{"id":"https://openalex.org/W7220375297","doi":"https://doi.org/10.26434/chemrxiv.15009864/v1","title":"Surface hydroxyls act as key intermediates in the selective oxidative dehydrogenation of 2-propanol on Co3O4","display_name":"Surface hydroxyls act as key intermediates in the selective oxidative dehydrogenation of 2-propanol on Co3O4","publication_year":2026,"publication_date":"2026-10-05","ids":{"openalex":"https://openalex.org/W7220375297","doi":"https://doi.org/10.26434/chemrxiv.15009864/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15009864/v1","doi":"https://doi.org/10.26434/chemrxiv.15009864/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15009864/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009864/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009864/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5073017196","display_name":"Pierfrancesco Ticali","orcid":"https://orcid.org/0000-0003-3514-0196","observed_orcids":["https://orcid.org/0000-0003-3514-0196"]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]},{"id":"https://openalex.org/I62318514","display_name":"University of Duisburg-Essen","ror":"https://ror.org/04mz5ra38","country_code":"DE","type":"education","lineage":["https://openalex.org/I62318514"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Pierfrancesco Ticali","raw_affiliation_strings":[". Department of Theoretical Chemistry , University of Duisburg-Essen","Institute of Inorganic Chemistry , Kiel University , Max-Eyth-Str. 2 , 24118 Kiel , Germany"],"raw_orcid":"https://orcid.org/0000-0003-3514-0196","affiliations":[{"raw_affiliation_string":". Department of Theoretical Chemistry , University of Duisburg-Essen","institution_ids":["https://openalex.org/I62318514"]},{"raw_affiliation_string":"Institute of Inorganic Chemistry , Kiel University , Max-Eyth-Str. 2 , 24118 Kiel , Germany","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039258905","display_name":"St\u00e9phane Kenmoe","orcid":"https://orcid.org/0000-0003-3622-2716","observed_orcids":["https://orcid.org/0000-0003-3622-2716"]},"institutions":[{"id":"https://openalex.org/I62318514","display_name":"University of Duisburg-Essen","ror":"https://ror.org/04mz5ra38","country_code":"DE","type":"education","lineage":["https://openalex.org/I62318514"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Stephane Kenmoe","raw_affiliation_strings":["Department of Theoretical Chemistry, University of Duisburg-Essen, Universit\u00e4tsstr. 2, Essen, Germany, 45141"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Theoretical Chemistry, University of Duisburg-Essen, Universit\u00e4tsstr. 2, Essen, Germany, 45141","institution_ids":["https://openalex.org/I62318514"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059113182","display_name":"Hamidreza Hajiyani","orcid":"https://orcid.org/0000-0002-1150-0567","observed_orcids":["https://orcid.org/0000-0002-1150-0567"]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Hamidreza Hajiyani","raw_affiliation_strings":["Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036056934","display_name":"Amir Omranpour","orcid":"https://orcid.org/0009-0008-1500-3067","observed_orcids":["https://orcid.org/0009-0008-1500-3067"]},"institutions":[{"id":"https://openalex.org/I904495901","display_name":"Ruhr University Bochum","ror":"https://ror.org/04tsk2644","country_code":"DE","type":"education","lineage":["https://openalex.org/I904495901"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Amir Omranpour","raw_affiliation_strings":["Lehrstuhl f\u00fcr Theoretische Chemie II","Research Alliance Ruhr","Research Center Chemical Sciences and Sustainability","Ruhr-Universit\u00e4t Bochum"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lehrstuhl f\u00fcr Theoretische Chemie II","institution_ids":[]},{"raw_affiliation_string":"Research Alliance Ruhr","institution_ids":[]},{"raw_affiliation_string":"Research Center Chemical Sciences and Sustainability","institution_ids":[]},{"raw_affiliation_string":"Ruhr-Universit\u00e4t Bochum","institution_ids":["https://openalex.org/I904495901"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006032538","display_name":"Nicolas Cosanne","orcid":"https://orcid.org/0009-0003-0039-2593","observed_orcids":["https://orcid.org/0009-0003-0039-2593"]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Nicolas Cosanne","raw_affiliation_strings":["Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5120273967","display_name":"Hauke Scheele","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Hauke Scheele","raw_affiliation_strings":["Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032612942","display_name":"Saskia Arnold","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Saskia