{"id":"https://openalex.org/W7225464200","doi":"https://doi.org/10.1021/acsnano.6c19623","title":"Unusual CD-ee Dependence in Self-Assembled Chiral Nanocomposites through Nanoparticle-Mediated Interactions","display_name":"Unusual CD-ee Dependence in Self-Assembled Chiral Nanocomposites through Nanoparticle-Mediated Interactions","publication_year":2026,"publication_date":"2026-11-07","ids":{"openalex":"https://openalex.org/W7225464200","doi":"https://doi.org/10.1021/acsnano.6c19623"},"language":"en","primary_location":{"id":"doi:10.1021/acsnano.6c19623","doi":"https://doi.org/10.1021/acsnano.6c19623","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsnano.6c19623","pdf_url":null,"source":{"id":"https://openalex.org/S145476921","display_name":"ACS Nano","issn_l":"1936-0851","issn":["1936-0851","1936-086X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Nano","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5161222600","display_name":"Caikun Cheng","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154099455","display_name":"Shandong University","ror":"https://ror.org/0207yh398","country_code":"CN","type":"education","lineage":["https://openalex.org/I154099455"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Caikun Cheng","raw_affiliation_strings":["Shandong University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shandong University , , ,","institution_ids":["https://openalex.org/I154099455"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5136455737","display_name":"Rongjuan Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154099455","display_name":"Shandong University","ror":"https://ror.org/0207yh398","country_code":"CN","type":"education","lineage":["https://openalex.org/I154099455"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Rongjuan Liu","raw_affiliation_strings":["Shandong University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shandong University , , ,","institution_ids":["https://openalex.org/I154099455"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161177888","display_name":"Zongze Zhang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154099455","display_name":"Shandong University","ror":"https://ror.org/0207yh398","country_code":"CN","type":"education","lineage":["https://openalex.org/I154099455"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zongze Zhang","raw_affiliation_strings":["Shandong University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shandong University , , ,","institution_ids":["https://openalex.org/I154099455"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016952275","display_name":"Jingjing Wei","orcid":"https://orcid.org/0000-0002-2197-8062","observed_orcids":["https://orcid.org/0000-0002-2197-8062"]},"institutions":[{"id":"https://openalex.org/I154099455","display_name":"Shandong University","ror":"https://ror.org/0207yh398","country_code":"CN","type":"education","lineage":["https://openalex.org/I154099455"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jingjing Wei","raw_affiliation_strings":["Shandong University , , ,","Shenzhen Research Institute of Shandong University , ,"],"raw_orcid":"https://orcid.org/0000-0002-2197-8062","affiliations":[{"raw_affiliation_string":"Shandong University , , ,","institution_ids":["https://openalex.org/I154099455"]},{"raw_affiliation_string":"Shenzhen Research Institute of Shandong University , ,","institution_ids":["https://openalex.org/I154099455"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100738627","display_name":"Fenghua Zhang","orcid":"https://orcid.org/0009-0005-6590-6545","observed_orcids":["https://orcid.org/0009-0005-6590-6545","https://orcid.org/0009-0001-6012-5118"]},"institutions":[{"id":"https://openalex.org/I154099455","display_name":"Shandong University","ror":"https://ror.org/0207yh398","country_code":"CN","type":"education","lineage":["https://openalex.org/I154099455"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Fenghua Zhang","raw_affiliation_strings":["Shandong University , , ,"],"raw_orcid":"https://orcid.org/0009-0005-6590-6545","affiliations":[{"raw_affiliation_string":"Shandong University , , ,","institution_ids":["https://openalex.org/I154099455"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5064341898","display_name":"Zhijie Yang","orcid":"https://orcid.org/0000-0002-5012-9852","observed_orcids":["https://orcid.org/0000-0002-5012-9852"]},"institutions":[{"id":"https://openalex.org/I154099455","display_name":"Shandong University","ror":"https://ror.org/0207yh398","country_code":"CN","type":"education","lineage":["https://openalex.org/I154099455"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Zhijie Yang","raw_affiliation_strings":["Shandong University , , ,"],"raw_orcid":"https://orcid.org/0000-0002-5012-9852","affiliations":[{"raw_affiliation_string":"Shandong