{"id":"https://openalex.org/W7224495498","doi":"https://doi.org/10.1021/acsanm.6c04295","title":"Solvent Choice to a Phase-Controllable Shift of Covellite-CuS Nanoparticles for Cation Exchange Reactions and Plasmonic Photodetectors","display_name":"Solvent Choice to a Phase-Controllable Shift of Covellite-CuS Nanoparticles for Cation Exchange Reactions and Plasmonic Photodetectors","publication_year":2026,"publication_date":"2026-10-29","ids":{"openalex":"https://openalex.org/W7224495498","doi":"https://doi.org/10.1021/acsanm.6c04295"},"language":"en","primary_location":{"id":"doi:10.1021/acsanm.6c04295","doi":"https://doi.org/10.1021/acsanm.6c04295","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsanm.6c04295","pdf_url":null,"source":{"id":"https://openalex.org/S4210191493","display_name":"ACS Applied Nano Materials","issn_l":"2574-0970","issn":["2574-0970"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-20","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Nano Materials","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5160146483","display_name":"Xinxin Zhang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xinxin Zhang","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028815928","display_name":"Yan Xia","orcid":"https://orcid.org/0000-0002-8390-8414","observed_orcids":["https://orcid.org/0000-0002-8390-8414","https://orcid.org/0009-0008-4593-9632"]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yan Xia","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160145149","display_name":"Shaobo He","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shaobo He","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160140597","display_name":"Liangjiao Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Liangjiao Xu","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018715137","display_name":"Jiaying Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jiaying Liu","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5126772730","display_name":"Yuqi Li","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuqi Li","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160087846","display_name":"Tingting Zhao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tingting Zhao","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160128728","display_name":"Yuxin Mo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuxin Mo","raw_affiliation_strings":["Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5103019814","display_name":"Lihui Chen","orcid":"https://orcid.org/0000-0001-9369-6374","observed_orcids":["https://orcid.org/0000-0001-9369-6374"]},"institutions":[{"id":"https://openalex.org/I31847773","display_name":"Zhejiang Ocean University","ror":"https://ror.org/03mys6533","country_code":"CN","type":"education","lineage":["https://openalex.org/I31847773"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Lihui Chen","raw_affiliation_strings":["National & local Joint Engineering Research Center of Harbor Oil & Gas Storage and Transportation Technology , ,","Zhejiang Key Laboratory of Pollution Control for Port-Petrochemical Industry , ,","Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,"],"raw_orcid":"https://orcid.org/0000-0001-9369-6374","affiliations":[{"raw_affiliation_string":"National & local Joint Engineering Research Center of Harbor Oil & Gas Storage and Transportation Technology , ,","institution_ids":[]},{"raw_affiliation_string":"Zhejiang Key Laboratory of Pollution Control for Port-Petrochemical Industry , ,","institution_ids":[]},{"raw_affiliation_string":"Zhejiang Ocean University , , No.1, Haida South Road, Lincheng Changzhi Island , ,","institution_ids":["https://openalex.org/I31847773"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5103019814"],"corresponding_institution_ids":["https://openalex.org/I31847773"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.66556252,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10321","display_name":"Quantum Dots Synthesis And Properties","score":0.6425999999046326,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10321","display_name":"Quantum Dots Synthesis And Properties","score":0.6425999999046326,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11907","display_name":"Copper-based nanomaterials and