{"id":"https://openalex.org/W7220854040","doi":"https://doi.org/10.26434/chemrxiv.15010012/v1","title":"A Highly Proton-Tolerant Multicenter Borane/Phosphazene Catalytic System for Efficient PO/CO2 Copolymerization toward CO2-Based Poly(carbonate-ether) Polyols","display_name":"A Highly Proton-Tolerant Multicenter Borane/Phosphazene Catalytic System for Efficient PO/CO2 Copolymerization toward CO2-Based Poly(carbonate-ether) Polyols","publication_year":2026,"publication_date":"2026-10-07","ids":{"openalex":"https://openalex.org/W7220854040","doi":"https://doi.org/10.26434/chemrxiv.15010012/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15010012/v1","doi":"https://doi.org/10.26434/chemrxiv.15010012/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010012/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010012/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010012/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5123564577","display_name":"Minghao Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Minghao Liu","raw_affiliation_strings":["Qingdao University of Science and Technology","State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]},{"raw_affiliation_string":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087861402","display_name":"Lihang Jiang","orcid":"https://orcid.org/0009-0004-4601-9038","observed_orcids":["https://orcid.org/0009-0004-4601-9038"]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Lihang Jiang","raw_affiliation_strings":["Qingdao University of Science and Technology","State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]},{"raw_affiliation_string":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100769599","display_name":"Zehao Wang","orcid":"https://orcid.org/0000-0002-7723-1945","observed_orcids":["https://orcid.org/0000-0002-7723-1945"]},"institutions":[{"id":"https://openalex.org/I4210156066","display_name":"State Key Laboratory of Chemical Engineering","ror":"https://ror.org/05803vc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210156066"]},{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zehao Wang","raw_affiliation_strings":["State Key Laboratory of Chemical Engineering and Low-carbon Technology, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Road, Hangzhou, Zhejiang, China, 310058"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Chemical Engineering and Low-carbon Technology, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Road, Hangzhou, Zhejiang, China, 310058","institution_ids":["https://openalex.org/I4210156066","https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5157833952","display_name":"Chenyao Yuan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chenyao Yuan","raw_affiliation_strings":["Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering","Qingdao University of Science and Technology"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5157802859","display_name":"Zhenwei Zhou","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhenwei Zhou","raw_affiliation_strings":["Qingdao University of Science and Technology","State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]},{"raw_affiliation_string":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030006368","display_name":"Jinbo Zhang","orcid":"https://orcid.org/0009-0001-9042-3845","observed_orcids":["https://orcid.org/0009-0001-9042-3845"]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jinbo Zhang","raw_affiliation_strings":["Qingdao University of Science and Technology","State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]},{"raw_affiliation_string":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5106123185","display_name":"Shaofeng Liu","orcid":"https://orcid.org/0000-0002-1230-0946","observed_orcids":["https://orcid.org/0000-0002-1230-0946"]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shaofeng Liu","raw_affiliation_strings":["Qingdao University of Science and Technology","State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering"],"raw_orcid":"https://orcid.org/0000-0002-1230-0946","affiliations":[{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]},{"raw_affiliation_string":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100629999","display_name":"Zhibo Li","orcid":"https://orcid.org/0000-0001-9512-1507","observed_orcids":["https://orcid.org/0000-0001-9512-1507","https://orcid.org/0009-0003-0516-8363"]},"institutions":[{"id":"https://openalex.org/I143413998","display_name":"Qingdao University of Science and Technology","ror":"https://ror.org/041j8js14","country_code":"CN","type":"education","lineage":["https://openalex.org/I143413998"]},{"id":"https://openalex.org/I4210156066","display_name":"State