{"id":"https://openalex.org/W7224797972","doi":"https://doi.org/10.1002/anie.4598413","title":"Photocatalytically Generated Nitrate Radicals Drive Decomposition of Perfluorooctanoic Acid","display_name":"Photocatalytically Generated Nitrate Radicals Drive Decomposition of Perfluorooctanoic Acid","publication_year":2026,"publication_date":"2026-10-30","ids":{"openalex":"https://openalex.org/W7224797972","doi":"https://doi.org/10.1002/anie.4598413","pmid":"https://pubmed.ncbi.nlm.nih.gov/42963192"},"language":"en","primary_location":{"id":"doi:10.1002/anie.4598413","doi":"https://doi.org/10.1002/anie.4598413","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.4598413","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4598413","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4598413","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5160152189","display_name":"Dawei Wang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I163340411","display_name":"Hohai University","ror":"https://ror.org/01wd4xt90","country_code":"CN","type":"education","lineage":["https://openalex.org/I163340411"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Dawei Wang","raw_affiliation_strings":["Key Laboratory of Integrated Regulation and Resource Development On Shallow Lake of Ministry of Education College of Environment Hohai University  Nanjing P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Integrated Regulation and Resource Development On Shallow Lake of Ministry of Education College of Environment Hohai University  Nanjing P. R. China","institution_ids":["https://openalex.org/I163340411"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100452091","display_name":"Zhuang Liu","orcid":"https://orcid.org/0000-0001-6898-5908","observed_orcids":["https://orcid.org/0000-0001-6898-5908"]},"institutions":[{"id":"https://openalex.org/I163340411","display_name":"Hohai University","ror":"https://ror.org/01wd4xt90","country_code":"CN","type":"education","lineage":["https://openalex.org/I163340411"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhuang Liu","raw_affiliation_strings":["Key Laboratory of Integrated Regulation and Resource Development On Shallow Lake of Ministry of Education College of Environment Hohai University  Nanjing P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Integrated Regulation and Resource Development On Shallow Lake of Ministry of Education College of Environment Hohai University  Nanjing P. R. China","institution_ids":["https://openalex.org/I163340411"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101784210","display_name":"Chaoyi Yin","orcid":"https://orcid.org/0000-0002-3464-4811","observed_orcids":["https://orcid.org/0000-0002-3464-4811"]},"institutions":[{"id":"https://openalex.org/I163340411","display_name":"Hohai University","ror":"https://ror.org/01wd4xt90","country_code":"CN","type":"education","lineage":["https://openalex.org/I163340411"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chaoyi Yin","raw_affiliation_strings":["Key Laboratory of Integrated Regulation and Resource Development On Shallow Lake of Ministry of Education College of Environment Hohai University  Nanjing P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Integrated Regulation and Resource Development On Shallow Lake of Ministry of Education College of Environment Hohai University  Nanjing P. R. China","institution_ids":["https://openalex.org/I163340411"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076905718","display_name":"Alessandro Gottuso","orcid":"https://orcid.org/0009-0003-5875-4745","observed_orcids":["https://orcid.org/0009-0003-5875-4745"]},"institutions":[{"id":"https://openalex.org/I183067930","display_name":"Shanghai Jiao Tong University","ror":"https://ror.org/0220qvk04","country_code":"CN","type":"education","lineage":["https://openalex.org/I183067930"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Alessandro Gottuso","raw_affiliation_strings":["State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China"],"raw_orcid":"https://orcid.org/0009-0003-5875-4745","affiliations":[{"raw_affiliation_string":"State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China","institution_ids":["https://openalex.org/I183067930"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028336124","display_name":"Jinming Luo","orcid":"https://orcid.org/0000-0001-8698-7624","observed_orcids":["https://orcid.org/0000-0001-8698-7624"]},"institutions":[{"id":"https://openalex.org/I183067930","display_name":"Shanghai Jiao Tong University","ror":"https://ror.org/0220qvk04","country_code":"CN","type":"education","lineage":["https://openalex.org/I183067930"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jinming