{"id":"https://openalex.org/W7222660937","doi":"https://doi.org/10.26434/chemrxiv.15010596/v1","title":"Probing Molecular Chirality from Vibrational to X-ray Energies in Cr(III) and Co(III) Complexes","display_name":"Probing Molecular Chirality from Vibrational to X-ray Energies in Cr(III) and Co(III) Complexes","publication_year":2026,"publication_date":"2026-10-16","ids":{"openalex":"https://openalex.org/W7222660937","doi":"https://doi.org/10.26434/chemrxiv.15010596/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15010596/v1","doi":"https://doi.org/10.26434/chemrxiv.15010596/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010596/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010596/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010596/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5050952752","display_name":"Nazanin Kordestani","orcid":"https://orcid.org/0000-0001-5108-920X","observed_orcids":["https://orcid.org/0000-0001-5108-920X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Nazanin Kordestani","raw_affiliation_strings":["CNRS"],"raw_orcid":"https://orcid.org/0000-0001-5108-920X","affiliations":[{"raw_affiliation_string":"CNRS","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5118589811","display_name":"Alessandro de Frenza","orcid":"https://orcid.org/0000-0001-6964-059X","observed_orcids":["https://orcid.org/0000-0001-6964-059X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Alessandro De Frenza","raw_affiliation_strings":["CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071601782","display_name":"Thierry Buffeteau","orcid":"https://orcid.org/0000-0001-7848-0794","observed_orcids":["https://orcid.org/0000-0001-7848-0794"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Thierry Buffeteau","raw_affiliation_strings":["CNRS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5107842669","display_name":"Yann Danten","orcid":"https://orcid.org/0000-0002-1994-2503","observed_orcids":["https://orcid.org/0000-0002-1994-2503"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Yann Danten","raw_affiliation_strings":["CNRS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033391511","display_name":"Nicolas Daugey","orcid":"https://orcid.org/0000-0002-6455-9458","observed_orcids":["https://orcid.org/0000-0002-6455-9458"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Nicolas Daugey","raw_affiliation_strings":["CNRS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059378013","display_name":"Patrick Rosa","orcid":"https://orcid.org/0000-0001-5670-2624","observed_orcids":["https://orcid.org/0000-0001-5670-2624"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Patrick Rosa","raw_affiliation_strings":["CNRS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002146590","display_name":"Marie\u2010Anne Arrio","orcid":"https://orcid.org/0000-0002-2945-6824","observed_orcids":["https://orcid.org/0000-0002-2945-6824"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Marie-Anne Arrio","raw_affiliation_strings":["CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033311799","display_name":"Am\u00e9lie Juhin","orcid":"https://orcid.org/0000-0003-0752-3034","observed_orcids":["https://orcid.org/0000-0003-0752-3034"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Am\u00e9lie Juhin","raw_affiliation_strings":["CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052285534","display_name":"Nathan J. Yutronkie","orcid":"https://orcid.org/0000-0002-8297-9376","observed_orcids":["https://orcid.org/0000-0002-8297-9376"]},"institutions":[{"id":"https://openalex.org/I2801997478","display_name":"European Synchrotron Radiation Facility","ror":"https://ror.org/02550n020","country_code":"FR","type":"facility","lineage":["https://openalex.org/I2801997478"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Nathan Yutronkie","raw_affiliation_strings":["European Synchrotron Radiation Facility (ESRF"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"European Synchrotron Radiation Facility (ESRF","institution_ids":["https://openalex.org/I2801997478"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009506042","display_name":"F. Wilhelm","orcid":"https://orcid.org/0000-0002-4425-3662","observed_orcids":["https://orcid.org/0000-0002-4425-3662"]},"institutions":[{"id":"https://openalex.org/I2801997478","display_name":"European Synchrotron Radiation Facility","ror":"https://ror.org/02550n020","country_code":"FR","type":"facility","lineage":["https://openalex.org/I2801997478"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Fabrice Wilhelm","raw_affiliation_strings":["European Synchrotron Radiation Facility (ESRF"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"European Synchrotron Radiation Facility (ESRF","institution_ids":["https://openalex.org/I2801997478"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040608141","display_name":"Andre\u00ef Rogalev","orcid":"https://orcid.org/0000-0002-0501-698X","observed_orcids":["https://orcid.org/0000-0002-0501-698X"]},"institutions":[{"id":"https://openalex.org/I2801997478","display_name":"European Synchrotron Radiation Facility","ror":"https://ror.org/02550n020","country_code":"FR","type":"facility","lineage":["https://openalex.org/I2801997478"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Andrei Rogalev","raw_affiliation_strings":["European Synchrotron Radiation Facility (ESRF"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"European