{"id":"https://openalex.org/W7214907953","doi":"https://doi.org/10.26434/chemrxiv.15009694/v1","title":"Out-of-equilibrium Pd(II)-based cage populations with chiral memory","display_name":"Out-of-equilibrium Pd(II)-based cage populations with chiral memory","publication_year":2026,"publication_date":"2026-09-30","ids":{"openalex":"https://openalex.org/W7214907953","doi":"https://doi.org/10.26434/chemrxiv.15009694/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15009694/v1","doi":"https://doi.org/10.26434/chemrxiv.15009694/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15009694/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009694/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009694/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011161354","display_name":"\u00c9lie Benchimol","orcid":"https://orcid.org/0000-0001-5741-7075","observed_orcids":["https://orcid.org/0000-0001-5741-7075"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]},{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE","NL"],"is_corresponding":false,"raw_author_name":"Elie Benchimol","raw_affiliation_strings":["Centre for Systems Chemistry , Stratingh Institute for Chemistry , University of Groningen , Nijenborgh 3 , 9747 AG , Groningen , the Netherlands","Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany"],"raw_orcid":"https://orcid.org/0000-0001-5741-7075","affiliations":[{"raw_affiliation_string":"Centre for Systems Chemistry , Stratingh Institute for Chemistry , University of Groningen , Nijenborgh 3 , 9747 AG , Groningen , the Netherlands","institution_ids":["https://openalex.org/I169381384"]},{"raw_affiliation_string":"Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027394912","display_name":"Bj\u00f6rn Schmidt","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Bj\u00f6rn Schmidt","raw_affiliation_strings":["Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074118404","display_name":"Irene Regeni","orcid":"https://orcid.org/0000-0001-9102-3053","observed_orcids":["https://orcid.org/0000-0001-9102-3053"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]},{"id":"https://openalex.org/I4210095283","display_name":"Institut de Science et d'Ing\u00e9nierie Supramol\u00e9culaires","ror":"https://ror.org/00xts7d02","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210095283","https://openalex.org/I4210128300","https://openalex.org/I68947357"]},{"id":"https://openalex.org/I68947357","display_name":"Universit\u00e9 de Strasbourg","ror":"https://ror.org/00pg6eq24","country_code":"FR","type":"education","lineage":["https://openalex.org/I68947357"]}],"countries":["DE","FR"],"is_corresponding":false,"raw_author_name":"Irene Regeni","raw_affiliation_strings":["Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany","Institut de science et d'ing\u00e9nierie supramol\u00e9culaire (ISIS) , University of Strasbourg & CNRS , Strasbourg , France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany","institution_ids":["https://openalex.org/I200332995"]},{"raw_affiliation_string":"Institut de science et d'ing\u00e9nierie supramol\u00e9culaire (ISIS) , University of Strasbourg & CNRS , Strasbourg , France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210095283","https://openalex.org/I68947357"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020888493","display_name":"Thorfinnur Gunnlaugsson","orcid":"https://orcid.org/0000-0003-4814-6853","observed_orcids":["https://orcid.org/0000-0003-4814-6853"]},"institutions":[{"id":"https://openalex.org/I205274468","display_name":"Trinity College Dublin","ror":"https://ror.org/02tyrky19","country_code":"IE","type":"education","lineage":["https://openalex.org/I205274468"]}],"countries":["IE"],"is_corresponding":false,"raw_author_name":"Thorfinnur Gunnlaugsson","raw_affiliation_strings":["Rinn Pharma & Biopharma , Trinity College Dublin , The University of Dublin , Dublin 2 , Ireland","School of Chemistry and Trinity Biomedical Sciences Institute (TBSI) , Trinity College Dublin , The University of Dublin , Dublin 2 , Ireland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Rinn Pharma & Biopharma , Trinity College Dublin , The University of Dublin , Dublin 2 , Ireland","institution_ids":["https://openalex.org/I205274468"]},{"raw_affiliation_string":"School of Chemistry and Trinity Biomedical Sciences Institute (TBSI) , Trinity College Dublin , The University of Dublin , Dublin 2 , Ireland","institution_ids":["https://openalex.org/I205274468"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5043202190","display_name":"Guido H. Clever","orcid":"https://orcid.org/0000-0001-8458-3060","observed_orcids":["https://orcid.org/0000-0001-8458-3060"]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Guido H. Clever","raw_affiliation_strings":["Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany","institution_ids":["https://openalex.org/I200332995"]}]}],"institutions":[],"countries_distinct_count":4,"institutions_distinct_count":6,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11419","display_name":"Supramolecular Self-Assembly in Materials","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/metallosupramolecular-assemblies","display_name":"metallosupramolecular assemblies","score":0.7699999809265137},{"id":"https://openalex.org/keywords/coordination-cages","display_name":"coordination cages","score":0.7739999890327454},{"id":"https://openalex.org/keywords/chiral-memory","display_name":"chiral memory","score":0.7120000123977661},{"id":"https://openalex.org/keywords/chemical-fuels","display_name":"chemical fuels","score":0.4699999988079071},{"id":"https://openalex.org/keywords/c60","display_name":"C60","score":0.8050000071525574},{"id":"https://openalex.org/keywords/ligand-exchange","display_name":"ligand exchange","score":0.9319999814033508},{"id":"https://openalex.org/keywords/host-guest-encapsulation","display_name":"guest encapsulation","score":0.9819999933242798},{"id":"https://openalex.org/keywords/diketopyrrolopyrrole","display_name":"diketopyrrolopyrrole","score":0.8820000290870667},{"id":"https://openalex.org/keywords/nonequilibrium-dynamics","display_name":"nonequilibrium dynamics","score":0.7730000019073486}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5163999795913696},{"id":"https://openalex.org/C160272327","wikidata":"https://www.wikidata.org/wiki/Q841007","display_name":"Cage","level":2,"score":0.4449000060558319},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.42309999465942383},{"id":"https://openalex.org/C53105671","wikidata":"https://www.wikidata.org/wiki/Q14777816","display_name":"Rational design","level":2,"score":0.4187999963760376},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.40619999170303345},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.34929999709129333},{"id":"https://openalex.org/C132677234","wikidata":"https://www.wikidata.org/wiki/Q3273544","display_name":"Structural motif","level":2,"score":0.3416000008583069},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3239000141620636},{"id":"https://openalex.org/C2777694918","wikidata":"https://www.wikidata.org/wiki/Q11171014","display_name":"Ratchet","level":3,"score":0.31949999928474426},{"id":"https://openalex.org/C184720557","wikidata":"https://www.wikidata.org/wiki/Q7825049","display_name":"Topology (electrical circuits)","level":2,"score":0.29980000853538513},{"id":"https://openalex.org/C162862793","wikidata":"https://www.wikidata.org/wiki/Q178026","display_name":"Fullerene","level":2,"score":0.2996000051498413},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2721000015735626},{"id":"https://openalex.org/C139425391","wikidata":"https://www.wikidata.org/wiki/Q2726733","display_name":"Molecular machine","level":2,"score":0.2705000042915344},{"id":"https://openalex.org/C12554922","wikidata":"https://www.wikidata.org/wiki/Q7100","display_name":"Biophysics","level":1,"score":0.25690001249313354},{"id":"https://openalex.org/C113709186","wikidata":"https://www.wikidata.org/wiki/Q5986738","display_name":"Icosahedral symmetry","level":2,"score":0.251800000667572}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15009694/v1","doi":"https://doi.org/10.26434/chemrxiv.15009694/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15009694/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009694/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15009694/v1","doi":"https://doi.org/10.26434/chemrxiv.15009694/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15009694/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009694/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1718665122","display_name":"EXC 