{"id":"https://openalex.org/W7224336955","doi":"https://doi.org/10.1016/j.xcrp.2026.103621","title":"Regioselective meta-C\u2212H borylation of aryl acetic acid derivatives enabled by iridium-aluminum bifunctional catalysts","display_name":"Regioselective meta-C\u2212H borylation of aryl acetic acid derivatives enabled by iridium-aluminum bifunctional catalysts","publication_year":2026,"publication_date":"2026-10-29","ids":{"openalex":"https://openalex.org/W7224336955","doi":"https://doi.org/10.1016/j.xcrp.2026.103621"},"language":"en","primary_location":{"id":"doi:10.1016/j.xcrp.2026.103621","doi":"https://doi.org/10.1016/j.xcrp.2026.103621","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.xcrp.2026.103621","pdf_url":null,"source":{"id":"https://openalex.org/S4210216867","display_name":"Cell Reports Physical Science","issn_l":"2666-3864","issn":["2666-3864"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-1","ki-jl-1","norway-1","oarl","poland-20"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Cell Reports Physical Science","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.1016/j.xcrp.2026.103621","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5012107059","display_name":"Netai Aditya","orcid":"https://orcid.org/0009-0000-5289-3961","observed_orcids":["https://orcid.org/0009-0000-5289-3961"]},"institutions":[{"id":"https://openalex.org/I127439422","display_name":"Indian Institute of Science Education and Research Kolkata","ror":"https://ror.org/00djv2c17","country_code":"IN","type":"education","lineage":["https://openalex.org/I127439422"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Netai Aditya","raw_affiliation_strings":["Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India","institution_ids":["https://openalex.org/I127439422"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001996604","display_name":"Debashis Ghosh","orcid":"https://orcid.org/0000-0001-8222-5737","observed_orcids":["https://orcid.org/0000-0001-8222-5737"]},"institutions":[{"id":"https://openalex.org/I127439422","display_name":"Indian Institute of Science Education and Research Kolkata","ror":"https://ror.org/00djv2c17","country_code":"IN","type":"education","lineage":["https://openalex.org/I127439422"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Debashis Ghosh","raw_affiliation_strings":["Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India","institution_ids":["https://openalex.org/I127439422"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079966616","display_name":"Shovan Das","orcid":"https://orcid.org/0000-0002-4596-0641","observed_orcids":["https://orcid.org/0000-0002-4596-0641"]},"institutions":[{"id":"https://openalex.org/I165998391","display_name":"Indian Association for the Cultivation of Science","ror":"https://ror.org/050p6gz73","country_code":"IN","type":"education","lineage":["https://openalex.org/I165998391"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Shovan Das","raw_affiliation_strings":["School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata 700032, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata 700032, India","institution_ids":["https://openalex.org/I165998391"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5160112979","display_name":"Sanjana Nayak","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I127439422","display_name":"Indian Institute of Science Education and Research Kolkata","ror":"https://ror.org/00djv2c17","country_code":"IN","type":"education","lineage":["https://openalex.org/I127439422"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Sanjana Nayak","raw_affiliation_strings":["Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India","institution_ids":["https://openalex.org/I127439422"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068360992","display_name":"Ayan Datta","orcid":"https://orcid.org/0000-0001-6723-087X","observed_orcids":["https://orcid.org/0000-0001-6723-087X","https://orcid.org/0009-0003-0813-613X"]},"institutions":[{"id":"https://openalex.org/I165998391","display_name":"Indian Association for the Cultivation of Science","ror":"https://ror.org/050p6gz73","country_code":"IN","type":"education","lineage":["https://openalex.org/I165998391"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Ayan Datta","raw_affiliation_strings":["School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata 700032, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata 700032, India","institution_ids":["https://openalex.org/I165998391"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5034202353","display_name":"Biplab Maji","orcid":"https://orcid.org/0000-0001-5034-423X","observed_orcids":["https://orcid.org/0000-0001-5034-423X"]},"institutions":[{"id":"https://openalex.org/I127439422","display_name":"Indian Institute of Science Education and Research Kolkata","ror":"https://ror.org/00djv2c17","country_code":"IN","type":"education","lineage":["https://openalex.org/I127439422"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Biplab Maji","raw_affiliation_strings":["Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India"],"raw_orcid":"https://orcid.org/0000-0001-5034-423X","affiliations":[{"raw_affiliation_string":"Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohanpur, Kolkata 