{"id":"https://openalex.org/W7213246396","doi":"https://doi.org/10.26434/chemrxiv.15008840/v1","title":"Nitroarylphosphines: An Overlooked Family of Ligands","display_name":"Nitroarylphosphines: An Overlooked Family of Ligands","publication_year":2026,"publication_date":"2026-09-15","ids":{"openalex":"https://openalex.org/W7213246396","doi":"https://doi.org/10.26434/chemrxiv.15008840/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15008840/v1","doi":"https://doi.org/10.26434/chemrxiv.15008840/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008840/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008840/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008840/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5151115305","display_name":"Rafael P\u00e9rez","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I43406934","display_name":"Universit\u00e9 Laval","ror":"https://ror.org/04sjchr03","country_code":"CA","type":"education","lineage":["https://openalex.org/I43406934"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Rafael P\u00e9rez","raw_affiliation_strings":["Chemistry, Universit\u00e9 Laval, 1045, avenue de la M\u00e9decine, Qu\u00e9bec, Quebec, Canada, G1V0A6"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry, Universit\u00e9 Laval, 1045, avenue de la M\u00e9decine, Qu\u00e9bec, Quebec, Canada, G1V0A6","institution_ids":["https://openalex.org/I43406934"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5151251342","display_name":"Jean-Wilfrid Hayes Perreault","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I43406934","display_name":"Universit\u00e9 Laval","ror":"https://ror.org/04sjchr03","country_code":"CA","type":"education","lineage":["https://openalex.org/I43406934"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Jean-Wilfrid Hayes Perreault","raw_affiliation_strings":["Chemistry, Universit\u00e9 Laval, 1045, avenue de la M\u00e9decine, Qu\u00e9bec, Quebec, Canada, G1V0A6"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry, Universit\u00e9 Laval, 1045, avenue de la M\u00e9decine, Qu\u00e9bec, Quebec, Canada, G1V0A6","institution_ids":["https://openalex.org/I43406934"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5015895214","display_name":"Guillaume B\u00e9langer\u2010Chabot","orcid":"https://orcid.org/0000-0001-5722-2657","observed_orcids":["https://orcid.org/0000-0001-5722-2657"]},"institutions":[{"id":"https://openalex.org/I43406934","display_name":"Universit\u00e9 Laval","ror":"https://ror.org/04sjchr03","country_code":"CA","type":"education","lineage":["https://openalex.org/I43406934"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Guillaume B\u00e9langer-Chabot","raw_affiliation_strings":["Chemistry, Universit\u00e9 Laval, 1045, avenue de la M\u00e9decine, Qu\u00e9bec, Quebec, Canada, G1V0A6"],"raw_orcid":"https://orcid.org/0000-0001-5722-2657","affiliations":[{"raw_affiliation_string":"Chemistry, Universit\u00e9 Laval, 1045, avenue de la M\u00e9decine, Qu\u00e9bec, Quebec, Canada, G1V0A6","institution_ids":["https://openalex.org/I43406934"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I43406934"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.5220000147819519,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.5220000147819519,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.3052000105381012,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.09830000251531601,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phosphine-ligands","display_name":"phosphine ligands","score":0.8029999732971191},{"id":"https://openalex.org/keywords/thermal-stability","display_name":"thermal stability","score":0.6710000038146973},{"id":"https://openalex.org/keywords/electronic-properties","display_name":"electronic properties","score":0.7459999918937683},{"id":"https://openalex.org/keywords/coordination-compounds","display_name":"metal complexes","score":0.8399999737739563},{"id":"https://openalex.org/keywords/nitro-group-effects","display_name":"nitro group effects","score":0.8009999990463257}],"concepts":[{"id":"https://openalex.org/C2781083472","wikidata":"https://www.wikidata.org/wiki/Q5891406","display_name":"Homoleptic","level":3,"score":0.8884000182151794},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5478000044822693},{"id":"https://openalex.org/C2777716191","wikidata":"https://www.wikidata.org/wiki/Q207877","display_name":"Phosphine","level":3,"score":0.4560000002384186},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.4138000011444092},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.3993000090122223},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.3928999900817871},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.3822999894618988},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.36149999499320984},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.34290000796318054},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.29750001430511475},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.29350000619888306},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.2849000096321106},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2702000141143799},{"id":"https://openalex.org/C2780639532","wikidata":"https://www.wikidata.org/wiki/Q7041427","display_name":"Nitro","level":3,"score":0.25220000743865967}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15008840/v1","doi":"https://doi.org/10.26434/chemrxiv.15008840/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008840/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008840/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15008840/v1","doi":"https://doi.org/10.26434/chemrxiv.15008840/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008840/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008840/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320334593","display_name":"Natural Sciences and Engineering Research Council of Canada","ror":"https://ror.org/01h531d29"},{"id":"https://openalex.org/F4320334841","display_name":"Fonds de recherche du Qu\u00e9bec \u2013 Nature et technologies","ror":"https://ror.org/00b9f9778"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7213246396.pdf","grobid_xml":"https://content.openalex.org/works/W7213246396.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W4411994493","https://openalex.org/W2749253773","https://openalex.org/W2950119428","https://openalex.org/W2065417280","https://openalex.org/W2009305636","https://openalex.org/W2078339266","https://openalex.org/W4405031981","https://openalex.org/W2789722664","https://openalex.org/W7149019356","https://openalex.org/W2829114875"],"abstract_inverted_index":{"Homoleptic":[0],"tris(nitroaryl)phoshines":[1],"are":[2,19],"very":[3],"rare,":[4],"\u201cexplosive-looking\u201d":[5],"molecules":[6],"that":[7,17,46],"have":[8],"until":[9],"now":[10],"never":[11],"been":[12],"fully":[13],"characterized.":[14],"We":[15,41],"show":[16,42],"they":[18,47],"accessible":[20],"from":[21],"nitroarylphosphine":[22],"oxides":[23],"and":[24,37,44,53],"are,":[25],"perhaps":[26],"surprisingly,":[27],"sufficiently":[28],"thermally":[29],"stable":[30],"to":[31],"be":[32],"handled":[33],"at":[34],"ambient":[35],"temperature":[36],"used":[38],"as":[39],"ligands.":[40],"experimentally":[43],"computationally":[45],"display":[48],"significantly":[49],"modulated":[50],"electronic":[51],"properties":[52],"we":[54],"demonstrate":[55],"several":[56],"examples":[57],"of":[58],"their":[59],"coordination":[60,74],"complexes,":[61],"thus":[62],"showing":[63],"the":[64],"nitro":[65],"group":[66],"is":[67],"an":[68],"overlooked":[69],"tuning":[70],"tool":[71],"in":[72],"phosphine":[73],"chemistry.":[75]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-09-16T00:00:00"}