University , , ,","institution_ids":["https://openalex.org/I154099455"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5064341898","https://openalex.org/A5100738627"],"corresponding_institution_ids":["https://openalex.org/I154099455"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11419","display_name":"Supramolecular Self-Assembly in Materials","score":0.3393999934196472,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11419","display_name":"Supramolecular Self-Assembly in Materials","score":0.3393999934196472,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.2240000069141388,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10131","display_name":"Gold and Silver Nanoparticles Synthesis and Applications","score":0.09309999644756317,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/circular-dichroism","display_name":"circular dichroism","score":0.9290000200271606},{"id":"https://openalex.org/keywords/enantiomeric-excess","display_name":"enantiomeric excess","score":0.9340000152587891},{"id":"https://openalex.org/keywords/gold-nanoparticles","display_name":"gold nanoparticles","score":0.9990000128746033},{"id":"https://openalex.org/keywords/supramolecular-self-assembly","display_name":"supramolecular self-assembly","score":0.921999990940094},{"id":"https://openalex.org/keywords/chiral-recognition","display_name":"chiral recognition","score":0.7390000224113464},{"id":"https://openalex.org/keywords/van-der-waals-forces","display_name":"van der Waals interactions","score":0.8410000205039978},{"id":"https://openalex.org/keywords/molecular-dynamics-simulation","display_name":"molecular dynamics simulation","score":0.6209999918937683}],"concepts":[{"id":"https://openalex.org/C126061179","wikidata":"https://www.wikidata.org/wiki/Q189627","display_name":"van der Waals force","level":3,"score":0.7379000186920166},{"id":"https://openalex.org/C2781379571","wikidata":"https://www.wikidata.org/wiki/Q423323","display_name":"Diimide","level":4,"score":0.723800003528595},{"id":"https://openalex.org/C93275456","wikidata":"https://www.wikidata.org/wiki/Q756449","display_name":"Supramolecular chemistry","level":3,"score":0.6581000089645386},{"id":"https://openalex.org/C104819515","wikidata":"https://www.wikidata.org/wiki/Q900961","display_name":"Colloidal gold","level":3,"score":0.585099995136261},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5521000027656555},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.550000011920929},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5479999780654907},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5425000190734863},{"id":"https://openalex.org/C2779189646","wikidata":"https://www.wikidata.org/wiki/Q417674","display_name":"Perylene","level":3,"score":0.5311999917030334},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.4505999982357025},{"id":"https://openalex.org/C486523","wikidata":"https://www.wikidata.org/wiki/Q494483","display_name":"Enantiomer","level":2,"score":0.40869998931884766},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3846000134944916},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.34880000352859497},{"id":"https://openalex.org/C137277065","wikidata":"https://www.wikidata.org/wiki/Q2915446","display_name":"Non-covalent interactions","level":4,"score":0.34060001373291016},{"id":"https://openalex.org/C92880739","wikidata":"https://www.wikidata.org/wiki/Q2639556","display_name":"Nanocomposite","level":2,"score":0.3314000070095062},{"id":"https://openalex.org/C192406513","wikidata":"https://www.wikidata.org/wiki/Q2427921","display_name":"Supramolecular assembly","level":4,"score":0.31439998745918274},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.31220000982284546},{"id":"https://openalex.org/C53105671","wikidata":"https://www.wikidata.org/wiki/Q14777816","display_name":"Rational design","level":2,"score":0.3012000024318695},{"id":"https://openalex.org/C158622935","wikidata":"https://www.wikidata.org/wiki/Q660848","display_name":"Nonlinear system","level":2,"score":0.29910001158714294},{"id":"https://openalex.org/C26856880","wikidata":"https://www.wikidata.org/wiki/Q910150","display_name":"Self-assembly","level":2,"score":0.2840999960899353},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.26600000262260437},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.26350000500679016},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.2621999979019165},{"id":"https://openalex.org/C130929614","wikidata":"https://www.wikidata.org/wiki/Q7644706","display_name":"Supramolecular polymers","level":4,"score":0.2572000026702881}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acsnano.6c19623","doi":"https://doi.org/10.1021/acsnano.6c19623","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsnano.6c19623","pdf_url":null,"source":{"id":"https://openalex.org/S145476921","display_name":"ACS