{"id":"https://openalex.org/W7225636117","doi":"https://doi.org/10.26902/jsc_id182202","title":"Synthesis, characterization, crystal structures and antibacterial activity of copper(II), nickel(II) and zinc(II) complexes with a chloro-substituted salicylaldimine Schiff base","display_name":"Synthesis, characterization, crystal structures and antibacterial activity of copper(II), nickel(II) and zinc(II) complexes with a chloro-substituted salicylaldimine Schiff base","publication_year":2026,"publication_date":"2026-11-09","ids":{"openalex":"https://openalex.org/W7225636117","doi":"https://doi.org/10.26902/jsc_id182202"},"language":"en","primary_location":{"id":"doi:10.26902/jsc_id182202","doi":"https://doi.org/10.26902/jsc_id182202","is_oa":false,"landing_page_url":"https://doi.org/10.26902/jsc_id182202","pdf_url":null,"source":{"id":"https://openalex.org/S4210204189","display_name":"\u0416\u0443\u0440\u043d\u0430\u043b \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0439 \u0445\u0438\u043c\u0438\u0438","issn_l":"0136-7463","issn":["0136-7463","2542-0976"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"\u0416\u0443\u0440\u043d\u0430\u043b \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0439 \u0445\u0438\u043c\u0438\u0438","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5161310753","display_name":"Peng Wang","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Peng Wang","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161304617","display_name":"Guoze Wang","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Guoze Wang","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110866248","display_name":"Dongzhe Zou","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D.-H. Zou","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110356006","display_name":"Wei Kan","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Wei Kan","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161307373","display_name":"Bing Zhao","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Bing Zhao","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5161340824","display_name":"C.-B. Sun","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"C.-B. Sun","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"68","issue":"4","first_page":"182202","last_page":"182202"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.8246999979019165,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.8246999979019165,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.13279999792575836,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12458","display_name":"Organometallic Compounds Synthesis and Characterization","score":0.017100000753998756,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/schiff-base-ligands","display_name":"Schiff base ligands","score":0.8379999995231628},{"id":"https://openalex.org/keywords/cu-ii-complexes","display_name":"copper(II) complexes","score":0.8809999823570251},{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/zinc-ii-complexes","display_name":"zinc(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/cyclopentylamine","display_name":"cyclopentylamine","score":0.8790000081062317},{"id":"https://openalex.org/keywords/square-planar-geometry","display_name":"square-planar coordination","score":0.7400000095367432},{"id":"https://openalex.org/keywords/tetrahedral-coordination","display_name":"tetrahedral coordination","score":0.9369999766349792},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6230000257492065},{"id":"https://openalex.org/keywords/antibacterial-activity","display_name":"antibacterial activity","score":0.9769999980926514},{"id":"https://openalex.org/keywords/minimum-inhibitory-concentration","display_name":"minimum inhibitory concentration","score":0.9829999804496765},{"id":"https://openalex.org/keywords/bacillus-subtilis","display_name":"Bacillus subtilis","score":0.8790000081062317},{"id":"https://openalex.org/keywords/staphylococcus-aureus","display_name":"Staphylococcus aureus","score":1.0},{"id":"https://openalex.org/keywords/escherichia-coli","display_name":"Escherichia coli","score":1.0}],"concepts":[{"id":"https://openalex.org/C2776428424","wikidata":"https://www.wikidata.org/wiki/Q2602701","display_name":"Schiff base","level":2,"score":0.7915999889373779},{"id":"https://openalex.org/C2780104969","wikidata":"https://www.wikidata.org/wiki/Q4774530","display_name":"Antibacterial activity","level":3,"score":0.7835999727249146},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7542999982833862},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.6819000244140625},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6787999868392944},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.4968999922275543},{"id":"https://openalex.org/C73922627","wikidata":"https://www.wikidata.org/wiki/Q754943","display_name":"Single crystal","level":2,"score":0.48410001397132874},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4397999942302704},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4196000099182129},{"id":"https://openalex.org/C103319777","wikidata":"https://www.wikidata.org/wiki/Q1979695","display_name":"Proton