Synchrotron Radiation Facility (ESRF","institution_ids":["https://openalex.org/I2801997478"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010445451","display_name":"Philippe Sainctavit","orcid":"https://orcid.org/0000-0001-9349-2558","observed_orcids":["https://orcid.org/0000-0001-9349-2558","https://orcid.org/0000-0001-5422-7778"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Philippe Sainctavit","raw_affiliation_strings":["CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS, UMR, 4 place Jussieu, Paris cedex, France, F-75252","institution_ids":["https://openalex.org/I1294671590"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5010766834","display_name":"Elizabeth Anne Hillard","orcid":"https://orcid.org/0000-0002-5149-0324","observed_orcids":["https://orcid.org/0000-0002-5149-0324"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Elizabeth A. Hillard","raw_affiliation_strings":["CNRS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNRS","institution_ids":["https://openalex.org/I1294671590"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12748","display_name":"Molecular spectroscopy and chirality","score":0.9599999785423279,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12748","display_name":"Molecular spectroscopy and chirality","score":0.9599999785423279,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11733","display_name":"X-ray Spectroscopy and Fluorescence Analysis","score":0.029400000348687172,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.001500000013038516,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/molecular-chirality","display_name":"molecular chirality","score":0.9940000176429749},{"id":"https://openalex.org/keywords/vibrational-circular-dichroism","display_name":"vibrational circular dichroism","score":0.9290000200271606},{"id":"https://openalex.org/keywords/electronic-circular-dichroism","display_name":"electronic circular dichroism","score":0.9990000128746033},{"id":"https://openalex.org/keywords/cr-iii-complexes","display_name":"chromium(III) complexes","score":0.8949999809265137},{"id":"https://openalex.org/keywords/cobalt-iii-complexes","display_name":"cobalt(III) complexes","score":1.0},{"id":"https://openalex.org/keywords/enantiomers","display_name":"enantiomers","score":0.5830000042915344},{"id":"https://openalex.org/keywords/co-k-edge","display_name":"Co K-edge","score":0.6039999723434448},{"id":"https://openalex.org/keywords/cr-k-edge","display_name":"Cr K-edge","score":0.9980000257492065}],"concepts":[{"id":"https://openalex.org/C92869835","wikidata":"https://www.wikidata.org/wiki/Q1209450","display_name":"Dichroic glass","level":2,"score":0.8519999980926514},{"id":"https://openalex.org/C133571119","wikidata":"https://www.wikidata.org/wiki/Q899102","display_name":"Circular dichroism","level":2,"score":0.7828999757766724},{"id":"https://openalex.org/C189010761","wikidata":"https://www.wikidata.org/wiki/Q7924663","display_name":"Vibrational circular dichroism","level":3,"score":0.7649000287055969},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.6502000093460083},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.5690000057220459},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5199999809265137},{"id":"https://openalex.org/C486523","wikidata":"https://www.wikidata.org/wiki/Q494483","display_name":"Enantiomer","level":2,"score":0.510699987411499},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5045999884605408},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.4699000120162964},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.41780000925064087},{"id":"https://openalex.org/C105600476","wikidata":"https://www.wikidata.org/wiki/Q1195643","display_name":"Dichroism","level":2,"score":0.39719998836517334},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.34220001101493835},{"id":"https://openalex.org/C180205008","wikidata":"https://www.wikidata.org/wiki/Q159190","display_name":"Amplitude","level":2,"score":0.3156999945640564},{"id":"https://openalex.org/C207114421","wikidata":"https://www.wikidata.org/wiki/Q133900","display_name":"Diffraction","level":2,"score":0.3109999895095825},{"id":"https://openalex.org/C24123453","wikidata":"https://www.wikidata.org/wiki/Q900121","display_name":"Molecular vibration","level":3,"score":0.3001999855041504},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.28839999437332153},{"id":"https://openalex.org/C146593782","wikidata":"https://www.wikidata.org/wiki/Q6553431","display_name":"Linear dichroism","level":3,"score":0.2529999911785126}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15010596/v1","doi":"https://doi.org/10.26434/chemrxiv.15010596/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010596/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010596/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15010596/v1","doi":"https://doi.org/10.26434/chemrxiv.15010596/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010596/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010596/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G420006731","display_name":"Experimental investigation of microscopic theory of X-ray Natural Circular Dichroism","funder_award_id":"ANR-21-CE29-0032","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G4906204642","display_name":"Comprehension of solvent structure with Raman Optical