Nano","issn_l":"1936-0851","issn":["1936-0851","1936-086X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Nano","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320322769","display_name":"Natural Science Foundation of Jiangsu Province","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320326189","display_name":"Taishan Scholar Project of Shandong Province","ror":null}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":51,"referenced_works":["https://openalex.org/W1964395161","https://openalex.org/W1966078827","https://openalex.org/W1978174691","https://openalex.org/W2003949305","https://openalex.org/W2019269997","https://openalex.org/W2027391007","https://openalex.org/W2032603982","https://openalex.org/W2065618769","https://openalex.org/W2069768729","https://openalex.org/W2080877087","https://openalex.org/W2134235045","https://openalex.org/W2139489702","https://openalex.org/W2147367474","https://openalex.org/W2158743397","https://openalex.org/W2318708806","https://openalex.org/W2334178294","https://openalex.org/W2415956020","https://openalex.org/W2529556931","https://openalex.org/W2563237063","https://openalex.org/W2601387812","https://openalex.org/W2797295904","https://openalex.org/W2891451125","https://openalex.org/W2945016021","https://openalex.org/W2945911360","https://openalex.org/W2977941338","https://openalex.org/W2980756966","https://openalex.org/W3021101949","https://openalex.org/W3082067964","https://openalex.org/W3115155858","https://openalex.org/W3123165572","https://openalex.org/W3135226753","https://openalex.org/W3182372257","https://openalex.org/W4206202563","https://openalex.org/W4381681883","https://openalex.org/W4389671830","https://openalex.org/W4390814565","https://openalex.org/W4391256272","https://openalex.org/W4395480469","https://openalex.org/W4402641541","https://openalex.org/W4403750541","https://openalex.org/W4405580752","https://openalex.org/W4406001168","https://openalex.org/W4406150980","https://openalex.org/W4407636289","https://openalex.org/W4409414419","https://openalex.org/W4410826024","https://openalex.org/W4413779133","https://openalex.org/W4414747573","https://openalex.org/W4415149006","https://openalex.org/W4415808347","https://openalex.org/W7133498317"],"related_works":["https://openalex.org/W4207038740","https://openalex.org/W7220845736","https://openalex.org/W4206796478","https://openalex.org/W4405455182","https://openalex.org/W3108266648","https://openalex.org/W3082067964","https://openalex.org/W3178387407","https://openalex.org/W1985469696","https://openalex.org/W3115155858","https://openalex.org/W4391176674"],"abstract_inverted_index":{"Abstract":[0],"Supramolecular":[1],"self-assembly":[2],"can":[3,95],"produce":[4],"a":[5,8,34,63,70,80,101,144,157],"linear":[6,50],"or":[7],"positive":[9,81,90],"nonlinear":[10,30],"CD":[11],"versus":[12],"enantiomeric":[13],"excess":[14],"(ee)":[15],"relationship.":[16],"Negative":[17],"\u201cracemate":[18],"rules\u201d":[19],"behavior":[20,52],"is":[21],"rare.":[22],"In":[23,46],"this":[24],"work,":[25],"we":[26],"report":[27],"an":[28],"unusual":[29],"CD-ee":[31,72,93],"dependence":[32],"in":[33,153],"coassembly":[35],"system":[36],"comprising":[37],"chiral":[38,119,162],"perylene":[39],"diimide":[40],"molecules":[41,124],"and":[42,79,91,97,109],"gold":[43],"nanoparticles":[44,116,148],"(AuNPs).":[45],"contrast":[47],"to":[48,69],"the":[49,58,115,118,133,138],"majority-rules":[51,139],"observed":[53],"for":[54,160],"pure":[55],"PDI":[56,123],"molecules,":[57],"introduction":[59],"of":[60,122],"AuNPs":[61],"induces":[62],"tendency":[64],"toward":[65],"heterochiral":[66],"coaggregation,":[67],"leading":[68],"negative":[71,92],"correlation":[73,82],"at":[74,83],"low":[75],"temperature":[76,85,135],"(278":[77],"K)":[78],"high":[84],"(318":[86],"K).":[87],"Even":[88],"both":[89],"correlations":[94],"coexist":[96],"be":[98],"tuned":[99],"within":[100],"single":[102],"self-assembling":[103],"system.":[104],"Combined":[105],"molecular":[106],"dynamics":[107],"simulations":[108],"preassembly":[110],"control":[111],"experiments":[112],"demonstrate":[113],"that":[114],"reshape":[117],"recognition":[120],"pathway":[121],"through":[125],"alkyl":[126],"chain\u2013chain":[127],"van":[128],"der":[129],"Waals":[130],"interactions,":[131],"while":[132],"assembly":[134],"further":[136],"modulates":[137],"behavior.":[140],"This":[141],"work":[142],"reveals":[143],"mechanism":[145],"by":[146],"which":[147],"act":[149],"as":[150],"regulatory":[151],"units":[152],"supramolecular":[154],"chirality,":[155],"offering":[156],"design":[158],"strategy":[159],"programmable":[161],"materials.":[163]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-11-08T00:00:00"}