{"id":"https://openalex.org/W7225311391","doi":"https://doi.org/10.1021/acs.langmuir.6c04471","title":"Anomalous Alloying Effect on Water\u2013Rare-Earth Chemical Bonding","display_name":"Anomalous Alloying Effect on Water\u2013Rare-Earth Chemical Bonding","publication_year":2026,"publication_date":"2026-11-05","ids":{"openalex":"https://openalex.org/W7225311391","doi":"https://doi.org/10.1021/acs.langmuir.6c04471"},"language":"en","primary_location":{"id":"doi:10.1021/acs.langmuir.6c04471","doi":"https://doi.org/10.1021/acs.langmuir.6c04471","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.langmuir.6c04471","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100618198","display_name":"Qian Wu","orcid":"https://orcid.org/0000-0003-4344-2864","observed_orcids":["https://orcid.org/0000-0003-4344-2864"]},"institutions":[{"id":"https://openalex.org/I165745306","display_name":"Southwest Petroleum University","ror":"https://ror.org/03h17x602","country_code":"CN","type":"education","lineage":["https://openalex.org/I165745306"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qian Wu","raw_affiliation_strings":["Southwest Petroleum University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Southwest Petroleum University , , ,","institution_ids":["https://openalex.org/I165745306"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5126323433","display_name":"Yongjun Guo","orcid":"https://orcid.org/0000-0001-5926-5802","observed_orcids":["https://orcid.org/0000-0001-5926-5802"]},"institutions":[{"id":"https://openalex.org/I165745306","display_name":"Southwest Petroleum University","ror":"https://ror.org/03h17x602","country_code":"CN","type":"education","lineage":["https://openalex.org/I165745306"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yongjun Guo","raw_affiliation_strings":["Southwest Petroleum University , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Southwest Petroleum University , , ,","institution_ids":["https://openalex.org/I165745306"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5050165386","display_name":"Jibiao Li","orcid":"https://orcid.org/0000-0002-1948-6675","observed_orcids":["https://orcid.org/0000-0002-1948-6675"]},"institutions":[{"id":"https://openalex.org/I4210086059","display_name":"Sichuan University of Arts and Science","ror":"https://ror.org/00erq7915","country_code":"CN","type":"education","lineage":["https://openalex.org/I4210086059"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Jibiao Li","raw_affiliation_strings":["Sichuan University of Arts and Science , , ,"],"raw_orcid":"https://orcid.org/0000-0002-1948-6675","affiliations":[{"raw_affiliation_string":"Sichuan University of Arts and Science , , ,","institution_ids":["https://openalex.org/I4210086059"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5050165386"],"corresponding_institution_ids":["https://openalex.org/I4210086059"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.3571999967098236,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.3571999967098236,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.31619998812675476,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.11680000275373459,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/water-activation","display_name":"water activation","score":0.6489999890327454},{"id":"https://openalex.org/keywords/entropy-of-mixing","display_name":"entropy of mixing","score":0.8610000014305115},{"id":"https://openalex.org/keywords/hydrogen-evolution-catalysts","display_name":"hydrogen evolution catalysts","score":0.7630000114440918}],"concepts":[{"id":"https://openalex.org/C154256306","wikidata":"https://www.wikidata.org/wiki/Q41795528","display_name":"Inert","level":2,"score":0.7142000198364258},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.6488999724388123},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.6118999719619751},{"id":"https://openalex.org/C178213299","wikidata":"https://www.wikidata.org/wiki/Q44424","display_name":"Chemical bond","level":2,"score":0.554099977016449},{"id":"https://openalex.org/C2780026712","wikidata":"https://www.wikidata.org/wiki/Q37756","display_name":"Alloy","level":2,"score":0.5493999719619751},{"id":"https://openalex.org/C2991951333","wikidata":"https://www.wikidata.org/wiki/Q188403","display_name":"Quantum