{"id":"https://openalex.org/W7225623552","doi":"https://doi.org/10.1134/s2070050426700340","title":"Catalytic Etching of Polycrystalline Rhodium during High-Temperature Oxidation of Ammonia with Air at 1133 K","display_name":"Catalytic Etching of Polycrystalline Rhodium during High-Temperature Oxidation of Ammonia with Air at 1133 K","publication_year":2026,"publication_date":"2026-11-09","ids":{"openalex":"https://openalex.org/W7225623552","doi":"https://doi.org/10.1134/s2070050426700340"},"language":"en","primary_location":{"id":"doi:10.1134/s2070050426700340","doi":"https://doi.org/10.1134/s2070050426700340","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s2070050426700340","pdf_url":null,"source":{"id":"https://openalex.org/S182539911","display_name":"Catalysis in Industry","issn_l":"2070-0504","issn":["2070-0504","2070-0555"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Catalysis in Industry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5066560924","display_name":"\u0410. \u041d. \u0421\u0430\u043b\u0430\u043d\u043e\u0432","orcid":"https://orcid.org/0000-0002-6426-4537","observed_orcids":["https://orcid.org/0000-0002-6426-4537"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"A. N. Salanov","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020485310","display_name":"\u0410. \u041d. \u0421\u0435\u0440\u043a\u043e\u0432\u0430","orcid":"https://orcid.org/0000-0003-0388-8984","observed_orcids":["https://orcid.org/0000-0003-0388-8984"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. N. Serkova","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103312025","display_name":"Anastasia  S. Zhirnova","orcid":"https://orcid.org/0009-0003-6999-7355","observed_orcids":["https://orcid.org/0009-0003-6999-7355"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. S. Zhirnova","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017357155","display_name":"Alexander V. Kalinkin","orcid":"https://orcid.org/0000-0003-0331-2459","observed_orcids":["https://orcid.org/0000-0003-0331-2459"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. V. Kalinkin","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038377952","display_name":"Mikhail Yu. Smirnov","orcid":"https://orcid.org/0000-0002-3964-2516","observed_orcids":["https://orcid.org/0000-0002-3964-2516"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"M. Yu. Smirnov","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049335346","display_name":"Svetlana V. Cherepanova","orcid":"https://orcid.org/0000-0002-2027-0062","observed_orcids":["https://orcid.org/0000-0002-2027-0062"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"S. V. Cherepanova","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022046419","display_name":"\u041b. \u0410. \u0418\u0441\u0443\u043f\u043e\u0432\u0430","orcid":"https://orcid.org/0000-0002-6221-1060","observed_orcids":["https://orcid.org/0000-0002-6221-1060"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"L. A. Isupova","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5055572174","display_name":"Valentin Nikolaevich Parmon","orcid":"https://orcid.org/0000-0002-8877-7388","observed_orcids":["https://orcid.org/0000-0002-8877-7388"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210094231","display_name":"Boreskov Institute of Catalysis","ror":"https://ror.org/00kftxm09","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"V. N. Parmon","raw_affiliation_strings":["Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5066560924"],"corresponding_institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210094231","https://openalex.org/I4210127387"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"18","issue":"4","first_page":"465","last_page":"485"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.9731000065803528,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.9731000065803528,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10626","display_name":"High-Temperature Coating Behaviors","score":0.018300000578165054,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.0032999999821186066,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rhodium","display_name":"rhodium","score":0.6800000071525574},{"id":"https://openalex.org/keywords/catalytic-etching","display_name":"catalytic etching","score":0.8479999899864197},{"id":"https://openalex.org/keywords/ammonia-oxidation","display_name":"ammonia oxidation","score":0.7960000038146973},{"id":"https://openalex.org/keywords/high-temperature-oxidation","display_name":"high-temperature oxidation","score":0.8569999933242798},{"id":"https://openalex.org/keywords/grain-boundaries","display_name":"grain boundaries","score":0.6830000281333923},{"id":"https://openalex.org/keywords/coherent-scattering-regions","display_name":"coherent scattering regions","score":0.45500001311302185}],"concepts":[{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.9229999780654907},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.7009000182151794},{"id":"https://openalex.org/C137637335","wikidata":"https://www.wikidata.org/wiki/Q899604","display_name":"Crystallite","level":2,"score":0.6561999917030334},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5615000128746033},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5239999890327454},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5220000147819519},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.49480000138282776},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.47189998626708984},{"id":"https://openalex.org/C100460472","wikidata":"https://www.wikidata.org/wiki/Q2368605","display_name":"Etching (microfabrication)","level":3,"score":0.4223000109195709},{"id":"https://openalex.org/C77851909","wikidata":"https://www.wikidata.org/wiki/Q6481705","display_name":"Lamellar structure","level":2,"score":0.376800000667572},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.33649998903274536},{"id":"https://openalex.org/C2776382133","wikidata":"https://www.wikidata.org/wiki/Q4087","display_name":"Ammonia","level":2,"score":0.322299987077713},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.31299999356269836},{"id":"https://openalex.org/C540031477","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen","level":2,"score":0.31209999322891235},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3093000054359436},{"id":"https://openalex.org/C26771246","wikidata":"https://www.wikidata.org/wiki/Q321095","display_name":"Scanning electron microscope","level":2,"score":0.3084999918937683},{"id":"https://openalex.org/C192191005","wikidata":"https://www.wikidata.org/wiki/Q466491","display_name":"Grain size","level":2,"score":0.30309998989105225},{"id":"https://openalex.org/C78030364","wikidata":"https://www.wikidata.org/wiki/Q5051391","display_name":"Catalytic oxidation","level":3,"score":0.3003000020980835},{"id":"https://openalex.org/C129955480","wikidata":"https://www.wikidata.org/wiki/Q1257738","display_name":"Agglomerate","level":2,"score":0.2994999885559082},{"id":"https://openalex.org/C47908070","wikidata":"https://www.wikidata.org/wiki/Q900515","display_name":"Grain boundary","level":3,"score":0.2660999894142151}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1134/s2070050426700340","doi":"https://doi.org/10.1134/s2070050426700340","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s2070050426700340","pdf_url":null,"source":{"id":"https://openalex.org/S182539911","display_name":"Catalysis in Industry","issn_l":"2070-0504","issn":["2070-0504","2070-0555"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Catalysis in Industry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":20,"referenced_works":["https://openalex.org/W58267224","https://openalex.org/W1504193762","https://openalex.org/W1556491460","https://openalex.org/W1967991486","https://openalex.org/W2000034923","https://openalex.org/W2000737244","https://openalex.org/W2000789418","https://openalex.org/W2002056951","https://openalex.org/W2014683962","https://openalex.org/W2016678881","https://openalex.org/W2038219778","https://openalex.org/W2045947726","https://openalex.org/W2062227298","https://openalex.org/W2079607981","https://openalex.org/W2085366032","https://openalex.org/W2914236996","https://openalex.org/W4252976654","https://openalex.org/W4293029395","https://openalex.org/W4317930501","https://openalex.org/W7121390454"],"related_works":["https://openalex.org/W3087085293","https://openalex.org/W2053265088","https://openalex.org/W4408924001","https://openalex.org/W7121390454","https://openalex.org/W4409462803","https://openalex.org/W4414589583","https://openalex.org/W3177389731","https://openalex.org/W1990202555","https://openalex.org/W4293029395","https://openalex.org/W2017878042"],"abstract_inverted_index":{"Abstract":[0],"The":[1,94,147,230],"role":[2],"of":[3,9,20,61,66,100,106,128,139,150,162,169,175,182,193,197,209,223,232],"Rh2O3":[4,84,176,217],"oxides":[5],"and":[6,53,63,111,172],"the":[7,13,18,64,70,101,121,126,143,160,173,186,191,215,242,246],"reaction":[8,65],"NH3":[10,27,67,77,90,151,198,237],"molecules":[11,68],"with":[12,29,69,136,166,179,206,220],"rhodium":[14,33,62,71,108,144,187],"oxide":[15,72,85,129,164,204],"oxygen":[16,73],"in":[17],"formation":[19,161,231],"an":[21],"etching":[22,234],"layer":[23],"on":[24,31,79,92,131,142,185,214,227],"Rh":[25,133],"during":[26,76,89,236],"oxidation":[28,60,78,91,152,196,238],"air":[30],"polycrystalline":[32],"(Rh(poly))":[34],"at":[35],"1133":[36],"K":[37],"has":[38],"been":[39],"identified":[40],"using":[41],"X-ray":[42,45,55],"diffraction":[43],"(XRD),":[44],"photoelectron":[46],"spectroscopy":[47,56],"(XPS),":[48],"scanning":[49],"electron":[50],"microscopy":[51],"(SEM),":[52],"energy-dispersive":[54],"(EDS)":[57],"methods.":[58],"Vigorous":[59],"simultaneously":[74],"occur":[75,240],"Rh(poly).":[80,93],"According":[81],"to":[82],"XPS,":[83],"layers":[86,130],"are":[87,212],"formed":[88,213],"XRD":[95],"data":[96,124],"yield":[97],"similar":[98],"values":[99],"fcc":[102],"cell":[103],"parameter":[104],"a":[105,137,167,180,194,207,221],"metallic":[107,132],"(3.802\u22123.803":[109],"\u00c5)":[110],"coherent":[112],"scattering":[113],"region":[114],"(CSR)":[115],"D":[116],"(39\u221255":[117],"nm)":[118],"for":[119],"all":[120],"samples.":[122],"These":[123],"indicate":[125],"presence":[127],"containing":[134],"subgrains":[135],"size":[138,168,208],"39\u221255":[140],"nm":[141,184],"grain":[145,188],"biundaries.":[146,189],"initial":[148],"stage":[149],"(t":[153,199],"\u2264":[154],"1":[155],"h)":[156],"is":[157],"characterized":[158],"by":[159],"porous":[163],"agglomerates":[165,205],"~0.7":[170],"\u03bcm":[171,211,225],"growth":[174],"crystalline":[177,218],"fibers":[178],"diameter":[181],"50\u2212100":[183],"In":[190],"case":[192],"long-term":[195],"\u2265":[200],"10":[201],"h),":[202],"lamellar":[203],"0.5\u22121.0":[210],"surface;":[216],"pyramids":[219],"height":[222],"1\u22122":[224],"grow":[226],"these":[228,233],"agglomerates.":[229],"structures":[235],"can":[239],"through":[241],"gas":[243],"phase":[244],"via":[245],"vapor\u2013liquid\u2013crystal":[247],"(VLC)":[248],"mechanism.":[249]},"counts_by_year":[],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2026-11-10T00:00:00"}