{"id":"https://openalex.org/W7213908166","doi":"https://doi.org/10.25259/ajbps_6_2026","title":"Synthesis, characterization, and antimicrobial activity of copper(II) and iron(III) complexes with sodium barbitone in selected pathogens","display_name":"Synthesis, characterization, and antimicrobial activity of copper(II) and iron(III) complexes with sodium barbitone in selected pathogens","publication_year":2026,"publication_date":"2026-09-21","ids":{"openalex":"https://openalex.org/W7213908166","doi":"https://doi.org/10.25259/ajbps_6_2026"},"language":"en","primary_location":{"id":"doi:10.25259/ajbps_6_2026","doi":"https://doi.org/10.25259/ajbps_6_2026","is_oa":true,"landing_page_url":"https://doi.org/10.25259/ajbps_6_2026","pdf_url":"https://ajbps.org/content/138/2026/6/1/pdf/AJBPS-6-13.pdf","source":{"id":"https://openalex.org/S4387278543","display_name":"American Journal of Biopharmacy and Pharmaceutical Sciences","issn_l":"2831-7599","issn":["2831-7599"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4323830092","host_organization_name":"Scientific Scholar","host_organization_lineage":["https://openalex.org/P4323830092"],"host_organization_lineage_names":["Scientific Scholar"],"type":"journal"},"license":"cc-by-nc-sa","license_id":"https://openalex.org/licenses/cc-by-nc-sa","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"American Journal of Biopharmacy and Pharmaceutical Sciences","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://ajbps.org/content/138/2026/6/1/pdf/AJBPS-6-13.pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5092641844","display_name":"Ayobami Sunday Akinnawo","orcid":"https://orcid.org/0000-0002-0120-1598","observed_orcids":["https://orcid.org/0000-0002-0120-1598"]},"institutions":[{"id":"https://openalex.org/I13144388","display_name":"Ekiti State University","ror":"https://ror.org/02c4zkr79","country_code":"NG","type":"education","lineage":["https://openalex.org/I13144388"]}],"countries":["NG"],"is_corresponding":true,"raw_author_name":"Ayobami Sunday Akinnawo","raw_affiliation_strings":["Department of Chemistry, Ekiti State University, Ado Ekiti, Nigeria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ekiti State University, Ado Ekiti, Nigeria","institution_ids":["https://openalex.org/I13144388"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090770791","display_name":"Sulaiman Adeoye Olagboye","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I13144388","display_name":"Ekiti State University","ror":"https://ror.org/02c4zkr79","country_code":"NG","type":"education","lineage":["https://openalex.org/I13144388"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Sulaiman Adeoye Olagboye","raw_affiliation_strings":["Department of Chemistry, Ekiti State University, Ado Ekiti, Nigeria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Ekiti State University, Ado Ekiti, Nigeria","institution_ids":["https://openalex.org/I13144388"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5152329781","display_name":"Temitope Peter Babayomi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I13144388","display_name":"Ekiti State University","ror":"https://ror.org/02c4zkr79","country_code":"NG","type":"education","lineage":["https://openalex.org/I13144388"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Temitope Peter Babayomi","raw_affiliation_strings":["Department of Industrial Chemistry, Ekiti State University, Ado Ekiti, Nigeria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Industrial Chemistry, Ekiti State University, Ado Ekiti, Nigeria","institution_ids":["https://openalex.org/I13144388"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5152407641","display_name":"Quadri Abiodun Lateef","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I18045400","display_name":"Federal University of Agriculture, Abeokuta","ror":"https://ror.org/050s1zm26","country_code":"NG","type":"education","lineage":["https://openalex.org/I18045400"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Quadri Abiodun Lateef","raw_affiliation_strings":["Department of Chemistry, Federal University of Agriculture, Abeokuta, Nigeria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Federal University of Agriculture, Abeokuta, Nigeria","institution_ids":["https://openalex.org/I18045400"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5152350159","display_name":"Seyi Joshua Oluwasina","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I13144388","display_name":"Ekiti State University","ror":"https://ror.org/02c4zkr79","country_code":"NG","type":"education","lineage":["https://openalex.org/I13144388"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Seyi Joshua Oluwasina","raw_affiliation_strings":["Department of Industrial Chemistry, Ekiti State University, Ado