{"id":"https://openalex.org/W7225320833","doi":"https://doi.org/10.1021/acs.inorgchem.6c04177","title":"Sulfur Vacancy-Engineered ZnIn2S4 Nanosheets Integrated with CoS1.097 for Enhanced Visible Light-Driven Nitrogen Photofixation","display_name":"Sulfur Vacancy-Engineered ZnIn2S4 Nanosheets Integrated with CoS1.097 for Enhanced Visible Light-Driven Nitrogen Photofixation","publication_year":2026,"publication_date":"2026-11-06","ids":{"openalex":"https://openalex.org/W7225320833","doi":"https://doi.org/10.1021/acs.inorgchem.6c04177"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.6c04177","doi":"https://doi.org/10.1021/acs.inorgchem.6c04177","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.6c04177","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100766524","display_name":"Yutong Zhang","orcid":"https://orcid.org/0000-0001-8275-9608","observed_orcids":["https://orcid.org/0000-0001-8275-9608"]},"institutions":[{"id":"https://openalex.org/I4405281598","display_name":"Taizhou University","ror":"https://ror.org/04m19xd94","country_code":"CN","type":"education","lineage":["https://openalex.org/I4405281598"]},{"id":"https://openalex.org/I82760581","display_name":"Taizhou University","ror":"https://ror.org/04fzhyx73","country_code":"CN","type":"education","lineage":["https://openalex.org/I82760581"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yu-Tong Zhang","raw_affiliation_strings":["Taizhou University , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Taizhou University , , , ,","institution_ids":["https://openalex.org/I4405281598","https://openalex.org/I82760581"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160826119","display_name":"Yan-Hua Feng","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1099802","display_name":"Shenyang Medical College","ror":"https://ror.org/02y9xvd02","country_code":"CN","type":"education","lineage":["https://openalex.org/I1099802"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yan-Hua Feng","raw_affiliation_strings":["Shenyang Medical College , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shenyang Medical College , , , ,","institution_ids":["https://openalex.org/I1099802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103033674","display_name":"Ping Zheng","orcid":"https://orcid.org/0000-0002-6585-7975","observed_orcids":["https://orcid.org/0000-0002-6585-7975"]},"institutions":[{"id":"https://openalex.org/I4405281598","display_name":"Taizhou University","ror":"https://ror.org/04m19xd94","country_code":"CN","type":"education","lineage":["https://openalex.org/I4405281598"]},{"id":"https://openalex.org/I82760581","display_name":"Taizhou University","ror":"https://ror.org/04fzhyx73","country_code":"CN","type":"education","lineage":["https://openalex.org/I82760581"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ping Zheng","raw_affiliation_strings":["Taizhou University , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Taizhou University , , , ,","institution_ids":["https://openalex.org/I4405281598","https://openalex.org/I82760581"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5013335788","display_name":"Zhenjun Song","orcid":"https://orcid.org/0000-0002-0493-9037","observed_orcids":["https://orcid.org/0000-0002-0493-9037"]},"institutions":[{"id":"https://openalex.org/I4405281598","display_name":"Taizhou University","ror":"https://ror.org/04m19xd94","country_code":"CN","type":"education","lineage":["https://openalex.org/I4405281598"]},{"id":"https://openalex.org/I82760581","display_name":"Taizhou University","ror":"https://ror.org/04fzhyx73","country_code":"CN","type":"education","lineage":["https://openalex.org/I82760581"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhenjun Song","raw_affiliation_strings":["Taizhou University , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-0493-9037","affiliations":[{"raw_affiliation_string":"Taizhou University , , , ,","institution_ids":["https://openalex.org/I4405281598","https://openalex.org/I82760581"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100344573","display_name":"Wei