{"id":"https://openalex.org/W7213445554","doi":"https://doi.org/10.26434/chemrxiv.15008942/v1","title":"Information Thresholds in Adaptive Quantum Control of Nonadiabatic Molecular Dynamics:","display_name":"Information Thresholds in Adaptive Quantum Control of Nonadiabatic Molecular Dynamics:","publication_year":2026,"publication_date":"2026-09-16","ids":{"openalex":"https://openalex.org/W7213445554","doi":"https://doi.org/10.26434/chemrxiv.15008942/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15008942/v1","doi":"https://doi.org/10.26434/chemrxiv.15008942/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008942/v1","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.26434/chemrxiv.15008942/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5151970074","display_name":"Oluwatoni Sobande","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I126541806","display_name":"Lagos State University","ror":"https://ror.org/01za8fg18","country_code":"NG","type":"education","lineage":["https://openalex.org/I126541806"]}],"countries":["NG"],"is_corresponding":false,"raw_author_name":"Oluwatoni Sobande","raw_affiliation_strings":["Department of Chemistry","Lagos State University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Lagos State University","institution_ids":["https://openalex.org/I126541806"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5151978624","display_name":"Oluwatoni. E Sobande","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Oluwatoni. E Sobande","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10566","display_name":"Laser-Matter Interactions and Applications","score":0.8647000193595886,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10566","display_name":"Laser-Matter Interactions and Applications","score":0.8647000193595886,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.06120000034570694,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.03689999878406525,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nonadiabatic-dynamics","display_name":"nonadiabatic dynamics","score":0.9110000133514404},{"id":"https://openalex.org/keywords/conical-intersections","display_name":"conical intersections","score":0.984000027179718},{"id":"https://openalex.org/keywords/information-threshold","display_name":"information threshold","score":0.6869999766349792},{"id":"https://openalex.org/keywords/control-fidelity","display_name":"control fidelity","score":0.8849999904632568},{"id":"https://openalex.org/keywords/vibronic-coupling","display_name":"vibronic coupling","score":0.6980000138282776},{"id":"https://openalex.org/keywords/pyrazine","display_name":"pyrazine","score":0.9639999866485596},{"id":"https://openalex.org/keywords/electronic-coherence","display_name":"electronic coherence","score":0.8320000171661377},{"id":"https://openalex.org/keywords/nuclear-observables","display_name":"nuclear observables","score":0.8240000009536743},{"id":"https://openalex.org/keywords/pulse-optimization","display_name":"pulse optimization","score":0.5479999780654907},{"id":"https://openalex.org/keywords/photochemical-reactions","display_name":"photochemical reactions","score":0.6600000262260437}],"concepts":[{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.5496000051498413},{"id":"https://openalex.org/C2781181686","wikidata":"https://www.wikidata.org/wiki/Q4226068","display_name":"Coherence (philosophical gambling strategy)","level":2,"score":0.5406000018119812},{"id":"https://openalex.org/C113364801","wikidata":"https://www.wikidata.org/wiki/Q26674","display_name":"High fidelity","level":2,"score":0.5271000266075134},{"id":"https://openalex.org/C31170391","wikidata":"https://www.wikidata.org/wiki/Q188619","display_name":"Hierarchy","level":2,"score":0.5184999704360962},{"id":"https://openalex.org/C208081375","wikidata":"https://www.wikidata.org/wiki/Q274502","display_name":"Degrees of freedom (physics and chemistry)","level":2,"score":0.4839000105857849},{"id":"https://openalex.org/C121864883","wikidata":"https://www.wikidata.org/wiki/Q677916","display_name":"Statistical physics","level":1,"score":0.47609999775886536},{"id":"https://openalex.org/C84114770","wikidata":"https://www.wikidata.org/wiki/Q46344","display_name":"Quantum","level":2,"score":0.44530001282691956},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.44020000100135803},{"id":"https://openalex.org/C2776459999","wikidata":"https://www.wikidata.org/wiki/Q2119376","display_name":"Fidelity","level":2,"score":0.4375999867916107},{"id":"https://openalex.org/C185798385","wikidata":"https://www.wikidata.org/wiki/Q1161707","display_name":"Benchmark (surveying)","level":2,"score":0.38670000433921814},{"id":"https://openalex.org/C2984281365","wikidata":"https://www.wikidata.org/wiki/Q906781","display_name":"Quantum control","level":3,"score":0.364300012588501},{"id":"https://openalex.org/C66024118","wikidata":"https://www.wikidata.org/wiki/Q1122506","display_name":"Computational model","level":2,"score":0.35589998960494995},{"id":"https://openalex.org/C159317903","wikidata":"https://www.wikidata.org/wiki/Q3198","display_name":"Photon","level":2,"score":0.35589998960494995},{"id":"https://openalex.org/C14036430","wikidata":"https://www.wikidata.org/wiki/Q3736076","display_name":"Function (biology)","level":2,"score":0.3319999873638153},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.32829999923706055},{"id":"https://openalex.org/C91575142","wikidata":"https://www.wikidata.org/wiki/Q1971426","display_name":"Optimal