{"id":"https://openalex.org/W7220846355","doi":"https://doi.org/10.1039/d6qi01597b","title":"Strong metal\u2013ligand covalency of N-heterocyclic carbene\u2013carbon disulfide ligands in cobalt complexes","display_name":"Strong metal\u2013ligand covalency of N-heterocyclic carbene\u2013carbon disulfide ligands in cobalt complexes","publication_year":2026,"publication_date":"2026-01-01","ids":{"openalex":"https://openalex.org/W7220846355","doi":"https://doi.org/10.1039/d6qi01597b"},"language":"en","primary_location":{"id":"doi:10.1039/d6qi01597b","doi":"https://doi.org/10.1039/d6qi01597b","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d6qi01597b","pdf_url":null,"source":{"id":"https://openalex.org/S2764402489","display_name":"Inorganic Chemistry Frontiers","issn_l":"2052-1545","issn":["2052-1545","2052-1553"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry Frontiers","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5144322570","display_name":"Subin Park","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4921948","display_name":"Pusan National University","ror":"https://ror.org/01an57a31","country_code":"KR","type":"education","lineage":["https://openalex.org/I4921948"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Subin Park","raw_affiliation_strings":["Department of Chemistry, Pusan National University, Busan, Republic of Korea","Institute for Future Earth, Pusan National University, Busan, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]},{"raw_affiliation_string":"Institute for Future Earth, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5146460148","display_name":"Jaegeum Cha","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4921948","display_name":"Pusan National University","ror":"https://ror.org/01an57a31","country_code":"KR","type":"education","lineage":["https://openalex.org/I4921948"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jaegeum Cha","raw_affiliation_strings":["Department of Chemistry, Pusan National University, Busan, Republic of Korea","Institute for Future Earth, Pusan National University, Busan, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]},{"raw_affiliation_string":"Institute for Future Earth, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5151677444","display_name":"Gayeong Lim","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4921948","display_name":"Pusan National University","ror":"https://ror.org/01an57a31","country_code":"KR","type":"education","lineage":["https://openalex.org/I4921948"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Gayeong Lim","raw_affiliation_strings":["Department of Chemistry, Pusan National University, Busan, Republic of Korea","Institute for Future Earth, Pusan National University, Busan, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]},{"raw_affiliation_string":"Institute for Future Earth, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079028591","display_name":"Jeongcheol Shin","orcid":"https://orcid.org/0000-0001-9589-5318","observed_orcids":["https://orcid.org/0000-0001-9589-5318"]},"institutions":[{"id":"https://openalex.org/I65832422","display_name":"Duksung Women's University","ror":"https://ror.org/01h6frr69","country_code":"KR","type":"education","lineage":["https://openalex.org/I65832422"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Jeongcheol Shin","raw_affiliation_strings":["Department of Chemistry, Duksung Women's University, Seoul, Republic of Korea"],"raw_orcid":"https://orcid.org/0000-0001-9589-5318","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Duksung Women's University, Seoul, Republic of Korea","institution_ids":["https://openalex.org/I65832422"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100773905","display_name":"Youngsuk Kim","orcid":"https://orcid.org/0000-0002-7378-2301","observed_orcids":["https://orcid.org/0000-0002-7378-2301"]},"institutions":[{"id":"https://openalex.org/I4921948","display_name":"Pusan National University","ror":"https://ror.org/01an57a31","country_code":"KR","type":"education","lineage":["https://openalex.org/I4921948"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Youngsuk Kim","raw_affiliation_strings":["Chemistry Institute for Functional Materials, Pusan National University, Busan, Republic of Korea","Department of Chemistry, Pusan National University, Busan, Republic of Korea","Institute for Future Earth, Pusan National University, Busan, Republic of Korea"],"raw_orcid":"https://orcid.org/0000-0002-7378-2301","affiliations":[{"raw_affiliation_string":"Chemistry Institute for Functional Materials, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]},{"raw_affiliation_string":"Department