{"id":"https://openalex.org/W7225311404","doi":"https://doi.org/10.1021/acs.est.6c01277","title":"Nanoconfinement Drives Non-Monotonic Methane Density in Shale Nanopores: Direct Observation of Competitive Water\u2013Gas Exchange","display_name":"Nanoconfinement Drives Non-Monotonic Methane Density in Shale Nanopores: Direct Observation of Competitive Water\u2013Gas Exchange","publication_year":2026,"publication_date":"2026-11-05","ids":{"openalex":"https://openalex.org/W7225311404","doi":"https://doi.org/10.1021/acs.est.6c01277"},"language":"en","primary_location":{"id":"doi:10.1021/acs.est.6c01277","doi":"https://doi.org/10.1021/acs.est.6c01277","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.est.6c01277","pdf_url":null,"source":{"id":"https://openalex.org/S13479253","display_name":"Environmental Science & Technology","issn_l":"0013-936X","issn":["0013-936X","1520-5851"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","fnege-4","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental Science & Technology","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5003820177","display_name":"Mengdi Sun","orcid":"https://orcid.org/0000-0002-3557-3939","observed_orcids":["https://orcid.org/0000-0002-3557-3939"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]},{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Mengdi Sun","raw_affiliation_strings":["Northeast Petroleum University , , ,","Peking University , , ,"],"raw_orcid":"https://orcid.org/0000-0002-3557-3939","affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]},{"raw_affiliation_string":"Peking University , , ,","institution_ids":["https://openalex.org/I20231570"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5060944850","display_name":"Yeping Ji","orcid":"https://orcid.org/0000-0001-9656-0763","observed_orcids":["https://orcid.org/0000-0001-9656-0763"]},"institutions":[{"id":"https://openalex.org/I1292875679","display_name":"Commonwealth Scientific and Industrial Research Organisation","ror":"https://ror.org/03qn8fb07","country_code":"AU","type":"government","lineage":["https://openalex.org/I1292875679","https://openalex.org/I2801453606","https://openalex.org/I4387156119"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Yeping Ji","raw_affiliation_strings":["CSIRO Energy , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CSIRO Energy , , ,","institution_ids":["https://openalex.org/I1292875679"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102331934","display_name":"Jilong Xu","orcid":"https://orcid.org/0000-0003-0199-5110","observed_orcids":["https://orcid.org/0000-0003-0199-5110","https://orcid.org/0000-0001-8623-1608"]},"institutions":[{"id":"https://openalex.org/I154425047","display_name":"University of Alberta","ror":"https://ror.org/0160cpw27","country_code":"CA","type":"education","lineage":["https://openalex.org/I154425047"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Jilong Xu","raw_affiliation_strings":["University of Alberta , , , ,"],"raw_orcid":"https://orcid.org/0000-0003-0199-5110","affiliations":[{"raw_affiliation_string":"University of Alberta , , , ,","institution_ids":["https://openalex.org/I154425047"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044729281","display_name":"Zhehui Jin","orcid":"https://orcid.org/0000-0001-8305-5637","observed_orcids":["https://orcid.org/0000-0001-8305-5637"]},"institutions":[{"id":"https://openalex.org/I154425047","display_name":"University of Alberta","ror":"https://ror.org/0160cpw27","country_code":"CA","type":"education","lineage":["https://openalex.org/I154425047"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Zhehui Jin","raw_affiliation_strings":["University of Alberta , , , ,"],"raw_orcid":"https://orcid.org/0000-0001-8305-5637","affiliations":[{"raw_affiliation_string":"University of Alberta , , , ,","institution_ids":["https://openalex.org/I154425047"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101464508","display_name":"Ke Xu","orcid":"https://orcid.org/0000-0002-6602-3382","observed_orcids":["https://orcid.org/0000-0002-6602-3382"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ke Xu","raw_affiliation_strings":["Peking University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Peking University , , ,","institution_ids":["https://openalex.org/I20231570"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160851691","display_name":"Jiajun Fu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jiajun Fu","raw_affiliation_strings":["Northeast Petroleum University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5053157432","display_name":"Mehdi