NMR","level":2,"score":0.3928999900817871},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.3668000102043152},{"id":"https://openalex.org/C127709339","wikidata":"https://www.wikidata.org/wiki/Q2677111","display_name":"Tetrahedral molecular geometry","level":3,"score":0.36550000309944153},{"id":"https://openalex.org/C207245611","wikidata":"https://www.wikidata.org/wiki/Q910058","display_name":"Condensation reaction","level":3,"score":0.3160000145435333},{"id":"https://openalex.org/C33559828","wikidata":"https://www.wikidata.org/wiki/Q397226","display_name":"Coordination number","level":3,"score":0.31290000677108765},{"id":"https://openalex.org/C3019249092","wikidata":"https://www.wikidata.org/wiki/Q274493","display_name":"Antibacterial agent","level":3,"score":0.31029999256134033},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.273499995470047},{"id":"https://openalex.org/C2777272437","wikidata":"https://www.wikidata.org/wiki/Q131238","display_name":"Bacillus subtilis","level":3,"score":0.26809999346733093},{"id":"https://openalex.org/C158842870","wikidata":"https://www.wikidata.org/wiki/Q6125309","display_name":"Pentagonal bipyramidal molecular geometry","level":3,"score":0.2630000114440918},{"id":"https://openalex.org/C194196696","wikidata":"https://www.wikidata.org/wiki/Q1753378","display_name":"Coordination geometry","level":4,"score":0.26019999384880066},{"id":"https://openalex.org/C193042331","wikidata":"https://www.wikidata.org/wiki/Q1772003","display_name":"Structure\u2013activity relationship","level":3,"score":0.25119999051094055},{"id":"https://openalex.org/C64885871","wikidata":"https://www.wikidata.org/wiki/Q2533665","display_name":"Elemental analysis","level":2,"score":0.2506999969482422}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26902/jsc_id182202","doi":"https://doi.org/10.26902/jsc_id182202","is_oa":false,"landing_page_url":"https://doi.org/10.26902/jsc_id182202","pdf_url":null,"source":{"id":"https://openalex.org/S4210204189","display_name":"\u0416\u0443\u0440\u043d\u0430\u043b \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0439 \u0445\u0438\u043c\u0438\u0438","issn_l":"0136-7463","issn":["0136-7463","2542-0976"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"\u0416\u0443\u0440\u043d\u0430\u043b \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0439 \u0445\u0438\u043c\u0438\u0438","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W3115884761","https://openalex.org/W3132078862","https://openalex.org/W2003053533","https://openalex.org/W2400641179","https://openalex.org/W7213905695","https://openalex.org/W2019039653","https://openalex.org/W4313479072","https://openalex.org/W4318480294","https://openalex.org/W3129290834","https://openalex.org/W4399623901"],"abstract_inverted_index":{"A":[0],"chloro-substituted":[1],"salicylaldimine":[2],"Schiff":[3],"base,":[4],"2-[(cyclopentylimino)methyl]-6-chlorophenol":[5],"(HL),":[6],"was":[7,69],"synthesized":[8],"by":[9,59,72],"condensation":[10],"of":[11,18,38,45,108,150],"3-chlorosalicylaldehyde":[12],"with":[13,20,40],"cyclopentylamine":[14],"in":[15,42],"methanol.":[16],"Reactions":[17],"HL":[19,39,109],"copper(II),":[21],"nickel(II)":[22],"and":[23,31,55,63,66,84,90,97,110,118,125,138,163,172,180],"zinc(II)":[24],"acetates":[25],"afforded":[26],"[CuL2]":[27],"(1),":[28],"[NiL2]":[29],"(2)":[30],"[ZnL2]":[32],"(3),":[33],"respectively,":[34],"while":[35,144],"the":[36,43,48,67,128],"reaction":[37],"Zn(OAc)2":[41],"presence":[44],"NH4SCN":[46],"produced":[47],"mixed-ligand":[49],"complex":[50,145],"[ZnL(HL)(NCS)]":[51],"(4).":[52],"The":[53,105,157],"ligand":[54,68],"complexes":[56,82,95,111],"were":[57,113],"characterized":[58,71],"elemental":[60],"analysis,":[61],"IR":[62],"UV\u2013Vis":[64],"spectroscopy,":[65],"additionally":[70],"1H":[73],"NMR":[74],"spectroscopy.":[75],"Single":[76],"crystal":[77],"X-ray":[78],"diffraction":[79],"revealed":[80],"that":[81],"1":[83],"2":[85],"possess":[86],"essentially":[87],"square-planar":[88],"CuN2O2":[89],"NiN2O2":[91],"coordination":[92,103,178],"environments,":[93],"whereas":[94],"3":[96,124],"4":[98,126,146],"exhibit":[99],"distorted":[100],"tetrahedral":[101],"ZnN2O2":[102],"geometries.":[104],"antibacterial":[106,181],"activities":[107],"1\u20134":[112],"evaluated":[114],"against":[115,132,154],"three":[116,119],"Gram-positive":[117],"Gram-negative":[120],"bacterial":[121],"strains.":[122],"Complexes":[123],"showed":[127],"lowest":[129],"MIC":[130,149,159],"values":[131],"B.":[133],"subtilis":[134],"(0.39":[135],"\u03bcg":[136,142,152],"mL\u20131)":[137],"S.":[139],"aureus":[140],"(1.56":[141],"mL\u20131),":[143],"exhibited":[147],"a":[148,173],"12.5":[151],"mL\u20131":[153],"E.":[155],"coli.":[156],"reported":[158],"endpoints":[160],"suggest":[161],"compound-":[162],"strain-dependent":[164],"activity,":[165],"but":[166],"replicate":[167],"variability":[168],"is":[169,183],"not":[170,184],"documented":[171],"causal":[174],"relationship":[175],"between":[176],"solid-state":[177],"geometry":[179],"activity":[182],"established.":[185]},"counts_by_year":[],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2026-11-10T00:00:00"}