{"id":"https://openalex.org/W7225598951","doi":"https://doi.org/10.1002/anie.3357957","title":"Radical C\u2500N Coupling at Electrified Carbon Nanotube Interfaces","display_name":"Radical C\u2500N Coupling at Electrified Carbon Nanotube Interfaces","publication_year":2026,"publication_date":"2026-11-08","ids":{"openalex":"https://openalex.org/W7225598951","doi":"https://doi.org/10.1002/anie.3357957","pmid":"https://pubmed.ncbi.nlm.nih.gov/42999970"},"language":"en","primary_location":{"id":"doi:10.1002/anie.3357957","doi":"https://doi.org/10.1002/anie.3357957","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.3357957","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.3357957","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.3357957","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5138403450","display_name":"Fuhua Qin","orcid":"https://orcid.org/0009-0008-8912-7070","observed_orcids":["https://orcid.org/0009-0008-8912-7070"]},"institutions":[{"id":"https://openalex.org/I183067930","display_name":"Shanghai Jiao Tong University","ror":"https://ror.org/0220qvk04","country_code":"CN","type":"education","lineage":["https://openalex.org/I183067930"]},{"id":"https://openalex.org/I4394709157","display_name":"Eastern Institute of Technology, Ningbo","ror":"https://ror.org/036mbz113","country_code":"CN","type":"education","lineage":["https://openalex.org/I4394709157"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Fuhua Qin","raw_affiliation_strings":["School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai China","School of the Environment and Sustainable Engineering Eastern Institute of Technology  Ningbo China"],"raw_orcid":"https://orcid.org/0009-0008-8912-7070","affiliations":[{"raw_affiliation_string":"School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai China","institution_ids":["https://openalex.org/I183067930"]},{"raw_affiliation_string":"School of the Environment and Sustainable Engineering Eastern Institute of Technology  Ningbo China","institution_ids":["https://openalex.org/I4394709157"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009705011","display_name":"Yanzi Shi","orcid":"https://orcid.org/0000-0002-7717-985X","observed_orcids":["https://orcid.org/0000-0002-7717-985X"]},"institutions":[{"id":"https://openalex.org/I183067930","display_name":"Shanghai Jiao Tong University","ror":"https://ror.org/0220qvk04","country_code":"CN","type":"education","lineage":["https://openalex.org/I183067930"]},{"id":"https://openalex.org/I4394709157","display_name":"Eastern Institute of Technology, Ningbo","ror":"https://ror.org/036mbz113","country_code":"CN","type":"education","lineage":["https://openalex.org/I4394709157"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yanzi Shi","raw_affiliation_strings":["School of Materials Science and Engineering Eastern Institute of Technology  Ningbo China","School of Materials Science and Engineering Shanghai Jiao Tong University  Shanghai China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Materials Science and Engineering Eastern Institute of Technology  Ningbo China","institution_ids":["https://openalex.org/I4394709157"]},{"raw_affiliation_string":"School of Materials Science and Engineering Shanghai Jiao Tong University  Shanghai China","institution_ids":["https://openalex.org/I183067930"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100400173","display_name":"Shuo Wang","orcid":"https://orcid.org/0000-0002-7907-9676","observed_orcids":["https://orcid.org/0000-0002-7907-9676"]},"institutions":[{"id":"https://openalex.org/I4394709157","display_name":"Eastern Institute of Technology, Ningbo","ror":"https://ror.org/036mbz113","country_code":"CN","type":"education","lineage":["https://openalex.org/I4394709157"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shuo Wang","raw_affiliation_strings":["School of Materials Science and Engineering Eastern Institute of Technology  Ningbo China"],"raw_orcid":"https://orcid.org/0000-0002-7907-9676","affiliations":[{"raw_affiliation_string":"School of Materials Science and Engineering Eastern Institute of Technology  Ningbo China","institution_ids":["https://openalex.org/I4394709157"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161266938","display_name":"Yuanlong Huang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4394709157","display_name":"Eastern Institute of Technology, Ningbo","ror":"https://ror.org/036mbz113","country_code":"CN","type":"education","lineage":["https://openalex.org/I4394709157"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuanlong Huang","raw_affiliation_strings":["School of the Environment and Sustainable Engineering Eastern Institute of Technology  Ningbo China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of the Environment and Sustainable Engineering Eastern Institute of Technology  Ningbo China","institution_ids":["https://openalex.org/I4394709157"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5077169016","display_name":"Yiming