{"id":"https://openalex.org/W7225729474","doi":"https://doi.org/10.1021/acs.inorgchem.6c04283","title":"Electrochemical Acetonitrile Release from Dinitrogen-Derived Rhenium Imido Complexes through Proton-Coupled Electron Transfer","display_name":"Electrochemical Acetonitrile Release from Dinitrogen-Derived Rhenium Imido Complexes through Proton-Coupled Electron Transfer","publication_year":2026,"publication_date":"2026-11-10","ids":{"openalex":"https://openalex.org/W7225729474","doi":"https://doi.org/10.1021/acs.inorgchem.6c04283"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.6c04283","doi":"https://doi.org/10.1021/acs.inorgchem.6c04283","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.6c04283","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1021/acs.inorgchem.6c04283","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5098707293","display_name":"Ciara I. Kiene","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Ciara I. Kiene","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078045434","display_name":"Richt S. van Alten","orcid":"https://orcid.org/0000-0002-5878-2290","observed_orcids":["https://orcid.org/0000-0002-5878-2290"]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Richt S. van Alten","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044433274","display_name":"Markus Finger","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Markus Finger","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055966002","display_name":"Josh Abbenseth","orcid":"https://orcid.org/0000-0002-8787-6253","observed_orcids":["https://orcid.org/0000-0002-8787-6253"]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Josh Abbenseth","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":"https://orcid.org/0000-0002-8787-6253","affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090776613","display_name":"Christian W\u00fcrtele","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Christian Wu\u0308rtele","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082529207","display_name":"Inke Siewert","orcid":"https://orcid.org/0000-0003-3121-3917","observed_orcids":["https://orcid.org/0000-0003-3121-3917"]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Inke Siewert","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":"https://orcid.org/0000-0003-3121-3917","affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5067235857","display_name":"Sven Schneider","orcid":"https://orcid.org/0000-0002-8432-7830","observed_orcids":["https://orcid.org/0000-0002-8432-7830"]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Sven Schneider","raw_affiliation_strings":["Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,"],"raw_orcid":"https://orcid.org/0000-0002-8432-7830","affiliations":[{"raw_affiliation_string":"Universita\u0308t Go\u0308ttingen , , Tammannstra\u00dfe 4 , ,","institution_ids":["https://openalex.org/I74656192"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5067235857"],"corresponding_institution_ids":["https://openalex.org/I74656192"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":{"value":4500,"currency":"USD","value_usd":4500},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9110999703407288,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9110999703407288,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.02160000056028366,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.01810000091791153,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9684000015258789},{"id":"https://openalex.org/C505216180","wikidata":"https://www.wikidata.org/wiki/Q737","display_name":"Rhenium","level":2,"score":0.8041999936103821},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.7872999906539917},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.741100013256073},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.7394999861717224},{"id":"https://openalex.org/C2779240715","wikidata":"https://www.wikidata.org/wiki/Q333936","display_name":"Nitrile","level":2,"score":0.7229999899864197},{"id":"https://openalex.org/C163127949","wikidata":"https://www.wikidata.org/wiki/Q64403","display_name":"Electrolysis","level":4,"score":0.5688999891281128},{"id":"https://openalex.org/C2778695967","wikidata":"https://www.wikidata.org/wiki/Q44791900","display_name":"Chloride","level":2,"score":0.5527999997138977},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5329999923706055},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4959999918937683},{"id":"https://openalex.org/C2778288590","wikidata":"https://www.wikidata.org/wiki/Q4996476","display_name":"Bulk electrolysis","level":5,"score":0.46560001373291016},{"id":"https://openalex.org/C91819851","wikidata":"https://www.wikidata.org/wiki/Q146889","display_name":"Pincer