{"id":"https://openalex.org/W7225336015","doi":"https://doi.org/10.1021/acs.orglett.6c04202","title":"Diastereoselective Radical Cascade via Dowd\u2013Beckwith-Type Ring Expansion: Modular Assembly of Fused Carbocycles","display_name":"Diastereoselective Radical Cascade via Dowd\u2013Beckwith-Type Ring Expansion: Modular Assembly of Fused Carbocycles","publication_year":2026,"publication_date":"2026-11-05","ids":{"openalex":"https://openalex.org/W7225336015","doi":"https://doi.org/10.1021/acs.orglett.6c04202"},"language":"en","primary_location":{"id":"doi:10.1021/acs.orglett.6c04202","doi":"https://doi.org/10.1021/acs.orglett.6c04202","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.orglett.6c04202","pdf_url":null,"source":{"id":"https://openalex.org/S201989124","display_name":"Organic Letters","issn_l":"1523-7052","issn":["1523-7052","1523-7060"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101749394","display_name":"Kolli Sai Prakash","orcid":"https://orcid.org/0000-0002-9067-6738","observed_orcids":["https://orcid.org/0000-0002-9067-6738"]},"institutions":[{"id":"https://openalex.org/I55664587","display_name":"Indian Institute of Chemical Technology","ror":"https://ror.org/040dky007","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I55664587","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Kolli Sai Prakash","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,","institution_ids":["https://openalex.org/I55664587","https://openalex.org/I66760702"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5114355155","display_name":"Maramoni Shivudu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I55664587","display_name":"Indian Institute of Chemical Technology","ror":"https://ror.org/040dky007","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I55664587","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Maramoni Shivudu","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,","institution_ids":["https://openalex.org/I55664587","https://openalex.org/I66760702"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002232579","display_name":"Anjali Rathaur","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I55664587","display_name":"Indian Institute of Chemical Technology","ror":"https://ror.org/040dky007","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I55664587","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Anjali Rathaur","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,","institution_ids":["https://openalex.org/I55664587","https://openalex.org/I66760702"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022809610","display_name":"Shiva Kumar Kota Balaji","orcid":"https://orcid.org/0009-0009-0993-8672","observed_orcids":["https://orcid.org/0009-0009-0993-8672"]},"institutions":[{"id":"https://openalex.org/I55664587","display_name":"Indian Institute of Chemical Technology","ror":"https://ror.org/040dky007","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I55664587","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Shiva Kumar Kota Balaji","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,","institution_ids":["https://openalex.org/I55664587","https://openalex.org/I66760702"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044184985","display_name":"Jyoti Sharma","orcid":"https://orcid.org/0000-0001-8118-9789","observed_orcids":["https://orcid.org/0000-0001-8118-9789","https://orcid.org/0009-0000-7965-0169"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Jyoti Sharma","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212National Chemical Laboratory (CSIR\u2212NCL) , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212National Chemical Laboratory (CSIR\u2212NCL) , , ,","institution_ids":["https://openalex.org/I3125981224","https://openalex.org/I66760702"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022075844","display_name":"Kumar Vanka","orcid":"https://orcid.org/0000-0001-7301-7573","observed_orcids":["https://orcid.org/0000-0001-7301-7573"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Kumar Vanka","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212National Chemical Laboratory (CSIR\u2212NCL) , , ,"],"raw_orcid":"https://orcid.org/0000-0001-7301-7573","affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212National Chemical Laboratory (CSIR\u2212NCL) , , ,","institution_ids":["https://openalex.org/I3125981224","https://openalex.org/I66760702"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160750649","display_name":"Resmi Kattukaram Raman","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I55664587","display_name":"Indian Institute of Chemical