Qin","orcid":"https://orcid.org/0000-0002-1552-5139","observed_orcids":["https://orcid.org/0000-0002-1552-5139"]},"institutions":[{"id":"https://openalex.org/I4394709157","display_name":"Eastern Institute of Technology, Ningbo","ror":"https://ror.org/036mbz113","country_code":"CN","type":"education","lineage":["https://openalex.org/I4394709157"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yiming Qin","raw_affiliation_strings":["School of the Environment and Sustainable Engineering Eastern Institute of Technology  Ningbo China"],"raw_orcid":"https://orcid.org/0000-0002-1552-5139","affiliations":[{"raw_affiliation_string":"School of the Environment and Sustainable Engineering Eastern Institute of Technology  Ningbo China","institution_ids":["https://openalex.org/I4394709157"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5077169016"],"corresponding_institution_ids":["https://openalex.org/I4394709157"],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":null,"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10074","display_name":"Carbon Nanotubes in Composites","score":0.0024999999441206455,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.0017000000225380063,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbon-nanotubes","display_name":"carbon nanotubes","score":0.8460000157356262},{"id":"https://openalex.org/keywords/electrified-interfaces","display_name":"electrified interfaces","score":0.8090000152587891},{"id":"https://openalex.org/keywords/aniline-derivatives","display_name":"aniline derivatives","score":0.7279999852180481},{"id":"https://openalex.org/keywords/nitrogen-containing-heterocycles","display_name":"nitrogen heterocycles","score":0.8859999775886536},{"id":"https://openalex.org/keywords/interfacial-charge-transfer","display_name":"interfacial charge transfer","score":0.9369999766349792},{"id":"https://openalex.org/keywords/nitrogen-centered-radicals","display_name":"nitrogen-centered radicals","score":0.9129999876022339},{"id":"https://openalex.org/keywords/radical-intermediates","display_name":"radical intermediates","score":0.4909999966621399}],"concepts":[{"id":"https://openalex.org/C513720949","wikidata":"https://www.wikidata.org/wiki/Q1778729","display_name":"Carbon nanotube","level":2,"score":0.7045999765396118},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.6518999934196472},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5975000262260437},{"id":"https://openalex.org/C60799052","wikidata":"https://www.wikidata.org/wiki/Q46221","display_name":"Electric field","level":2,"score":0.5335000157356262},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.5253999829292297},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5042999982833862},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.491100013256073},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.44679999351501465},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.4422999918460846},{"id":"https://openalex.org/C2779244968","wikidata":"https://www.wikidata.org/wiki/Q186414","display_name":"Aniline","level":2,"score":0.3874000012874603},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.38580000400543213},{"id":"https://openalex.org/C96444392","wikidata":"https://www.wikidata.org/wiki/Q1993452","display_name":"Radical ion","level":3,"score":0.38190001249313354},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.37560001015663147},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.37439998984336853},{"id":"https://openalex.org/C202374169","wikidata":"https://www.wikidata.org/wiki/Q124291","display_name":"Electrical conductor","level":2,"score":0.3587999939918518},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3465000092983246},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.3409999907016754},{"id":"https://openalex.org/C188082385","wikidata":"https://www.wikidata.org/wiki/Q73792","display_name":"Charge (physics)","level":2,"score":0.3327000141143799},{"id":"https://openalex.org/C48424934","wikidata":"https://www.wikidata.org/wiki/Q898912","display_name":"Coupling reaction","level":3,"score":0.3312999904155731},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.32030001282691956},{"id":"https://openalex.org/C9652623","wikidata":"https://www.wikidata.org/wiki/Q190109","display_name":"Field (mathematics)","level":2,"score":0.3165999948978424},{"id":"https://openalex.org/C2777332933","wikidata":"https://www.wikidata.org/wiki/Q170409","display_name":"Functional group","level":3,"score":0.2996000051498413},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.29660001397132874},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.2906000018119812},{"id":"https://openalex.org/C2777619693","wikidata":"https://www.wikidata.org/wiki/Q539430","display_name":"Nanotube","level":3,"score":0.27459999918937683},{"id":"https://openalex.org/C83155894","wikidata":"https://www.wikidata.org/wiki/Q17073685","display_name":"Oxidative