chemical","level":3,"score":0.47620001435279846},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4496000111103058},{"id":"https://openalex.org/C117626034","wikidata":"https://www.wikidata.org/wiki/Q26336","display_name":"Electrostatics","level":2,"score":0.44670000672340393},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.438400000333786},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.41780000925064087},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4023999869823456},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.39899998903274536},{"id":"https://openalex.org/C2984173401","wikidata":"https://www.wikidata.org/wiki/Q2914535","display_name":"Bonding strength","level":2,"score":0.3547999858856201},{"id":"https://openalex.org/C106301342","wikidata":"https://www.wikidata.org/wiki/Q4117933","display_name":"Entropy (arrow of time)","level":2,"score":0.34040001034736633},{"id":"https://openalex.org/C138777275","wikidata":"https://www.wikidata.org/wiki/Q6884054","display_name":"Mixing (physics)","level":2,"score":0.3328000009059906},{"id":"https://openalex.org/C177801218","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Chemical reaction","level":2,"score":0.32269999384880066},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.3172000050544739},{"id":"https://openalex.org/C2982804355","wikidata":"https://www.wikidata.org/wiki/Q26336","display_name":"Electrostatic interaction","level":2,"score":0.3142000138759613},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.3125999867916107},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.311599999666214},{"id":"https://openalex.org/C124223222","wikidata":"https://www.wikidata.org/wiki/Q2281940","display_name":"Chemical process","level":2,"score":0.29499998688697815},{"id":"https://openalex.org/C198664488","wikidata":"https://www.wikidata.org/wiki/Q191390","display_name":"Metallic bonding","level":3,"score":0.2806999981403351},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.2752000093460083},{"id":"https://openalex.org/C2776799497","wikidata":"https://www.wikidata.org/wiki/Q484298","display_name":"Surface (topology)","level":2,"score":0.26989999413490295},{"id":"https://openalex.org/C71100877","wikidata":"https://www.wikidata.org/wiki/Q483788","display_name":"Atomic radius","level":2,"score":0.2687000036239624},{"id":"https://openalex.org/C106773901","wikidata":"https://www.wikidata.org/wiki/Q19588","display_name":"Transition metal","level":3,"score":0.26669999957084656},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.26260000467300415},{"id":"https://openalex.org/C2986219828","wikidata":"https://www.wikidata.org/wiki/Q1193095","display_name":"Coupling strength","level":2,"score":0.26109999418258667},{"id":"https://openalex.org/C84114770","wikidata":"https://www.wikidata.org/wiki/Q46344","display_name":"Quantum","level":2,"score":0.25130000710487366}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.langmuir.6c04471","doi":"https://doi.org/10.1021/acs.langmuir.6c04471","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.langmuir.6c04471","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":81,"referenced_works":["https://openalex.org/W1480171480","https://openalex.org/W1528588768","https://openalex.org/W1547883012","https://openalex.org/W1561412729","https://openalex.org/W1970127494","https://openalex.org/W1970648125","https://openalex.org/W1972725254","https://openalex.org/W1973634181","https://openalex.org/W1977956754","https://openalex.org/W1978885192","https://openalex.org/W1979544533","https://openalex.org/W1980701169","https://openalex.org/W1982595063","https://openalex.org/W1982636142","https://openalex.org/W1989389325","https://openalex.org/W1991630775","https://openalex.org/W2000536749","https://openalex.org/W2000723365","https://openalex.org/W2000809676","https://openalex.org/W2004423809","https://openalex.org/W2008160179","https://openalex.org/W2011377242","https://openalex.org/W2014674060","https://openalex.org/W2015762944","https://openalex.org/W2015865951","https://openalex.org/W2016355541","https://openalex.org/W2016366655","https://openalex.org/W2019584170","https://openalex.org/W2020481794","https://openalex.org/W2022956627","https://openalex.org/W2023140555","https://openalex.org/W2032364562","https://openalex.org/W2034229688","https://openalex.org/W2036530432","https://openalex.org/W2040837725","https://openalex.org/W2042997794","https://openalex.org/W2043535587","https://openalex.org/W2043943217","https://openalex.org/W2050756904","https://openalex.org/W2064807075","https://openalex