{"id":"https://openalex.org/W7225411526","doi":"https://doi.org/10.3390/catal16110988","title":"Boron-Accelerated Fe3+/Fe2+ Recycling Enhances Periodate Activation for Sulfamethazine Degradation","display_name":"Boron-Accelerated Fe3+/Fe2+ Recycling Enhances Periodate Activation for Sulfamethazine Degradation","publication_year":2026,"publication_date":"2026-11-06","ids":{"openalex":"https://openalex.org/W7225411526","doi":"https://doi.org/10.3390/catal16110988"},"language":"en","primary_location":{"id":"doi:10.3390/catal16110988","doi":"https://doi.org/10.3390/catal16110988","is_oa":true,"landing_page_url":"https://doi.org/10.3390/catal16110988","pdf_url":null,"source":{"id":"https://openalex.org/S2738539744","display_name":"Catalysts","issn_l":"2073-4344","issn":["2073-4344"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Catalysts","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.3390/catal16110988","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5040173318","display_name":"Zhuoyu Bu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I204710742","display_name":"Ministry of Ecology and Environment","ror":"https://ror.org/04gwbew76","country_code":"CN","type":"government","lineage":["https://openalex.org/I204710742"]},{"id":"https://openalex.org/I4210166709","display_name":"Nanjing Institute of Environmental Sciences","ror":"https://ror.org/05ycd7562","country_code":"CN","type":"facility","lineage":["https://openalex.org/I204710742","https://openalex.org/I4210166709"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhuoyu Bu","raw_affiliation_strings":["Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China","institution_ids":["https://openalex.org/I204710742","https://openalex.org/I4210166709"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161040888","display_name":"Nanhao Xu","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Nanhao Xu","raw_affiliation_strings":["Hangzhou Environmental Protection & Scientific Research Design Co., Ltd., Hangzhou 310000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Hangzhou Environmental Protection & Scientific Research Design Co., Ltd., Hangzhou 310000, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161012336","display_name":"Wei Wang","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Wei Wang","raw_affiliation_strings":["Zhejiang Huanyao Environmental Construction Co., Ltd., Hangzhou 310000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Huanyao Environmental Construction Co., Ltd., Hangzhou 310000, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5161112897","display_name":"Shang Gao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I204710742","display_name":"Ministry of Ecology and Environment","ror":"https://ror.org/04gwbew76","country_code":"CN","type":"government","lineage":["https://openalex.org/I204710742"]},{"id":"https://openalex.org/I4210166709","display_name":"Nanjing Institute of Environmental Sciences","ror":"https://ror.org/05ycd7562","country_code":"CN","type":"facility","lineage":["https://openalex.org/I204710742","https://openalex.org/I4210166709"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Shang Gao","raw_affiliation_strings":["Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China","institution_ids":["https://openalex.org/I204710742","https://openalex.org/I4210166709"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5026999902","display_name":"Yuwei Pan","orcid":"https://orcid.org/0000-0001-5939-8613","observed_orcids":["https://orcid.org/0000-0001-5939-8613"]},"institutions":[{"id":"https://openalex.org/I167027274","display_name":"Nanjing Forestry University","ror":"https://ror.org/03m96p165","country_code":"CN","type":"education","lineage":["https://openalex.org/I167027274"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yuwei Pan","raw_affiliation_strings":["College of Ecology and Environment, Nanjing Forestry University, Nanjing 210037, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Ecology and Environment, Nanjing Forestry University, Nanjing 210037, China","institution_ids":["https://openalex.org/I167027274"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5026999902","https://openalex.org/A5161112897"],"corresponding_institution_ids":["https://openalex.org/I167027274","https://openalex.org/I204710742","https://openalex.org/I4210166709"],"apc_list":{"value":2200,"currency":"CHF","value_usd":2654},"apc_paid":{"value":2200,"currency":"CHF","value_usd":2654},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"16","issue":"11","first_page":"988","last_page":"988"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12078","display_name":"Environmental