{"id":"https://openalex.org/W7225009295","doi":"https://doi.org/10.1002/aic.70746","title":"Support\u2010controlled Pd cluster catalysts for selective hydrogenation of \u03b1, \u03b2\u2010unsaturated aldehydes to saturated aldehydes","display_name":"Support\u2010controlled Pd cluster catalysts for selective hydrogenation of \u03b1, \u03b2\u2010unsaturated aldehydes to saturated aldehydes","publication_year":2026,"publication_date":"2026-10-30","ids":{"openalex":"https://openalex.org/W7225009295","doi":"https://doi.org/10.1002/aic.70746"},"language":"en","primary_location":{"id":"doi:10.1002/aic.70746","doi":"https://doi.org/10.1002/aic.70746","is_oa":true,"landing_page_url":"https://doi.org/10.1002/aic.70746","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/aic.70746","source":{"id":"https://openalex.org/S147177414","display_name":"AIChE Journal","issn_l":"0001-1541","issn":["0001-1541","1547-5905"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"AIChE Journal","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/aic.70746","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5121481698","display_name":"Wenli Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4472751","display_name":"Anhui Normal University","ror":"https://ror.org/05fsfvw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I4472751"]},{"id":"https://openalex.org/I70908550","display_name":"Anhui Polytechnic University","ror":"https://ror.org/041sj0284","country_code":"CN","type":"education","lineage":["https://openalex.org/I70908550"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Wenli Xu","raw_affiliation_strings":["College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","School of Chemical and Environmental Engineering, Anhui Laboratory of Clean Catalytic Engineering, Anhui Polytechnic University  Wuhu China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","institution_ids":["https://openalex.org/I4472751"]},{"raw_affiliation_string":"School of Chemical and Environmental Engineering, Anhui Laboratory of Clean Catalytic Engineering, Anhui Polytechnic University  Wuhu China","institution_ids":["https://openalex.org/I70908550"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5141174062","display_name":"Hao Fan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4472751","display_name":"Anhui Normal University","ror":"https://ror.org/05fsfvw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I4472751"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hao Fan","raw_affiliation_strings":["College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","institution_ids":["https://openalex.org/I4472751"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070574260","display_name":"Long Kuai","orcid":"https://orcid.org/0000-0002-8633-0320","observed_orcids":["https://orcid.org/0000-0002-8633-0320"]},"institutions":[{"id":"https://openalex.org/I70908550","display_name":"Anhui Polytechnic University","ror":"https://ror.org/041sj0284","country_code":"CN","type":"education","lineage":["https://openalex.org/I70908550"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Long Kuai","raw_affiliation_strings":["School of Chemical and Environmental Engineering, Anhui Laboratory of Clean Catalytic Engineering, Anhui Polytechnic University  Wuhu China"],"raw_orcid":"https://orcid.org/0000-0002-8633-0320","affiliations":[{"raw_affiliation_string":"School of Chemical and Environmental Engineering, Anhui Laboratory of Clean Catalytic Engineering, Anhui Polytechnic University  Wuhu China","institution_ids":["https://openalex.org/I70908550"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087347944","display_name":"Zixuan Guo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4472751","display_name":"Anhui Normal University","ror":"https://ror.org/05fsfvw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I4472751"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zixuan Guo","raw_affiliation_strings":["College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","institution_ids":["https://openalex.org/I4472751"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160273040","display_name":"Heng Wu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4472751","display_name":"Anhui Normal University","ror":"https://ror.org/05fsfvw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I4472751"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Heng Wu","raw_affiliation_strings":["College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","institution_ids":["https://openalex.org/I4472751"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100396692","display_name":"Shuai Chen","orcid":"https://orcid.org/0000-0002-9950-6049","observed_orcids":["https://orcid.org/0000-0002-9950-6049","https://orcid.org/0000-0002-6265-7097"]},"institutions":[{"id":"https://openalex.org/I4472751","display_name":"Anhui Normal University","ror":"https://ror.org/05fsfvw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I4472751"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shuai Chen","raw_affiliation_strings":["College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","institution_ids":["https://openalex.org/I4472751"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5045572261","display_name":"Baoyou