{"id":"https://openalex.org/W7214788242","doi":"https://doi.org/10.48550/arxiv.2609.31875","title":"Heteroatom Position Controls Ultrafast Photodynamics of Oxazole and Isoxazole","display_name":"Heteroatom Position Controls Ultrafast Photodynamics of Oxazole and Isoxazole","publication_year":2026,"publication_date":"2026-09-25","ids":{"openalex":"https://openalex.org/W7214788242","doi":"https://doi.org/10.48550/arxiv.2609.31875"},"language":"en","primary_location":{"id":"pmh:oai:arXiv.org:2609.31875","doi":null,"is_oa":true,"landing_page_url":"https://arxiv.org/abs/2609.31875","pdf_url":"https://arxiv.org/pdf/2609.31875","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["arxiv","datacite"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://arxiv.org/pdf/2609.31875","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5153410856","display_name":"Briony Downes-Ward","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Downes-Ward, Briony","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5150010512","display_name":"Paul Javed","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Javed, Paul","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5125210242","display_name":"Huynh V. S. Lam","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Lam, Huynh V. S.","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043868604","display_name":"Sajib Kumar Saha","orcid":"https://orcid.org/0000-0002-4094-2604","observed_orcids":["https://orcid.org/0000-0002-4094-2604"]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Saha, Sajib K.","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023488081","display_name":"Surjendu Bhattacharyya","orcid":"https://orcid.org/0000-0001-7107-8006","observed_orcids":["https://orcid.org/0000-0001-7107-8006"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Bhattacharyya, Surjendu","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027558195","display_name":"Martin Centurion","orcid":"https://orcid.org/0000-0002-5662-2293","observed_orcids":["https://orcid.org/0000-0002-5662-2293"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Centurion, Martin","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011127261","display_name":"Xinxin Cheng","orcid":"https://orcid.org/0000-0001-7586-8240","observed_orcids":["https://orcid.org/0000-0001-7586-8240"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Cheng, Xinxin","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033534342","display_name":"R. J. England","orcid":"https://orcid.org/0000-0003-4093-0213","observed_orcids":["https://orcid.org/0000-0003-4093-0213"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"England, R. Joel","raw_affiliation_strings":["Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5153451945","display_name":"Casey Foley","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Foley, Casey","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071675883","display_name":"Smita Ganguly","orcid":"https://orcid.org/0000-0002-4988-4658","observed_orcids":["https://orcid.org/0000-0002-4988-4658"]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ganguly, Smita","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044741351","display_name":"Patrick L. Kramer","orcid":"https://orcid.org/0000-0001-8589-1540","observed_orcids":["https://orcid.org/0000-0001-8589-1540"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kramer, Patrick L.","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021138378","display_name":"Jinxin Lang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lang, Jinxin","raw_affiliation_strings":["Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065316557","display_name":"Randy A. Lemons","orcid":"https://orcid.org/0000-0002-5608-0455","observed_orcids":["https://orcid.org/0000-0002-5608-0455"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lemons, Randy","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035903861","display_name":"Ming\u2010Fu Lin","orcid":"https://orcid.org/0000-0001-8086-2484","observed_orcids":["https://orcid.org/0000-0001-8086-2484"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lin, Ming-Fu","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100769528","display_name":"Yusong Liu","orcid":"https://orcid.org/0000-0002-5156-6720","observed_orcids":["https://orcid.org/0000-0002-5156-6720"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Liu, Yusong","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5153533315","display_name":"Tu T. Nguyen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nguyen, Tu T.","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102023249","display_name":"J. Pedro F. Nunes","orcid":"https://orcid.org/0000-0003-0670-6023","observed_orcids":["https://orcid.org/0000-0003-0670-6023"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Nunes, Joao Pedro Figueira","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5153405833","display_name":"Chatura