Activity","funder_award_id":"ANR-21-CE29-0006","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G7092823349","display_name":"Light-based understanding of magneto-chiral interactions and chirality-induced spin selectivity","funder_award_id":"ANR-24-EXLU-0006","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G7207223558","display_name":null,"funder_award_id":"CH-7393","funder_id":"https://openalex.org/F4320320887","funder_display_name":"European Synchrotron Radiation Facility"}],"funders":[{"id":"https://openalex.org/F4320320883","display_name":"Agence Nationale de la Recherche","ror":"https://ror.org/00rbzpz17"},{"id":"https://openalex.org/F4320320887","display_name":"European Synchrotron Radiation Facility","ror":"https://ror.org/02550n020"},{"id":"https://openalex.org/F4320322892","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73"},{"id":"https://openalex.org/F4320323712","display_name":"Universit\u00e9 de Bordeaux","ror":"https://ror.org/057qpr032"},{"id":"https://openalex.org/F4320326256","display_name":"Grand \u00c9quipement National De Calcul Intensif","ror":"https://ror.org/0010d1q40"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7222660937.pdf","grobid_xml":"https://content.openalex.org/works/W7222660937.grobid-xml"},"referenced_works_count":34,"referenced_works":["https://openalex.org/W1966519714","https://openalex.org/W1967698682","https://openalex.org/W1972449167","https://openalex.org/W1977332449","https://openalex.org/W1982862311","https://openalex.org/W1988091937","https://openalex.org/W1996670928","https://openalex.org/W2010745498","https://openalex.org/W2011215428","https://openalex.org/W2011398620","https://openalex.org/W2011482103","https://openalex.org/W2012476498","https://openalex.org/W2059205366","https://openalex.org/W2077372520","https://openalex.org/W2087426136","https://openalex.org/W2090360761","https://openalex.org/W2092689035","https://openalex.org/W2119547517","https://openalex.org/W2128187248","https://openalex.org/W2132454074","https://openalex.org/W2137827843","https://openalex.org/W2155591085","https://openalex.org/W2325403657","https://openalex.org/W2326967306","https://openalex.org/W2532371402","https://openalex.org/W2616749086","https://openalex.org/W3008082379","https://openalex.org/W3037530884","https://openalex.org/W3151716479","https://openalex.org/W4211036066","https://openalex.org/W4402554772","https://openalex.org/W4406667458","https://openalex.org/W4411531305","https://openalex.org/W7204453731"],"related_works":["https://openalex.org/W2011398620","https://openalex.org/W53033380","https://openalex.org/W2062892373","https://openalex.org/W2489091942","https://openalex.org/W3128344761","https://openalex.org/W2060860009","https://openalex.org/W2081464027","https://openalex.org/W3137402233","https://openalex.org/W1967814108","https://openalex.org/W2312508335"],"abstract_inverted_index":{"The":[0,165],"expression":[1],"of":[2,62,70,149,159,169,180,191],"molecular":[3],"chirality":[4],"across":[5],"widely":[6],"separated":[7],"energy":[8],"regimes":[9],"was":[10],"investigated":[11],"in":[12,52,75,87,105,185],"enantiomeric":[13],"Cr(III)":[14,173],"and":[15,28,39,49,60,64,125,174],"Co(III)":[16,175],"tris(trans-1,2-cyclohexanediamine)":[17],"complexes":[18,176],"using":[19],"vibrational":[20],"circular":[21,25,31],"dichroism":[22,26,32],"(VCD),":[23],"electronic":[24,189],"(ECD),":[27],"X-ray":[29,37],"natural":[30],"(XNCD),":[33],"supported":[34],"by":[35],"single-crystal":[36],"diffraction":[38],"density":[40],"functional":[41],"theory":[42],"(DFT).":[43],"Crystallographic":[44],"analysis":[45],"establishes":[46],"the":[47,53,57,71,78,88,101,119,143,147,154,162,178,186],"\u039b-\u03b4\u03b4\u03b4/lel3":[48],"\u0394-\u03bb\u03bb\u03bb/lel3":[50],"configurations":[51],"solid":[54],"state,":[55],"while":[56],"ECD":[58],"spectra":[59,67],"comparison":[61],"experimental":[63,157],"DFT-calculated":[65],"VCD":[66],"support":[68],"retention":[69],"lel3":[72],"stereochemical":[73],"arrangement":[74],"solution.":[76],"At":[77,118],"Co":[79,144],"K-edge,":[80,121],"pronounced":[81],"opposite-sign":[82],"XNCD":[83,128,160,167,182],"responses":[84,168],"are":[85],"observed":[86],"pre-edge":[89],"region,":[90],"with":[91],"an":[92,110],"amplitude":[93,140],"approximately":[94],"1.5":[95],"times":[96],"that":[97],"previously":[98],"reported":[99],"for":[100],"Co(III)\u2013ethylenediamine":[102],"system":[103],"measured":[104],"axial":[106,116],"geometry,":[107],"corresponding":[108],"to":[109,142,183],"estimated":[111],"threefold":[112],"enhancement":[113],"under":[114],"equivalent":[115],"conditions.":[117],"Cr":[120,163],"a":[122],"clear,":[123],"reproducible":[124],"well-resolved":[126],"enantiomer-dependent":[127],"response,":[129],"featuring":[130],"several":[131],"distinct":[132,166],"dichroic":[133],"contributions,":[134],"is":[135],"observed,":[136],"despite":[137],"its":[138],"lower":[139],"relative":[141],"analogue.":[145],"To":[146],"best":[148],"our":[150],"knowledge,":[151],"this":[152],"constitutes":[153],"first":[155],"clear":[156],"observation":[158],"at":[161],"K-edge.":[164],"these":[170],"structurally":[171],"related":[172],"demonstrate":[177],"sensitivity":[179],"K-edge":[181],"differences":[184],"local":[187],"chiral":[188],"environment":[190],"transition-metal":[192],"centers.":[193]},"counts_by_year":[],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2026-10-17T00:00:00"}