remediation with nanomaterials","score":0.0010000000474974513,"subfield":{"id":"https://openalex.org/subfields/2305","display_name":"Environmental Engineering"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sulfamethazine-degradation","display_name":"sulfamethazine degradation","score":0.9309999942779541},{"id":"https://openalex.org/keywords/periodate-activation","display_name":"periodate activation","score":0.9110000133514404},{"id":"https://openalex.org/keywords/elemental-boron","display_name":"elemental boron","score":0.796999990940094},{"id":"https://openalex.org/keywords/fe3-fe2-redox-cycling","display_name":"Fe3+/Fe2+ redox cycling","score":0.9710000157356262},{"id":"https://openalex.org/keywords/hydroxyl-radical-production","display_name":"hydroxyl radical generation","score":0.828000009059906},{"id":"https://openalex.org/keywords/antibiotic-removal-from-water","display_name":"antibiotic removal from water","score":0.6970000267028809},{"id":"https://openalex.org/keywords/transformation-intermediates","display_name":"transformation intermediates","score":0.9129999876022339},{"id":"https://openalex.org/keywords/degradation-pathways","display_name":"degradation pathways","score":0.7919999957084656},{"id":"https://openalex.org/keywords/b-b-bonds","display_name":"B\u2013B bonds","score":0.5759999752044678},{"id":"https://openalex.org/keywords/radical-quenching","display_name":"radical quenching","score":0.5649999976158142}],"concepts":[{"id":"https://openalex.org/C2776789926","wikidata":"https://www.wikidata.org/wiki/Q417139","display_name":"Periodate","level":2,"score":0.7860000133514404},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7742999792098999},{"id":"https://openalex.org/C2779679103","wikidata":"https://www.wikidata.org/wiki/Q5251805","display_name":"Degradation (telecommunications)","level":2,"score":0.6877999901771545},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5884000062942505},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.5823000073432922},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5012000203132629},{"id":"https://openalex.org/C121745418","wikidata":"https://www.wikidata.org/wiki/Q585536","display_name":"Quenching (fluorescence)","level":3,"score":0.4239000082015991},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.39739999175071716},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.3598000109195709},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.34139999747276306},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.335099995136261},{"id":"https://openalex.org/C501308230","wikidata":"https://www.wikidata.org/wiki/Q618","display_name":"Boron","level":2,"score":0.33500000834465027},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.32420000433921814},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.29899999499320984},{"id":"https://openalex.org/C157021035","wikidata":"https://www.wikidata.org/wiki/Q696715","display_name":"Biodegradation","level":2,"score":0.298799991607666},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.2953999936580658},{"id":"https://openalex.org/C2778148179","wikidata":"https://www.wikidata.org/wiki/Q911571","display_name":"Electron donor","level":3,"score":0.28870001435279846},{"id":"https://openalex.org/C2778591166","wikidata":"https://www.wikidata.org/wiki/Q484152","display_name":"Oxidation state","level":3,"score":0.26089999079704285}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.3390/catal16110988","doi":"https://doi.org/10.3390/catal16110988","is_oa":true,"landing_page_url":"https://doi.org/10.3390/catal16110988","pdf_url":null,"source":{"id":"https://openalex.org/S2738539744","display_name":"Catalysts","issn_l":"2073-4344","issn":["2073-4344"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Catalysts","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.3390/catal16110988","doi":"https://doi.org/10.3390/catal16110988","is_oa":true,"landing_page_url":"https://doi.org/10.3390/catal16110988","pdf_url":null,"source":{"id":"https://openalex.org/S2738539744","display_name":"Catalysts","issn_l":"2073-4344","issn":["2073-4344"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310310987","host_organization_name":"Multidisciplinary Digital Publishing Institute","host_organization_lineage":["https://openalex.org/P4310310987"],"host_organization_lineage_names":["Multidisciplinary Digital Publishing Institute"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Catalysts","raw_type":"journal-article"},"sustainable_development_goals":[{"score":0.965499997138977,"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6"},{"score":0.8799999952316284,"display_name":"Responsible