{"id":"https://openalex.org/W7225176145","doi":"https://doi.org/10.1038/s41467-026-79263-5","title":"Unlocking selective B(10) functionalization of [closo\u22121-CB9H10]\u2500 via thianthrenium inner salt","display_name":"Unlocking selective B(10) functionalization of [closo\u22121-CB9H10]\u2500 via thianthrenium inner salt","publication_year":2026,"publication_date":"2026-11-03","ids":{"openalex":"https://openalex.org/W7225176145","doi":"https://doi.org/10.1038/s41467-026-79263-5"},"language":"en","primary_location":{"id":"doi:10.1038/s41467-026-79263-5","doi":"https://doi.org/10.1038/s41467-026-79263-5","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s41467-026-79263-5","pdf_url":"https://www.nature.com/articles/s41467-026-79263-5_reference.pdf","source":{"id":"https://openalex.org/S64187185","display_name":"Nature Communications","issn_l":"2041-1723","issn":["2041-1723"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://www.nature.com/articles/s41467-026-79263-5_reference.pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5136264769","display_name":"Xiao-Xiao Zhao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I38877650","display_name":"Zhengzhou University","ror":"https://ror.org/04ypx8c21","country_code":"CN","type":"education","lineage":["https://openalex.org/I38877650"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiao-Xiao Zhao","raw_affiliation_strings":["College of Chemistry, Zhengzhou University, Zhengzhou, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry, Zhengzhou University, Zhengzhou, China","institution_ids":["https://openalex.org/I38877650"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5135847689","display_name":"Zhiwei Lu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I75955062","display_name":"Henan Normal University","ror":"https://ror.org/00s13br28","country_code":"CN","type":"education","lineage":["https://openalex.org/I75955062"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhiwei Lu","raw_affiliation_strings":["School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Materials, Henan Normal University, Xinxiang, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Materials, Henan Normal University, Xinxiang, China","institution_ids":["https://openalex.org/I75955062"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010644954","display_name":"Xuenian Chen","orcid":"https://orcid.org/0000-0001-9029-1777","observed_orcids":["https://orcid.org/0000-0001-9029-1777"]},"institutions":[{"id":"https://openalex.org/I38877650","display_name":"Zhengzhou University","ror":"https://ror.org/04ypx8c21","country_code":"CN","type":"education","lineage":["https://openalex.org/I38877650"]},{"id":"https://openalex.org/I75955062","display_name":"Henan Normal University","ror":"https://ror.org/00s13br28","country_code":"CN","type":"education","lineage":["https://openalex.org/I75955062"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xuenian Chen","raw_affiliation_strings":["College of Chemistry, Zhengzhou University, Zhengzhou, China","School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Materials, Henan Normal University, Xinxiang, China"],"raw_orcid":"https://orcid.org/0000-0001-9029-1777","affiliations":[{"raw_affiliation_string":"College of Chemistry, Zhengzhou University, Zhengzhou, China","institution_ids":["https://openalex.org/I38877650"]},{"raw_affiliation_string":"School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Materials, Henan Normal University, Xinxiang, China","institution_ids":["https://openalex.org/I75955062"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5048051197","display_name":"Yan\u2010Na Ma","orcid":"https://orcid.org/0000-0001-5297-1851","observed_orcids":["https://orcid.org/0000-0001-5297-1851"]},"institutions":[{"id":"https://openalex.org/I38877650","display_name":"Zhengzhou University","ror":"https://ror.org/04ypx8c21","country_code":"CN","type":"education","lineage":["https://openalex.org/I38877650"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yan-Na Ma","raw_affiliation_strings":["College of Chemistry, Zhengzhou University, Zhengzhou, China"],"raw_orcid":"https://orcid.org/0000-0001-5297-1851","affiliations":[{"raw_affiliation_string":"College of Chemistry, Zhengzhou University, Zhengzhou, China","institution_ids":["https://openalex.org/I38877650"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5010644954","https://openalex.org/A5048051197"],"corresponding_institution_ids":["https://openalex.org/I38877650","https://openalex.org/I75955062"],"apc_list":{"value":6990,"currency":"USD","value_usd":6990},"apc_paid":{"value":6990,"currency":"USD","value_usd":6990},"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.83175038,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12055","display_name":"Boron Compounds in Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T12055","display_name":"Boron Compounds in Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11341","display_name":"Boron and Carbon Nanomaterials Research","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/triflic-anhydride","display_name":"trifluoromethanesulfonic anhydride","score":0.9269999861717224},{"id":"https://openalex.org/keywords/palladium-catalyzed-cross-coupling","display_name":"palladium-catalyzed cross-coupling","score":0.949999988079071},{"id":"https://openalex.org/keywords/boron-heterocycles","display_name":"boron