30959999561309814},{"id":"https://openalex.org/C62609721","wikidata":"https://www.wikidata.org/wiki/Q3023293","display_name":"Specific energy","level":2,"score":0.29510000348091125},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.2838999927043915},{"id":"https://openalex.org/C21881925","wikidata":"https://www.wikidata.org/wiki/Q3503313","display_name":"Power density","level":3,"score":0.257999986410141}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1016/j.nxmate.2026.104007","doi":"https://doi.org/10.1016/j.nxmate.2026.104007","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.nxmate.2026.104007","pdf_url":null,"source":{"id":"https://openalex.org/S4387287712","display_name":"Next Materials","issn_l":"2949-8228","issn":["2949-8228"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-1","norway-1","oarl"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Next Materials","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1016/j.nxmate.2026.104007","doi":"https://doi.org/10.1016/j.nxmate.2026.104007","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.nxmate.2026.104007","pdf_url":null,"source":{"id":"https://openalex.org/S4387287712","display_name":"Next Materials","issn_l":"2949-8228","issn":["2949-8228"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-1","norway-1","oarl"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Next Materials","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":52,"referenced_works":["https://openalex.org/W1863376134","https://openalex.org/W1978126078","https://openalex.org/W1989937017","https://openalex.org/W2013903153","https://openalex.org/W2101262472","https://openalex.org/W2317208446","https://openalex.org/W2534046162","https://openalex.org/W2735656840","https://openalex.org/W2753367371","https://openalex.org/W2884042457","https://openalex.org/W2888480870","https://openalex.org/W2938659122","https://openalex.org/W2949330638","https://openalex.org/W2962002168","https://openalex.org/W2973180144","https://openalex.org/W2978404528","https://openalex.org/W2980179975","https://openalex.org/W3012181034","https://openalex.org/W3020080400","https://openalex.org/W3082494323","https://openalex.org/W3112937840","https://openalex.org/W3202218610","https://openalex.org/W4295950550","https://openalex.org/W4306386333","https://openalex.org/W4309580028","https://openalex.org/W4311754158","https://openalex.org/W4313420300","https://openalex.org/W4320715928","https://openalex.org/W4321164256","https://openalex.org/W4323544162","https://openalex.org/W4360981547","https://openalex.org/W4386121950","https://openalex.org/W4386890740","https://openalex.org/W4388494208","https://openalex.org/W4388629210","https://openalex.org/W4388921960","https://openalex.org/W4389122702","https://openalex.org/W4389247343","https://openalex.org/W4390716191","https://openalex.org/W4391450229","https://openalex.org/W4394981669","https://openalex.org/W4396659206","https://openalex.org/W4403277691","https://openalex.org/W4405663279","https://openalex.org/W4406181514","https://openalex.org/W4406934883","https://openalex.org/W4407918850","https://openalex.org/W4408811775","https://openalex.org/W4412409080","https://openalex.org/W4412460589","https://openalex.org/W4415517091","https://openalex.org/W7128157866"],"related_works":[],"abstract_inverted_index":{"The":[0,105,133,162],"performance":[1],"of":[2,13,72,83,140,156,174],"ZIF-67":[3,73,97],"as":[4,129],"a":[5,26,30,38,47,55,79,136,153],"supercapacitor":[6,113,199],"electrode":[7,53,106],"is":[8],"hindered":[9],"by":[10,24],"the":[11,69,75,130,191],"underutilisation":[12],"its":[14],"internal":[15],"structure":[16],"and":[17,77,91,98,171,176],"poor":[18],"conductivity.":[19],"This":[20,189],"can":[21],"be":[22],"alleviated":[23],"designing":[25],"hierarchical":[27],"system":[28],"with":[29,168],"redox-active":[31,65],"metal":[32],"oxide":[33],"material.":[34],"In":[35],"this":[36],"work,":[37],"two-step":[39],"electrodeposition":[40],"approach":[41],"was":[42,107],"used":[43,108],"sequentially":[44],"to":[45,89,109,152],"fabricate":[46,110],"ZIF-67@V":[48,115],"2":[49,60,100,116],"O":[50,61,101,117],"5":[51,62,102,118,184],"composite":[52,76],"on":[54],"carbon":[56,123],"cloth":[57],"substrate.":[58],"V":[59,99],"provides":[63],"more":[64],"sites,":[66],"thereby":[67],"complementing":[68],"high":[70,80,137,166],"porosity":[71],"in":[74],"yielding":[78],"specific":[81,138,154],"capacity":[82,172],"146.7":[84],"mAh":[85,93],"g":[86,94,148,186],"\u22121":[87,95,144,149,160,187],"compared":[88],"69.7":[90],"76.4":[92],"for":[96,195],",":[103,150],"respectively.":[104],"an":[111],"asymmetric":[112],"device,":[114],"//":[119],"HH-AC,":[120],"where":[121],"activated":[122],"from":[124],"recycled":[125],"human":[126],"hair":[127],"served":[128],"negative":[131],"electrode.":[132],"device":[134,163],"delivered":[135],"energy":[139],"58.8":[141],"Wh":[142],"kg":[143,159],"at":[145,183],"1":[146],"A":[147,185],"corresponding":[151],"power":[155],"788.9":[157],"W":[158],".":[161,188],"also":[164],"exhibited":[165],"stability,":[167],"coulombic":[169],"efficiency":[170],"retention":[173],"99.4%":[175],"87.4%,":[177],"respectively,":[178],"after":[179],"10000":[180],"GCD":[181],"cycles":[182],"makes":[190],"proposed":[192],"work":[193],"suitable":[194],"incorporation":[196],"into":[197],"practical":[198],"devices.":[200]},"counts_by_year":[],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2026-11-11T00:00:00"}