applications","score":0.32690000534057617,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10131","display_name":"Gold and Silver Nanoparticles Synthesis and Applications","score":0.01899999938905239,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/amine-solvents","display_name":"amine solvents","score":0.6299999952316284},{"id":"https://openalex.org/keywords/digenite","display_name":"digenite","score":0.6359999775886536},{"id":"https://openalex.org/keywords/djurleite","display_name":"djurleite","score":1.0},{"id":"https://openalex.org/keywords/cation-exchange","display_name":"cation exchange","score":0.9039999842643738},{"id":"https://openalex.org/keywords/plasmonic-photodetectors","display_name":"plasmonic photodetectors","score":0.8309999704360962},{"id":"https://openalex.org/keywords/metal-sulfide-nanoparticles","display_name":"metal sulfide nanoparticles","score":0.5910000205039978},{"id":"https://openalex.org/keywords/cuins2","display_name":"CuInS2","score":0.8109999895095825},{"id":"https://openalex.org/keywords/cugas2","display_name":"CuGaS2","score":0.996999979019165},{"id":"https://openalex.org/keywords/zns","display_name":"ZnS","score":0.8539999723434448}],"concepts":[{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.7386999726295471},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.6545000076293945},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.5978999733924866},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5745000243186951},{"id":"https://openalex.org/C3045981","wikidata":"https://www.wikidata.org/wiki/Q8039317","display_name":"Wurtzite crystal structure","level":3,"score":0.5515000224113464},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5393999814987183},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.5180000066757202},{"id":"https://openalex.org/C110879396","wikidata":"https://www.wikidata.org/wiki/Q58392","display_name":"Plasmon","level":2,"score":0.4860999882221222},{"id":"https://openalex.org/C2779219880","wikidata":"https://www.wikidata.org/wiki/Q204952","display_name":"Zinc sulfide","level":3,"score":0.4772999882698059},{"id":"https://openalex.org/C158733187","wikidata":"https://www.wikidata.org/wiki/Q104567","display_name":"Chalcogen","level":2,"score":0.46709999442100525},{"id":"https://openalex.org/C2780596425","wikidata":"https://www.wikidata.org/wiki/Q221205","display_name":"Sulfide","level":2,"score":0.3962000012397766},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3652999997138977},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.36489999294281006},{"id":"https://openalex.org/C85255121","wikidata":"https://www.wikidata.org/wiki/Q7201984","display_name":"Plasmonic nanoparticles","level":3,"score":0.36419999599456787},{"id":"https://openalex.org/C2780134926","wikidata":"https://www.wikidata.org/wiki/Q5748761","display_name":"Hexagonal phase","level":3,"score":0.3635999858379364},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.35690000653266907},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3547999858856201},{"id":"https://openalex.org/C132439834","wikidata":"https://www.wikidata.org/wiki/Q7559035","display_name":"Solvent effects","level":3,"score":0.3215999901294708},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.320499986410141},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.30399999022483826},{"id":"https://openalex.org/C2779921683","wikidata":"https://www.wikidata.org/wiki/Q179619","display_name":"Cadmium sulfide","level":2,"score":0.29019999504089355},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.2694999873638153},{"id":"https://openalex.org/C95311098","wikidata":"https://www.wikidata.org/wiki/Q7783078","display_name":"Thermal treatment","level":2,"score":0.257999986410141},{"id":"https://openalex.org/C177562468","wikidata":"https://www.wikidata.org/wiki/Q182893","display_name":"Dispersion (optics)","level":2,"score":0.2565999925136566}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acsanm.6c04295","doi":"https://doi.org/10.1021/acsanm.6c04295","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsanm.6c04295","pdf_url":null,"source":{"id":"https://openalex.org/S4210191493","display_name":"ACS Applied Nano Materials","issn_l":"2574-0970","issn":["2574-0970"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-20","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Nano