Geng","orcid":"https://orcid.org/0000-0002-3657-0510","observed_orcids":["https://orcid.org/0000-0002-3657-0510","https://orcid.org/0000-0003-2049-3984"]},"institutions":[{"id":"https://openalex.org/I4472751","display_name":"Anhui Normal University","ror":"https://ror.org/05fsfvw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I4472751"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Baoyou Geng","raw_affiliation_strings":["College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China"],"raw_orcid":"https://orcid.org/0000-0002-3657-0510","affiliations":[{"raw_affiliation_string":"College of Chemistry and Molecular Sciences, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University  Wuhu China","institution_ids":["https://openalex.org/I4472751"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5045572261","https://openalex.org/A5070574260"],"corresponding_institution_ids":["https://openalex.org/I4472751","https://openalex.org/I70908550"],"apc_list":{"value":4940,"currency":"USD","value_usd":4940},"apc_paid":null,"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.72639197,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12240","display_name":"Nanomaterials for catalytic reactions","score":0.9746000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12240","display_name":"Nanomaterials for catalytic reactions","score":0.9746000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":0.017500000074505806,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.00559999980032444,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/selective-hydrogenation","display_name":"selective hydrogenation","score":0.9539999961853027},{"id":"https://openalex.org/keywords/alpha-beta-unsaturated-aldehydes","display_name":"\u03b1,\u03b2-unsaturated aldehydes","score":0.9940000176429749},{"id":"https://openalex.org/keywords/cinnamaldehyde","display_name":"cinnamaldehyde","score":0.9470000267028809},{"id":"https://openalex.org/keywords/aerosol-spray-pyrolysis","display_name":"aerosol spray pyrolysis","score":0.9340000152587891},{"id":"https://openalex.org/keywords/single-atom-catalysts","display_name":"single-atom catalysts","score":0.8740000128746033},{"id":"https://openalex.org/keywords/c-c-bond-cleavage","display_name":"C\u2013C bond cleavage","score":0.5460000038146973},{"id":"https://openalex.org/keywords/catalyst-reusability","display_name":"catalyst reusability","score":0.6650000214576721},{"id":"https://openalex.org/keywords/acrolein","display_name":"acrolein","score":0.847000002861023},{"id":"https://openalex.org/keywords/crotonaldehyde","display_name":"crotonaldehyde","score":0.9950000047683716},{"id":"https://openalex.org/keywords/biorefinery","display_name":"biorefinery","score":0.9160000085830688}],"concepts":[{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.840399980545044},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.7401999831199646},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7254999876022339},{"id":"https://openalex.org/C175689099","wikidata":"https://www.wikidata.org/wiki/Q908109","display_name":"Homolysis","level":3,"score":0.6467000246047974},{"id":"https://openalex.org/C2777435628","wikidata":"https://www.wikidata.org/wiki/Q204036","display_name":"Cinnamaldehyde","level":3,"score":0.5885999798774719},{"id":"https://openalex.org/C44578547","wikidata":"https://www.wikidata.org/wiki/Q907567","display_name":"Heterolysis","level":3,"score":0.5281000137329102},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.47189998626708984},{"id":"https://openalex.org/C175583648","wikidata":"https://www.wikidata.org/wiki/Q903156","display_name":"Heterogeneous catalysis","level":3,"score":0.428600013256073},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.41179999709129333},{"id":"https://openalex.org/C164866538","wikidata":"https://www.wikidata.org/wiki/Q367351","display_name":"Cluster (spacecraft)","level":2,"score":0.3910999894142151},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3855000138282776},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.38370001316070557},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.3402999937534332},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3384999930858612},{"id":"https://openalex.org/C190667039","wikidata":"https://www.wikidata.org/wiki/Q3738104","display_name":"Chemoselectivity","level":3,"score":0.3212999999523163},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.31859999895095825},{"id":"https://openalex.org/C2780301381","wikidata":"https://www.wikidata.org/wiki/Q864683","display_name":"Biorefinery","level":3,"score":0.2937000095844269},{"id":"https://openalex.org/C45083100","wikidata":"https://www.wikidata.org/wiki/Q17156221","display_name":"Nanomaterial-based catalyst","level":3,"score":0.2824999988079071},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.26159998774528503},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.25049999356269836}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/aic.70746","doi":"https://doi.org/10.1002/aic.70746","is_oa":true,"landing_page_url":"https://doi.org/10.1002/aic.70746","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/aic.70746","source":{"id":"https://openalex.org/S147177414","display_name":"AIChE