{"id":"https://openalex.org/W7225333607","doi":"https://doi.org/10.1021/jacs.6c12170","title":"Physicochemical Reaction Control Enables Molar-Mass-Selective Macromolecular Electrolysis","display_name":"Physicochemical Reaction Control Enables Molar-Mass-Selective Macromolecular Electrolysis","publication_year":2026,"publication_date":"2026-11-06","ids":{"openalex":"https://openalex.org/W7225333607","doi":"https://doi.org/10.1021/jacs.6c12170"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.6c12170","doi":"https://doi.org/10.1021/jacs.6c12170","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.6c12170","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5058147980","display_name":"Sean R. Gitter","orcid":"https://orcid.org/0000-0003-2426-5321","observed_orcids":["https://orcid.org/0000-0003-2426-5321"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sean R. Gitter","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":"https://orcid.org/0000-0003-2426-5321","affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160957770","display_name":"Gerald A. Camarella","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gerald A. Camarella","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5026265495","display_name":"Rhys W. Hughes","orcid":"https://orcid.org/0000-0003-1751-051X","observed_orcids":["https://orcid.org/0000-0003-1751-051X"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Rhys W. Hughes","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":"https://orcid.org/0000-0003-1751-051X","affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007507136","display_name":"Ani N. Davis","orcid":"https://orcid.org/0000-0002-9762-7883","observed_orcids":["https://orcid.org/0000-0002-9762-7883"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ani N. Davis","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5107495843","display_name":"Graham C. Gilchrist","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Graham C. Gilchrist","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040555326","display_name":"Joshua D. Marquez","orcid":"https://orcid.org/0000-0001-5132-8194","observed_orcids":["https://orcid.org/0000-0001-5132-8194"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joshua D. Marquez","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047303971","display_name":"Heyi Liang","orcid":"https://orcid.org/0000-0002-8308-3547","observed_orcids":["https://orcid.org/0000-0002-8308-3547"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Heyi Liang","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-8308-3547","affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081764848","display_name":"Brent S. Sumerlin","orcid":"https://orcid.org/0000-0001-5749-5444","observed_orcids":["https://orcid.org/0000-0001-5749-5444"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Brent S. Sumerlin","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":"https://orcid.org/0000-0001-5749-5444","affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5086833077","display_name":"Austin M. Evans","orcid":"https://orcid.org/0000-0002-3597-2454","observed_orcids":["https://orcid.org/0000-0002-3597-2454"]},"institutions":[{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Austin M. Evans","raw_affiliation_strings":["University of Florida , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-3597-2454","affiliations":[{"raw_affiliation_string":"University of Florida , , , ,","institution_ids":["https://openalex.org/I33213144"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5081764848","https://openalex.org/A5086833077"],"corresponding_institution_ids":["https://openalex.org/I33213144"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9351000189781189,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9351000189781189,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.0406000018119812,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10660","display_name":"Conducting polymers and applications","score":0.007499999832361937,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/redox-activation","display_name":"redox activation","score":0.6520000100135803},{"id":"https://openalex.org/keywords/radical-adsorption","display_name":"radical adsorption","score":0.7329999804496765},{"id":"https://openalex.org/keywords/graphite-electrodes","display_name":"graphite electrodes","score":0.8149999976158142},{"id":"https://openalex.org/keywords/vitreous-carbon-electrode","display_name":"vitreous carbon electrode","score":0.9269999861717224},{"id":"https://openalex.org/keywords/polymer-desorption","display_name":"polymer