coupling of methane","level":3,"score":0.2728999853134155}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/anie.3357957","doi":"https://doi.org/10.1002/anie.3357957","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.3357957","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.3357957","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:42999970","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42999970","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1002/anie.3357957","doi":"https://doi.org/10.1002/anie.3357957","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.3357957","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.3357957","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1444814963","display_name":null,"funder_award_id":"42405106","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G6290978785","display_name":null,"funder_award_id":"42405095","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7225598951.pdf","grobid_xml":"https://content.openalex.org/works/W7225598951.grobid-xml"},"referenced_works_count":48,"referenced_works":["https://openalex.org/W1968540065","https://openalex.org/W2003156636","https://openalex.org/W2009164158","https://openalex.org/W2077782725","https://openalex.org/W2097148620","https://openalex.org/W2137890896","https://openalex.org/W2292472768","https://openalex.org/W2510283575","https://openalex.org/W2512351034","https://openalex.org/W2520813356","https://openalex.org/W2546614251","https://openalex.org/W2569012662","https://openalex.org/W2789366878","https://openalex.org/W2808322721","https://openalex.org/W2813373686","https://openalex.org/W2889401928","https://openalex.org/W2894687639","https://openalex.org/W2894907979","https://openalex.org/W2912162704","https://openalex.org/W2948327457","https://openalex.org/W2953222240","https://openalex.org/W3043384614","https://openalex.org/W3086436553","https://openalex.org/W3173946883","https://openalex.org/W4240675387","https://openalex.org/W4292937804","https://openalex.org/W4298616245","https://openalex.org/W4310565737","https://openalex.org/W4383498093","https://openalex.org/W4390908189","https://openalex.org/W4396506915","https://openalex.org/W4400538964","https://openalex.org/W4400978284","https://openalex.org/W4401207857","https://openalex.org/W4401744866","https://openalex.org/W4404756382","https://openalex.org/W4406437545","https://openalex.org/W4408322626","https://openalex.org/W4410886516","https://openalex.org/W4411084135","https://openalex.org/W4412638155","https://openalex.org/W4413112008","https://openalex.org/W4414664063","https://openalex.org/W4414941470","https://openalex.org/W4415450075","https://openalex.org/W7125513067","https://openalex.org/W7131273985","https://openalex.org/W7154942052"],"related_works":["https://openalex.org/W2018886946","https://openalex.org/W4410831465","https://openalex.org/W4283591224","https://openalex.org/W4403302356","https://openalex.org/W1983645627","https://openalex.org/W2742628252","https://openalex.org/W2016568432","https://openalex.org/W2096176363","https://openalex.org/W2031158742","https://openalex.org/W2521932480"],"abstract_inverted_index":{"Nitrogen-containing":[0],"motifs":[1],"are":[2],"central":[3],"to":[4,99],"pharmaceuticals,":[5],"materials,":[6],"and":[7,18,40,75],"bioactive":[8],"molecules,":[9],"yet":[10],"controlling":[11],"radical":[12,34,87,100,119],"C\u2500N":[13,35],"bond":[14],"formation":[15],"under":[16,44,122],"mild":[17],"catalyst-free":[19],"conditions":[20],"remains":[21],"challenging.":[22],"Here,":[23],"we":[24],"report":[25],"an":[26,123],"electrified":[27],"carbon":[28],"nanotube":[29],"(CNT)":[30],"interface":[31],"that":[32,50,92,113],"promotes":[33],"coupling":[36,57],"of":[37,58],"aniline":[38],"derivatives":[39],"N-containing":[41],"heterocyclic":[42],"compounds":[43],"ambient":[45],"conditions.":[46],"Mechanistic":[47],"experiments":[48],"show":[49],"the":[51,56,59,68,93,97,108],"enhanced":[52],"reactivity":[53],"arises":[54],"from":[55],"applied":[60,94,125],"electric":[61,126],"field":[62,95],"with":[63],"interfacial":[64],"charge":[65],"transfer":[66],"through":[67],"CNT":[69],"network.":[70],"Radical":[71],"trapping,":[72],"redox":[73],"probing,":[74],"density":[76],"functional":[77],"theory":[78],"calculations":[79],"support":[80],"a":[81],"field-assisted":[82],"electron-transfer":[83],"pathway":[84],"involving":[85],"nitrogen-centered":[86],"intermediates.":[88],"Our":[89],"results":[90],"indicate":[91],"lowers":[96],"barrier":[98],"generation,":[101],"underscoring":[102],"its":[103],"critical":[104],"role":[105],"in":[106],"enabling":[107],"reaction.":[109],"This":[110],"work":[111],"demonstrates":[112],"conductive":[114],"nanointerfaces":[115],"can":[116],"enable":[117],"localized":[118],"bond-forming":[120],"chemistry":[121],"externally":[124],"field.":[127]},"counts_by_year":[],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2026-11-09T00:00:00"}