movement","level":3,"score":0.40540000796318054},{"id":"https://openalex.org/C33989665","wikidata":"https://www.wikidata.org/wiki/Q5357962","display_name":"Electrocatalyst","level":4,"score":0.3603000044822693},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.34139999747276306},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.27649998664855957},{"id":"https://openalex.org/C518104683","wikidata":"https://www.wikidata.org/wiki/Q880","display_name":"Platinum","level":3,"score":0.2678000032901764},{"id":"https://openalex.org/C2780906950","wikidata":"https://www.wikidata.org/wiki/Q424898","display_name":"Thianthrene","level":2,"score":0.25999999046325684},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.258899986743927}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.inorgchem.6c04283","doi":"https://doi.org/10.1021/acs.inorgchem.6c04283","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.6c04283","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1021/acs.inorgchem.6c04283","doi":"https://doi.org/10.1021/acs.inorgchem.6c04283","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.6c04283","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":61,"referenced_works":["https://openalex.org/W1970449020","https://openalex.org/W1988091937","https://openalex.org/W2008423326","https://openalex.org/W2011215428","https://openalex.org/W2024819329","https://openalex.org/W2037570317","https://openalex.org/W2037906407","https://openalex.org/W2039293281","https://openalex.org/W2065998871","https://openalex.org/W2066610771","https://openalex.org/W2067718414","https://openalex.org/W2086654460","https://openalex.org/W2089617448","https://openalex.org/W2091999692","https://openalex.org/W2092157292","https://openalex.org/W2096747776","https://openalex.org/W2119547517","https://openalex.org/W2124784566","https://openalex.org/W2145408306","https://openalex.org/W2150697053","https://openalex.org/W2294512153","https://openalex.org/W2295535048","https://openalex.org/W2317239842","https://openalex.org/W2317433266","https://openalex.org/W2326398752","https://openalex.org/W2340760970","https://openalex.org/W2508800879","https://openalex.org/W2530475862","https://openalex.org/W2739439285","https://openalex.org/W2840935399","https://openalex.org/W2901406848","https://openalex.org/W2911997094","https://openalex.org/W2932297636","https://openalex.org/W2970699026","https://openalex.org/W3000410519","https://openalex.org/W3006234984","https://openalex.org/W3023120551","https://openalex.org/W3030209662","https://openalex.org/W3037395050","https://openalex.org/W3048565185","https://openalex.org/W3048630403","https://openalex.org/W3160952151","https://openalex.org/W3200087632","https://openalex.org/W4220694746","https://openalex.org/W4245966329","https://openalex.org/W4283018175","https://openalex.org/W4293792339","https://openalex.org/W4307161038","https://openalex.org/W4307309219","https://openalex.org/W4310705210","https://openalex.org/W4319294493","https://openalex.org/W4366162499","https://openalex.org/W4385073150","https://openalex.org/W4393045038","https://openalex.org/W4396217822","https://openalex.org/W4399731462","https://openalex.org/W4406930457","https://openalex.org/W4407658436","https://openalex.org/W4409878037","https://openalex.org/W4412348537","https://openalex.org/W4414858041"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"The":[1,70,88,114],"oxidation":[2,64,90,109],"of":[3,13,19,28,38,43,51,83,110,126],"rhenium(III)":[4,127],"azavinylidene":[5,46],"complexes":[6,47],"that":[7],"originate":[8],"from":[9],"the":[10,16,26,33,39,49,60,74,84,102,111,133],"reductive":[11],"splitting":[12],"dinitrogen":[14],"enables":[15],"stepwise":[17],"conversion":[18],"N2":[20],"to":[21,80,93,116,132],"nitriles.":[22],"We":[23],"here":[24],"report":[25],"development":[27],"an":[29,129],"electrochemical":[30],"protocol":[31],"and":[32,35,53,59],"experimental":[34],"computational":[36],"examination":[37],"reaction":[40],"mechanism.":[41,134],"Electrolysis":[42],"N2-derived":[44],"{ReIII\u2013N\u2550CHCH3}":[45],"in":[48,66,73,119],"presence":[50],"chloride":[52,94],"NEt3":[54],"affords":[55,101],"MeCN":[56],"nearly":[57],"quantitatively":[58],"respective":[61],"ReIV":[62],"3-electron":[63],"products":[65],"yields":[67,72],"around":[68],"50%.":[69],"lower":[71],"Re":[75],"product":[76,104],"can":[77],"be":[78],"attributed":[79],"degradation":[81],"processes":[82],"supporting":[85],"pincer":[86],"ligands.":[87],"first":[89],"is":[91],"coupled":[92],"addition.":[95],"Subsequent":[96],"proton-coupled":[97],"electron":[98],"transfer":[99],"(PCET)":[100],"nitrile":[103],"as":[105,128],"a":[106,120],"net":[107],"2-electron":[108],"nitrogenous":[112],"ligand.":[113],"overoxidation":[115],"rhenium(IV)":[117],"originates":[118],"large":[121],"potential":[122],"inversion":[123],"upon":[124],"restoration":[125],"inherent":[130],"feature":[131]},"counts_by_year":[],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2026-11-11T00:00:00"}