Key Laboratory of Chemical Engineering","ror":"https://ror.org/05803vc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210156066"]},{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhibo Li","raw_affiliation_strings":["Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering","Qingdao University of Science and Technology","State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","State Key Laboratory of Chemical Engineering and Low-carbon Technology, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Road, Hangzhou, Zhejiang, China, 310058"],"raw_orcid":"https://orcid.org/0000-0001-9512-1507","affiliations":[{"raw_affiliation_string":"Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering","institution_ids":[]},{"raw_affiliation_string":"Qingdao University of Science and Technology","institution_ids":["https://openalex.org/I143413998"]},{"raw_affiliation_string":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering","institution_ids":[]},{"raw_affiliation_string":"State Key Laboratory of Chemical Engineering and Low-carbon Technology, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Road, Hangzhou, Zhejiang, China, 310058","institution_ids":["https://openalex.org/I4210156066","https://openalex.org/I76130692"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.9520999789237976,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.9520999789237976,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.04619999974966049,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/propylene-oxide","display_name":"propylene oxide","score":0.8009999990463257},{"id":"https://openalex.org/keywords/carbon-dioxide","display_name":"carbon dioxide","score":0.6060000061988831},{"id":"https://openalex.org/keywords/ring-opening-copolymerization","display_name":"ring-opening copolymerization","score":0.9959999918937683},{"id":"https://openalex.org/keywords/chain-transfer-agent","display_name":"chain transfer agent","score":0.9179999828338623},{"id":"https://openalex.org/keywords/metal-free-catalysis","display_name":"metal-free catalysis","score":0.734000027179718},{"id":"https://openalex.org/keywords/glass-transition-temperature","display_name":"glass transition temperature","score":0.578000009059906}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.6234999895095825},{"id":"https://openalex.org/C2776540798","wikidata":"https://www.wikidata.org/wiki/Q62246","display_name":"Polycarbonate","level":2,"score":0.5946000218391418},{"id":"https://openalex.org/C2777505466","wikidata":"https://www.wikidata.org/wiki/Q727742","display_name":"Propylene oxide","level":5,"score":0.5781000256538391},{"id":"https://openalex.org/C11432220","wikidata":"https://www.wikidata.org/wiki/Q1975334","display_name":"Dispersity","level":2,"score":0.5748999714851379},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5601000189781189},{"id":"https://openalex.org/C2777983707","wikidata":"https://www.wikidata.org/wiki/Q415979","display_name":"Propylene carbonate","level":4,"score":0.513700008392334},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5040000081062317},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5006999969482422},{"id":"https://openalex.org/C49852136","wikidata":"https://www.wikidata.org/wiki/Q906487","display_name":"Depolymerization","level":2,"score":0.4648999869823456},{"id":"https://openalex.org/C2780659211","wikidata":"https://www.wikidata.org/wiki/Q181699","display_name":"Carbonate","level":2,"score":0.45159998536109924},{"id":"https://openalex.org/C2778826510","wikidata":"https://www.wikidata.org/wiki/Q15634214","display_name":"Borane","level":3,"score":0.4205000102519989},{"id":"https://openalex.org/C131847037","wikidata":"https://www.wikidata.org/wiki/Q7899036","display_name":"Upper critical solution temperature","level":5,"score":0.41350001096725464},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3961000144481659},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3822999894618988},{"id":"https://openalex.org/C45206210","wikidata":"https://www.wikidata.org/wiki/Q2415817","display_name":"Nanoscopic scale","level":2,"score":0.3797999918460846},{"id":"https://openalex.org/C110884469","wikidata":"https://www.wikidata.org/wiki/Q906367","display_name":"Miscibility","level":3,"score":0.3686000108718872},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3467999994754791},{"id":"https://openalex.org/C2777954637","wikidata":"https://www.wikidata.org/wiki/Q151324","display_name":"Propene","level":3,"score":0.34439998865127563},{"id":"https://openalex.org/C45211672","wikidata":"https://www.wikidata.org/wiki/Q4119016","display_name":"Biodegradable