desorption","score":0.49900001287460327}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8400999903678894},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.6948999762535095},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5710999965667725},{"id":"https://openalex.org/C11432220","wikidata":"https://www.wikidata.org/wiki/Q1975334","display_name":"Dispersity","level":2,"score":0.5496000051498413},{"id":"https://openalex.org/C204389451","wikidata":"https://www.wikidata.org/wiki/Q178593","display_name":"Macromolecule","level":2,"score":0.5361999869346619},{"id":"https://openalex.org/C163127949","wikidata":"https://www.wikidata.org/wiki/Q64403","display_name":"Electrolysis","level":4,"score":0.5159000158309937},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.4578000009059906},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4390000104904175},{"id":"https://openalex.org/C196503311","wikidata":"https://www.wikidata.org/wiki/Q145623","display_name":"Molar mass","level":3,"score":0.42320001125335693},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.4065000116825104},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4020000100135803},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.37880000472068787},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.3743000030517578},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.37049999833106995},{"id":"https://openalex.org/C175113610","wikidata":"https://www.wikidata.org/wiki/Q3394849","display_name":"Reaction rate","level":3,"score":0.36230000853538513},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.3619999885559082},{"id":"https://openalex.org/C2779498867","wikidata":"https://www.wikidata.org/wiki/Q2402182","display_name":"Prepolymer","level":3,"score":0.34470000863075256},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.2978000044822693},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.295199990272522},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.29319998621940613},{"id":"https://openalex.org/C177801218","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Chemical reaction","level":2,"score":0.28949999809265137},{"id":"https://openalex.org/C203220038","wikidata":"https://www.wikidata.org/wiki/Q7226547","display_name":"Polymer degradation","level":3,"score":0.28679999709129333},{"id":"https://openalex.org/C132050475","wikidata":"https://www.wikidata.org/wiki/Q736232","display_name":"Methacrylate","level":4,"score":0.27559998631477356},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.2671999931335449},{"id":"https://openalex.org/C2780801859","wikidata":"https://www.wikidata.org/wiki/Q2013175","display_name":"Glycidyl methacrylate","level":4,"score":0.2517000138759613}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jacs.6c12170","doi":"https://doi.org/10.1021/jacs.6c12170","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.6c12170","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"},{"id":"https://openalex.org/F4320337531","display_name":"Defense Sciences Office, DARPA","ror":"https://ror.org/0447fe631"},{"id":"https://openalex.org/F4320338281","display_name":"Army Research Office","ror":"https://ror.org/05epdh915"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":70,"referenced_works":["https://openalex.org/W38573453","https://openalex.org/W170822695","https://openalex.org/W1975665022","https://openalex.org/W1987595700","https://openalex.org/W2001729253","https://openalex.org/W2018294724","https://openalex.org/W2042503787","https://openalex.org/W2065062420","https://openalex.org/W2080488246","https://openalex.org/W2103820855","https://openalex.org/W2164072937","https://openalex.org/W2165682602","https://openalex.org/W2279836435","https://openalex.org/W2287970811","https://openalex.org/W2331673407","https://openalex.org/W2336805901","https://openalex.org/W2734739831","https://openalex.org/W2761551323","https://openalex.org/W2789270720","https://openalex.org/W2792564663","https://openalex.org/W2793718405","https://openalex.org/W2793967588","https://openalex.org/W2801305065","https://openalex.org/W2801633248","https://openalex.org/W2971273696","https://openalex.org/W2977788314","https://openalex.org/W3017534963","https://openalex.org/W3031291328","https://openalex.org/W3108530513","https://openalex.org/W3122840358","https://openalex.org/W3161934905","https://openalex.org/W3217650884","https://openalex.org/W4200095031","https://openalex.org/W4200204780","https://openalex.org/W4206007278","https://openalex.org/W4206774170","https://openalex.org/W4280565476","https://openalex.org/W4280578187","https://openalex.org/W4281684534","https://openalex.org/W4308994247","https://openalex.org/W4362678471","https://openalex.org/W4385751594","https://openalex.org/W4387011989","https://openalex.org/W4389132574","https://openalex.org/W4389179578","https://openalex.org/W4390245651","https://openalex.org/W4390964448","https://