{"id":"https://openalex.org/W7225618888","doi":"https://doi.org/10.4314/bcse.v41i1.13","title":"Thermochemistry of anticancer active molecules: Enthalpies of solution, solvation, and sublimation/vaporization for phenyl acetate and para substituted phenyl benzoate compounds","display_name":"Thermochemistry of anticancer active molecules: Enthalpies of solution, solvation, and sublimation/vaporization for phenyl acetate and para substituted phenyl benzoate compounds","publication_year":2026,"publication_date":"2026-11-09","ids":{"openalex":"https://openalex.org/W7225618888","doi":"https://doi.org/10.4314/bcse.v41i1.13"},"language":"en","primary_location":{"id":"doi:10.4314/bcse.v41i1.13","doi":"https://doi.org/10.4314/bcse.v41i1.13","is_oa":true,"landing_page_url":"https://doi.org/10.4314/bcse.v41i1.13","pdf_url":null,"source":{"id":"https://openalex.org/S170147049","display_name":"Bulletin of the Chemical Society of Ethiopia","issn_l":"1011-3924","issn":["1011-3924","1726-801X"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-scientific","cwts-core","doaj","dongbi-d","jpps-2","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310311046","host_organization_name":"Chemical Society of Ethiopia","host_organization_lineage":["https://openalex.org/P4310311046"],"host_organization_lineage_names":["Chemical Society of Ethiopia"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Bulletin of the Chemical Society of Ethiopia","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://doi.org/10.4314/bcse.v41i1.13","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5161359087","display_name":"Rawand Samad","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Rawand Samad","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5161359087"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"41","issue":"1","first_page":"191","last_page":"206"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12852","display_name":"Chemical Thermodynamics and Molecular Structure","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12852","display_name":"Chemical Thermodynamics and Molecular Structure","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13539","display_name":"thermodynamics and calorimetric analyses","score":0.0006000000284984708,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11881","display_name":"Crystallization and Solubility Studies","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phenyl-esters","display_name":"phenyl esters","score":0.8550000190734863},{"id":"https://openalex.org/keywords/phenyl-acetate","display_name":"phenyl acetate","score":0.9800000190734863},{"id":"https://openalex.org/keywords/enthalpy-of-solution","display_name":"enthalpy of solution","score":0.875},{"id":"https://openalex.org/keywords/solvation-enthalpy","display_name":"solvation enthalpy","score":0.9700000286102295},{"id":"https://openalex.org/keywords/evaporation-enthalpy","display_name":"evaporation enthalpy","score":0.9369999766349792},{"id":"https://openalex.org/keywords/enthalpy-of-sublimation","display_name":"enthalpy of sublimation","score":0.9679999947547913},{"id":"https://openalex.org/keywords/benzene-solution","display_name":"benzene solution","score":0.5889999866485596},{"id":"https://openalex.org/keywords/molar-refractivity","display_name":"molar refractivity","score":0.9229999780654907},{"id":"https://openalex.org/keywords/anticancer-agents","display_name":"anticancer agents","score":0.6729999780654907}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9399999976158142},{"id":"https://openalex.org/C29563950","wikidata":"https://www.wikidata.org/wiki/Q183410","display_name":"Thermochemistry","level":2,"score":0.8687999844551086},{"id":"https://openalex.org/C148093993","wikidata":"https://www.wikidata.org/wiki/Q739398","display_name":"Solvation","level":3,"score":0.8073999881744385},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.7721999883651733},{"id":"https://openalex.org/C202270520","wikidata":"https://www.wikidata.org/wiki/Q634314","display_name":"Calorimetry","level":2,"score":0.746999979019165},{"id":"https://openalex.org/C147368240","wikidata":"https://www.wikidata.org/wiki/Q721706","display_name":"Standard enthalpy of formation","level":2,"score":0.7376000285148621},{"id":"https://openalex.org/C205963292","wikidata":"https://www.wikidata.org/wiki/Q900787","display_name":"Enthalpy change of solution","level":3,"score":0.6787999868392944},{"id":"https://openalex.org/C79289859","wikidata":"https://www.wikidata.org/wiki/Q911664","display_name":"Standard enthalpy of reaction","level":3,"score":0.49970000982284546},{"id":"https://openalex.org/C60778519","wikidata":"https://www.wikidata.org/wiki/Q483538","display_name":"Enthalpy of