741246, India","institution_ids":["https://openalex.org/I127439422"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5034202353","https://openalex.org/A5068360992"],"corresponding_institution_ids":["https://openalex.org/I127439422","https://openalex.org/I165998391"],"apc_list":{"value":5620,"currency":"USD","value_usd":5620},"apc_paid":{"value":5620,"currency":"USD","value_usd":5620},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.70954878,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"7","issue":"11","first_page":"103621","last_page":"103621"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.000699999975040555,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lewis-acid-base-interactions","display_name":"Lewis acid-base interactions","score":0.6209999918937683},{"id":"https://openalex.org/keywords/phenylacetamide","display_name":"phenylacetamide","score":0.9390000104904175},{"id":"https://openalex.org/keywords/ligand-engineering","display_name":"ligand engineering","score":0.8040000200271606},{"id":"https://openalex.org/keywords/napropamide","display_name":"napropamide","score":0.8190000057220459},{"id":"https://openalex.org/keywords/ketoprofen","display_name":"ketoprofen","score":0.9990000128746033},{"id":"https://openalex.org/keywords/late-stage-functionalization","display_name":"late-stage functionalization","score":0.9350000023841858},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.5540000200271606}],"concepts":[{"id":"https://openalex.org/C2776413204","wikidata":"https://www.wikidata.org/wiki/Q17113001","display_name":"Borylation","level":4,"score":0.921999990940094},{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.8111000061035156},{"id":"https://openalex.org/C2780443040","wikidata":"https://www.wikidata.org/wiki/Q3737863","display_name":"Bifunctional","level":3,"score":0.8016999959945679},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7914000153541565},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.6290000081062317},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5426999926567078},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.506600022315979},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5034000277519226},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.4657999873161316},{"id":"https://openalex.org/C528581852","wikidata":"https://www.wikidata.org/wiki/Q877","display_name":"Iridium","level":3,"score":0.444599986076355},{"id":"https://openalex.org/C19927201","wikidata":"https://www.wikidata.org/wiki/Q6537198","display_name":"Lewis acid catalysis","level":4,"score":0.4011000096797943},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.3578000068664551},{"id":"https://openalex.org/C2779412933","wikidata":"https://www.wikidata.org/wiki/Q3119091","display_name":"Bifunctional catalyst","level":4,"score":0.35339999198913574},{"id":"https://openalex.org/C2781350956","wikidata":"https://www.wikidata.org/wiki/Q408228","display_name":"Terpyridine","level":3,"score":0.3425999879837036},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3357999920845032},{"id":"https://openalex.org/C2777864310","wikidata":"https://www.wikidata.org/wiki/Q335768","display_name":"Boronic acid","level":2,"score":0.32409998774528503},{"id":"https://openalex.org/C71866858","wikidata":"https://www.wikidata.org/wiki/Q902756","display_name":"Negishi coupling","level":3,"score":0.3093999922275543},{"id":"https://openalex.org/C2778844314","wikidata":"https://www.wikidata.org/wiki/Q191700","display_name":"Benzoic acid","level":2,"score":0.28850001096725464},{"id":"https://openalex.org/C55803922","wikidata":"https://www.wikidata.org/wiki/Q1755472","display_name":"SBus","level":4,"score":0.2881999909877777},{"id":"https://openalex.org/C2776673659","wikidata":"https://www.wikidata.org/wiki/Q47512","display_name":"Acetic acid","level":2,"score":0.2815000116825104},{"id":"https://openalex.org/C11111787","wikidata":"https://www.wikidata.org/wiki/Q675972","display_name":"Coordination sphere","level":3,"score":0.27730000019073486},{"id":"https://openalex.org/C39679061","wikidata":"https://www.wikidata.org/wiki/Q5506522","display_name":"Frustrated Lewis pair","level":4,"score":0.26669999957084656},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.2635999917984009},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.25780001282691956},{"id":"https://openalex.org/C109474758","wikidata":"https://www.wikidata.org/wiki/Q1411716","display_name":"Homogeneous catalysis","level":3,"score":0.25589999556541443}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1016/j.xcrp.2026.103621","doi":"https://doi.org/10.1016/j.xcrp.2026.103621","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.xcrp.2026.103621","pdf_url":null,"source":{"id":"https://openalex.org/S4210216867","display_name":"Cell Reports Physical Science","issn_l":"2666-3864","issn":["2666-3864"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-1","ki-jl-1","norway-1","oarl","poland-20"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Cell Reports Physical