consumption and production","id":"https://metadata.un.org/sdg/12"}],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322769","display_name":"Natural Science Foundation of Jiangsu Province","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W1965399035","https://openalex.org/W1978568671","https://openalex.org/W2009989575","https://openalex.org/W2042066659","https://openalex.org/W2173348792","https://openalex.org/W2287748332","https://openalex.org/W2331715140","https://openalex.org/W2756636171","https://openalex.org/W2797208558","https://openalex.org/W2951280635","https://openalex.org/W3008560914","https://openalex.org/W3017277606","https://openalex.org/W3042858448","https://openalex.org/W3096374481","https://openalex.org/W3134869145","https://openalex.org/W3194147595","https://openalex.org/W3209005928","https://openalex.org/W3213669988","https://openalex.org/W4200002079","https://openalex.org/W4213037304","https://openalex.org/W4281560188","https://openalex.org/W4291281060","https://openalex.org/W4292664266","https://openalex.org/W4309554296","https://openalex.org/W4318754697","https://openalex.org/W4366163470","https://openalex.org/W4379644423","https://openalex.org/W4385603532","https://openalex.org/W4385997993","https://openalex.org/W4387353037","https://openalex.org/W4391043310","https://openalex.org/W4392613379","https://openalex.org/W4394850774","https://openalex.org/W4401742116","https://openalex.org/W4402510753","https://openalex.org/W4406064743","https://openalex.org/W4407318245","https://openalex.org/W4413295395","https://openalex.org/W7082248079"],"related_works":["https://openalex.org/W4289813120","https://openalex.org/W4313200618","https://openalex.org/W4362704015","https://openalex.org/W4417067151","https://openalex.org/W7082248079","https://openalex.org/W7134916299","https://openalex.org/W4410529663","https://openalex.org/W4375955531","https://openalex.org/W4413031466","https://openalex.org/W3195806632"],"abstract_inverted_index":{"Elemental":[0],"boron,":[1],"an":[2,51],"eco-friendly":[3],"and":[4,59,80,93,111,165],"cost-effective":[5],"metalloid":[6],"reductant,":[7],"was":[8,87,96],"employed":[9],"as":[10,89,116],"a":[11,180],"reductive":[12],"co-catalyst":[13],"to":[14,47,119,122],"accelerate":[15],"Fe3+/Fe2+":[16,126],"redox":[17,127],"cycling":[18],"in":[19,161,188],"Fe2+-initiated":[20],"periodate":[21,177],"(PI)":[22],"activation":[23,178],"for":[24,143,185],"sulfamethazine":[25],"(SMT)":[26],"degradation.":[27],"The":[28,147],"standalone":[29],"Fe2+/PI":[30],"system":[31,44,149],"achieved":[32],"only":[33],"24.1%":[34],"SMT":[35,144],"elimination":[36],"within":[37],"30":[38],"min,":[39],"whereas":[40],"the":[41,73,90],"constructed":[42],"B/Fe2+/PI":[43,148],"delivered":[45],"up":[46],"97.7%":[48],"removal":[49],"under":[50],"extremely":[52],"low":[53],"iron":[54],"dosage":[55],"(10":[56],"\u03bcM":[57],"Fe2+)":[58],"acidic":[60],"condition":[61],"(pH":[62],"3.0).":[63],"Radical":[64],"quenching":[65],"assays":[66],"combined":[67],"with":[68,82],"molecular":[69],"probe":[70],"identification":[71],"revealed":[72],"co-existence":[74],"of":[75],"Fe(IV),":[76],"\u2022OH,":[77,83],"1O2,":[78],"O2\u2022\u2212,":[79],"IO3\u2022\u2212,":[81],"among":[84],"which":[85,139],"\u2022OH":[86],"identified":[88,133],"dominant":[91],"oxidant,":[92],"its":[94],"generation":[95],"notably":[97],"amplified":[98],"by":[99,134],"boron.":[100],"X-ray":[101],"photoelectron":[102],"spectroscopy":[103],"(XPS)":[104],"characterization":[105],"demonstrated":[106],"that":[107],"surface":[108],"B-B":[109],"bonds":[110],"low-valent":[112],"boron":[113],"moieties":[114],"act":[115],"electron":[117],"donors":[118],"reduce":[120],"Fe3+":[121],"Fe2+,":[123],"sustaining":[124],"continuous":[125],"turnover.":[128],"Eight":[129],"transformation":[130],"intermediates":[131],"were":[132,145],"mass":[135],"spectrometry,":[136],"based":[137],"on":[138],"plausible":[140],"degradation":[141],"pathways":[142],"proposed.":[146],"exhibited":[150],"robust":[151],"tolerance":[152],"against":[153],"prevalent":[154],"inorganic":[155],"anions,":[156],"maintained":[157],"favorable":[158],"catalytic":[159],"capability":[160],"natural":[162],"lake":[163],"water,":[164],"preserved":[166],"stable":[167],"performance":[168],"across":[169],"five":[170],"successive":[171],"recycling":[172],"runs.":[173],"Accordingly,":[174],"boron-augmented":[175],"Fe2+-triggered":[176],"represents":[179],"promising":[181],"low-iron":[182],"technical":[183],"paradigm":[184],"antibiotic":[186],"remediation":[187],"water":[189],"environments.":[190]},"counts_by_year":[],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2026-11-07T00:00:00"}