polymer","level":3,"score":0.3391999900341034},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.29760000109672546},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.27900001406669617},{"id":"https://openalex.org/C153914509","wikidata":"https://www.wikidata.org/wiki/Q191090","display_name":"Metathesis","level":4,"score":0.2703000009059906},{"id":"https://openalex.org/C175583648","wikidata":"https://www.wikidata.org/wiki/Q903156","display_name":"Heterogeneous catalysis","level":3,"score":0.25940001010894775},{"id":"https://openalex.org/C153953470","wikidata":"https://www.wikidata.org/wiki/Q10863702","display_name":"Post-metallocene catalyst","level":5,"score":0.25929999351501465},{"id":"https://openalex.org/C2777502316","wikidata":"https://www.wikidata.org/wiki/Q2712515","display_name":"Stabilizer (aeronautics)","level":2,"score":0.2542000114917755},{"id":"https://openalex.org/C2776230335","wikidata":"https://www.wikidata.org/wiki/Q357415","display_name":"Adipic acid","level":2,"score":0.25290000438690186},{"id":"https://openalex.org/C2776743539","wikidata":"https://www.wikidata.org/wiki/Q421313","display_name":"Lactide","level":4,"score":0.2524999976158142},{"id":"https://openalex.org/C122865956","wikidata":"https://www.wikidata.org/wiki/Q825643","display_name":"Glass transition","level":3,"score":0.25209999084472656}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15010012/v1","doi":"https://doi.org/10.26434/chemrxiv.15010012/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010012/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010012/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15010012/v1","doi":"https://doi.org/10.26434/chemrxiv.15010012/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010012/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010012/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7220854040.pdf","grobid_xml":"https://content.openalex.org/works/W7220854040.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W7159635099","https://openalex.org/W4317717881","https://openalex.org/W7162137164","https://openalex.org/W7129548656","https://openalex.org/W4226186020","https://openalex.org/W4402676308","https://openalex.org/W4226531488","https://openalex.org/W4309781049","https://openalex.org/W7161125728","https://openalex.org/W7128431495"],"abstract_inverted_index":{"Low-molecular-weight":[0],"CO2-based":[1,166],"poly(carbonate-ether)":[2,167],"polyols":[3,117,168],"from":[4],"ring-opening":[5],"copolymerization":[6],"(ROCOP)":[7],"of":[8,31,34,62,81,94,107,147,165],"propylene":[9],"oxide":[10],"(PO)":[11],"with":[12,55,120,169],"CO2":[13,131],"are":[14],"highly":[15,35],"desired":[16],"as":[17],"soft":[18],"blocks":[19],"to":[20,75,111,144],"synthesize":[21],"sustainable":[22],"polyurethanes.":[23],"However,":[24],"such":[25],"process":[26],"remains":[27],"great":[28],"challenges":[29],"because":[30],"the":[32,59,92,100,134,163],"demanding":[33],"proton-tolerant":[36],"catalysts.":[37],"Herein,":[38],"we":[39],"report":[40],"a":[41,47,159],"binary":[42,101],"organocatalysis":[43],"system":[44,102],"based":[45],"on":[46],"nanoscopic":[48],"multicenter":[49],"borane":[50],"Lewis":[51],"acid":[52],"(POSS-B8)":[53],"combined":[54],"various":[56],"organobases":[57],"for":[58,162,175],"tunable":[60,156],"ROCOP":[61,88],"PO":[63,82],"and":[64,83,130,139,155,172],"CO2.":[65],"The":[66],"confined":[67],"POSS-B8":[68,128],"framework":[69],"not":[70],"only":[71],"endows":[72],"excellent":[73],"tolerance":[74],"proton":[76],"but":[77],"enables":[78],"cooperative":[79],"activation":[80],"CO2,":[84],"thereby":[85],"facilitating":[86],"PO/CO2":[87],"while":[89],"effectively":[90],"suppressing":[91],"formation":[93],"cyclic":[95],"propene":[96],"carbonate":[97,135],"(cPC).":[98],"Remarkably,":[99],"can":[103,150],"tolerate":[104],"high":[105],"loadings":[106],"chain-transfer":[108],"agents":[109],"(up":[110],"400":[112],"equivalents),":[113],"affording":[114],"low-molecular-weight":[115],"polycarbonate":[116],"(0.6":[118],"kDa)":[119],"narrow":[121],"dispersity":[122],"(\u00d0":[123],"=":[124],"1.16).":[125],"By":[126],"tuning":[127],"loading":[129],"pressure,":[132],"both":[133],"content":[136],"(19-64":[137],"mol%)":[138],"glass":[140],"transition":[141],"temperature":[142],"(-58.6":[143],"4.7":[145],"\u00b0C)":[146],"resulting":[148],"polymers":[149],"be":[151],"modulated.":[152],"This":[153],"metal-free":[154],"platform":[157],"offers":[158],"versatile":[160],"strategy":[161],"preparation":[164],"controlled":[170],"structure":[171],"strong":[173],"potential":[174],"industrial":[176],"applications.":[177]},"counts_by_year":[],"updated_date":"2026-10-28T10:33:24.094632","created_date":"2026-10-08T00:00:00"}