Ostadhassan","orcid":"https://orcid.org/0000-0001-9235-4399","observed_orcids":["https://orcid.org/0000-0001-9235-4399","https://orcid.org/0000-0003-1285-5439"]},"institutions":[{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Mehdi Ostadhassan","raw_affiliation_strings":["Northeast Petroleum University , , ,"],"raw_orcid":"https://orcid.org/0000-0001-9235-4399","affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033269566","display_name":"Erfan Mohammadian","orcid":"https://orcid.org/0000-0002-7362-5031","observed_orcids":["https://orcid.org/0000-0002-7362-5031"]},"institutions":[{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Erfan Mohammadian","raw_affiliation_strings":["Northeast Petroleum University , , ,"],"raw_orcid":"https://orcid.org/0000-0002-7362-5031","affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062041023","display_name":"Qamar Yasin","orcid":"https://orcid.org/0000-0002-0155-4502","observed_orcids":["https://orcid.org/0000-0002-0155-4502"]},"institutions":[{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qamar Yasin","raw_affiliation_strings":["Northeast Petroleum University , , ,"],"raw_orcid":"https://orcid.org/0000-0002-0155-4502","affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075759908","display_name":"Tomasz P. Blach","orcid":"https://orcid.org/0000-0003-0648-2867","observed_orcids":["https://orcid.org/0000-0003-0648-2867"]},"institutions":[{"id":"https://openalex.org/I11701301","display_name":"Griffith University","ror":"https://ror.org/02sc3r913","country_code":"AU","type":"education","lineage":["https://openalex.org/I11701301"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Tomasz P. Blach","raw_affiliation_strings":["Griffith University , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Griffith University , , , ,","institution_ids":["https://openalex.org/I11701301"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5131402277","display_name":"Yubin Ke","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Yubin Ke","raw_affiliation_strings":["Spallation Source Neutron Science Center , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Spallation Source Neutron Science Center , ,","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019893827","display_name":"Chun\u2010Ming Wu","orcid":"https://orcid.org/0000-0002-2476-2785","observed_orcids":["https://orcid.org/0000-0002-2476-2785"]},"institutions":[{"id":"https://openalex.org/I1334950195","display_name":"Australian Nuclear Science and Technology Organisation","ror":"https://ror.org/05j7fep28","country_code":"AU","type":"government","lineage":["https://openalex.org/I1334950195","https://openalex.org/I2801453606","https://openalex.org/I4387156119"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Chunming Wu","raw_affiliation_strings":["Australian Nuclear Science and Technology Organization , , , ,"],"raw_orcid":"https://orcid.org/0000-0002-2476-2785","affiliations":[{"raw_affiliation_string":"Australian Nuclear Science and Technology Organization , , , ,","institution_ids":["https://openalex.org/I1334950195"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009029749","display_name":"Liliana de Campo","orcid":"https://orcid.org/0000-0003-4799-2935","observed_orcids":["https://orcid.org/0000-0003-4799-2935"]},"institutions":[{"id":"https://openalex.org/I1334950195","display_name":"Australian Nuclear Science and Technology Organisation","ror":"https://ror.org/05j7fep28","country_code":"AU","type":"government","lineage":["https://openalex.org/I1334950195","https://openalex.org/I2801453606","https://openalex.org/I4387156119"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Liliana de Campo","raw_affiliation_strings":["Australian Nuclear Science and Technology Organization , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Australian Nuclear Science and Technology Organization , , , ,","institution_ids":["https://openalex.org/I1334950195"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028777364","display_name":"David A. Wood","orcid":"https://orcid.org/0000-0003-3202-4069","observed_orcids":["https://orcid.org/0000-0003-3202-4069"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"David A. Wood","raw_affiliation_strings":["DWA Energy Limited , ,"],"raw_orcid":"https://orcid.org/0000-0003-3202-4069","affiliations":[{"raw_affiliation_string":"DWA Energy Limited , ,","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022743478","display_name":"Qinhong Hu","orcid":"https://orcid.org/0000-0002-4782-319X","observed_orcids":["https://orcid.org/0000-0002-4782-319X"]},"institutions":[{"id":"https://openalex.org/I4210162190","display_name":"China University of Petroleum, East