Ekiti, Nigeria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Industrial Chemistry, Ekiti State University, Ado Ekiti, Nigeria","institution_ids":["https://openalex.org/I13144388"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5152403106","display_name":"Linus Onyema Nwefuru","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I11892038","display_name":"University of Nigeria","ror":"https://ror.org/01sn1yx84","country_code":"NG","type":"education","lineage":["https://openalex.org/I11892038"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Linus Onyema Nwefuru","raw_affiliation_strings":["Department of Microbiology, University of Nigeria, Enugu, Nigeria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Microbiology, University of Nigeria, Enugu, Nigeria","institution_ids":["https://openalex.org/I11892038"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5152364299","display_name":"Blessing Olamide Ojeyinka","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181631907","display_name":"University of Ibadan","ror":"https://ror.org/03wx2rr30","country_code":"NG","type":"education","lineage":["https://openalex.org/I181631907"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Blessing Olamide Ojeyinka","raw_affiliation_strings":["Department of Pharmaceutical Chemistry, University of Ibadan, Ibadan, Nigeria,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Pharmaceutical Chemistry, University of Ibadan, Ibadan, Nigeria,","institution_ids":["https://openalex.org/I181631907"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5152405425","display_name":"Joseph Oluwafemi Adewole","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I141584323","display_name":"University of Hertfordshire","ror":"https://ror.org/0267vjk41","country_code":"GB","type":"education","lineage":["https://openalex.org/I141584323"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Joseph Oluwafemi Adewole","raw_affiliation_strings":["Department of Public Health, University of Hertfordshire, Hatfield, United Kingdom,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Public Health, University of Hertfordshire, Hatfield, United Kingdom,","institution_ids":["https://openalex.org/I141584323"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5152338656","display_name":"Ngozi Precious Okorie","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4387155461","display_name":"Alex Ekwueme Federal University, Ndufu-Alike","ror":"https://ror.org/04thacr56","country_code":"NG","type":"education","lineage":["https://openalex.org/I4387155461"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Ngozi Precious Okorie","raw_affiliation_strings":["Department of Microbiology, Alex Ekwueme Federal University Ndufu Alike Ikwo, Ebonyi, Nigeria,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Microbiology, Alex Ekwueme Federal University Ndufu Alike Ikwo, Ebonyi, Nigeria,","institution_ids":["https://openalex.org/I4387155461"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":6,"corresponding_author_ids":["https://openalex.org/A5092641844"],"corresponding_institution_ids":["https://openalex.org/I13144388"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.6658248,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"6","issue":null,"first_page":"13","last_page":"13"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9961000084877014,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9961000084877014,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.0015999999595806003,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12458","display_name":"Organometallic Compounds Synthesis and Characterization","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cu-ii-complexes","display_name":"copper(II) complexes","score":0.9330000281333923},{"id":"https://openalex.org/keywords/iron-iii-complexes","display_name":"iron(III) complexes","score":1.0},{"id":"https://openalex.org/keywords/metal-coordination","display_name":"metal coordination","score":0.6949999928474426},{"id":"https://openalex.org/keywords/antimicrobial-activity","display_name":"antimicrobial activity","score":0.8370000123977661},{"id":"https://openalex.org/keywords/antibacterial-activity","display_name":"antibacterial activity","score":0.9390000104904175},{"id":"https://openalex.org/keywords/antifungal-activity","display_name":"antifungal activity","score":1.0},{"id":"https://openalex.org/keywords/salmonella-enterica-serovar-typhi","display_name":"Salmonella typhi","score":0.9539999961853027},{"id":"https://openalex.org/keywords/ralstonia-solanacearum","display_name":"Ralstonia solanacearum","score":0.9990000128746033},{"id":"https://openalex.org/keywords/pectobacterium-carotovorum","display_name":"Erwinia carotovora","score":0.9990000128746033},{"id":"https://openalex.org/keywords/enterococcus-faecalis","display_name":"Enterococcus