{"id":"https://openalex.org/W7225318029","doi":"https://doi.org/10.1021/jacs.6c20698","title":"Charge-to-Mass Ratio Regulation of Solvated Li+ Clusters for Ultrafast-Charging Lithium Battery Electrolytes","display_name":"Charge-to-Mass Ratio Regulation of Solvated Li+ Clusters for Ultrafast-Charging Lithium Battery Electrolytes","publication_year":2026,"publication_date":"2026-11-05","ids":{"openalex":"https://openalex.org/W7225318029","doi":"https://doi.org/10.1021/jacs.6c20698"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.6c20698","doi":"https://doi.org/10.1021/jacs.6c20698","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.6c20698","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5017886663","display_name":"Guohuang Kang","orcid":"https://orcid.org/0009-0003-6773-907X","observed_orcids":["https://orcid.org/0009-0003-6773-907X"]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Guohuang Kang","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":"https://orcid.org/0009-0003-6773-907X","affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113966044","display_name":"Jiachao Duan","orcid":"https://orcid.org/0009-0007-4189-3457","observed_orcids":["https://orcid.org/0009-0007-4189-3457"]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jiachao Duan","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160913190","display_name":"Yue Cao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yue Cao","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160844615","display_name":"Qi Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qi Liu","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160806819","display_name":"Yuanyuan Zhang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuanyuan Zhang","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5136466352","display_name":"Manxue Zhang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Manxue Zhang","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050944748","display_name":"Feiyu Kang","orcid":"https://orcid.org/0000-0002-3704-4379","observed_orcids":["https://orcid.org/0000-0002-3704-4379"]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Feiyu Kang","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5083586792","display_name":"Yidan Cao","orcid":"https://orcid.org/0000-0002-2914-9699","observed_orcids":["https://orcid.org/0000-0002-2914-9699"]},"institutions":[{"id":"https://openalex.org/I99065089","display_name":"Tsinghua University","ror":"https://ror.org/03cve4549","country_code":"CN","type":"education","lineage":["https://openalex.org/I99065089"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yidan Cao","raw_affiliation_strings":["Tsinghua University , , ,"],"raw_orcid":"https://orcid.org/0000-0002-2914-9699","affiliations":[{"raw_affiliation_string":"Tsinghua University , , ,","institution_ids":["https://openalex.org/I99065089"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5083586792"],"corresponding_institution_ids":["https://openalex.org/I99065089"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.8661999702453613,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.8661999702453613,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.1266999989748001,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10663","display_name":"Battery Modeling and Management","score":0.00419999985024333,"subfield":{"id":"https://openalex.org/subfields/2203","display_name":"Automotive Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lithium-battery-electrolytes","display_name":"lithium battery electrolytes","score":0.6919999718666077},{"id":"https://openalex.org/keywords/ultrafast-charging","display_name":"ultrafast charging","score":0.7549999952316284},{"id":"https://openalex.org/keywords/solvent-separated-ion-pairs","display_name":"solvent-separated ion pairs","score":0.8040000200271606},{"id":"https://openalex.org/keywords/methyl-acetate","display_name":"methyl acetate","score":0.8650000095367432},{"id":"https://openalex.org/keywords/fluoroethylene-carbonate","display_name":"fluoroethylene carbonate","score":0.9309999942779541},{"id":"https://openalex.org/keywords/lithium-ion-diffusion","display_name":"lithium ion diffusion","score":0.6200000047683716},{"id":"https://openalex.org/keywords/ligand-exchange","display_name":"ligand exchange","score":0.8820000290870667}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8725000023841858},{"id":"https://openalex.org/C29452124","wikidata":"https://www.wikidata.org/wiki/Q835950","display_name":"Interphase","level":2,"score":0.848800003528595},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.8410999774932861},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.7430999875068665},{"id":"https://openalex.org/C148093993","wikidata":"https://www.wikidata.org/wiki/Q739398","display_name":"Solvation","level":3,"score":0.6886000037193298},{"id":"https://openalex.org/C164866538","wikidata":"https://www.wikidata.org/wiki/Q367351","display_name":"Cluster (spacecraft)","level":2,"score":0.6747000217437744},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.5515999794006348},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5123000144958496},{"id":"https://openalex.org/C555008776","wikidata":"https://www.wikidata.org/wiki/Q267298","display_name":"Battery (electricity)","level":3,"score":0.49959999322891235},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.4936999976634979},{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.46779999136924744},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.4677000045776367},{"id":"https://openalex.org/C132543647","wikidata":"https://www.wikidata.org/wiki/Q80097","display_name":"Electrochemical cell","level":4,"score":0.3806000053882599},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3736000061035156},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.35370001196861267},{"id":"https://openalex.org/C40231798","wikidata":"https://www.wikidata.org/wiki/Q1333743","display_name":"Composition (language)","level":2,"score":0.3418000042438507},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.33399999141693115},{"id":"https://openalex.org/C2780659211","wikidata":"https://www.wikidata.org/wiki/Q181699","display_name":"Carbonate","level":2,"score":0.3255000114440918},{"id":"https://openalex.org/C131540310","wikidata":"https://www.wikidata.org/wiki/Q907564","display_name":"Conductivity","level":2,"score":0.2809000015258789},{"id":"https://openalex.org/C149823470","wikidata":"https://www.wikidata.org/wiki/Q1088326","display_name":"Solvation shell","level":4,"score":0.2646999955177307},{"id":"https://openalex.org/C102264631","wikidata":"https://www.wikidata.org/wiki/Q903563","display_name":"Concentration cell","level":4,"score":0.2630000114440918},{"id":"https://openalex.org/C125086356","wikidata":"https://www.wikidata.org/wiki/Q62525","display_name":"Electrochemical potential","level":4,"score":0.26080000400543213},{"id":"https://openalex.org/C64147673","wikidata":"https://www.wikidata.org/wiki/Q6007318","display_name":"Implicit solvation","level":4,"score":0.2590000033378601},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.25619998574256897},{"id":"https://openalex.org/C3017540586","wikidata":"https://www.wikidata.org/wiki/Q612728","display_name":"Cluster size","level":3,"score":0.25049999356269836}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jacs.6c20698","doi":"https://doi.org/10.1021/jacs.6c20698","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.6c20698","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320317337","display_name":"Science and Technology Foundation of Shenzhen City","ror":null},{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":43,"referenced_works":["https://openalex.org/W1999184503","https://openalex.org/W2003354164","https://openalex.org/W2025010304","https://openalex.org/W2030765885","https://openalex.org/W2169211003","https://openalex.org/W2331458798","https://openalex.org/W2522472223","https://openalex.org/W2788451670","https://openalex.org/W2812155923","https://openalex.org/W2922443589","https://openalex.org/W2978440387","https://openalex.org/W3035811909","https://openalex.org/W3095930111","https://openalex.org/W3112870719","https://openalex.org/W3154158328","https://openalex.org/W3192501834","https://openalex.org/W3193044426","https://openalex.org/W4205320316","https://openalex.org/W4221063282","https://openalex.org/W4224903459","https://openalex.org/W4297324421","https://openalex.org/W4319591926","https://openalex.org/W4322008430","https://openalex.org/W4381612551","https://openalex.org/W4383341002","https://openalex.org/W4385348084","https://openalex.org/W4387219571","https://openalex.org/W4391560355","https://openalex.org/W4392242379","https://openalex.org/W4396734319","https://openalex.org/W4402508061","https://openalex.org/W4402695700","https://openalex.org/W4404228702","https://openalex.org/W4405795285","https://openalex.org/W4406093320","https://openalex.org/W4408310281","https://openalex.org/W4410903651","https://openalex.org/W4413142073","https://openalex.org/W4414985666","https://openalex.org/W4416181754","https://openalex.org/W4416872521","https://openalex.org/W7141974110","https://openalex.org/W7161717269"],"related_works":["https://openalex.org/W7138884593","https://openalex.org/W7164194346","https://openalex.org/W4416615463","https://openalex.org/W4409581447","https://openalex.org/W7212304500","https://openalex.org/W7171662591","https://openalex.org/W3205612088","https://openalex.org/W4385348084","https://openalex.org/W7135369809","https://openalex.org/W4407366137"],"abstract_inverted_index":{"Abstract":[0],"Extreme":[1],"fast":[2],"charging":[3],"of":[4,35,48],"high-energy":[5],"lithium":[6],"batteries":[7],"is":[8,30,43],"limited":[9],"by":[10,81],"coupled":[11],"Li+":[12,96,126],"transport,":[13,181],"interfacial":[14],"desolvation,":[15],"and":[16,41,71,77,102,112,124,141,154,163,183],"electrode":[17],"degradation.":[18],"Here,":[19],"we":[20,84],"introduce":[21],"q/Mcluster":[22,63,175],"as":[23],"a":[24,65,86,118,145,171],"composition-derived":[25],"prescreening":[26],"descriptor,":[27,83],"where":[28],"q":[29],"the":[31,36,44,49,53,129],"assigned":[32],"charge":[33],"number":[34],"Li-centered":[37],"carrier":[38],"(+1":[39],"here)":[40],"Mcluster":[42],"abundance-weighted":[45],"composition":[46,69,100],"mass":[47,70,101],"cationic":[50],"clusters":[51,97],"in":[52,128,144],"four":[54],"most":[55],"populated":[56],"solvent-separated":[57],"ion-pair":[58],"(SSIP)":[59],"configurations.":[60],"A":[61],"higher":[62],"identifies":[64],"lower":[66,99,119],"average":[67],"cluster":[68,121],"prioritizes":[72],"electrolyte":[73,91],"candidates":[74],"for":[75,136,160,179],"transport":[76],"electrochemical":[78,184],"testing.":[79],"Guided":[80],"this":[82],"develop":[85],"methyl":[87],"acetate/fluoroethylene":[88],"carbonate":[89],"(MA/FEC)":[90],"that":[92],"favors":[93],"MA-rich":[94],"solvated":[95],"with":[98],"dynamic":[103],"ligand":[104],"exchange,":[105],"while":[106,167],"FEC":[107],"supports":[108],"interphase":[109,165],"stabilization.":[110],"Simulations":[111],"experiments":[113],"show":[114],"weaker":[115],"Li+\u2013solvent":[116],"association,":[117],"calculated":[120],"ligand-removal":[122],"energy,":[123],"faster":[125],"diffusion":[127],"optimized":[130],"formulation.":[131],"It":[132],"enables":[133],"stable":[134],"operation":[135],"1000":[137],"cycles":[138,143],"at":[139],"15C":[140],"500":[142],"1":[146],"Ah":[147],"pouch":[148],"cell":[149],"under":[150],"3C":[151],"charging.":[152],"Composition":[153],"cross-family":[155],"controls":[156],"support":[157],"complementary":[158],"roles":[159],"MA-regulated":[161],"solvation":[162],"FEC-derived":[164],"stabilization,":[166],"revealing":[168],"limits":[169],"to":[170],"single-parameter":[172],"ranking.":[173],"Thus,":[174],"helps":[176],"prioritize":[177],"formulations":[178],"independent":[180],"interfacial,":[182],"validation.":[185]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2026-11-06T00:00:00"}