China","ror":"https://ror.org/05gbn2817","country_code":"CN","type":"education","lineage":["https://openalex.org/I4210162190"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Qinhong Hu","raw_affiliation_strings":["China University of Petroleum (East China) , , ,"],"raw_orcid":"https://orcid.org/0000-0002-4782-319X","affiliations":[{"raw_affiliation_string":"China University of Petroleum (East China) , , ,","institution_ids":["https://openalex.org/I4210162190"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160748731","display_name":"Zhejun Pan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Zhejun Pan","raw_affiliation_strings":["Northeast Petroleum University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020801795","display_name":"Klaus Regenauer\u2010Lieb","orcid":"https://orcid.org/0000-0002-2198-5895","observed_orcids":["https://orcid.org/0000-0002-2198-5895","https://orcid.org/0000-0001-9867-7893"]},"institutions":[{"id":"https://openalex.org/I205640436","display_name":"Curtin University","ror":"https://ror.org/02n415q13","country_code":"AU","type":"education","lineage":["https://openalex.org/I205640436"]}],"countries":["AU"],"is_corresponding":true,"raw_author_name":"Klaus Regenauer-Lieb","raw_affiliation_strings":["Curtin University , , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Curtin University , , , ,","institution_ids":["https://openalex.org/I205640436"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100393094","display_name":"Bo Liu","orcid":"https://orcid.org/0000-0003-0136-7237","observed_orcids":["https://orcid.org/0000-0003-0136-7237"]},"institutions":[{"id":"https://openalex.org/I921716337","display_name":"Northeast Petroleum University","ror":"https://ror.org/03net5943","country_code":"CN","type":"education","lineage":["https://openalex.org/I921716337"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Bo Liu","raw_affiliation_strings":["Northeast Petroleum University , , ,"],"raw_orcid":"https://orcid.org/0000-0003-0136-7237","affiliations":[{"raw_affiliation_string":"Northeast Petroleum University , , ,","institution_ids":["https://openalex.org/I921716337"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":8,"corresponding_author_ids":["https://openalex.org/A5020801795","https://openalex.org/A5022743478","https://openalex.org/A5100393094","https://openalex.org/A5160748731"],"corresponding_institution_ids":["https://openalex.org/I205640436","https://openalex.org/I4210162190","https://openalex.org/I921716337"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10399","display_name":"Hydrocarbon exploration and reservoir analysis","score":0.9945999979972839,"subfield":{"id":"https://openalex.org/subfields/1907","display_name":"Geology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10399","display_name":"Hydrocarbon exploration and reservoir analysis","score":0.9945999979972839,"subfield":{"id":"https://openalex.org/subfields/1907","display_name":"Geology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10635","display_name":"Hydraulic Fracturing and Reservoir Analysis","score":0.0013000000035390258,"subfield":{"id":"https://openalex.org/subfields/2103","display_name":"Fuel Technology"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11588","display_name":"Atmospheric and Environmental Gas Dynamics","score":0.0012000000569969416,"subfield":{"id":"https://openalex.org/subfields/2306","display_name":"Global and Planetary Change"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/shale-nanopores","display_name":"shale nanopores","score":0.8450000286102295},{"id":"https://openalex.org/keywords/nanoconfinement","display_name":"nanoconfinement","score":0.8949999809265137},{"id":"https://openalex.org/keywords/water-adsorption","display_name":"water adsorption","score":0.46000000834465027},{"id":"https://openalex.org/keywords/kerogen","display_name":"kerogen","score":0.8330000042915344},{"id":"https://openalex.org/keywords/quartz-surface","display_name":"quartz surface","score":0.777999997138977},{"id":"https://openalex.org/keywords/water-film","display_name":"water film","score":0.4180000126361847},{"id":"https://openalex.org/keywords/water-clusters","display_name":"water clusters","score":0.5109999775886536},{"id":"https://openalex.org/keywords/microfracture","display_name":"microfracture","score":0.781000018119812},{"id":"https://openalex.org/keywords/gas-migration","display_name":"gas migration","score":0.6340000033378601},{"id":"https://openalex.org/keywords/hydraulic-fracturing","display_name":"hydraulic fracturing","score":0.8420000076293945},{"id":"https://openalex.org/keywords/longmaxi-shale","display_name":"Longmaxi