.org/W2066512076","https://openalex.org/W2067746562","https://openalex.org/W2068035701","https://openalex.org/W2069988560","https://openalex.org/W2073849165","https://openalex.org/W2087746033","https://openalex.org/W2093307998","https://openalex.org/W2102572148","https://openalex.org/W2105081100","https://openalex.org/W2111073819","https://openalex.org/W2120145199","https://openalex.org/W2126954122","https://openalex.org/W2136339388","https://openalex.org/W2146546128","https://openalex.org/W2147032026","https://openalex.org/W2152103620","https://openalex.org/W2158043072","https://openalex.org/W2160248419","https://openalex.org/W2169904128","https://openalex.org/W2267714992","https://openalex.org/W2332104279","https://openalex.org/W2757803490","https://openalex.org/W2783955276","https://openalex.org/W2784356185","https://openalex.org/W2885901182","https://openalex.org/W2892068630","https://openalex.org/W2975586142","https://openalex.org/W3176191040","https://openalex.org/W3203123649","https://openalex.org/W4300006503","https://openalex.org/W4378979648","https://openalex.org/W4385286534","https://openalex.org/W4390990587","https://openalex.org/W4403548243","https://openalex.org/W4410519907","https://openalex.org/W4411257197","https://openalex.org/W4413452043","https://openalex.org/W4416674521","https://openalex.org/W4416827839","https://openalex.org/W7152476537","https://openalex.org/W7165811595"],"related_works":["https://openalex.org/W7165811595","https://openalex.org/W2915005615","https://openalex.org/W4362520576","https://openalex.org/W7161054119","https://openalex.org/W2089423207","https://openalex.org/W2545141002","https://openalex.org/W2087746033","https://openalex.org/W2800244740","https://openalex.org/W4413452043","https://openalex.org/W4404562895"],"abstract_inverted_index":{"Abstract":[0],"Conventional":[1],"single-atom":[2,39],"alloying":[3,148],"(SAA)":[4,41],"effect":[5,55],"is":[6,61],"generally":[7],"regarded":[8],"as":[9],"a":[10,29,211],"design":[11,220],"strategy":[12],"modulating":[13],"the":[14,64,80,84,93,100,111,114,122,145,166,170,175,182,190,194,219],"surface":[15,67],"properties":[16],"of":[17,23,92,99,116,128,140,147,169,184,193,205,221],"an":[18,52],"alloy":[19],"system":[20],"between":[21,90],"those":[22],"its":[24],"individual":[25,131],"elemental":[26],"components.":[27],"For":[28],"long":[30],"time,":[31],"chemists":[32],"have":[33,50,105],"used":[34],"this":[35,47,137],"rule":[36,115],"to":[37,79,149],"make":[38],"alloys":[40],"with":[42,69,174],"desired":[43],"catalytic":[44],"performance.":[45],"In":[46,77],"study,":[48],"we":[49,104],"discovered":[51],"anomalous":[53,138,195],"SAA":[54,112,196],"on":[56],"water\u2013rare-earth":[57,85,108,124,141,206],"chemical":[58],"bonding,":[59],"which":[60],"exemplified":[62],"in":[63,110,165,188],"inert":[65,101],"Cd(0001)":[66,102],"doped":[68],"single":[70],"rare-earth":[71,95],"atoms":[72],"(Sc,":[73],"Y,":[74],"and":[75,97,119,153,157,218],"La).":[76],"contrast":[78],"conventional":[81],"expectation":[82],"that":[83,91,98,107,127,136,162],"coupling":[86],"strength":[87],"would":[88],"fall":[89],"pure":[94,130],"surfaces":[96],"surface,":[103],"demonstrated":[106],"couplings":[109],"break":[113],"\u201cin-between":[117],"mixing\u201d":[118],"synergistically":[120],"strengthen":[121,151],"local":[123],"interactions,":[125],"surpassing":[126],"any":[129],"surface.":[132],"Mechanistic":[133],"analysis":[134],"shows":[135],"enhancement":[139],"bonding":[142,167],"originates":[143],"from":[144],"ability":[146],"further":[150],"first-order":[152],"second-order":[154],"quantum":[155],"electrostatics":[156],"suppress":[158],"remaining":[159],"covalent":[160],"components":[161],"exist":[163],"only":[164,201],"channel":[168],"2a1":[171],"orbital":[172],"overlapped":[173],"atomic":[176],"metal":[177],"states.":[178],"These":[179],"findings":[180],"highlight":[181],"importance":[183],"SAA-based":[185],"mixing":[186],"entropy":[187],"reconstructing":[189],"underlying":[191],"mechanism":[192],"effect.":[197],"Our":[198],"investigations":[199],"not":[200],"deepen":[202],"our":[203],"understanding":[204],"interactions":[207],"but":[208],"also":[209],"provide":[210],"new":[212],"ground":[213],"for":[214],"controllable":[215],"water":[216],"activation":[217],"rare-earth-based":[222],"hydrogen":[223],"evolution":[224],"catalysts.":[225]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2026-11-06T00:00:00"}