vaporization","level":3,"score":0.462799996137619},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.4099999964237213},{"id":"https://openalex.org/C61441594","wikidata":"https://www.wikidata.org/wiki/Q132814","display_name":"Evaporation","level":2,"score":0.40380001068115234},{"id":"https://openalex.org/C59801894","wikidata":"https://www.wikidata.org/wiki/Q721706","display_name":"Standard enthalpy change of formation","level":3,"score":0.4027999937534332},{"id":"https://openalex.org/C132704077","wikidata":"https://www.wikidata.org/wiki/Q4531954","display_name":"Enthalpy of atomization","level":4,"score":0.3750999867916107},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3305000066757202},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3287999927997589},{"id":"https://openalex.org/C109663097","wikidata":"https://www.wikidata.org/wiki/Q182453","display_name":"Adiabatic process","level":2,"score":0.2973000109195709},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.26100000739097595},{"id":"https://openalex.org/C170961132","wikidata":"https://www.wikidata.org/wiki/Q745224","display_name":"Activity coefficient","level":3,"score":0.25999999046325684}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.4314/bcse.v41i1.13","doi":"https://doi.org/10.4314/bcse.v41i1.13","is_oa":true,"landing_page_url":"https://doi.org/10.4314/bcse.v41i1.13","pdf_url":null,"source":{"id":"https://openalex.org/S170147049","display_name":"Bulletin of the Chemical Society of Ethiopia","issn_l":"1011-3924","issn":["1011-3924","1726-801X"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-scientific","cwts-core","doaj","dongbi-d","jpps-2","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310311046","host_organization_name":"Chemical Society of Ethiopia","host_organization_lineage":["https://openalex.org/P4310311046"],"host_organization_lineage_names":["Chemical Society of Ethiopia"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Bulletin of the Chemical Society of Ethiopia","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.4314/bcse.v41i1.13","doi":"https://doi.org/10.4314/bcse.v41i1.13","is_oa":true,"landing_page_url":"https://doi.org/10.4314/bcse.v41i1.13","pdf_url":null,"source":{"id":"https://openalex.org/S170147049","display_name":"Bulletin of the Chemical Society of Ethiopia","issn_l":"1011-3924","issn":["1011-3924","1726-801X"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-scientific","cwts-core","doaj","dongbi-d","jpps-2","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310311046","host_organization_name":"Chemical Society of Ethiopia","host_organization_lineage":["https://openalex.org/P4310311046"],"host_organization_lineage_names":["Chemical Society of Ethiopia"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Bulletin of the Chemical Society of Ethiopia","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W3001449809","https://openalex.org/W2077757562","https://openalex.org/W2742388482","https://openalex.org/W4308470512","https://openalex.org/W3047784655","https://openalex.org/W2526977150","https://openalex.org/W4407360510","https://openalex.org/W4415260613","https://openalex.org/W2330151492","https://openalex.org/W4382652155"],"abstract_inverted_index":{"The":[0,67],"solution,":[1,34],"solvation,":[2,35],"and":[3,12,29,36,83,100,115],"evaporation":[4,116,128],"enthalpies":[5,20,38],"of":[6,14,21,59,69,127,130],"phenyl":[7,23,41,61,105],"esters":[8,24,42,62],"indicate":[9],"the":[10,15,18,22,53,56,60,78,97,104,109,113,120,125,131],"stability":[11],"quality":[13],"molecules.":[16],"Therefore,":[17],"phase-transition":[19],"evaluate":[25],"molecular":[26],"activity,":[27],"efficiency,":[28],"stability.":[30],"In":[31,89],"this":[32,134],"work,":[33],"sublimation/vaporization":[37],"for":[39,96,108],"para-substituted":[40],"were":[43,136],"determined":[44,64],"using":[45,73],"adiabatic":[46],"solution":[47,57,84,114],"calorimetry":[48,85],"at":[49,86],"298.15":[50],"K.":[51],"For":[52],"first":[54,110],"time,":[55],"enthalpy":[58,68,94,117,129],"was":[63,71],"in":[65,103,133,138],"benzene.":[66],"solvation":[70,93],"estimated":[72],"an":[74],"additive":[75],"scheme":[76],"approach,":[77],"Abraham":[79],"model,":[80],"molar":[81],"refraction,":[82],"standard":[87,122],"temperature.":[88],"addition,":[90],"we":[91],"predicted":[92],"values":[95,126],"ethyl,":[98],"propyl,":[99],"butyl":[101],"groups":[102],"ester":[106],"compounds":[107,132],"time.":[111],"Additionally,":[112],"measurements":[118],"had":[119],"lowest":[121],"deviations.":[123],"Moreover,":[124],"work":[135],"discussed":[137],"comparison":[139],"with":[140],"those":[141],"literature":[142],"data.":[143],"KEY":[144],"WORDS:":[145],"Evaporation":[146],"enthalpy,":[147,149],"Solvation":[148],"Solution":[150],"calorimetry,":[151],"Phenyl":[152],"Ester":[153],"Bull.":[154],"Chem.":[155],"Soc.":[156],"Ethiop.":[157],"2027,":[158],"41(1),":[159],"191-206.":[160],"DOI:":[161],"https://dx.doi.org/10.4314/bcse.v41i1.13":[162]},"counts_by_year":[],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2026-11-10T00:00:00"}