of Chemistry, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]},{"raw_affiliation_string":"Institute for Future Earth, Pusan National University, Busan, Republic of Korea","institution_ids":["https://openalex.org/I4921948"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5079028591","https://openalex.org/A5100773905"],"corresponding_institution_ids":["https://openalex.org/I4921948","https://openalex.org/I65832422"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.61865491,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9711999893188477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9711999893188477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.007699999958276749,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.005900000222027302,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbene-ligands","display_name":"N-heterocyclic carbene ligands","score":0.8389999866485596},{"id":"https://openalex.org/keywords/cobalt-complexes","display_name":"cobalt complexes","score":0.9980000257492065},{"id":"https://openalex.org/keywords/metal-ligand-covalency","display_name":"metal-ligand covalency","score":0.9580000042915344},{"id":"https://openalex.org/keywords/spin-localization","display_name":"spin localization","score":0.5540000200271606},{"id":"https://openalex.org/keywords/coordination-environment","display_name":"coordination environment","score":0.7129999995231628},{"id":"https://openalex.org/keywords/ligand-to-metal-charge-transfer","display_name":"ligand-to-metal charge transfer","score":0.4350000023841858}],"concepts":[{"id":"https://openalex.org/C515602321","wikidata":"https://www.wikidata.org/wiki/Q740","display_name":"Cobalt","level":2,"score":0.843999981880188},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6545000076293945},{"id":"https://openalex.org/C27256138","wikidata":"https://www.wikidata.org/wiki/Q1230226","display_name":"Disulfide bond","level":2,"score":0.593999981880188},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5809999704360962},{"id":"https://openalex.org/C2778591166","wikidata":"https://www.wikidata.org/wiki/Q484152","display_name":"Oxidation state","level":3,"score":0.5338000059127808},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4715000092983246},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.41190001368522644},{"id":"https://openalex.org/C35325081","wikidata":"https://www.wikidata.org/wiki/Q7577416","display_name":"Spin states","level":2,"score":0.3675999939441681},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.36079999804496765},{"id":"https://openalex.org/C42704618","wikidata":"https://www.wikidata.org/wiki/Q910917","display_name":"Spin (aerodynamics)","level":2,"score":0.3009999990463257},{"id":"https://openalex.org/C107814960","wikidata":"https://www.wikidata.org/wiki/Q611957","display_name":"Solid-state","level":2,"score":0.28760001063346863},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.27730000019073486},{"id":"https://openalex.org/C48103436","wikidata":"https://www.wikidata.org/wiki/Q599031","display_name":"State (computer science)","level":2,"score":0.25290000438690186}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/d6qi01597b","doi":"https://doi.org/10.1039/d6qi01597b","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d6qi01597b","pdf_url":null,"source":{"id":"https://openalex.org/S2764402489","display_name":"Inorganic Chemistry Frontiers","issn_l":"2052-1545","issn":["2052-1545","2052-1553"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry Frontiers","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4643161432","display_name":null,"funder_award_id":"RS-2023-00301938","funder_id":"https://openalex.org/F4320321408","funder_display_name":"Ministry of Education"},{"id":"https://openalex.org/G7551560019","display_name":null,"funder_award_id":"RS-2025-00520203","funder_id":"https://openalex.org/F4320322111","funder_display_name":"Korea Basic Science Institute"},{"id":"https://openalex.org/G7924946259","display_name":null,"funder_award_id":"RS-2024-00403266","funder_id":"https://openalex.org/F4320322111","funder_display_name":"Korea Basic Science Institute"},{"id":"https://openalex.org/G9000926656","display_name":null,"funder_award_id":"RS-2026-25590908","funder_id":"https://openalex.org/F4320328359","funder_display_name":"Ministry of Science and ICT, South Korea"},{"id":"https://openalex.org/G9000927102","display_name":null,"funder_award_id":"RS-2023-00210804","funder_id":"https://openalex.org/F4320328359","funder_display_name":"Ministry of Science and ICT, South