shale","score":0.9340000152587891}],"concepts":[{"id":"https://openalex.org/C516920438","wikidata":"https://www.wikidata.org/wiki/Q37129","display_name":"Methane","level":2,"score":0.7423999905586243},{"id":"https://openalex.org/C153127940","wikidata":"https://www.wikidata.org/wiki/Q221378","display_name":"Oil shale","level":2,"score":0.676800012588501},{"id":"https://openalex.org/C2779196632","wikidata":"https://www.wikidata.org/wiki/Q938398","display_name":"Kerogen","level":4,"score":0.6187999844551086},{"id":"https://openalex.org/C2779096232","wikidata":"https://www.wikidata.org/wiki/Q890794","display_name":"Hydraulic fracturing","level":2,"score":0.6158999800682068},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.529699981212616},{"id":"https://openalex.org/C78762247","wikidata":"https://www.wikidata.org/wiki/Q1273174","display_name":"Petroleum engineering","level":1,"score":0.4738999903202057},{"id":"https://openalex.org/C2775865663","wikidata":"https://www.wikidata.org/wiki/Q7247687","display_name":"Produced water","level":2,"score":0.4733999967575073},{"id":"https://openalex.org/C2993020645","wikidata":"https://www.wikidata.org/wiki/Q564726","display_name":"Shale gas","level":3,"score":0.46540001034736633},{"id":"https://openalex.org/C59427239","wikidata":"https://www.wikidata.org/wiki/Q40858","display_name":"Natural gas","level":2,"score":0.41130000352859497},{"id":"https://openalex.org/C2779870107","wikidata":"https://www.wikidata.org/wiki/Q43010","display_name":"Quartz","level":2,"score":0.4075999855995178},{"id":"https://openalex.org/C24345647","wikidata":"https://www.wikidata.org/wiki/Q1147488","display_name":"Unconventional oil","level":3,"score":0.40220001339912415},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3774999976158142},{"id":"https://openalex.org/C6494504","wikidata":"https://www.wikidata.org/wiki/Q82480","display_name":"Sedimentary rock","level":2,"score":0.3531000018119812},{"id":"https://openalex.org/C147534773","wikidata":"https://www.wikidata.org/wiki/Q190120","display_name":"Water vapor","level":2,"score":0.352400004863739},{"id":"https://openalex.org/C104015590","wikidata":"https://www.wikidata.org/wiki/Q1451740","display_name":"Neutron scattering","level":3,"score":0.33970001339912415},{"id":"https://openalex.org/C39432304","wikidata":"https://www.wikidata.org/wiki/Q188847","display_name":"Environmental science","level":0,"score":0.3319999873638153},{"id":"https://openalex.org/C6648577","wikidata":"https://www.wikidata.org/wiki/Q622669","display_name":"Porosity","level":2,"score":0.32600000500679016},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.32260000705718994},{"id":"https://openalex.org/C2776469828","wikidata":"https://www.wikidata.org/wiki/Q955546","display_name":"Coalbed methane","level":4,"score":0.31029999256134033},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.3100999891757965},{"id":"https://openalex.org/C199289684","wikidata":"https://www.wikidata.org/wiki/Q83353","display_name":"Mineralogy","level":1,"score":0.3052000105381012},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3021000027656555},{"id":"https://openalex.org/C2779681308","wikidata":"https://www.wikidata.org/wiki/Q1049254","display_name":"Enhanced oil recovery","level":2,"score":0.2935999929904938},{"id":"https://openalex.org/C40212044","wikidata":"https://www.wikidata.org/wiki/Q1799034","display_name":"Clay minerals","level":2,"score":0.28519999980926514},{"id":"https://openalex.org/C134514944","wikidata":"https://www.wikidata.org/wiki/Q817136","display_name":"Wetting","level":2,"score":0.2671999931335449},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.2563000023365021},{"id":"https://openalex.org/C2778668878","wikidata":"https://www.wikidata.org/wiki/Q6380338","display_name":"Reservoir simulation","level":2,"score":0.25290000438690186},{"id":"https://openalex.org/C518851703","wikidata":"https://www.wikidata.org/wiki/Q24489","display_name":"Coal","level":2,"score":0.25279998779296875}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.est.6c01277","doi":"https://doi.org/10.1021/acs.est.6c01277","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.est.6c01277","pdf_url":null,"source":{"id":"https://openalex.org/S13479253","display_name":"Environmental Science & Technology","issn_l":"0013-936X","issn":["0013-936X","1520-5851"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","fnege-4","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Environmental Science & Technology","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320334704","display_name":"Australian Research