Science","raw_type":"journal-article"},{"id":"pmh:oai:doaj.org/article:5c21ba652f474ca1a57a93bf0dd06ac7","doi":null,"is_oa":false,"landing_page_url":"https://doaj.org/article/5c21ba652f474ca1a57a93bf0dd06ac7","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Cell Reports Physical Science, Vol 7, Iss 11, Pp 103621- (2026)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.1016/j.xcrp.2026.103621","doi":"https://doi.org/10.1016/j.xcrp.2026.103621","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.xcrp.2026.103621","pdf_url":null,"source":{"id":"https://openalex.org/S4210216867","display_name":"Cell Reports Physical Science","issn_l":"2666-3864","issn":["2666-3864"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-1","ki-jl-1","norway-1","oarl","poland-20"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Cell Reports Physical Science","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320327976","display_name":"Indian Institute of Science Education and Research Kolkata","ror":"https://ror.org/00djv2c17"},{"id":"https://openalex.org/F4320334771","display_name":"Science and Engineering Research Board","ror":"https://ror.org/03ffdsr55"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":40,"referenced_works":["https://openalex.org/W1901089361","https://openalex.org/W2045655273","https://openalex.org/W2085536088","https://openalex.org/W2088032565","https://openalex.org/W2097872311","https://openalex.org/W2126362475","https://openalex.org/W2180888575","https://openalex.org/W2187678462","https://openalex.org/W2286162655","https://openalex.org/W2339051409","https://openalex.org/W2343279338","https://openalex.org/W2409910804","https://openalex.org/W2519849782","https://openalex.org/W2555125208","https://openalex.org/W2597842176","https://openalex.org/W2751576575","https://openalex.org/W2896969592","https://openalex.org/W2903424054","https://openalex.org/W2911421767","https://openalex.org/W2912440643","https://openalex.org/W2940265010","https://openalex.org/W2951236048","https://openalex.org/W2974324441","https://openalex.org/W3026059719","https://openalex.org/W3112119362","https://openalex.org/W3134466926","https://openalex.org/W3158255131","https://openalex.org/W3161731200","https://openalex.org/W4211011646","https://openalex.org/W4220818622","https://openalex.org/W4281392124","https://openalex.org/W4295565784","https://openalex.org/W4301368836","https://openalex.org/W4309777346","https://openalex.org/W4317897817","https://openalex.org/W4319990363","https://openalex.org/W4366602447","https://openalex.org/W4377966525","https://openalex.org/W4401995778","https://openalex.org/W4412703097"],"related_works":["https://openalex.org/W4388034429","https://openalex.org/W2940265010","https://openalex.org/W4414430266","https://openalex.org/W4395693975","https://openalex.org/W4254242243","https://openalex.org/W4412703097","https://openalex.org/W3191264422","https://openalex.org/W4244271740","https://openalex.org/W4283711892","https://openalex.org/W2171105141"],"abstract_inverted_index":{"Remote":[0],"C\u2013H":[1],"functionalization":[2,118],"provides":[3],"a":[4,58],"powerful":[5],"strategy":[6],"for":[7,68],"overcoming":[8],"the":[9,44,64,94,101,124,134,138],"inherent":[10],"selectivity":[11],"of":[12,24,30,75,83,104,119,141],"arene":[13],"functionalization.":[14],"While":[15],"reversible":[16],"secondary-sphere":[17],"interactions":[18,107],"have":[19],"enabled":[20],"remote":[21,71],"regioselective":[22],"borylation":[23,74,82],"benzoic":[25],"acid":[26,32],"derivatives,":[27],"analogous":[28],"transformations":[29],"phenylacetic":[31],"derivatives":[33],"and":[34,88,108,116,121,130,137],"higher":[35],"homologs":[36],"remain":[37],"largely":[38],"unexplored":[39],"because":[40],"increased":[41],"distance":[42],"from":[43,93],"directing":[45],"group":[46],"disfavors":[47],"metallamacrocyclic":[48],"transition":[49],"states.":[50],"Herein,":[51],"we":[52],"report":[53],"bifunctional":[54,109],"iridium":[55],"catalysts":[56],"featuring":[57],"tunable":[59],"Lewis-acidic":[60],"aluminum":[61,142],"site":[62],"in":[63,145],"secondary":[65],"coordination":[66],"sphere":[67],"highly":[69],"selective":[70],"meta":[72],"-C\u2013H":[73],"phenylacetamides.":[76],"Systematic":[77],"ligand":[78,135],"engineering":[79],"further":[80],"enables":[81],"previously":[84],"inaccessible":[85],"arylpropanamides,":[86],"arylbutanamides,":[87],"aryloxyacetamides.":[89],"The":[90],"distinct":[91],"regioselectivity":[92],"conventional":[95],"[Ir(cod)(OMe)]":[96],"2":[97],"/dtbpy":[98],"system":[99],"highlights":[100],"decisive":[102],"roles":[103],"Lewis":[105,143],"acid-base":[106],"catalyst":[110],"design.":[111],"Gram-scale":[112],"synthesis,":[113],"downstream":[114],"diversification,":[115],"late-stage":[117],"napropamide":[120],"ketoprofen":[122],"demonstrate":[123],"method's":[125],"synthetic":[126],"utility.":[127],"Control":[128],"experiments":[129],"DFT":[131],"studies":[132],"elucidate":[133],"design":[136],"crucial":[139],"role":[140],"acidity":[144],"controlling":[146],"selectivity.":[147]},"counts_by_year":[],"updated_date":"2026-11-02T09:45:03.842371","created_date":"2026-10-30T00:00:00"}