faecalis","score":0.9909999966621399},{"id":"https://openalex.org/keywords/serpula-lacrymans","display_name":"Serpula lacrymans","score":0.984000027179718},{"id":"https://openalex.org/keywords/trichophyton-verrucosum","display_name":"Trichophyton verrucosum","score":0.9990000128746033},{"id":"https://openalex.org/keywords/epidermophyton-floccosum","display_name":"Epidermophyton floccosum","score":0.9929999709129333},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.44200000166893005}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7594000101089478},{"id":"https://openalex.org/C4937899","wikidata":"https://www.wikidata.org/wiki/Q68541106","display_name":"Antimicrobial","level":2,"score":0.6434000134468079},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.6295999884605408},{"id":"https://openalex.org/C2780104969","wikidata":"https://www.wikidata.org/wiki/Q4774530","display_name":"Antibacterial activity","level":3,"score":0.47110000252723694},{"id":"https://openalex.org/C537181965","wikidata":"https://www.wikidata.org/wiki/Q658","display_name":"Sodium","level":2,"score":0.43160000443458557},{"id":"https://openalex.org/C523546767","wikidata":"https://www.wikidata.org/wiki/Q10876","display_name":"Bacteria","level":2,"score":0.3919999897480011},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.36320000886917114},{"id":"https://openalex.org/C118629725","wikidata":"https://www.wikidata.org/wiki/Q2686738","display_name":"Deprotonation","level":3,"score":0.3612000048160553},{"id":"https://openalex.org/C89423630","wikidata":"https://www.wikidata.org/wiki/Q7193","display_name":"Microbiology","level":1,"score":0.34130001068115234},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3093000054359436},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.2919999957084656},{"id":"https://openalex.org/C199164860","wikidata":"https://www.wikidata.org/wiki/Q6822745","display_name":"Metal ions in aqueous solution","level":3,"score":0.2912999987602234},{"id":"https://openalex.org/C2777272437","wikidata":"https://www.wikidata.org/wiki/Q131238","display_name":"Bacillus subtilis","level":3,"score":0.2863999903202057},{"id":"https://openalex.org/C2779870022","wikidata":"https://www.wikidata.org/wiki/Q190901","display_name":"Ammonium","level":2,"score":0.2847999930381775},{"id":"https://openalex.org/C2780662933","wikidata":"https://www.wikidata.org/wiki/Q2701588","display_name":"Proteus vulgaris","level":4,"score":0.2563000023365021},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.25519999861717224},{"id":"https://openalex.org/C547475151","wikidata":"https://www.wikidata.org/wiki/Q25419","display_name":"Escherichia coli","level":3,"score":0.25060001015663147}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.25259/ajbps_6_2026","doi":"https://doi.org/10.25259/ajbps_6_2026","is_oa":true,"landing_page_url":"https://doi.org/10.25259/ajbps_6_2026","pdf_url":"https://ajbps.org/content/138/2026/6/1/pdf/AJBPS-6-13.pdf","source":{"id":"https://openalex.org/S4387278543","display_name":"American Journal of Biopharmacy and Pharmaceutical Sciences","issn_l":"2831-7599","issn":["2831-7599"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4323830092","host_organization_name":"Scientific Scholar","host_organization_lineage":["https://openalex.org/P4323830092"],"host_organization_lineage_names":["Scientific Scholar"],"type":"journal"},"license":"cc-by-nc-sa","license_id":"https://openalex.org/licenses/cc-by-nc-sa","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"American Journal of Biopharmacy and Pharmaceutical Sciences","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.25259/ajbps_6_2026","doi":"https://doi.org/10.25259/ajbps_6_2026","is_oa":true,"landing_page_url":"https://doi.org/10.25259/ajbps_6_2026","pdf_url":"https://ajbps.org/content/138/2026/6/1/pdf/AJBPS-6-13.pdf","source":{"id":"https://openalex.org/S4387278543","display_name":"American Journal of Biopharmacy and Pharmaceutical Sciences","issn_l":"2831-7599","issn":["2831-7599"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4323830092","host_organization_name":"Scientific Scholar","host_organization_lineage":["https://openalex.org/P4323830092"],"host_organization_lineage_names":["Scientific Scholar"],"type":"journal"},"license":"cc-by-nc-sa","license_id":"https://openalex.org/licenses/cc-by-nc-sa","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"American Journal of Biopharmacy and Pharmaceutical Sciences","raw_type":"journal-article"},"sustainable_development_goals":[{"score":0.8048999905586243,"id":"https://metadata.un.org/sdg/3","display_name":"Good health and