Luo","raw_affiliation_strings":["State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China"],"raw_orcid":"https://orcid.org/0000-0001-8698-7624","affiliations":[{"raw_affiliation_string":"State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China","institution_ids":["https://openalex.org/I183067930"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055653134","display_name":"Yu Lei","orcid":"https://orcid.org/0000-0002-0120-6110","observed_orcids":["https://orcid.org/0000-0002-0120-6110"]},"institutions":[{"id":"https://openalex.org/I183067930","display_name":"Shanghai Jiao Tong University","ror":"https://ror.org/0220qvk04","country_code":"CN","type":"education","lineage":["https://openalex.org/I183067930"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yu Lei","raw_affiliation_strings":["State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-0120-6110","affiliations":[{"raw_affiliation_string":"State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China","institution_ids":["https://openalex.org/I183067930"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101592759","display_name":"Mingce Long","orcid":"https://orcid.org/0000-0002-5168-8330","observed_orcids":["https://orcid.org/0000-0002-5168-8330"]},"institutions":[{"id":"https://openalex.org/I183067930","display_name":"Shanghai Jiao Tong University","ror":"https://ror.org/0220qvk04","country_code":"CN","type":"education","lineage":["https://openalex.org/I183067930"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Mingce Long","raw_affiliation_strings":["State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-5168-8330","affiliations":[{"raw_affiliation_string":"State Key Laboratory of Green Papermaking and Resource Recycling School of Environmental Science and Engineering Shanghai Jiao Tong University  Shanghai P. R. China","institution_ids":["https://openalex.org/I183067930"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5084133194","display_name":"Francesco Parrino","orcid":"https://orcid.org/0000-0001-7507-941X","observed_orcids":["https://orcid.org/0000-0001-7507-941X"]},"institutions":[{"id":"https://openalex.org/I193223587","display_name":"University of Trento","ror":"https://ror.org/05trd4x28","country_code":"IT","type":"education","lineage":["https://openalex.org/I193223587"]}],"countries":["IT"],"is_corresponding":true,"raw_author_name":"Francesco Parrino","raw_affiliation_strings":["Department of Industrial Engineering University of Trento  Trento Italy"],"raw_orcid":"https://orcid.org/0000-0001-7507-941X","affiliations":[{"raw_affiliation_string":"Department of Industrial Engineering University of Trento  Trento Italy","institution_ids":["https://openalex.org/I193223587"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5084133194","https://openalex.org/A5160152189"],"corresponding_institution_ids":["https://openalex.org/I163340411","https://openalex.org/I193223587"],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":null,"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.73235245,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11869","display_name":"Per- and polyfluoroalkyl substances research","score":0.9380000233650208,"subfield":{"id":"https://openalex.org/subfields/2304","display_name":"Environmental Chemistry"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11869","display_name":"Per- and polyfluoroalkyl substances research","score":0.9380000233650208,"subfield":{"id":"https://openalex.org/subfields/2304","display_name":"Environmental Chemistry"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.04960000142455101,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.004399999976158142,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nitrate-radical","display_name":"nitrate radical","score":0.8970000147819519},{"id":"https://openalex.org/keywords/perfluorooctanoic-acid","display_name":"perfluorooctanoic acid","score":0.9869999885559082},{"id":"https://openalex.org/keywords/pfas-degradation","display_name":"PFAS degradation","score":0.8180000185966492},{"id":"https://openalex.org/keywords/photocatalysis","display_name":"photocatalysis","score":0.871999979019165},{"id":"https://openalex.org/keywords/titanium-dioxide","display_name":"titanium dioxide","score":0.7559999823570251},{"id":"https://openalex.org/keywords/fluoride-release","display_name":"fluoride release","score":0.4909999966621399},{"id":"https://openalex.org/keywords/hydrogen-atom-transfer","display_name":"hydrogen atom