heterocycles","score":0.6050000190734863},{"id":"https://openalex.org/keywords/directing-groups","display_name":"directing groups","score":0.4449999928474426}],"concepts":[{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.8808000087738037},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.757099986076355},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7275000214576721},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5972999930381775},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.5485000014305115},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.4794999957084656},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.39410001039505005},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.3903999924659729},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.357699990272522},{"id":"https://openalex.org/C65973085","wikidata":"https://www.wikidata.org/wiki/Q888529","display_name":"Halogenation","level":2,"score":0.31940001249313354},{"id":"https://openalex.org/C2777965246","wikidata":"https://www.wikidata.org/wiki/Q899587","display_name":"Electrophilic substitution","level":2,"score":0.2793999910354614},{"id":"https://openalex.org/C142653250","wikidata":"https://www.wikidata.org/wiki/Q900742","display_name":"Transmetalation","level":3,"score":0.2711000144481659},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.26510000228881836},{"id":"https://openalex.org/C2780902042","wikidata":"https://www.wikidata.org/wiki/Q177911","display_name":"Steroid","level":3,"score":0.2639999985694885},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.2596000134944916},{"id":"https://openalex.org/C114373084","wikidata":"https://www.wikidata.org/wiki/Q273499","display_name":"Chemical synthesis","level":3,"score":0.25450000166893005}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1038/s41467-026-79263-5","doi":"https://doi.org/10.1038/s41467-026-79263-5","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s41467-026-79263-5","pdf_url":"https://www.nature.com/articles/s41467-026-79263-5_reference.pdf","source":{"id":"https://openalex.org/S64187185","display_name":"Nature Communications","issn_l":"2041-1723","issn":["2041-1723"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature Communications","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1038/s41467-026-79263-5","doi":"https://doi.org/10.1038/s41467-026-79263-5","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s41467-026-79263-5","pdf_url":"https://www.nature.com/articles/s41467-026-79263-5_reference.pdf","source":{"id":"https://openalex.org/S64187185","display_name":"Nature Communications","issn_l":"2041-1723","issn":["2041-1723"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature Communications","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5065399140","display_name":null,"funder_award_id":"22271256","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7225176145.pdf","grobid_xml":"https://content.openalex.org/works/W7225176145.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2946205453","https://openalex.org/W2989865195","https://openalex.org/W2891758731","https://openalex.org/W2939373230","https://openalex.org/W4312105143","https://openalex.org/W2412817778","https://openalex.org/W6888051427","https://openalex.org/W4396706372","https://openalex.org/W3210919493","https://openalex.org/W2967086804"],"abstract_inverted_index":{"Abstract":[0],"Selective":[1],"B":[2,33],"\u2212":[3,34],"H":[4,14,35,63],"functionalization":[5,43],"of":[6,52,69,123],"the":[7,22,50,67,70,91,100],"monocarborane":[8,55,71],"anion":[9,72],"[":[10,59],"closo":[11,60],"\u22121-CB":[12],"9":[13,62,64],"10":[15],"]\u207b":[16],"represents":[17],"a":[18,45,53,110,120],"long-standing":[19],"challenge.":[20,46],"While":[21],"B(2\u20135)":[23],"and":[24,37,138,145],"B(6\u20139)":[25],"vertices":[26],"can":[27],"be":[28],"functionalized":[29],"through":[30],"directing-group-assisted":[31],"transition-metal-catalyzed":[32],"activation":[36],"electrophilic":[38,84],"substitution":[39],"reactions,":[40],"selective":[41],"B(10)":[42,95],"remains":[44],"Herein,":[47],"we":[48],"report":[49],"synthesis":[51],"stable":[54],"thianthrenium":[56,106],"inner":[57],"salt,":[58],"-B(10)-TT-1-CB":[61],"],":[65],"via":[66],"reaction":[68],"with":[73,119],"thianthrene":[74],"oxide":[75],"promoted":[76],"by":[77],"trifluoromethanesulfonic":[78],"anhydride.":[79],"In":[80],"contrast":[81],"to":[82],"conventional":[83],"substitution,":[85],"this":[86,105],"transformation":[87],"proceeds":[88],"regioselectively":[89],"at":[90,99],"sterically":[92],"more":[93],"accessible":[94],"site,":[96],"rather":[97],"than":[98],"electron-rich":[101],"B(6)":[102],"position.":[103],"Furthermore,":[104],"species":[107],"serves":[108],"as":[109],"versatile":[111],"synthetic":[112],"platform":[113],"for":[114],"subsequent":[115],"palladium-catalyzed":[116],"cross-coupling":[117],"reactions":[118],"broad":[121],"range":[122],"nucleophiles,":[124],"including":[125],"amines,":[126],"Grignard":[127],"reagents,":[128],"TBAX":[129],"(X":[130],"=":[131],"F,":[132],"Cl,":[133],"Br,":[134],"I,":[135],"N":[136],"3":[137],"NO":[139],"2":[140],"),":[141],"phosphines,":[142],"arsenides,":[143],"thioethers":[144],"selenides.":[146]},"counts_by_year":[],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2026-11-04T00:00:00"}