well-being"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7213908166.pdf","grobid_xml":"https://content.openalex.org/works/W7213908166.grobid-xml"},"referenced_works_count":25,"referenced_works":["https://openalex.org/W68034868","https://openalex.org/W1998751487","https://openalex.org/W2008770125","https://openalex.org/W2022140866","https://openalex.org/W2031641870","https://openalex.org/W2088977152","https://openalex.org/W2089012528","https://openalex.org/W2100145642","https://openalex.org/W2729329054","https://openalex.org/W2750959598","https://openalex.org/W2889197732","https://openalex.org/W3008104356","https://openalex.org/W3040629668","https://openalex.org/W3182348964","https://openalex.org/W4360614104","https://openalex.org/W4380727875","https://openalex.org/W4388521973","https://openalex.org/W4395009167","https://openalex.org/W4397015782","https://openalex.org/W4402317040","https://openalex.org/W4404548090","https://openalex.org/W4407165556","https://openalex.org/W4407561259","https://openalex.org/W4407748186","https://openalex.org/W7162989610"],"related_works":["https://openalex.org/W7160147637","https://openalex.org/W7167587132","https://openalex.org/W4388521973","https://openalex.org/W3001188360","https://openalex.org/W4385646281","https://openalex.org/W2108529211","https://openalex.org/W1484004796","https://openalex.org/W2319474861","https://openalex.org/W3040629668","https://openalex.org/W2288953121"],"abstract_inverted_index":{"Objectives:":[0],"The":[1,64,92,123,171,186,242],"rapid":[2],"emergence":[3],"of":[4,31,116,189,248],"antimicrobial":[5,227],"resistance":[6],"has":[7],"increased":[8],"the":[9,114,119,129,190,199,215,246],"search":[10],"for":[11,254],"potent":[12],"therapeutic":[13,29,266],"agents,":[14],"such":[15],"as":[16,167,175],"metal-based":[17],"transition":[18],"compounds":[19,30,125],"with":[20,34,78,232],"biological":[21],"activities.":[22],"Therefore,":[23],"this":[24],"study":[25],"aims":[26],"to":[27,112,196,204,239],"examine":[28],"barbitone":[32,80],"complexes":[33,66,93,172,192,225,234],"copper(II)":[35,71,233],"and":[36,52,62,74,86,101,106,145,149,159,163,180,198,211,262],"iron(III)":[37,75],"ions":[38],"against":[39,128,229],"Salmonella":[40],"Typhi,":[41],"Pseudomonas":[42],"glycinea,":[43,139],"Ralstonia":[44],"solanacearum,":[45,141],"Erwinia":[46],"carotovora,":[47],"Streptococcus":[48],"faecalis":[49,147],"(bacterial":[50],"pathogens)":[51],"Serpula":[53],"lacrymans,":[54,155],"Trichophyton":[55],"verrucosum,":[56],"Epidermophyton":[57],"floccosum":[58,161],"(fungal":[59],"strains).":[60],"Materials":[61],"Methods:":[63],"metal":[65,120,224],"were":[67,94,110,126,165,173],"synthesized":[68,124],"by":[69,96],"reacting":[70],"sulphate":[72],"pentahydrate":[73],"chloride":[76],"hexahydrate":[77],"sodium":[79],"using":[81],"stoichiometric":[82],"metal-ligand":[83],"ratios":[84],"(1:1":[85],"1:2)":[87],"in":[88],"a":[89,252],"water-methanol":[90],"medium.":[91],"characterized":[95],"melting":[97,187],"points,":[98],"solubility,":[99],"color,":[100],"gravimetric":[102],"analysis.":[103],"Ultraviolet-visible":[104],"(UV-Vis)":[105],"Infrared":[107],"spectroscopic":[108],"methods":[109],"used":[111],"establish":[113],"mode":[115],"coordination":[117],"at":[118],"center.":[121],"Results:":[122],"tested":[127,230],"five":[130],"bacterial":[131],"pathogens":[132],"(":[133,153],"S":[134],".":[135],"Typhi":[136],",":[137,144,158],"P.":[138],"R.":[140],"E.":[142,160],"carotovora":[143],"S.":[146,154],")":[148],"three":[150],"fungal":[151],"strains":[152],"T.":[156],"verrucosum":[157],"),":[162],"they":[164],"obtained":[166],"stable,":[168],"colored":[169],"solids.":[170],"formulated":[174],"[CuL(H2O)":[176],"SO4].4H2O,":[177],"[CuL2(H2O)SO4].4H2O,":[178],"[FeL(H2O)Cl3].5H2O,":[179],"[FeL2(H2O)Cl3].5H2O":[181],"where":[182],"L":[183],"represents":[184],"(NaC8H11N2O3).":[185],"points":[188],"formed":[191],"ranged":[193],"from":[194,202],"120\u00b0C":[195],"192\u00b0C,":[197],"percentage":[200],"yields":[201],"62%":[203],"71%.":[205],"Coordination":[206],"occurred":[207],"through":[208],"deprotonated":[209],"nitrogen":[210],"oxygen":[212],"atoms,":[213],"while":[214],"UVVis":[216],"bands":[217],"indicate":[218],"an":[219],"octahedral":[220],"geometry.":[221],"Conclusion:":[222],"All":[223],"demonstrated":[226],"activity":[228,238],"pathogens,":[231],"showing":[235],"superior":[236],"antibacterial":[237],"iron":[240],"complexes.":[241],"findings,":[243],"based":[244],"on":[245],"zone":[247],"inhibition":[249],"screening,":[250],"provide":[251],"basis":[253],"future":[255],"assessment":[256],"involving":[257],"minimum":[258],"inhibitory":[259],"concentration":[260],"determination":[261],"toxicity":[263],"investigation":[264],"before":[265],"potential":[267],"can":[268],"be":[269],"fully":[270],"evaluated.":[271]},"counts_by_year":[],"updated_date":"2026-10-27T15:51:10.671819","created_date":"2026-09-22T00:00:00"}