Perera","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Perera, Chatura","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077145820","display_name":"Alexander H. Reid","orcid":"https://orcid.org/0000-0002-7587-295X","observed_orcids":["https://orcid.org/0000-0002-7587-295X"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Reid, Alexander H.","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031880771","display_name":"Ethan Ross","orcid":"https://orcid.org/0000-0003-0310-8626","observed_orcids":["https://orcid.org/0000-0003-0310-8626"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ross, Ethan","raw_affiliation_strings":["Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050533650","display_name":"Artem Rudenko","orcid":"https://orcid.org/0000-0002-9154-8463","observed_orcids":["https://orcid.org/0000-0002-9154-8463"]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Rudenko, Artem","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045334841","display_name":"Xiaozhe Shen","orcid":"https://orcid.org/0000-0002-6844-608X","observed_orcids":["https://orcid.org/0000-0002-6844-608X","https://orcid.org/0000-0001-8423-1022","https://orcid.org/0000-0002-2366-3697"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shen, Xiaozhe","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5153516830","display_name":"John Searles","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Searles, John","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009193801","display_name":"Anbu Selvam Venkatachalam","orcid":"https://orcid.org/0000-0002-5206-6955","observed_orcids":["https://orcid.org/0000-0002-5206-6955"]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Venkatachalam, Anbu Selvam","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5125101898","display_name":"Enliang Wang","orcid":"https://orcid.org/0000-0002-5703-6501","observed_orcids":["https://orcid.org/0000-0002-5703-6501"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wang, Enliang","raw_affiliation_strings":["Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005028919","display_name":"Stephen P. Weathersby","orcid":"https://orcid.org/0000-0002-0253-4781","observed_orcids":["https://orcid.org/0000-0002-0253-4781"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Weathersby, Stephen P.","raw_affiliation_strings":["\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2021Department of Chemistry , Kansas State University , Manhattan , Kansas 66506 , USA \u00b6James R. Macdonald Laboratory ,","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065285421","display_name":"Vinod Kumarappan","orcid":"https://orcid.org/0000-0002-8346-7401","observed_orcids":["https://orcid.org/0000-0002-8346-7401"]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kumarappan, Vinod","raw_affiliation_strings":["\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"\u2020Department of Chemistry , University of Missouri , Columbia , Missouri 65211 , USA","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038839224","display_name":"Arthur G. Suits","orcid":"https://orcid.org/0000-0001-5405-8361","observed_orcids":["https://orcid.org/0000-0001-5405-8361"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Suits, Arthur G.","raw_affiliation_strings":["Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032181533","display_name":"Christine M. Aikens","orcid":"https://orcid.org/0000-0002-0854-7997","observed_orcids":["https://orcid.org/0000-0002-0854-7997"]},"institutions":[{"id":"https://openalex.org/I189590672","display_name":"Kansas State University","ror":"https://ror.org/05p1j8758","country_code":"US","type":"education","lineage":["https://openalex.org/I189590672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Aikens, Christine","raw_affiliation_strings":["Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics , Kansas State University , Manhattan , Kansas 66506 , USA","institution_ids":["https://openalex.org/I189590672"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5003883207","display_name":"Daniel Rolles","orcid":"https://orcid.org/0000-0002-3965-3477","observed_orcids":["https://orcid.org/0000-0002-3965-3477"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Rolles, Daniel","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10566","display_name":"Laser-Matter Interactions and Applications","score":0.7490000128746033,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10566","display_name":"Laser-Matter Interactions and Applications","score":0.7490000128746033,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.12430000305175781,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.046799998730421066,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/oxazoles","display_name":"oxazoles","score":0.9919999837875366},{"id":"https://openalex.org/keywords/isoxazoles","display_name":"isoxazoles","score":1.0},{"id":"https://openalex.org/keywords/photoinduced-ring-opening","display_name":"photoinduced