Materials","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320325436","display_name":"Department of Education of Zhejiang Province","ror":"https://ror.org/05gj07w56"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W1990147288","https://openalex.org/W2040265643","https://openalex.org/W2068559689","https://openalex.org/W2167590372","https://openalex.org/W2285538685","https://openalex.org/W2313745588","https://openalex.org/W2317531234","https://openalex.org/W2530917854","https://openalex.org/W2614279387","https://openalex.org/W2732680259","https://openalex.org/W2787668281","https://openalex.org/W2800436097","https://openalex.org/W2871923847","https://openalex.org/W2886183244","https://openalex.org/W2903999303","https://openalex.org/W2953837173","https://openalex.org/W2981245324","https://openalex.org/W2997507304","https://openalex.org/W3001315055","https://openalex.org/W3091995026","https://openalex.org/W3124716649","https://openalex.org/W3134776787","https://openalex.org/W3165060107","https://openalex.org/W3210308991","https://openalex.org/W4281752121","https://openalex.org/W4313893510","https://openalex.org/W4389494167","https://openalex.org/W4402596956","https://openalex.org/W4405337276","https://openalex.org/W4408151776","https://openalex.org/W4409810335","https://openalex.org/W4410707060","https://openalex.org/W4414105476","https://openalex.org/W4416977797","https://openalex.org/W4417299070","https://openalex.org/W7128381464","https://openalex.org/W7160612673","https://openalex.org/W7202078301"],"related_works":["https://openalex.org/W4402596956","https://openalex.org/W4410707060","https://openalex.org/W3091995026","https://openalex.org/W7202078301","https://openalex.org/W3046098600","https://openalex.org/W2614279387","https://openalex.org/W2093576896","https://openalex.org/W4414105476","https://openalex.org/W4412048066","https://openalex.org/W3044244006"],"abstract_inverted_index":{"Abstract":[0],"Among":[1],"the":[2,7,40,66,84,100,161,187,194],"copper-deficient":[3],"Cu2\u2212xS":[4,26,105,116],"nanoparticles":[5],"(NPs),":[6],"unique":[8],"disulfide":[9],"(S\u2212S)":[10],"covalent":[11],"bonds":[12,42],"in":[13,193],"covellite-CuS":[14,67],"NPs":[15,68,76,82,98,106,117,134,150,169],"provide":[16,178],"an":[17],"ideal":[18],"template":[19],"for":[20,109,182],"a":[21,31,35,62,119,136,142,154,179,183],"phase-controllable":[22],"shift":[23,64,185],"into":[24,79,95],"other":[25],"NPs.":[27],"In":[28,90],"this":[29],"regard,":[30],"rational":[32],"choice":[33],"of":[34,49,65,186,199],"reducing":[36],"solvent":[37,86],"to":[38,60,159],"break":[39],"S\u2212S":[41],"is":[43],"highly":[44],"desirable.":[45],"Herein,":[46],"two":[47,114],"solvents":[48],"R\u2212NH2":[50,85],"and":[51,127,129,132,141],"R\u2212SH,":[52],"where":[53],"R":[54],"=":[55],"linear":[56],"dodecyl,":[57],"were":[58,77,93,122,146],"selected":[59],"trigger":[61],"phase":[63,115,140,145,184],"before":[69],"cation":[70],"exchange":[71],"(CE)":[72],"reactions.":[73],"The":[74,102],"CuS":[75,188],"reduced":[78],"cubic-phase":[80],"digenite-Cu1.8S":[81],"by":[83,99],"under":[87],"thermal":[88],"heating.":[89],"contrast,":[91],"they":[92],"converted":[94],"hexagonal-phase":[96],"djurleite-Cu1.94S":[97,149],"R\u2212SH.":[101],"above":[103],"three-phase":[104],"are":[107],"suitable":[108],"plasmonic":[110],"photodetectors.":[111],"Thereafter,":[112],"these":[113],"with":[118,124,135,152,203],"plate-like":[120],"morphology":[121],"exchanged":[123,151],"Zn2+,":[125],"In3+,":[126],"Ga3+,":[128,153],"ZnS,":[130],"CuInS2,":[131],"CuGaS2":[133],"cubic":[137],"zinc":[138],"blende":[139],"hexagonal":[143],"wurtzite":[144],"produced.":[147],"For":[148],"dissolution/reprecipitation":[155],"mechanism":[156],"was":[157],"proposed":[158],"interpret":[160],"unusual":[162],"reaction":[163],"behaviors.":[164],"These":[165],"polymorphic":[166,197],"metal":[167,201],"sulfide":[168],"exhibit":[170],"distinct":[171],"optical":[172],"responses.":[173],"Therefore,":[174],"our":[175],"research":[176],"achievements":[177],"facile":[180],"approach":[181],"NPs,":[189],"holding":[190],"great":[191],"promise":[192],"CE":[195],"reaction-enabled":[196],"synthesis":[198],"binary/ternary/multinary":[200],"sulfides":[202],"phase-related":[204],"physicochemical":[205],"properties.":[206]},"counts_by_year":[],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2026-10-30T00:00:00"}