Council","ror":"https://ror.org/05mmh0f86"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W1521514229","https://openalex.org/W2046599671","https://openalex.org/W2053294416","https://openalex.org/W2072795637","https://openalex.org/W2084589379","https://openalex.org/W2114878967","https://openalex.org/W2226595659","https://openalex.org/W2283357245","https://openalex.org/W2323163069","https://openalex.org/W2482513827","https://openalex.org/W2515798532","https://openalex.org/W2520466307","https://openalex.org/W2611440481","https://openalex.org/W2614887862","https://openalex.org/W2755847266","https://openalex.org/W2794228913","https://openalex.org/W2794362637","https://openalex.org/W2969408340","https://openalex.org/W2977983626","https://openalex.org/W3003114466","https://openalex.org/W3094212385","https://openalex.org/W3177340256","https://openalex.org/W3190325586","https://openalex.org/W3194096973","https://openalex.org/W3200566824","https://openalex.org/W3211801243","https://openalex.org/W4309951951","https://openalex.org/W4386520124","https://openalex.org/W4399921072","https://openalex.org/W4404929607","https://openalex.org/W4407352234","https://openalex.org/W4409872435","https://openalex.org/W4410014093","https://openalex.org/W4411145944","https://openalex.org/W4413051407","https://openalex.org/W4413093763","https://openalex.org/W4413987595","https://openalex.org/W4415785809"],"related_works":["https://openalex.org/W4309951951","https://openalex.org/W4407844889","https://openalex.org/W4206705391","https://openalex.org/W6904267633","https://openalex.org/W3099243595","https://openalex.org/W7157202339","https://openalex.org/W4402404724","https://openalex.org/W2024077808","https://openalex.org/W4416139142","https://openalex.org/W4386520124"],"abstract_inverted_index":{"Abstract":[0],"The":[1,133],"efficiency":[2],"of":[3,70,78,136],"unconventional":[4],"gas":[5,160,177],"recovery":[6,213],"is":[7],"fundamentally":[8],"governed":[9],"by":[10],"the":[11,74,79,168],"nanoscale":[12],"partitioning":[13],"and":[14,19,37,50,62,140,175,185,198,210],"competitive":[15],"exchange":[16,187],"between":[17,195],"methane":[18,92,154],"water":[20,117,137,173],"in":[21,33,112,214],"shale":[22],"reservoirs,":[23],"yet":[24],"direct":[25,68],"experimental":[26],"insight":[27],"into":[28,127],"their":[29],"coupled":[30],"behavior":[31],"under":[32],"situ":[34],"conditions":[35],"(pressure":[36],"temperature)":[38],"remains":[39],"elusive.":[40],"Here,":[41],"we":[42,163],"integrate":[43],"a":[44,84,95,192,203],"first-of-its-kind":[45],"approach,":[46],"combining":[47],"contrast-matching":[48],"ultra-":[49],"small-angle":[51],"neutron":[52],"scattering":[53],"(USANS/SANS)":[54],"at":[55,107,146],"50":[56],"MPa":[57],"with":[58,102,144,179],"vapor":[59],"sorption,":[60],"cryo-microscopy,":[61],"molecular":[63],"simulations,":[64],"to":[65,87,151],"achieve":[66],"unprecedented":[67],"visualization":[69],"methane\u2013water":[71],"distribution":[72],"across":[73],"multiscale":[75],"pore\u2013fracture":[76,180],"network":[77],"Longmaxi":[80],"Shale.":[81],"We":[82],"report":[83],"fundamental":[85],"revision":[86],"classical":[88],"models,":[89],"discovering":[90],"that":[91,165],"density":[93],"exhibits":[94],"non-monotonic":[96],"dependence":[97],"on":[98,121,130],"pore":[99],"size,":[100],"increasing":[101,142],"nanoconfinement":[103],"but":[104,125],"peaking":[105],"sharply":[106],"\u22482":[108],"nm":[109,114],"before":[110],"declining":[111],"sub-2":[113],"pores.":[115],"Mechanistically,":[116],"forms":[118],"continuous":[119],"films":[120],"hydrophilic":[122],"quartz":[123,139],"surfaces":[124],"aggregates":[126],"distinct":[128],"clusters":[129],"organic":[131],"kerogen.":[132],"stronger":[134],"affinity":[135],"for":[138,171,206],"its":[141],"interaction":[143],"kerogen":[145],"higher":[147],"saturations":[148],"enable":[149],"it":[150],"displace":[152],"adsorbed":[153],"competitively,":[155],"thereby":[156],"directly":[157],"controlling":[158],"local":[159],"saturation.":[161],"Furthermore,":[162],"reveal":[164],"microfractures":[166],"are":[167],"dominant":[169],"pathways":[170],"early":[172],"flowback":[174],"subsequent":[176],"migration,":[178],"connectivity":[181],"dictating":[182],"fluid":[183],"accessibility":[184],"phase":[186],"efficiency.":[188],"These":[189],"results":[190],"establish":[191],"mechanistic":[193],"link":[194],"interfacial":[196],"nanophysics":[197],"macro-scale":[199],"reservoir":[200],"performance,":[201],"providing":[202],"scientific":[204],"foundation":[205],"optimizing":[207],"hydraulic":[208],"fracturing":[209],"maximizing":[211],"resource":[212],"deep":[215],"sedimentary":[216],"systems.":[217]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2026-11-06T00:00:00"}