Chen","orcid":"https://orcid.org/0000-0003-3233-8877","observed_orcids":["https://orcid.org/0000-0003-3233-8877","https://orcid.org/0000-0002-1233-9023"]},"institutions":[{"id":"https://openalex.org/I4405281598","display_name":"Taizhou University","ror":"https://ror.org/04m19xd94","country_code":"CN","type":"education","lineage":["https://openalex.org/I4405281598"]},{"id":"https://openalex.org/I82760581","display_name":"Taizhou University","ror":"https://ror.org/04fzhyx73","country_code":"CN","type":"education","lineage":["https://openalex.org/I82760581"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Wei Chen","raw_affiliation_strings":["Taizhou University , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-1233-9023","affiliations":[{"raw_affiliation_string":"Taizhou University , , , ,","institution_ids":["https://openalex.org/I4405281598","https://openalex.org/I82760581"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100402966","display_name":"Min Zhang","orcid":"https://orcid.org/0000-0002-9865-9887","observed_orcids":["https://orcid.org/0000-0002-9865-9887"]},"institutions":[{"id":"https://openalex.org/I4210123686","display_name":"Quzhou University","ror":"https://ror.org/024nfx323","country_code":"CN","type":"education","lineage":["https://openalex.org/I4210123686"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Min Zhang","raw_affiliation_strings":["Quzhou University , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-9865-9887","affiliations":[{"raw_affiliation_string":"Quzhou University , , , ,","institution_ids":["https://openalex.org/I4210123686"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100433232","display_name":"Jun Zhang","orcid":"https://orcid.org/0000-0002-9831-6796","observed_orcids":["https://orcid.org/0000-0002-9831-6796","https://orcid.org/0000-0003-3607-213X"]},"institutions":[{"id":"https://openalex.org/I1099802","display_name":"Shenyang Medical College","ror":"https://ror.org/02y9xvd02","country_code":"CN","type":"education","lineage":["https://openalex.org/I1099802"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Jun Zhang","raw_affiliation_strings":["Shenyang Medical College , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shenyang Medical College , , , ,","institution_ids":["https://openalex.org/I1099802"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5100344573","https://openalex.org/A5100402966","https://openalex.org/A5100433232"],"corresponding_institution_ids":["https://openalex.org/I1099802","https://openalex.org/I4210123686","https://openalex.org/I4405281598","https://openalex.org/I82760581"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.6776999831199646,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.6776999831199646,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12112","display_name":"Ammonia Synthesis and Nitrogen Reduction","score":0.3156999945640564,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10275","display_name":"2D Materials and Applications","score":0.0019000000320374966,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photocatalytic-nitrogen-fixation","display_name":"photocatalytic nitrogen fixation","score":0.8190000057220459},{"id":"https://openalex.org/keywords/znin2s4-nanosheets","display_name":"ZnIn2S4 nanosheets","score":0.9240000247955322},{"id":"https://openalex.org/keywords/sulfur-vacancies","display_name":"sulfur vacancies","score":0.871999979019165},{"id":"https://openalex.org/keywords/cobalt-sulfide","display_name":"cobalt sulfide","score":0.8659999966621399},{"id":"https://openalex.org/keywords/s-scheme-heterojunction","display_name":"S-scheme heterojunction","score":0.9789999723434448},{"id":"https://openalex.org/keywords/visible-light-photocatalysis","display_name":"visible light photocatalysis","score":0.8840000033378601},{"id":"https://openalex.org/keywords/ammonia-synthesis","display_name":"ammonia synthesis","score":0.8669999837875366},{"id":"https://openalex.org/keywords/charge-separation","display_name":"charge