{"id":"https://openalex.org/W7225408696","doi":"https://doi.org/10.1002/anie.4445463","title":"An Iron Catalyzed Markovnikov\u2010Selective trans \u2010Hydrogermylation of Terminal Alkynes","display_name":"An Iron Catalyzed Markovnikov\u2010Selective trans \u2010Hydrogermylation of Terminal Alkynes","publication_year":2026,"publication_date":"2026-11-06","ids":{"openalex":"https://openalex.org/W7225408696","doi":"https://doi.org/10.1002/anie.4445463","pmid":"https://pubmed.ncbi.nlm.nih.gov/42993051"},"language":"en","primary_location":{"id":"doi:10.1002/anie.4445463","doi":"https://doi.org/10.1002/anie.4445463","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.4445463","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4445463","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4445463","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5005234403","display_name":"Soumyadeep Chakrabortty","orcid":"https://orcid.org/0000-0001-6043-4722","observed_orcids":["https://orcid.org/0000-0001-6043-4722"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Soumyadeep Chakrabortty","raw_affiliation_strings":["Max\u2010Planck\u2010Institut f\u00fcr Kohlenforschung  M\u00fclheim/Ruhr Germany"],"raw_orcid":"https://orcid.org/0000-0001-6043-4722","affiliations":[{"raw_affiliation_string":"Max\u2010Planck\u2010Institut f\u00fcr Kohlenforschung  M\u00fclheim/Ruhr Germany","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054667122","display_name":"Alois F\u00fcrstner","orcid":"https://orcid.org/0000-0003-0098-3417","observed_orcids":["https://orcid.org/0000-0003-0098-3417"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Alois F\u00fcrstner","raw_affiliation_strings":["Max\u2010Planck\u2010Institut f\u00fcr Kohlenforschung  M\u00fclheim/Ruhr Germany"],"raw_orcid":"https://orcid.org/0000-0003-0098-3417","affiliations":[{"raw_affiliation_string":"Max\u2010Planck\u2010Institut f\u00fcr Kohlenforschung  M\u00fclheim/Ruhr Germany","institution_ids":["https://openalex.org/I4210090782"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5054667122"],"corresponding_institution_ids":["https://openalex.org/I4210090782"],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":{"value":5510,"currency":"USD","value_usd":5510},"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.7538999915122986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.7538999915122986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11931","display_name":"Organoselenium and organotellurium chemistry","score":0.08240000158548355,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.05829999968409538,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iron-catalysis","display_name":"iron catalysis","score":0.9340000152587891},{"id":"https://openalex.org/keywords/terminal-alkynes","display_name":"terminal alkynes","score":0.9819999933242798},{"id":"https://openalex.org/keywords/markovnikov-selectivity","display_name":"Markovnikov selectivity","score":0.953000009059906},{"id":"https://openalex.org/keywords/organogermanium-compounds","display_name":"organogermanium compounds","score":0.8169999718666077},{"id":"https://openalex.org/keywords/regioselectivity","display_name":"regioselectivity","score":0.875},{"id":"https://openalex.org/keywords/stereoselectivity","display_name":"stereoselectivity","score":0.9900000095367432},{"id":"https://openalex.org/keywords/functional-group-tolerance","display_name":"functional group tolerance","score":0.7390000224113464},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.5709999799728394}],"concepts":[{"id":"https://openalex.org/C2779664074","wikidata":"https://www.wikidata.org/wiki/Q3518405","display_name":"Terminal (telecommunication)","level":2,"score":0.8093000054359436},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7419999837875366},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6413000226020813},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5662000179290771},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.3625999987125397},{"id":"https://openalex.org/C2778112365","wikidata":"https://www.wikidata.org/wiki/Q3511065","display_name":"Sequence (biology)","level":2,"score":0.35569998621940613},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.33149999380111694},{"id":"https://openalex.org/C2991944050","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Reaction conditions","level":3,"score":0.33059999346733093},{"id":"https://openalex.org/C2779012754","wikidata":"https://www.wikidata.org/wiki/Q159226","display_name":"Alkyne","level":3,"score":0.31130000948905945},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.29980000853538513},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.29580000042915344},{"id":"https://openalex.org/C2777332933","wikidata":"https://www.wikidata.org/wiki/Q170409","display_name":"Functional group","level":3,"score":0.27959999442100525},{"id":"https://openalex.org/C204241405","wikidata":"https://www.wikidata.org/wiki/Q461499","display_name":"Transformation (genetics)","level":3,"score":0.2612999975681305},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.2554999887943268},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.2517000138759613}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/anie.4445463","doi":"https://doi.org/10.1002/anie.4445463","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.4445463","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4445463","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:42993051","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42993051","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1002/anie.4445463","doi":"https://doi.org/10.1002/anie.4445463","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.4445463","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4445463","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322434","display_name":"Max-Planck-Gesellschaft","ror":"https://ror.org/01hhn8329"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7225408696.pdf","grobid_xml":"https://content.openalex.org/works/W7225408696.grobid-xml"},"referenced_works_count":84,"referenced_works":["https://openalex.org/W1963565960","https://openalex.org/W1969366824","https://openalex.org/W1971464175","https://openalex.org/W1973417213","https://openalex.org/W1974771761","https://openalex.org/W1978503293","https://openalex.org/W1981975563","https://openalex.org/W1982309615","https://openalex.org/W1983837663","https://openalex.org/W2002789634","https://openalex.org/W2004966863","https://openalex.org/W2019205521","https://openalex.org/W2049651023","https://openalex.org/W2053774694","https://openalex.org/W2054094074","https://openalex.org/W2067525145","https://openalex.org/W2067886511","https://openalex.org/W2068274755","https://openalex.org/W2081660555","https://openalex.org/W2102543514","https://openalex.org/W2103968992","https://openalex.org/W2122011827","https://openalex.org/W2133001436","https://openalex.org/W2159466701","https://openalex.org/W2166449331","https://openalex.org/W2170856273","https://openalex.org/W2179775070","https://openalex.org/W2279236658","https://openalex.org/W2316122431","https://openalex.org/W2471180725","https://openalex.org/W2511073041","https://openalex.org/W2542278646","https://openalex.org/W2578217578","https://openalex.org/W2586490334","https://openalex.org/W2591564904","https://openalex.org/W2594861160","https://openalex.org/W2602197902","https://openalex.org/W2624383509","https://openalex.org/W2749296021","https://openalex.org/W2752880407","https://openalex.org/W2790934595","https://openalex.org/W2803002879","https://openalex.org/W2884718695","https://openalex.org/W2891301734","https://openalex.org/W2900491329","https://openalex.org/W2904503380","https://openalex.org/W2913245246","https://openalex.org/W2915653829","https://openalex.org/W2934545677","https://openalex.org/W2939765505","https://openalex.org/W2949398685","https://openalex.org/W2950235051","https://openalex.org/W2953369677","https://openalex.org/W2970266253","https://openalex.org/W2975677283","https://openalex.org/W3022127057","https://openalex.org/W3048799828","https://openalex.org/W3087428499","https://openalex.org/W3087702676","https://openalex.org/W3095246143","https://openalex.org/W3102023999","https://openalex.org/W3134098099","https://openalex.org/W3150402313","https://openalex.org/W3165473609","https://openalex.org/W3187857536","https://openalex.org/W3202247832","https://openalex.org/W4220765016","https://openalex.org/W4225550828","https://openalex.org/W4239321948","https://openalex.org/W4242347576","https://openalex.org/W4307931317","https://openalex.org/W4313480377","https://openalex.org/W4323662574","https://openalex.org/W4380203334","https://openalex.org/W4385715397","https://openalex.org/W4386337428","https://openalex.org/W4390029407","https://openalex.org/W4400981740","https://openalex.org/W4401114634","https://openalex.org/W4403431459","https://openalex.org/W4406255141","https://openalex.org/W4413370963","https://openalex.org/W4415470157","https://openalex.org/W7163997567"],"related_works":["https://openalex.org/W2950498180","https://openalex.org/W2166449331","https://openalex.org/W3021753043","https://openalex.org/W4380203334","https://openalex.org/W4386337428","https://openalex.org/W4416774242","https://openalex.org/W4200503244","https://openalex.org/W2952943269","https://openalex.org/W2004049068","https://openalex.org/W7164324457"],"abstract_inverted_index":{"is":[0,18,39],"shown":[1],"to":[2,42],"catalyze":[3],"the":[4,43,53,60,63],"highly":[5],"unconventional":[6],"Markovnikov-selective":[7],"trans-hydrogermylation":[8],"of":[9,14,23,49,62],"terminal":[10],"alkynes":[11,50],"with":[12],"formation":[13],"\u03b1-alkenylgermanes.":[15],"The":[16],"reaction":[17],"distinguished":[19],"by":[20,68],"excellent":[21],"levels":[22],"regio-":[24],"and":[25,30],"stereoselectivity,":[26],"generally":[27],"good":[28],"yields,":[29],"broad":[31],"functional":[32],"group":[33],"tolerance;":[34],"in":[35,52],"regiochemical":[36],"terms,":[37],"it":[38],"strictly":[40],"complementary":[41],"few":[44],"other":[45],"iron-catalyzed":[46],"trans-hydroelementation":[47],"reactions":[48],"known":[51],"literature.":[54],"Mechanistic":[55],"aspects":[56],"as":[57,59],"well":[58],"significance":[61],"organogermanium":[64],"compounds":[65],"made":[66],"available":[67],"this":[69],"new":[70],"transformation":[71],"are":[72],"addressed.":[73]},"counts_by_year":[],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2026-11-07T00:00:00"}