Korea"},{"id":"https://openalex.org/G9000927253","display_name":null,"funder_award_id":"RS-2025-02215028","funder_id":"https://openalex.org/F4320328359","funder_display_name":"Ministry of Science and ICT, South Korea"},{"id":"https://openalex.org/G9000928644","display_name":null,"funder_award_id":"RS-2025-25424736","funder_id":"https://openalex.org/F4320321408","funder_display_name":"Ministry of Education"}],"funders":[{"id":"https://openalex.org/F4320321408","display_name":"Ministry of Education","ror":"https://ror.org/01p262204"},{"id":"https://openalex.org/F4320322111","display_name":"Korea Basic Science Institute","ror":"https://ror.org/0417sdw47"},{"id":"https://openalex.org/F4320328359","display_name":"Ministry of Science and ICT, South Korea","ror":"https://ror.org/01wpjm123"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":83,"referenced_works":["https://openalex.org/W561481425","https://openalex.org/W1971080513","https://openalex.org/W1971680076","https://openalex.org/W1982567581","https://openalex.org/W1988254927","https://openalex.org/W1991312972","https://openalex.org/W2003143283","https://openalex.org/W2003555872","https://openalex.org/W2004317657","https://openalex.org/W2005227604","https://openalex.org/W2012419965","https://openalex.org/W2021992459","https://openalex.org/W2023271753","https://openalex.org/W2025080505","https://openalex.org/W2030054392","https://openalex.org/W2032719166","https://openalex.org/W2038533471","https://openalex.org/W2042054507","https://openalex.org/W2046286719","https://openalex.org/W2052796878","https://openalex.org/W2053983981","https://openalex.org/W2072237511","https://openalex.org/W2079935930","https://openalex.org/W2086936309","https://openalex.org/W2090309515","https://openalex.org/W2103029770","https://openalex.org/W2131400546","https://openalex.org/W2143981217","https://openalex.org/W2148284063","https://openalex.org/W2148374597","https://openalex.org/W2151640189","https://openalex.org/W2312952953","https://openalex.org/W2313535374","https://openalex.org/W2327596617","https://openalex.org/W2329146555","https://openalex.org/W2561907941","https://openalex.org/W2604156473","https://openalex.org/W2620477936","https://openalex.org/W2767245009","https://openalex.org/W2770470827","https://openalex.org/W2791254231","https://openalex.org/W2811352597","https://openalex.org/W2885371647","https://openalex.org/W2926036315","https://openalex.org/W3015824199","https://openalex.org/W3125471342","https://openalex.org/W3162227746","https://openalex.org/W3170738095","https://openalex.org/W3177506355","https://openalex.org/W3197903425","https://openalex.org/W4205824088","https://openalex.org/W4211172071","https://openalex.org/W4283758603","https://openalex.org/W4296116792","https://openalex.org/W4309474696","https://openalex.org/W4318185851","https://openalex.org/W4323294884","https://openalex.org/W4386895018","https://openalex.org/W4388233759","https://openalex.org/W4392151381","https://openalex.org/W4396583648","https://openalex.org/W4396785727","https://openalex.org/W4402824362","https://openalex.org/W4403468425","https://openalex.org/W4403829041","https://openalex.org/W4404250636","https://openalex.org/W4406714580","https://openalex.org/W4407382670","https://openalex.org/W4407478041","https://openalex.org/W4407850272","https://openalex.org/W4408992312","https://openalex.org/W4410213539","https://openalex.org/W4412095156","https://openalex.org/W4413984466","https://openalex.org/W4415431523","https://openalex.org/W7125769734","https://openalex.org/W7172437028","https://openalex.org/W7220891521","https://openalex.org/W7220912981","https://openalex.org/W7220969289","https://openalex.org/W7221037944","https://openalex.org/W7221053954","https://openalex.org/W7221055540"],"related_works":["https://openalex.org/W2761480752","https://openalex.org/W2038703785","https://openalex.org/W2736917437","https://openalex.org/W7220451694","https://openalex.org/W2057424197","https://openalex.org/W3132169684","https://openalex.org/W2084669299","https://openalex.org/W4229055287","https://openalex.org/W3080651952","https://openalex.org/W1632799680"],"abstract_inverted_index":{"Formal":[0],"ligand":[1],"oxidation":[2],"state":[3],"does":[4],"not":[5],"dictate":[6],"spin":[7,16],"localization:":[8],"strong":[9],"Co\u2013ligand":[10],"covalency":[11],"gives":[12],"either":[13],"predominantly":[14],"Co-centered":[15],"or":[17],"a":[18],"closed-shell":[19],"singlet,":[20],"depending":[21],"on":[22],"the":[23],"coordination":[24],"environment.":[25]},"counts_by_year":[],"updated_date":"2026-10-25T09:29:13.331239","created_date":"2026-10-08T00:00:00"}