openalex.org/W4392230508","https://openalex.org/W4393279247","https://openalex.org/W4393928617","https://openalex.org/W4398179852","https://openalex.org/W4402391898","https://openalex.org/W4402847868","https://openalex.org/W4406954892","https://openalex.org/W4407677360","https://openalex.org/W4408117808","https://openalex.org/W4408233122","https://openalex.org/W4408441083","https://openalex.org/W4409571509","https://openalex.org/W4412508841","https://openalex.org/W4412826285","https://openalex.org/W4414336000","https://openalex.org/W4414563682","https://openalex.org/W4415097950","https://openalex.org/W4416758662","https://openalex.org/W7118468214","https://openalex.org/W7123429748","https://openalex.org/W7129266586","https://openalex.org/W7130646306","https://openalex.org/W7168298517"],"related_works":["https://openalex.org/W4402847868","https://openalex.org/W4408117808","https://openalex.org/W4391638359","https://openalex.org/W1973941198","https://openalex.org/W2154764281","https://openalex.org/W2167379892","https://openalex.org/W4406091799","https://openalex.org/W4200095031","https://openalex.org/W1979765165","https://openalex.org/W7037571934"],"abstract_inverted_index":{"Abstract":[0],"Tailoring":[1],"molar-mass":[2,228,245],"distributions":[3,31,246],"postsynthetically":[4,247],"remains":[5],"a":[6,35,61,113,139,155,262,270],"long-standing":[7],"challenge":[8],"in":[9,163,173,275],"polymer":[10,19,71,141,147,180,277],"chemistry":[11],"that":[12,24,130,169],"conventionally":[13],"requires":[14],"the":[15,86,97,124,150,227,234],"synthesis":[16],"of":[17,65,88,100,108,115,158,207,236,273],"dedicated":[18],"libraries.":[20],"Here,":[21],"we":[22,128],"show":[23,129],"heterogeneous":[25,68],"macromolecular":[26,133,266],"electrolysis":[27],"can":[28],"edit":[29],"polymer-molar-mass":[30],"on":[32,96,138,178,186],"demand":[33],"from":[34,44,53,60,149],"single":[36,140],"prepolymer":[37],"sample,":[38],"tuning":[39],"number-average":[40],"molar":[41],"mass":[42],"(Mn)":[43],"60":[45],"to":[46,55,105,123,146,165,192,202,222,230,242],"902":[47],"kg":[48],"mol\u20131":[49],"and":[50,184,219,268],"dispersity":[51],"(\u0110)":[52],"1.3":[54],"7.":[56],"This":[57,103,161],"capability":[58],"arises":[59],"previously":[62],"unrecognized":[63],"mode":[64],"selectivity":[66,274],"where":[67,175],"electroreduction":[69],"mediates":[70],"substrate":[72],"reactivity":[73,220],"through":[74],"physicochemical":[75,159],"reaction":[76],"control.":[77,160],"In":[78],"this":[79,132],"electrolytic":[80],"transformation,":[81],"molar-mass-dependent":[82],"transport":[83],"physically":[84],"affects":[85],"rate":[87],"redox":[89],"activation":[90,107,206],"with":[91],"an":[92],"approximately":[93],"linear":[94],"dependence":[95],"diffusion":[98],"coefficient":[99],"these":[101,240],"macromolecules.":[102],"leads":[104],"preferential":[106,121],"lower-molar-mass":[109],"polymers,":[110],"which":[111,153,225],"is":[112,143,154,217],"consequence":[114],"more":[116,190],"rapidly":[117],"diffusing":[118],"species":[119],"having":[120],"access":[122],"electrode":[125],"interface.":[126],"Moreover,":[127],"during":[131],"electrolysis,":[134],"every":[135],"redox-active":[136],"unit":[137],"chain":[142],"activated":[144],"prior":[145],"desorption":[148],"working":[151],"electrode,":[152],"distinct":[156],"manifestation":[157],"stands":[162],"contrast":[164],"conventional":[166],"postpolymerization":[167],"transformations":[168,267],"are":[170,189],"inherently":[171],"stochastic":[172,223],"nature,":[174],"target":[176],"units":[177],"individual":[179,208],"chains":[181,209],"statistically":[182],"react":[183],"reactions":[185],"large":[187],"polymers":[188],"likely":[191],"occur.":[193],"Electrode":[194],"identity":[195],"controls":[196],"polymer\u2013electrode":[197],"interactions.":[198],"Strong":[199],"radical":[200],"adsorption":[201,216],"graphite":[203],"drives":[204],"complete":[205],"before":[210],"desorption.":[211],"On":[212],"reticulated":[213],"vitreous":[214],"carbon,":[215],"weaker":[218],"reverts":[221],"activation,":[224],"causes":[226],"distribution":[229],"shift":[231],"gradually":[232],"over":[233],"course":[235],"electrolysis.":[237],"We":[238],"leveraged":[239],"differences":[241],"arbitrarily":[243],"tune":[244],"by":[248],"selectively":[249],"deconstructing":[250],"prototypical":[251],"N-(methacryloxy)phthalimide":[252],"methacrylate":[253],"copolymers.":[254],"These":[255],"findings":[256],"establish":[257],"interfacial":[258],"electrochemical":[259],"environments":[260],"as":[261],"platform":[263],"for":[264],"molar-mass-selective":[265],"introduce":[269],"new":[271],"axis":[272],"synthetic":[276],"chemistry.":[278]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2026-11-06T00:00:00"}