Arnold","raw_affiliation_strings":["Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039691617","display_name":"Martin Muhler","orcid":"https://orcid.org/0000-0001-5343-6922","observed_orcids":["https://orcid.org/0000-0001-5343-6922"]},"institutions":[{"id":"https://openalex.org/I904495901","display_name":"Ruhr University Bochum","ror":"https://ror.org/04tsk2644","country_code":"DE","type":"education","lineage":["https://openalex.org/I904495901"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Martin Muhler","raw_affiliation_strings":["Laboratory of Industrial Chemistry, Ruhr University Bochum, Universit\u00e4tsstra\u00dfe 150, Bochum, Germany, 44801"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Industrial Chemistry, Ruhr University Bochum, Universit\u00e4tsstra\u00dfe 150, Bochum, Germany, 44801","institution_ids":["https://openalex.org/I904495901"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000126422","display_name":"Malte Behrens","orcid":"https://orcid.org/0000-0003-3407-5011","observed_orcids":["https://orcid.org/0000-0003-3407-5011"]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Malte Behrens","raw_affiliation_strings":["Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","Surface and Interface Science KiNSIS, Kiel University, Christian-Albrechts-Platz, 4, Kiel, Germany, 24118"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]},{"raw_affiliation_string":"Surface and Interface Science KiNSIS, Kiel University, Christian-Albrechts-Platz, 4, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030369146","display_name":"Sharif Najafishirtari","orcid":"https://orcid.org/0000-0003-2121-7439","observed_orcids":["https://orcid.org/0000-0003-2121-7439"]},"institutions":[{"id":"https://openalex.org/I32021983","display_name":"Christian-Albrechts-Universit\u00e4t zu Kiel","ror":"https://ror.org/04v76ef78","country_code":"DE","type":"education","lineage":["https://openalex.org/I32021983"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Sharif Najafishirtari","raw_affiliation_strings":["Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","Surface and Interface Science KiNSIS, Kiel University, Christian-Albrechts-Platz, 4, Kiel, Germany, 24118"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]},{"raw_affiliation_string":"Surface and Interface Science KiNSIS, Kiel University, Christian-Albrechts-Platz, 4, Kiel, Germany, 24118","institution_ids":["https://openalex.org/I32021983"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.6342999935150146,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.6342999935150146,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.3610999882221222,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.0017000000225380063,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/2-propanol-oxidation","display_name":"2-propanol oxidation","score":0.9210000038146973},{"id":"https://openalex.org/keywords/co3o4","display_name":"Co3O4","score":0.8579999804496765},{"id":"https://openalex.org/keywords/surface-hydroxyl-groups","display_name":"surface hydroxyl groups","score":0.9300000071525574},{"id":"https://openalex.org/keywords/alcohol-oxidation","display_name":"alcohol oxidation","score":0.5910000205039978},{"id":"https://openalex.org/keywords/acetone-production","display_name":"acetone production","score":0.7919999957084656},{"id":"https://openalex.org/keywords/hydrogen-acceptor","display_name":"hydrogen acceptor","score":0.6309999823570251},{"id":"https://openalex.org/keywords/reaction-intermediates","display_name":"reaction intermediates","score":0.8159999847412109},{"id":"https://openalex.org/keywords/low-temperature-catalysis","display_name":"low-temperature catalysis","score":0.7699999809265137},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.5289999842643738}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8222000002861023},{"id":"https://openalex.org/C119889771","wikidata":"https://www.wikidata.org/wiki/Q898262","display_name":"Dehydrogenation","level":3,"score":0.673799991607666},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.645799994468689},{"id":"https://openalex.org/C114157696","wikidata":"https://www.wikidata.org/wiki/Q3082836","display_name":"Alcohol oxidation","level":3,"score":0.5532000064849854},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.5386000275611877},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5353999733924866},{"id":"https://openalex.org/C2781066024","wikidata":"https://www.wikidata.org/wiki/Q156","display_name":"Alcohol","level":2,"score":0.40139999985694885},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3896999955177307},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.38839998841285706},{"id":"https://openalex.org/C2781213060","wikidata":"https://www.wikidata.org/wiki/Q49546","display_name":"Acetone","level":2,"score":0.38760000467300415},{"id":"https://openalex.org/C57600042","wikidata":"https://www.wikidata.org/wiki/Q227564","display_name":"Oxidative