Journal","issn_l":"0001-1541","issn":["0001-1541","1547-5905"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"AIChE Journal","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/aic.70746","doi":"https://doi.org/10.1002/aic.70746","is_oa":true,"landing_page_url":"https://doi.org/10.1002/aic.70746","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/aic.70746","source":{"id":"https://openalex.org/S147177414","display_name":"AIChE Journal","issn_l":"0001-1541","issn":["0001-1541","1547-5905"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"AIChE Journal","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7225009295.pdf","grobid_xml":"https://content.openalex.org/works/W7225009295.grobid-xml"},"referenced_works_count":50,"referenced_works":["https://openalex.org/W1768517216","https://openalex.org/W1970127494","https://openalex.org/W1979544533","https://openalex.org/W1981368803","https://openalex.org/W2023390323","https://openalex.org/W2528956049","https://openalex.org/W2930961564","https://openalex.org/W2975586142","https://openalex.org/W2999739097","https://openalex.org/W3006662681","https://openalex.org/W3083770223","https://openalex.org/W3111097600","https://openalex.org/W3167503671","https://openalex.org/W3183888331","https://openalex.org/W3216831125","https://openalex.org/W4205512909","https://openalex.org/W4210329666","https://openalex.org/W4213179957","https://openalex.org/W4281649055","https://openalex.org/W4283589570","https://openalex.org/W4293379581","https://openalex.org/W4296700855","https://openalex.org/W4318614116","https://openalex.org/W4322732677","https://openalex.org/W4323660250","https://openalex.org/W4362523084","https://openalex.org/W4368356155","https://openalex.org/W4378176793","https://openalex.org/W4382918274","https://openalex.org/W4387843331","https://openalex.org/W4389219003","https://openalex.org/W4391091852","https://openalex.org/W4392615570","https://openalex.org/W4393200350","https://openalex.org/W4394011007","https://openalex.org/W4394915902","https://openalex.org/W4398139306","https://openalex.org/W4398177279","https://openalex.org/W4399854204","https://openalex.org/W4402605057","https://openalex.org/W4402849814","https://openalex.org/W4402966963","https://openalex.org/W4403299654","https://openalex.org/W4404111120","https://openalex.org/W4404354072","https://openalex.org/W4405357285","https://openalex.org/W4406038892","https://openalex.org/W4412761298","https://openalex.org/W4414078501","https://openalex.org/W7135012751"],"related_works":["https://openalex.org/W2538661784","https://openalex.org/W4366772331","https://openalex.org/W1964068083","https://openalex.org/W3212002563","https://openalex.org/W4415383316","https://openalex.org/W4280564011","https://openalex.org/W2285201286","https://openalex.org/W7204038320","https://openalex.org/W2810634787","https://openalex.org/W3115665049"],"abstract_inverted_index":{"Abstract":[0],"Selective":[1],"hydrogenation":[2,53],"of":[3,23,29,54,87],"\u03b1,":[4],"\u03b2\u2010unsaturated":[5],"aldehydes":[6],"remains":[7],"challenging":[8],"due":[9],"to":[10,57,115],"competitive":[11],"C\uf8feC":[12,52,104],"and":[13,32,79,92,102,127,134,142],"C\uf8feO":[14],"bond":[15],"activation.":[16],"We":[17],"report":[18],"an":[19],"aerosol":[20],"spray\u2010pyrolysis":[21],"synthesis":[22],"Pd":[24,42],"catalysts":[25,82],"with":[26,70,83],"tunable":[27],"dispersions":[28],"nanoparticles,":[30],"clusters,":[31],"single":[33],"atoms,":[34],"by":[35],"varying":[36],"the":[37,128],"Ti/Ce":[38],"ratio":[39],"in":[40],"supports.":[41],"clusters":[43,96],"on":[44],"Ti\u2010doped":[45],"CeO":[46],"2":[47,67,100],"achieve":[48],"97.9%":[49],"selectivity":[50,86],"toward":[51],"cinnamaldehyde":[55],"(CAL)":[56],"phenylpropanal":[58],"(HCAL)":[59],"under":[60],"mild":[61],"conditions":[62],"(70\u00b0C,":[63],"1":[64],"MPa":[65],"H":[66,99],"),":[68],"along":[69],"complete":[71],"conversion":[72],"within":[73],"0.5":[74],"h,":[75],"outperforming":[76],"nanoparticles":[77],"(56.1%)":[78],"single\u2010atom":[80,109],"dominant":[81],"a":[84,139,144],"favored":[85],"acetalization.":[88],"Synchrotron":[89],"XAFS,":[90],"AC\u2010STEM,":[91],"DFT":[93],"reveal":[94],"that":[95],"enable":[97],"homolytic":[98],"cleavage":[101],"strong":[103],"adsorption":[105],"(\u22121.39":[106],"eV),":[107],"while":[108],"sites":[110],"promote":[111],"heterolytic":[112],"splitting":[113],"leading":[114],"acid\u2010catalyzed":[116],"side":[117],"reactions.":[118],"The":[119],"catalyst":[120,147],"shows":[121],"robust":[122],"recyclability":[123],"over":[124],"10":[125],"cycles,":[126],"strategy":[129],"is":[130],"universal":[131],"for":[132,149],"acrolein":[133],"crotonaldehyde.":[135],"This":[136],"work":[137],"establishes":[138],"structure\u2010selectivity":[140],"framework":[141],"offers":[143],"potentially":[145],"scalable":[146],"design":[148],"sustainable":[150],"biorefinery":[151],"processes.":[152]},"counts_by_year":[],"updated_date":"2026-11-02T09:45:03.842371","created_date":"2026-11-01T00:00:00"}