2033: RESOLV (Ruhr Explores Solvation)","funder_award_id":"390677874","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"},{"id":"https://openalex.org/G274347230","display_name":null,"funder_award_id":"EXC2033","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"},{"id":"https://openalex.org/G2757395467","display_name":"GRK 2376: Umgrenzungsgesteuerte Chemie","funder_award_id":"331085229","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"},{"id":"https://openalex.org/G2861540686","display_name":"Supramolecular approach to novel nano-materials for biological and material applications","funder_award_id":"13/IA/1865","funder_id":"https://openalex.org/F4320320847","funder_display_name":"Science Foundation Ireland"},{"id":"https://openalex.org/G783068140","display_name":null,"funder_award_id":"GRK 2376","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"}],"funders":[{"id":"https://openalex.org/F4320320847","display_name":"Science Foundation Ireland","ror":"https://ror.org/0271asj38"},{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"},{"id":"https://openalex.org/F4320334759","display_name":"Deutsches Elektronen-Synchrotron","ror":"https://ror.org/01js2sh04"},{"id":"https://openalex.org/F8766430056","display_name":"Research Ireland","ror":"https://ror.org/010t7sr36"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7214907953.pdf","grobid_xml":"https://content.openalex.org/works/W7214907953.grobid-xml"},"referenced_works_count":2,"referenced_works":["https://openalex.org/W4400195182","https://openalex.org/W7171549215"],"related_works":["https://openalex.org/W4396615111","https://openalex.org/W2121755991","https://openalex.org/W4307426797","https://openalex.org/W4389726299","https://openalex.org/W4387952082","https://openalex.org/W6944095117","https://openalex.org/W4400505596","https://openalex.org/W7159099908","https://openalex.org/W2617558393","https://openalex.org/W6944407692"],"abstract_inverted_index":{"Metallosupramolecular":[0],"assembly":[1,73],"has":[2,15],"considerably":[3],"progressed":[4],"the":[5,27,102,105],"rational":[6],"creation":[7],"of":[8,40,52,104],"complex":[9,149],"nano":[10],"structures.":[11],"Yet,":[12],"their":[13],"use":[14],"remained":[16],"largely":[17],"constrained":[18],"to":[19,74,124],"operating":[20,86],"under":[21],"thermodynamic":[22],"control,":[23],"far":[24],"from":[25],"reaching":[26],"functional":[28],"sophistication":[29],"seen":[30],"in":[31],"out-of-equilibrium":[32],"biological":[33],"systems.":[34,151],"Here,":[35],"we":[36],"show":[37],"that":[38],"populations":[39,136],"heteroleptic":[41],"Pd2L4-type":[42],"coordination":[43,134],"cages":[44],"can":[45,98],"be":[46,75,99],"transiently":[47],"and":[48,60,82,97,145],"repeatedly":[49],"driven":[50],"out":[51],"equilibrium":[53],"using":[54],"a":[55,71,107,125,138],"chiral":[56,108,126],"cage-based":[57],"chemical":[58],"fuel":[59],"C":[61],"60":[62],"fullerene":[63],"as":[64,93,137],"an":[65,94],"anti-fuel.":[66],"This":[67,129],"fueling":[68],"cycle":[69],"allows":[70],"temporary":[72],"formed":[76,111],"through":[77],"competition":[78],"between":[79],"ligand":[80,121],"exchange":[81],"guest":[83],"encapsulation":[84],"reactions,":[85],"at":[87],"different":[88],"timescales.":[89],"The":[90],"system":[91],"behaves":[92],"energy":[95],"ratchet":[96],"refueled.":[100],"At":[101],"center":[103],"assembly,":[106],"figure-of-eight":[109],"motif":[110],"by":[112],"red":[113],"diketopyrrolopyrrole":[114],"ligands":[115],"partially":[116],"retains":[117],"its":[118],"handedness":[119],"during":[120],"exchange,":[122],"leading":[123],"memory":[127],"effect.":[128],"work":[130],"establishes":[131],"chemically":[132],"fueled":[133],"cage":[135],"versatile":[139],"basis":[140],"for":[141],"encoding":[142],"transient":[143],"structural":[144],"stereochemical":[146],"information":[147],"within":[148],"dynamic":[150]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2026-10-01T00:00:00"}