phosphorylation","level":2,"score":0.3488999903202057},{"id":"https://openalex.org/C41183919","wikidata":"https://www.wikidata.org/wiki/Q423026","display_name":"Active site","level":3,"score":0.3456999957561493},{"id":"https://openalex.org/C53105671","wikidata":"https://www.wikidata.org/wiki/Q14777816","display_name":"Rational design","level":2,"score":0.3395000100135803},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.3366999924182892},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.3228999972343445},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.310699999332428},{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.2757999897003174},{"id":"https://openalex.org/C175583648","wikidata":"https://www.wikidata.org/wiki/Q903156","display_name":"Heterogeneous catalysis","level":3,"score":0.27459999918937683},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.26409998536109924},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.2623000144958496},{"id":"https://openalex.org/C2992086430","wikidata":"https://www.wikidata.org/wiki/Q428653","display_name":"Molecular oxygen","level":3,"score":0.25769999623298645},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2529999911785126}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15009864/v1","doi":"https://doi.org/10.26434/chemrxiv.15009864/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15009864/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009864/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15009864/v1","doi":"https://doi.org/10.26434/chemrxiv.15009864/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15009864/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009864/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2843521846","display_name":null,"funder_award_id":"TRR247","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"},{"id":"https://openalex.org/G3733334895","display_name":"TRR 247: Heterogene Oxidationskatalyse in der Fl\u00fcssigphase \u2013 Materialien und Mechanismen in der thermischen, Elektro und Photokatalyse","funder_award_id":"388390466","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"}],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7220375297.pdf","grobid_xml":"https://content.openalex.org/works/W7220375297.grobid-xml"},"referenced_works_count":1,"referenced_works":["https://openalex.org/W4410282715"],"related_works":["https://openalex.org/W2946648921","https://openalex.org/W4415946058","https://openalex.org/W2496748595","https://openalex.org/W4318833931","https://openalex.org/W1990015942","https://openalex.org/W4414840893","https://openalex.org/W4366822685","https://openalex.org/W2035472033","https://openalex.org/W2101490368","https://openalex.org/W4324057916"],"abstract_inverted_index":{"Transition-metal":[0],"oxides":[1],"typically":[2],"catalyze":[3],"aerobic":[4],"oxidation":[5,70,129,146],"reactions":[6],"with":[7,16,59,73],"high":[8,17],"activity":[9],"even":[10],"at":[11],"low":[12],"temperatures,":[13],"but":[14],"rarely":[15],"selectivity.":[18],"Owing":[19],"to":[20,66],"the":[21,30,44,107,134],"complexity":[22],"of":[23,33,43,106,127,137],"competing":[24],"surface":[25,46,77,109,138],"processes":[26],"on":[27,76,130],"such":[28],"catalysts,":[29],"rational":[31],"design":[32],"selective":[34],"low-temperature":[35],"catalysts":[36],"still":[37],"requires":[38],"a":[39,74,123],"deeper":[40],"mechanistic":[41,125],"understanding":[42],"active":[45,108,142],"and":[47,63,101,111,132],"reaction":[48],"intermediates.":[49],"In":[50],"this":[51],"work,":[52],"we":[53],"combine":[54],"operando":[55],"modulation-excitation":[56],"infrared":[57],"spectroscopy":[58],"density":[60],"functional":[61],"theory":[62],"molecular":[64],"dynamics":[65],"mechanistically":[67],"investigate":[68],"2-propanol":[69],"over":[71],"Co3O4":[72,131],"focus":[75],"hydroxyls,":[78,94,113],"acting":[79],"as":[80,117,141],"hydrogen":[81],"acceptors":[82],"during":[83],"alcohol":[84,128],"adsorption.":[85],"We":[86],"identify":[87],"two":[88],"chemically":[89],"distinct":[90],"hydroxyl":[91,139],"populations:":[92],"linear":[93],"which":[95,114],"actively":[96],"participate":[97],"in":[98,144],"acetone":[99],"formation":[100],"can":[102],"be":[103],"considered":[104],"part":[105],"ensemble,":[110],"bridged":[112],"behave":[115],"largely":[116],"spectators.":[118],"Together,":[119],"these":[120],"results":[121],"provide":[122],"molecular-level":[124],"picture":[126],"establish":[133],"dynamic":[135],"role":[136],"species":[140],"players":[143],"heterogeneous":[145],"catalysis.":[147]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2026-10-06T00:00:00"}