transfer","score":0.9629999995231628},{"id":"https://openalex.org/keywords/decarboxylation","display_name":"decarboxylation","score":0.9079999923706055},{"id":"https://openalex.org/keywords/hydroxylation","display_name":"hydroxylation","score":0.9039999842643738},{"id":"https://openalex.org/keywords/adsorbent-regeneration","display_name":"adsorbent regeneration","score":0.8109999895095825},{"id":"https://openalex.org/keywords/water-remediation","display_name":"water remediation","score":0.6990000009536743},{"id":"https://openalex.org/keywords/transient-absorption-spectroscopy","display_name":"transient absorption spectroscopy","score":0.7639999985694885}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.891700029373169},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.7886999845504761},{"id":"https://openalex.org/C2776384668","wikidata":"https://www.wikidata.org/wiki/Q182168","display_name":"Nitrate","level":2,"score":0.7146999835968018},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.6504999995231628},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.6470000147819519},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.47209998965263367},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.45660001039505005},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.45320001244544983},{"id":"https://openalex.org/C533411734","wikidata":"https://www.wikidata.org/wiki/Q171877","display_name":"Hydrogen peroxide","level":2,"score":0.4180999994277954},{"id":"https://openalex.org/C2775979320","wikidata":"https://www.wikidata.org/wiki/Q418348","display_name":"Perfluorooctanoic acid","level":2,"score":0.4025999903678894},{"id":"https://openalex.org/C66887884","wikidata":"https://www.wikidata.org/wiki/Q2126498","display_name":"Radiolysis","level":3,"score":0.39969998598098755},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.39879998564720154},{"id":"https://openalex.org/C2781109383","wikidata":"https://www.wikidata.org/wiki/Q898497","display_name":"Hydroxylation","level":3,"score":0.3873000144958496},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.3824999928474426},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.3634999990463257},{"id":"https://openalex.org/C2780595602","wikidata":"https://www.wikidata.org/wiki/Q898436","display_name":"Decarboxylation","level":3,"score":0.35850000381469727},{"id":"https://openalex.org/C2778504605","wikidata":"https://www.wikidata.org/wiki/Q83320","display_name":"Nitric acid","level":2,"score":0.3582000136375427},{"id":"https://openalex.org/C56783068","wikidata":"https://www.wikidata.org/wiki/Q172867","display_name":"Scavenger","level":3,"score":0.35589998960494995},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.34619998931884766},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.32899999618530273},{"id":"https://openalex.org/C2776617377","wikidata":"https://www.wikidata.org/wiki/Q182329","display_name":"Ammonium nitrate","level":2,"score":0.3156999945640564},{"id":"https://openalex.org/C2780828025","wikidata":"https://www.wikidata.org/wiki/Q44793182","display_name":"Fluoride","level":2,"score":0.3086000084877014},{"id":"https://openalex.org/C107211472","wikidata":"https://www.wikidata.org/wiki/Q284486","display_name":"Human decontamination","level":2,"score":0.30489999055862427},{"id":"https://openalex.org/C190960625","wikidata":"https://www.wikidata.org/wiki/Q1058719","display_name":"Water treatment","level":2,"score":0.29910001158714294},{"id":"https://openalex.org/C2777858879","wikidata":"https://www.wikidata.org/wiki/Q104334","display_name":"Carbonic acid","level":2,"score":0.29159998893737793},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.29109999537467957},{"id":"https://openalex.org/C2781066024","wikidata":"https://www.wikidata.org/wiki/Q156","display_name":"Alcohol","level":2,"score":0.2786000072956085},{"id":"https://openalex.org/C2779679103","wikidata":"https://www.wikidata.org/wiki/Q5251805","display_name":"Degradation (telecommunications)","level":2,"score":0.27549999952316284},{"id":"https://openalex.org/C48333953","wikidata":"https://www.wikidata.org/wiki/Q192036","display_name":"Chemical decomposition","level":3,"score":0.2745000123977661},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.2718999981880188}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/anie.4598413","doi":"https://doi.org/10.1002/anie.4598413","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.4598413","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4598413","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:42963192","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42963192","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1002/anie.4598413","doi":"https://doi.org/10.1002/anie.4598413","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.4598413","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.4598413","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/6","score":0.9090999960899353,"display_name":"Clean