{"id":"https://openalex.org/W7220833489","doi":"https://doi.org/10.26434/chemrxiv.15010033/v1","title":"Case Studies of Homemorphic Isomerization: Interconversion of In/Out Isomers of Bicyclo[6.5.1]tetradecane and Related Bicyclic Hydrocarbons","display_name":"Case Studies of Homemorphic Isomerization: Interconversion of In/Out Isomers of Bicyclo[6.5.1]tetradecane and Related Bicyclic Hydrocarbons","publication_year":2026,"publication_date":"2026-10-07","ids":{"openalex":"https://openalex.org/W7220833489","doi":"https://doi.org/10.26434/chemrxiv.15010033/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15010033/v1","doi":"https://doi.org/10.26434/chemrxiv.15010033/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010033/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010033/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010033/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5077800695","display_name":"Marsel Z. Shafikov","orcid":"https://orcid.org/0000-0003-0495-0364","observed_orcids":["https://orcid.org/0000-0003-0495-0364"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Marsel Z. Shafikov","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0003-0495-0364","affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5064454551","display_name":"John Andrew Gladysz","orcid":"https://orcid.org/0000-0002-7012-4872","observed_orcids":["https://orcid.org/0000-0002-7012-4872"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"John A. Gladysz","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.1988999992609024,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.1988999992609024,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.11490000039339066,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.11249999701976776,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/bicyclic-hydrocarbons","display_name":"bicyclic hydrocarbons","score":0.9079999923706055},{"id":"https://openalex.org/keywords/transition-state","display_name":"transition state","score":0.5019999742507935},{"id":"https://openalex.org/keywords/activation-barrier","display_name":"activation barrier","score":0.7110000252723694}],"concepts":[{"id":"https://openalex.org/C126661725","wikidata":"https://www.wikidata.org/wiki/Q903420","display_name":"Isomerization","level":3,"score":0.9171000123023987},{"id":"https://openalex.org/C24961977","wikidata":"https://www.wikidata.org/wiki/Q225972","display_name":"Bicyclic molecule","level":2,"score":0.8424000144004822},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6593000292778015},{"id":"https://openalex.org/C89031862","wikidata":"https://www.wikidata.org/wiki/Q906964","display_name":"Transition state","level":3,"score":0.5289000272750854},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5153999924659729},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.4372999966144562},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4300000071525574},{"id":"https://openalex.org/C98045186","wikidata":"https://www.wikidata.org/wiki/Q205663","display_name":"Process (computing)","level":2,"score":0.37220001220703125},{"id":"https://openalex.org/C132525143","wikidata":"https://www.wikidata.org/wiki/Q141488","display_name":"Graph","level":2,"score":0.3125},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.2540000081062317}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15010033/v1","doi":"https://doi.org/10.26434/chemrxiv.15010033/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010033/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010033/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15010033/v1","doi":"https://doi.org/10.26434/chemrxiv.15010033/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15010033/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010033/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7220833489.pdf"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W4396226306","https://openalex.org/W2095526239","https://openalex.org/W2106762456","https://openalex.org/W102665859","https://openalex.org/W2025481278","https://openalex.org/W1991140080","https://openalex.org/W3005335555","https://openalex.org/W2977341415","https://openalex.org/W1992064487","https://openalex.org/W2328874243"],"abstract_inverted_index":{"Homeomorphic":[0],"isomerization":[1,110],"is":[2,54,69,111],"equivalent":[3],"to":[4,71],"turning":[5],"a":[6,15,82],"molecule":[7],"inside":[8],"out":[9],"in":[10,87,104,113],"the":[11,22,42,45,58,62,65,74,97,107],"same":[12],"manner":[13],"as":[14],"reversible":[16],"article":[17],"of":[18,24,36,44,84,96,109],"clothing.":[19],"Manifestations":[20],"include":[21],"interconversion":[23],"(a)":[25],"in,in":[26],"and":[27,33,99,106],"out,out":[28],"isomers,":[29],"or":[30],"(b)":[31],"in,out":[32],"out,in":[34],"isomers":[35],"bicyclic":[37],"molecules,":[38],"but":[39],"without":[40],"inverting":[41],"configurations":[43],"bridgehead":[46],"atoms.":[47],"In":[48],"this":[49,51],"preprint,":[50],"topological":[52],"process":[53,108],"probed":[55],"computationally":[56],"for":[57],"title":[59],"molecules.":[60],"For":[61],"in,in/out,out":[63],"manifold,":[64],"CH":[66,79],"2":[67,76],"tether":[68,80],"able":[70],"transit":[72],"through":[73],"CH(CH":[75],")":[77],"6":[78],"with":[81,90],"barrier":[83],"~26":[85],"kcal/mol,":[86],"good":[88],"agreement":[89],"an":[91],"experimental":[92],"measurement.":[93],"The":[94],"geometries":[95],"ground":[98],"transition":[100],"states":[101],"are":[102],"analyzed":[103],"detail":[105],"visualized":[112],"animations.":[114]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-10-08T00:00:00"}