separation","score":0.8130000233650208},{"id":"https://openalex.org/keywords/proton-coupled-electron-transfer","display_name":"proton-coupled electron transfer","score":0.9509999752044678}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8248999714851379},{"id":"https://openalex.org/C79794668","wikidata":"https://www.wikidata.org/wiki/Q1616270","display_name":"Heterojunction","level":2,"score":0.8094000220298767},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.777899980545044},{"id":"https://openalex.org/C518881349","wikidata":"https://www.wikidata.org/wiki/Q682","display_name":"Sulfur","level":2,"score":0.6873000264167786},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6869999766349792},{"id":"https://openalex.org/C156622251","wikidata":"https://www.wikidata.org/wiki/Q1036221","display_name":"Hydrothermal circulation","level":2,"score":0.680899977684021},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.6704999804496765},{"id":"https://openalex.org/C104663316","wikidata":"https://www.wikidata.org/wiki/Q76299","display_name":"Visible spectrum","level":2,"score":0.6086999773979187},{"id":"https://openalex.org/C2776382133","wikidata":"https://www.wikidata.org/wiki/Q4087","display_name":"Ammonia","level":2,"score":0.5220000147819519},{"id":"https://openalex.org/C156328458","wikidata":"https://www.wikidata.org/wiki/Q5275423","display_name":"Diffuse reflectance infrared fourier transform","level":4,"score":0.49300000071525574},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.47909998893737793},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.47119998931884766},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.46380001306533813},{"id":"https://openalex.org/C2777822432","wikidata":"https://www.wikidata.org/wiki/Q216681","display_name":"In situ","level":2,"score":0.4616999924182892},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.4505000114440918},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.40779998898506165},{"id":"https://openalex.org/C82261727","wikidata":"https://www.wikidata.org/wiki/Q1154504","display_name":"Diffuse reflection","level":2,"score":0.40459999442100525},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.373199999332428},{"id":"https://openalex.org/C111337013","wikidata":"https://www.wikidata.org/wiki/Q2737837","display_name":"Irradiation","level":2,"score":0.35910001397132874},{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.34630000591278076},{"id":"https://openalex.org/C146088050","wikidata":"https://www.wikidata.org/wiki/Q744818","display_name":"Transmission electron microscopy","level":2,"score":0.33009999990463257},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.32359999418258667},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.3118000030517578},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.2802000045776367},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.2596000134944916},{"id":"https://openalex.org/C175583648","wikidata":"https://www.wikidata.org/wiki/Q903156","display_name":"Heterogeneous catalysis","level":3,"score":0.25780001282691956},{"id":"https://openalex.org/C2779679103","wikidata":"https://www.wikidata.org/wiki/Q5251805","display_name":"Degradation (telecommunications)","level":2,"score":0.25119999051094055},{"id":"https://openalex.org/C2776871784","wikidata":"https://www.wikidata.org/wiki/Q10861356","display_name":"Hydrothermal synthesis","level":3,"score":0.25099998712539673}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.inorgchem.6c04177","doi":"https://doi.org/10.1021/acs.inorgchem.6c04177","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.6c04177","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320329355","display_name":"Quzhou Municipal Science and Technology Bureau","ror":"https://ror.org/03y07st38"},{"id":"https://openalex.org/F4320338464","display_name":"Natural Science Foundation of Zhejiang