water and sanitation"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G584354335","display_name":null,"funder_award_id":"2022YFC3205300","funder_id":"https://openalex.org/F4320335777","funder_display_name":"National Key Research and Development Program of China"},{"id":"https://openalex.org/G7502674655","display_name":null,"funder_award_id":"52370072","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320322769","display_name":"Natural Science Foundation of Jiangsu Province","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320335777","display_name":"National Key Research and Development Program of China","ror":null}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7224797972.pdf","grobid_xml":"https://content.openalex.org/works/W7224797972.grobid-xml"},"referenced_works_count":32,"referenced_works":["https://openalex.org/W2012487005","https://openalex.org/W2015338499","https://openalex.org/W2019189347","https://openalex.org/W2076643825","https://openalex.org/W2077657767","https://openalex.org/W2079490940","https://openalex.org/W2081709688","https://openalex.org/W2324576880","https://openalex.org/W2497102241","https://openalex.org/W2501836896","https://openalex.org/W2616183545","https://openalex.org/W2758695957","https://openalex.org/W2810936740","https://openalex.org/W2887698450","https://openalex.org/W2955742385","https://openalex.org/W3034477194","https://openalex.org/W3036669734","https://openalex.org/W3041994524","https://openalex.org/W3105082993","https://openalex.org/W3201014572","https://openalex.org/W4200259284","https://openalex.org/W4280547033","https://openalex.org/W4289782487","https://openalex.org/W4313653220","https://openalex.org/W4387330911","https://openalex.org/W4387589875","https://openalex.org/W4394790632","https://openalex.org/W4408782462","https://openalex.org/W4409552119","https://openalex.org/W4413193728","https://openalex.org/W7138860239","https://openalex.org/W7168127245"],"related_works":["https://openalex.org/W2750922007","https://openalex.org/W2991570316","https://openalex.org/W4295745508","https://openalex.org/W2418082994","https://openalex.org/W3045437258","https://openalex.org/W1978210820","https://openalex.org/W1969358193","https://openalex.org/W2273106255","https://openalex.org/W2321237905","https://openalex.org/W7053198909"],"abstract_inverted_index":{"ABSTRACT":[0],"Nitrate":[1],"radicals":[2,68,106],"(NO":[3],"3":[4,28,147],"\u2022)":[5],"generated":[6],"in":[7,93],"irradiated":[8],"aqueous":[9],"TiO":[10],"2":[11],"suspensions":[12],"at":[13],"acidic":[14,163],"pH":[15],"drive":[16],"decomposition":[17],"of":[18,35,43,52,66,91,140,142,145,156,165,171],"perfluorooctanoic":[19],"acid":[20],"(PFOA).":[21],"The":[22,50,64,86,133],"key":[23],"role":[24],"played":[25],"by":[26,32,47,81,117],"NO":[27,146],"\u2022":[29,148],"is":[30,73],"demonstrated":[31,80],"the":[33,36,40,58,70,76,113,122,137,143,162],"dependence":[34],"reaction":[37],"rate":[38],"on":[39],"initial":[41],"concentration":[42],"nitrate":[44,53,67,105],"ions":[45,54],"and":[46,119],"scavenging":[48],"tests.":[49],"amount":[51],"remains":[55],"constant":[56],"during":[57],"process,":[59],"indicating":[60],"its":[61],"catalytic":[62],"behavior.":[63],"existence":[65],"under":[69],"given":[71],"conditions":[72],"here":[74],"for":[75,169],"first":[77,138],"time":[78],"directly":[79],"time\u2010resolved":[82],"transient":[83],"absorption":[84],"spectroscopy.":[85],"process":[87,135],"achieves":[88],"\u223c90%":[89],"degradation":[90],"PFOA":[92],"9":[94],"h":[95],"with":[96,149,161],"ca.":[97],"57%":[98],"fluoride":[99],"liberation.":[100],"Theoretical":[101],"results":[102],"suggest":[103],"that":[104],"trigger":[107],"water\u2010mediated":[108],"hydrogen":[109],"atom":[110],"transfer":[111],"from":[112],"protonated":[114],"PFOA,":[115],"followed":[116],"decarboxylation":[118],"hydroxylation":[120],"to":[121,130],"corresponding":[123],"alcohol":[124],"(experimentally":[125],"detected),":[126],"which":[127],"eventually":[128],"evolves":[129],"shorter\u2010chain":[131],"intermediates.":[132],"proposed":[134],"represents":[136],"proof":[139],"concept":[141],"reactivity":[144],"PFAS,":[150],"but":[151],"more":[152],"importantly":[153],"may":[154],"be":[155],"practical":[157],"relevance":[158],"when":[159],"coupled":[160],"regeneration":[164],"adsorbents":[166],"currently":[167],"used":[168],"remediation":[170],"water":[172],"effluents":[173],"containing":[174],"PFAS.":[175]},"counts_by_year":[],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2026-10-31T00:00:00"}