ring opening","score":0.878000020980835},{"id":"https://openalex.org/keywords/ultrafast-structural-dynamics","display_name":"ultrafast structural dynamics","score":0.6679999828338623},{"id":"https://openalex.org/keywords/photochemical-fragmentation","display_name":"photochemical fragmentation","score":0.5590000152587891},{"id":"https://openalex.org/keywords/n-o-bond-cleavage","display_name":"N-O bond cleavage","score":0.7919999957084656},{"id":"https://openalex.org/keywords/surface-hopping","display_name":"surface hopping","score":0.7940000295639038},{"id":"https://openalex.org/keywords/nonadiabatic-dynamics","display_name":"nonadiabatic dynamics","score":0.8140000104904175},{"id":"https://openalex.org/keywords/conical-intersections","display_name":"conical intersections","score":0.796999990940094},{"id":"https://openalex.org/keywords/excited-state-potential-energy-surface","display_name":"excited-state potential energy surface","score":0.8349999785423279},{"id":"https://openalex.org/keywords/structural-isomers","display_name":"structural isomers","score":0.5849999785423279},{"id":"https://openalex.org/keywords/ultrafast-electron-diffraction","display_name":"ultrafast electron diffraction","score":0.8799999952316284}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7311999797821045},{"id":"https://openalex.org/C20950531","wikidata":"https://www.wikidata.org/wiki/Q161940","display_name":"Heteroatom","level":3,"score":0.657800018787384},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5680999755859375},{"id":"https://openalex.org/C155220765","wikidata":"https://www.wikidata.org/wiki/Q16905737","display_name":"Photoexcitation","level":3,"score":0.5062000155448914},{"id":"https://openalex.org/C2778203186","wikidata":"https://www.wikidata.org/wiki/Q413437","display_name":"Oxazole","level":2,"score":0.4993000030517578},{"id":"https://openalex.org/C2780242237","wikidata":"https://www.wikidata.org/wiki/Q17155550","display_name":"Surface hopping","level":3,"score":0.40630000829696655},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.39160001277923584},{"id":"https://openalex.org/C2779240715","wikidata":"https://www.wikidata.org/wiki/Q333936","display_name":"Nitrile","level":2,"score":0.38690000772476196},{"id":"https://openalex.org/C2781269603","wikidata":"https://www.wikidata.org/wiki/Q899683","display_name":"Isoxazole","level":2,"score":0.3856000006198883},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.38350000977516174},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.3797999918460846},{"id":"https://openalex.org/C24857813","wikidata":"https://www.wikidata.org/wiki/Q3153596","display_name":"Conical intersection","level":3,"score":0.37040001153945923},{"id":"https://openalex.org/C191015642","wikidata":"https://www.wikidata.org/wiki/Q1132459","display_name":"Fragmentation (computing)","level":2,"score":0.3547999858856201},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3495999872684479},{"id":"https://openalex.org/C51141536","wikidata":"https://www.wikidata.org/wiki/Q838801","display_name":"Nanosecond","level":3,"score":0.3465000092983246},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.3375000059604645},{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.3366999924182892},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.32710000872612},{"id":"https://openalex.org/C178596936","wikidata":"https://www.wikidata.org/wiki/Q844471","display_name":"Ultrashort pulse","level":3,"score":0.32510000467300415},{"id":"https://openalex.org/C202235601","wikidata":"https://www.wikidata.org/wiki/Q7361732","display_name":"Structural isomer","level":2,"score":0.320499986410141},{"id":"https://openalex.org/C175156509","wikidata":"https://www.wikidata.org/wiki/Q1990218","display_name":"Cleavage (geology)","level":3,"score":0.30790001153945923},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.3077000081539154},{"id":"https://openalex.org/C89464430","wikidata":"https://www.wikidata.org/wiki/Q849516","display_name":"Metastability","level":2,"score":0.28850001096725464},{"id":"https://openalex.org/C70050531","wikidata":"https://www.wikidata.org/wiki/Q899089","display_name":"Delocalized electron","level":2,"score":0.26660001277923584},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.25870001316070557},{"id":"https://openalex.org/C2776234943","wikidata":"https://www.wikidata.org/wiki/Q18356231","display_name":"Ultrafast electron diffraction","level":4,"score":0.25540000200271606},{"id":"https://openalex.org/C33062035","wikidata":"https://www.wikidata.org/wiki/Q3296863","display_name":"Singlet