control","level":2,"score":0.3253999948501587},{"id":"https://openalex.org/C169699857","wikidata":"https://www.wikidata.org/wiki/Q2122243","display_name":"Quantum information","level":3,"score":0.30469998717308044},{"id":"https://openalex.org/C2775924081","wikidata":"https://www.wikidata.org/wiki/Q55608371","display_name":"Control (management)","level":2,"score":0.30250000953674316},{"id":"https://openalex.org/C203479927","wikidata":"https://www.wikidata.org/wiki/Q5165939","display_name":"Controller (irrigation)","level":2,"score":0.29679998755455017},{"id":"https://openalex.org/C179799912","wikidata":"https://www.wikidata.org/wiki/Q205084","display_name":"Computational complexity theory","level":2,"score":0.2906999886035919},{"id":"https://openalex.org/C15184713","wikidata":"https://www.wikidata.org/wiki/Q7269042","display_name":"Quantum dynamics","level":3,"score":0.28540000319480896},{"id":"https://openalex.org/C86025842","wikidata":"https://www.wikidata.org/wiki/Q5358432","display_name":"Electronic structure","level":2,"score":0.28369998931884766},{"id":"https://openalex.org/C37798101","wikidata":"https://www.wikidata.org/wiki/Q7300259","display_name":"Reaction dynamics","level":3,"score":0.2806999981403351},{"id":"https://openalex.org/C113603373","wikidata":"https://www.wikidata.org/wiki/Q2362761","display_name":"Wave function","level":2,"score":0.2743000090122223},{"id":"https://openalex.org/C178596936","wikidata":"https://www.wikidata.org/wiki/Q844471","display_name":"Ultrashort pulse","level":3,"score":0.2711000144481659},{"id":"https://openalex.org/C11413529","wikidata":"https://www.wikidata.org/wiki/Q8366","display_name":"Algorithm","level":1,"score":0.2680000066757202},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.26420000195503235},{"id":"https://openalex.org/C33332235","wikidata":"https://www.wikidata.org/wiki/Q18362","display_name":"Theoretical physics","level":1,"score":0.2619999945163727},{"id":"https://openalex.org/C15706264","wikidata":"https://www.wikidata.org/wiki/Q230883","display_name":"Quantum state","level":3,"score":0.25519999861717224},{"id":"https://openalex.org/C58053490","wikidata":"https://www.wikidata.org/wiki/Q176555","display_name":"Quantum computer","level":3,"score":0.25189998745918274}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15008942/v1","doi":"https://doi.org/10.26434/chemrxiv.15008942/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008942/v1","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15008942/v1","doi":"https://doi.org/10.26434/chemrxiv.15008942/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008942/v1","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W7213446357","https://openalex.org/W7117646660","https://openalex.org/W3009101807","https://openalex.org/W2890714007","https://openalex.org/W2934774694","https://openalex.org/W4296694002","https://openalex.org/W1567362555","https://openalex.org/W69352865","https://openalex.org/W2793686761","https://openalex.org/W2013931754"],"abstract_inverted_index":{"Ultrafast":[0],"photochemical":[1],"reactions":[2],"can":[3],"undergo":[4],"strongly":[5],"nonadiabatic":[6,116],"dynamics":[7],"near":[8],"conical":[9],"intersections,":[10],"where":[11],"electronic":[12,25,85,90],"and":[13,20,84,92,141,161],"nuclear":[14,88,142],"degrees":[15],"of":[16,65,77,139],"freedom":[17],"become":[18,29],"coupled":[19],"conventional":[21],"descriptions":[22],"based":[23],"on":[24,112,135],"populations":[26,86],"alone":[27],"may":[28],"insufficient":[30],"for":[31,39],"control.":[32],"This":[33,119],"paper":[34],"proposes":[35],"an":[36,54,123],"information-aware":[37],"framework":[38],"adaptive":[40],"quantum":[41],"control":[42,72,109,127,157],"in":[43],"which":[44],"the":[45,67,101,115,136,172],"information":[46,78,103,155],"supplied":[47],"to":[48,87,105,114,129],"a":[49,59,75,107,147],"controller":[50],"is":[51,99,120],"treated":[52],"as":[53,178],"explicit":[55],"experimental":[56],"variable.":[57],"Using":[58],"benchmark":[60],"four-mode":[61],"linear":[62],"vibronic-coupling":[63],"model":[64],"pyrazine,":[66],"proposed":[68],"computational":[69,149,182],"study":[70],"compares":[71],"performance":[73],"across":[74],"hierarchy":[76],"levels,":[79],"from":[80],"final":[81],"reaction":[82],"outcomes":[83],"observables,":[89],"coherences,":[91],"complete":[93],"quantum-state":[94],"information.":[95,143],"The":[96,144],"central":[97],"hypothesis":[98],"that":[100],"minimum":[102],"required":[104],"achieve":[106],"specified":[108],"fidelity":[110,128],"depends":[111],"proximity":[113],"branching":[117],"region.":[118],"formalized":[121],"through":[122],"information-threshold":[124],"function":[125],"relating":[126],"conical-intersection":[130],"proximity,":[131],"with":[132],"particular":[133],"emphasis":[134],"marginal":[137],"benefit":[138],"coherence":[140],"manuscript":[145],"provides":[146],"reproducible":[148],"protocol,":[150],"including":[151],"pulse":[152],"parameterization,":[153],"optimization,":[154],"ablation,":[156],"objectives,":[158],"validation":[159],"criteria,":[160],"falsification":[162],"tests.":[163],"No":[164],"simulations":[165],"or":[166],"new":[167],"numerical":[168,173],"calculations":[169],"are":[170,175],"reported;":[171],"predictions":[174],"explicitly":[176],"identified":[177],"hypotheses":[179],"requiring":[180],"future":[181],"testing.":[183]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-09-17T00:00:00"}