Technology","ror":"https://ror.org/040dky007","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I55664587","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Resmi Kattukaram Raman","raw_affiliation_strings":["Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,","institution_ids":["https://openalex.org/I55664587","https://openalex.org/I66760702"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5007684250","display_name":"Chada Raji Reddy","orcid":"https://orcid.org/0000-0003-1491-7381","observed_orcids":["https://orcid.org/0000-0003-1491-7381"]},"institutions":[{"id":"https://openalex.org/I55664587","display_name":"Indian Institute of Chemical Technology","ror":"https://ror.org/040dky007","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I55664587","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I99364266","display_name":"Academy of Scientific and Innovative Research","ror":"https://ror.org/053rcsq61","country_code":"IN","type":"education","lineage":["https://openalex.org/I99364266"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Chada Raji Reddy","raw_affiliation_strings":["Academy of Scientific and Innovative Research (AcSIR) , ,","Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,"],"raw_orcid":"https://orcid.org/0000-0003-1491-7381","affiliations":[{"raw_affiliation_string":"Academy of Scientific and Innovative Research (AcSIR) , ,","institution_ids":["https://openalex.org/I99364266"]},{"raw_affiliation_string":"Council of Scientific and Industrial Research\u2212Indian Institute of Chemical Technology (CSIR\u2212IICT) , , ,","institution_ids":["https://openalex.org/I55664587","https://openalex.org/I66760702"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.7710000276565552,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.7710000276565552,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.09920000284910202,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.06350000202655792,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ring-expansion","display_name":"ring expansion","score":0.921999990940094},{"id":"https://openalex.org/keywords/fused-carbocycles","display_name":"fused carbocycles","score":0.9169999957084656},{"id":"https://openalex.org/keywords/aromatic-aldehydes","display_name":"aromatic aldehydes","score":0.9900000095367432},{"id":"https://openalex.org/keywords/benzoylation","display_name":"benzoylation","score":0.9779999852180481},{"id":"https://openalex.org/keywords/quaternary-stereocenters","display_name":"quaternary stereocenters","score":0.9200000166893005},{"id":"https://openalex.org/keywords/tertiary-stereocenters","display_name":"tertiary stereocenters","score":0.8349999785423279},{"id":"https://openalex.org/keywords/free-radical-mechanism","display_name":"radical mechanism","score":0.5320000052452087}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9279999732971191},{"id":"https://openalex.org/C134195300","wikidata":"https://www.wikidata.org/wiki/Q902071","display_name":"Stereocenter","level":4,"score":0.9086999893188477},{"id":"https://openalex.org/C138716334","wikidata":"https://www.wikidata.org/wiki/Q268477","display_name":"Diastereomer","level":2,"score":0.7142000198364258},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.6944000124931335},{"id":"https://openalex.org/C34146451","wikidata":"https://www.wikidata.org/wiki/Q5048094","display_name":"Cascade","level":2,"score":0.6901999711990356},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.6732000112533569},{"id":"https://openalex.org/C58548122","wikidata":"https://www.wikidata.org/wiki/Q838390","display_name":"Cascade reaction","level":3,"score":0.6177999973297119},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5641000270843506},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4512999951839447},{"id":"https://openalex.org/C101468663","wikidata":"https://www.wikidata.org/wiki/Q1620158","display_name":"Modular design","level":2,"score":0.4050999879837036},{"id":"https://openalex.org/C129694887","wikidata":"https://www.wikidata.org/wiki/Q47455153","display_name":"Stereoisomerism","level":3,"score":0.3806999921798706},{"id":"https://openalex.org/C20327893","wikidata":"https://www.wikidata.org/wiki/Q7280479","display_name":"Radical cyclization","level":2,"score":0.3490999937057495},{"id":"https://openalex.org/C2777814067","wikidata":"https://www.wikidata.org/wiki/Q1752317","display_name":"Tandem","level":2,"score":0.3400000035762787},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.2994000017642975},{"id":"https://openalex.org/C181647583","wikidata":"https://www.wikidata.org/wiki/Q903429","display_name":"Stereoselectivity","level":3,"score":0.2903999984264374},{"id":"https://openalex.org/C2989255885","wikidata":"https://www.wikidata.org/wiki/Q500256","display_name":"Molecular