state","level":3,"score":0.2551000118255615}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:arXiv.org:2609.31875","doi":null,"is_oa":true,"landing_page_url":"https://arxiv.org/abs/2609.31875","pdf_url":"https://arxiv.org/pdf/2609.31875","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},{"id":"doi:10.48550/arxiv.2609.31875","doi":"https://doi.org/10.48550/arxiv.2609.31875","is_oa":true,"landing_page_url":"https://doi.org/10.48550/arxiv.2609.31875","pdf_url":null,"source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Preprint"}],"best_oa_location":{"id":"pmh:oai:arXiv.org:2609.31875","doi":null,"is_oa":true,"landing_page_url":"https://arxiv.org/abs/2609.31875","pdf_url":"https://arxiv.org/pdf/2609.31875","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1229526393","display_name":null,"funder_award_id":"AC02-76SF00515","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G1286251239","display_name":null,"funder_award_id":"DE-AC02","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G1815137805","display_name":null,"funder_award_id":"DE-FG02- 86ER13491","funder_id":"https://openalex.org/F4320337744","funder_display_name":"Chemical Sciences, Geosciences, and Biosciences Division"},{"id":"https://openalex.org/G2181953994","display_name":null,"funder_award_id":"DESC0020276","funder_id":"https://openalex.org/F4320337744","funder_display_name":"Chemical Sciences, Geosciences, and Biosciences Division"},{"id":"https://openalex.org/G2371548206","display_name":null,"funder_award_id":"76SF00515","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G262532246","display_name":null,"funder_award_id":"DEAC02\u221276SF00515","funder_id":"https://openalex.org/F4320338381","funder_display_name":"SLAC National Accelerator Laboratory"},{"id":"https://openalex.org/G303061748","display_name":null,"funder_award_id":"DE\u2013AC02\u201376SF00515","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G333714909","display_name":null,"funder_award_id":"FG02-86ER13491","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G3770966485","display_name":null,"funder_award_id":"DE-FG02","funder_id":"https://openalex.org/F4320337744","funder_display_name":"Chemical Sciences, Geosciences, and Biosciences Division"},{"id":"https://openalex.org/G3826261775","display_name":null,"funder_award_id":"DEFG02-86ER13491","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G4235786860","display_name":null,"funder_award_id":"AC02\u201076SF00515","funder_id":"https://openalex.org/F4320338381","funder_display_name":"SLAC National Accelerator Laboratory"},{"id":"https://openalex.org/G4542546232","display_name":"Time-resolved XUV and X-ray Photoelectron Spectroscopy of Gas-phase Molecules","funder_award_id":"2409365","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G4654690619","display_name":null,"funder_award_id":"DE-AC02-76SF00515","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G495301720","display_name":null,"funder_award_id":"DE-AC02-76SF0051 5","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G498139845","display_name":null,"funder_award_id":"DE-AC02","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G5570207115","display_name":null,"funder_award_id":"AC02\u201076SF00515","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G5648016710","display_name":null,"funder_award_id":"DE-FG02","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G5993526748","display_name":null,"funder_award_id":"DE-SC0020276","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G6550344761","display_name":null,"funder_award_id":"76SF00515","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G669032952","display_name":"ATOMIC PHYSICS WITH HIGHLY CHARGED IONS","funder_award_id":"FG02-86ER13491","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G6990529307","display_name":"ATOMIC PHYSICS WITH HIGHLY CHARGED IONS","funder_award_id":"FG02-86ER13491","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G7283024673","display_name":null,"funder_award_id":"AC02-76SF00515","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G7331630580","display_name":null,"funder_award_id":"DE-AC02-76SF00515","funder_id":"https://openalex.org/F4320337744","funder_display_name":"Chemical Sciences, Geosciences, and Biosciences Division"},{"id":"https://openalex.org/G7596616185","display_name":null,"funder_award_id":"XDB34020000","funder_id":"https://openalex.org/F4320321133","funder_display_name":"Chinese Academy of Sciences"},{"id":"https://openalex.org/G768088173","display_name":null,"funder_award_id":"YD2030002020","funder_id":"https://openalex.org/F4320325599","funder_display_name":"University of Science and Technology of China"},{"id":"https://openalex.org/G8067403712","display_name":null,"funder_award_id":"DE-SC0020276","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G8382000481","display_name":null,"funder_award_id":"76SF00515","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G911061179","display_name":null,"funder_award_id":"DE-AC-02-76SF00515","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320321133","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35"},{"id":"https://openalex.org/F4320325599","display_name":"University of Science and Technology of