Province","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":49,"referenced_works":["https://openalex.org/W2626655409","https://openalex.org/W3034585612","https://openalex.org/W4281916281","https://openalex.org/W4313530173","https://openalex.org/W4387439726","https://openalex.org/W4387453392","https://openalex.org/W4389347812","https://openalex.org/W4403466273","https://openalex.org/W4407203788","https://openalex.org/W4408069467","https://openalex.org/W4408318454","https://openalex.org/W4408363159","https://openalex.org/W4409199918","https://openalex.org/W4410835664","https://openalex.org/W4412492341","https://openalex.org/W4412753588","https://openalex.org/W4413304865","https://openalex.org/W4414107040","https://openalex.org/W4415610463","https://openalex.org/W4416674358","https://openalex.org/W4417093569","https://openalex.org/W7109196916","https://openalex.org/W7117580311","https://openalex.org/W7124998879","https://openalex.org/W7127448027","https://openalex.org/W7131117182","https://openalex.org/W7140046857","https://openalex.org/W7143287708","https://openalex.org/W7153244012","https://openalex.org/W7154612286","https://openalex.org/W7154680245","https://openalex.org/W7155647676","https://openalex.org/W7156092233","https://openalex.org/W7156380548","https://openalex.org/W7160246784","https://openalex.org/W7160766698","https://openalex.org/W7161983633","https://openalex.org/W7162310444","https://openalex.org/W7162449040","https://openalex.org/W7162664340","https://openalex.org/W7162760620","https://openalex.org/W7166075791","https://openalex.org/W7166859928","https://openalex.org/W7167278577","https://openalex.org/W7167583373","https://openalex.org/W7168153028","https://openalex.org/W7169618289","https://openalex.org/W7169874227","https://openalex.org/W7172428873"],"related_works":["https://openalex.org/W4392626547","https://openalex.org/W4391887932","https://openalex.org/W2291048787","https://openalex.org/W2225030849","https://openalex.org/W4206753499","https://openalex.org/W4391508868","https://openalex.org/W4405431397","https://openalex.org/W4387453392","https://openalex.org/W4391974012","https://openalex.org/W4412621692"],"abstract_inverted_index":{"Abstract":[0],"Herein,":[1],"S-scheme":[2,68,132],"heterojunction":[3],"photocatalysts":[4],"integrating":[5],"sulfur":[6],"vacancy-engineered":[7],"ZnIn2S4":[8],"(Sv-ZnInS)":[9],"with":[10],"CoS1.097":[11],"(CoS)":[12],"were":[13],"successfully":[14],"synthesized":[15],"via":[16,76,122],"a":[17,123,137],"simple":[18],"hydrothermal":[19],"reaction.":[20],"The":[21,67,89,111],"formed":[22],"CoS/Sv-ZnInS":[23,133],"heterostructures":[24],"exhibited":[25],"considerably":[26],"high":[27],"catalytic":[28],"activity":[29],"toward":[30,140],"visible":[31,141],"light-driven":[32,142],"photocatalytic":[33,143],"nitrogen":[34],"(N2)":[35],"fixation.":[36,145],"Notably,":[37],"the":[38,118],"optimized":[39],"3CoS/Sv-ZnInS":[40,119],"sample":[41],"achieved":[42],"an":[43,59],"ammonia":[44],"yield":[45],"of":[46,54],"18.18":[47],"\u00b1":[48],"0.39":[49],"mg\u00b7L\u20131":[50],"after":[51],"1":[52],"h":[53],"visible-light":[55],"illumination,":[56],"which":[57],"was":[58,74,94],"approximately":[60],"2.4-fold":[61],"enhancement":[62],"relative":[63],"to":[64],"pristine":[65],"Sv-ZnInS.":[66],"charge":[69],"separation":[70],"and":[71,85,102],"transfer":[72],"pathway":[73],"elucidated":[75],"in":[77,103],"situ":[78,104],"irradiated":[79],"X-ray":[80],"photoelectron":[81],"spectroscopy,":[82],"noble-metal":[83],"loading,":[84],"band":[86],"structure":[87],"analysis.":[88],"underlying":[90],"N2":[91,115,144],"photofixation":[92,116],"mechanism":[93],"systematically":[95],"investigated":[96],"using":[97],"density":[98],"functional":[99],"theory":[100],"calculations":[101],"diffuse":[105],"reflectance":[106],"infrared":[107],"Fourier":[108],"transform":[109],"spectroscopy.":[110],"results":[112],"revealed":[113],"that":[114,131],"over":[117],"catalyst":[120],"occurred":[121],"multistep":[124],"proton-coupled":[125],"electron":[126],"transfer.":[127],"Our":[128],"findings":[129],"indicate":[130],"heterojunctions":[134],"may":[135],"offer":[136],"viable":[138],"route":[139]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2026-11-06T00:00:00"}