conformation","level":3,"score":0.28949999809265137},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.28200000524520874},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.28029999136924744},{"id":"https://openalex.org/C204241405","wikidata":"https://www.wikidata.org/wiki/Q461499","display_name":"Transformation (genetics)","level":3,"score":0.2736000120639801},{"id":"https://openalex.org/C172456720","wikidata":"https://www.wikidata.org/wiki/Q2945392","display_name":"Intramolecular reaction","level":3,"score":0.26759999990463257},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.2671000063419342}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.orglett.6c04202","doi":"https://doi.org/10.1021/acs.orglett.6c04202","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.orglett.6c04202","pdf_url":null,"source":{"id":"https://openalex.org/S201989124","display_name":"Organic Letters","issn_l":"1523-7052","issn":["1523-7052","1523-7060"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Letters","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320721","display_name":"Council of Scientific and Industrial Research, India","ror":"https://ror.org/021wm7p51"},{"id":"https://openalex.org/F4320320767","display_name":"University Grants Commission","ror":"https://ror.org/04p800546"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":31,"referenced_works":["https://openalex.org/W1976163948","https://openalex.org/W2001274982","https://openalex.org/W2014373921","https://openalex.org/W2025322505","https://openalex.org/W2033976650","https://openalex.org/W2043116979","https://openalex.org/W2330478699","https://openalex.org/W2570783998","https://openalex.org/W2602713292","https://openalex.org/W2951000536","https://openalex.org/W2951066096","https://openalex.org/W2953188540","https://openalex.org/W3111791175","https://openalex.org/W3181785486","https://openalex.org/W4210748568","https://openalex.org/W4229042007","https://openalex.org/W4283769247","https://openalex.org/W4289224431","https://openalex.org/W4324020738","https://openalex.org/W4376636749","https://openalex.org/W4378230693","https://openalex.org/W4387970146","https://openalex.org/W4396545460","https://openalex.org/W4399363939","https://openalex.org/W4399906318","https://openalex.org/W4403282508","https://openalex.org/W4403299889","https://openalex.org/W4406814550","https://openalex.org/W4413767382","https://openalex.org/W4416305861","https://openalex.org/W4417146536"],"related_works":["https://openalex.org/W2528931447","https://openalex.org/W2603873551","https://openalex.org/W1994065084","https://openalex.org/W4408119889","https://openalex.org/W2073792892","https://openalex.org/W2951527145","https://openalex.org/W4387970146","https://openalex.org/W2951665232","https://openalex.org/W2953188540","https://openalex.org/W2558272602"],"abstract_inverted_index":{"Abstract":[0],"We":[1],"report":[2],"an":[3],"unprecedented":[4],"radical-promoted":[5],"cascade":[6,18],"reaction":[7,67],"of":[8,36,64,110,124],"vinyl":[9],"cycloalkanone":[10],"carboxylates":[11],"with":[12,27,88,100],"aromatic":[13],"aldehydes,":[14],"featuring":[15],"a":[16,50,61,70,101,118],"benzoylation/ring-expansion/oxa-cyclization":[17],"that":[19,73],"enables":[20],"rapid":[21],"access":[22],"to":[23,55],"functionalized":[24],"cis-fused":[25],"carbocycles":[26],"high":[28],"diastereoselectivity.":[29,113],"This":[30],"transformation":[31],"proceeds":[32],"through":[33],"the":[34,65,84,89,108,111,122],"formation":[35],"two":[37],"C\u2013C":[38],"bonds":[39],"and":[40,46,104],"one":[41],"C\u2013O":[42],"bond,":[43],"generating":[44],"quaternary":[45],"tertiary":[47],"stereocenters":[48],"as":[49],"single":[51],"diastereomer":[52],"in":[53,83],"good":[54],"excellent":[56],"yields.":[57],"The":[58],"strategy":[59],"represents":[60],"novel":[62],"dimension":[63],"Dowd\u2013Beckwith-type":[66],"by":[68,95],"incorporating":[69],"benzoyl":[71],"group":[72],"not":[74],"only":[75],"facilitates":[76],"ring":[77],"expansion":[78],"but":[79],"also":[80],"actively":[81],"participates":[82],"subsequent":[85],"intramolecular":[86],"cyclization":[87],"\u03b2-keto":[90],"radical.":[91],"Mechanistic":[92],"investigations,":[93],"supported":[94],"DFT":[96],"calculations,":[97],"are":[98],"consistent":[99],"radical-mediated":[102],"pathway":[103],"provide":[105],"insight":[106],"into":[107],"origin":[109],"observed":[112],"Further,":[114],"this":[115],"method":[116],"offers":[117],"versatile":[119],"platform":[120],"for":[121],"synthesis":[123],"complex":[125],"fused":[126],"carbocyclic":[127],"scaffolds.":[128]},"counts_by_year":[],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2026-11-06T00:00:00"}