China","ror":"https://ror.org/04c4dkn09"},{"id":"https://openalex.org/F4320332359","display_name":"Office of Science","ror":"https://ror.org/00mmn6b08"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"},{"id":"https://openalex.org/F4320337744","display_name":"Chemical Sciences, Geosciences, and Biosciences Division","ror":null},{"id":"https://openalex.org/F4320338381","display_name":"SLAC National Accelerator Laboratory","ror":"https://ror.org/05gzmn429"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7214788242.pdf","grobid_xml":"https://content.openalex.org/works/W7214788242.grobid-xml"},"referenced_works_count":26,"referenced_works":["https://openalex.org/W1516729178","https://openalex.org/W1987399251","https://openalex.org/W1993077801","https://openalex.org/W2012669304","https://openalex.org/W2028770952","https://openalex.org/W2052513034","https://openalex.org/W2059854481","https://openalex.org/W2068920655","https://openalex.org/W2069006374","https://openalex.org/W2092516834","https://openalex.org/W2177527467","https://openalex.org/W2321098994","https://openalex.org/W2390996797","https://openalex.org/W2472474400","https://openalex.org/W2478294658","https://openalex.org/W2802290512","https://openalex.org/W2889207959","https://openalex.org/W2972738436","https://openalex.org/W2981300362","https://openalex.org/W3014422557","https://openalex.org/W3017062992","https://openalex.org/W3026847731","https://openalex.org/W3203920290","https://openalex.org/W4385492815","https://openalex.org/W4391568136","https://openalex.org/W4403247943"],"related_works":["https://openalex.org/W3014422557","https://openalex.org/W2390996797","https://openalex.org/W3043074948","https://openalex.org/W7204791846","https://openalex.org/W2219853570","https://openalex.org/W2323931536","https://openalex.org/W2330208545","https://openalex.org/W4388308388","https://openalex.org/W2007514029","https://openalex.org/W2095555014"],"abstract_inverted_index":{"The":[0],"ultrafast":[1,47],"photochemistry":[2],"of":[3,17,31,161,205,210],"heterocyclic":[4],"compounds":[5],"is":[6],"central":[7],"to":[8],"photobiology":[9],"and":[10,35,43,98,127,156,166,197,224],"materials":[11],"chemistry,":[12],"yet":[13],"direct":[14],"experimental":[15,88,179],"observation":[16],"their":[18],"structural":[19,29,214],"dynamics":[20,55,77],"remains":[21],"rare.":[22],"Here":[23],"we":[24],"present":[25],"the":[26,39,87,104,134,178,187,207],"first":[27],"real-time":[28],"characterization":[30],"photoinduced":[32],"ring":[33,65,143],"opening":[34,66,144],"subsequent":[36],"fragmentation":[37,69,122],"in":[38,184,213],"isomeric":[40],"pair":[41],"oxazole":[42],"isoxazole":[44],"using":[45],"MeV":[46],"electron":[48],"diffraction":[49,89,170],"(UED),":[50],"complemented":[51],"by":[52,68,79,120,138,191],"non-adiabatic":[53],"molecular":[54],"simulations.":[56],"Upon":[57],"photoexcitation":[58],"at":[59],"200":[60],"nm,":[61],"both":[62,96],"isomers":[63,215],"undergo":[64,112],"followed":[67,119],"into":[70,123],"various":[71],"products,":[72],"but":[73],"with":[74,147,177,186],"strikingly":[75],"different":[76],"governed":[78],"heteroatom":[80,211],"positioning.":[81],"Trajectory":[82],"Surface":[83],"Hopping":[84],"simulations":[85],"reproduce":[86],"signatures,":[90],"which":[91],"are":[92,183],"surprisingly":[93],"similar":[94],"for":[95,103],"isomers,":[97],"reveal":[99],"distinct":[100],"mechanistic":[101],"pathways":[102],"two":[105],"isomers.":[106],"For":[107],"isoxazole,":[108],"all":[109],"trajectories":[110],"exclusively":[111],"N-O":[113],"bond":[114],"cleavage":[115,155],"within":[116],"40":[117],"fs,":[118],"sequential":[121],"HCN":[124],"+":[125,129],"ketene":[126],"HCO":[128],"vinyl":[130],"nitrene":[131],"channels":[132],"on":[133],"hundreds-of-femtoseconds":[135],"timescale.":[136],"Oxazole,":[137],"contrast,":[139],"shows":[140],"significantly":[141],"slower":[142],"(290":[145],"fs)":[146],"only":[148],"85%":[149],"efficiency,":[150],"proceeding":[151],"primarily":[152],"through":[153],"O-C":[154],"accessing":[157],"a":[158],"richer":[159],"landscape":[160],"intermediates":[162],"including":[163],"nitrile":[164],"ylide":[165],"O-pyramidalized":[167],"structures.":[168],"Simulated":[169],"patterns":[171],"derived":[172],"from":[173],"trajectory":[174,198],"ensembles,":[175],"convolved":[176],"instrument":[180],"response":[181],"function,":[182],"agreement":[185],"branching":[188],"ratios":[189],"observed":[190],"UED.":[192],"This":[193],"synergy":[194],"between":[195],"UED":[196],"surface":[199],"hopping":[200],"provides":[201],"an":[202],"atomistic":[203],"picture":[204],"how":[206],"simple":[208],"interchange":[209],"connectivity":[212],"fundamentally":[216],"reshapes":[217],"excited-state":[218],"potential":[219],"surfaces,":[220],"conical":[221],"intersection":[222],"accessibility,":[223],"photochemical":[225],"outcome.":[226]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2026-09-30T00:00:00"}