{"id":"https://openalex.org/W7212119070","doi":"https://doi.org/10.26434/chemrxiv.15008613/v1","title":"Broadband Visible Emission from a Rigid Ground State in an Ionic Zn-MOF Single Crystal","display_name":"Broadband Visible Emission from a Rigid Ground State in an Ionic Zn-MOF Single Crystal","publication_year":2026,"publication_date":"2026-09-10","ids":{"openalex":"https://openalex.org/W7212119070","doi":"https://doi.org/10.26434/chemrxiv.15008613/v1"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv.15008613/v1","doi":"https://doi.org/10.26434/chemrxiv.15008613/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008613/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008613/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008613/v1","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5151153727","display_name":"Laura Nathalia Diaz-Rozo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I129774422","display_name":"University of Vienna","ror":"https://ror.org/03prydq77","country_code":"AT","type":"education","lineage":["https://openalex.org/I129774422"]}],"countries":["AT"],"is_corresponding":false,"raw_author_name":"Laura Nathalia Diaz-Rozo","raw_affiliation_strings":["Faculty of Physics, University of Vienna, Boltzmanngasse 5, Vienna, Vienna, Austria, 1090"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Physics, University of Vienna, Boltzmanngasse 5, Vienna, Vienna, Austria, 1090","institution_ids":["https://openalex.org/I129774422"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029232534","display_name":"Arthur Mantel","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210127897","display_name":"Czech Academy of Sciences, Heyrovsky Institute","ror":"https://ror.org/02sat5y74","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210127897"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Arthur Mantel","raw_affiliation_strings":["Heyrovsky Institute of the CAS, Dolejskova 2155/3, Prague, Prague, Czechia, 182 00"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Heyrovsky Institute of the CAS, Dolejskova 2155/3, Prague, Prague, Czechia, 182 00","institution_ids":["https://openalex.org/I4210127897"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5009624172","display_name":"Hidetsugu Shiozawa","orcid":"https://orcid.org/0000-0003-0603-2508","observed_orcids":["https://orcid.org/0000-0003-0603-2508"]},"institutions":[{"id":"https://openalex.org/I129774422","display_name":"University of Vienna","ror":"https://ror.org/03prydq77","country_code":"AT","type":"education","lineage":["https://openalex.org/I129774422"]},{"id":"https://openalex.org/I4210127897","display_name":"Czech Academy of Sciences, Heyrovsky Institute","ror":"https://ror.org/02sat5y74","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210127897"]}],"countries":["AT","CZ"],"is_corresponding":false,"raw_author_name":"Hidetsugu Shiozawa","raw_affiliation_strings":["Faculty of Physics, University of Vienna, Boltzmanngasse 5, Vienna, Vienna, Austria, 1090","Heyrovsky Institute of the CAS, Dolejskova 2155/3, Prague, Prague, Czechia, 182 00"],"raw_orcid":"https://orcid.org/0000-0003-0603-2508","affiliations":[{"raw_affiliation_string":"Faculty of Physics, University of Vienna, Boltzmanngasse 5, Vienna, Vienna, Austria, 1090","institution_ids":["https://openalex.org/I129774422"]},{"raw_affiliation_string":"Heyrovsky Institute of the CAS, Dolejskova 2155/3, Prague, Prague, Czechia, 182 00","institution_ids":["https://openalex.org/I4210127897"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9976000189781189,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9976000189781189,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.0015999999595806003,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zinc-based-mof","display_name":"zinc-based MOF","score":0.6579999923706055},{"id":"https://openalex.org/keywords/photoluminescence","display_name":"photoluminescence","score":0.875},{"id":"https://openalex.org/keywords/structural-relaxation","display_name":"structural relaxation","score":0.4950000047683716},{"id":"https://openalex.org/keywords/excited-state-potential-energy-surface","display_name":"excited-state potential energy surface","score":0.8709999918937683},{"id":"https://openalex.org/keywords/dimethyl-sulfoxide","display_name":"dimethyl sulfoxide","score":0.7889999747276306},{"id":"https://openalex.org/keywords/1-2-dichloroethane","display_name":"1,2-dichloroethane","score":0.968999981880188},{"id":"https://openalex.org/keywords/single-crystal-growth","display_name":"single crystal growth","score":0.47699999809265137}],"concepts":[{"id":"https://openalex.org/C509933004","wikidata":"https://www.wikidata.org/wiki/Q194163","display_name":"Broadband","level":2,"score":0.6133999824523926},{"id":"https://openalex.org/C73922627","wikidata":"https://www.wikidata.org/wiki/Q754943","display_name":"Single crystal","level":2,"score":0.6036999821662903},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5828999876976013},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5494999885559082},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.5034999847412109},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.38909998536109924},{"id":"https://openalex.org/C48103436","wikidata":"https://www.wikidata.org/wiki/Q599031","display_name":"State (computer science)","level":2,"score":0.3488999903202057},{"id":"https://openalex.org/C107814960","wikidata":"https://www.wikidata.org/wiki/Q611957","display_name":"Solid-state","level":2,"score":0.32120001316070557},{"id":"https://openalex.org/C2993376436","wikidata":"https://www.wikidata.org/wiki/Q899869","display_name":"Ionic crystal","level":3,"score":0.31119999289512634},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.30889999866485596},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.30889999866485596},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.2989000082015991},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.29440000653266907},{"id":"https://openalex.org/C104663316","wikidata":"https://www.wikidata.org/wiki/Q76299","display_name":"Visible spectrum","level":2,"score":0.2824999988079071},{"id":"https://openalex.org/C96141758","wikidata":"https://www.wikidata.org/wiki/Q216817","display_name":"Emission spectrum","level":3,"score":0.27320000529289246},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.26100000739097595}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv.15008613/v1","doi":"https://doi.org/10.26434/chemrxiv.15008613/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008613/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008613/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.15008613/v1","doi":"https://doi.org/10.26434/chemrxiv.15008613/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15008613/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008613/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6022392870","display_name":"Optical band-gap engineering of metal-organic crystals","funder_award_id":"GA22-23407S","funder_id":"https://openalex.org/F4320321006","funder_display_name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky"},{"id":"https://openalex.org/G8465498904","display_name":"Addressing single-molecule magnets via 1D nanoframeworks","funder_award_id":"PIN9127924","funder_id":"https://openalex.org/F4320321181","funder_display_name":"Austrian Science Fund"},{"id":"https://openalex.org/G8590477180","display_name":null,"funder_award_id":"10.55776","funder_id":"https://openalex.org/F4320321181","funder_display_name":"Austrian Science Fund"}],"funders":[{"id":"https://openalex.org/F4320321006","display_name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky","ror":"https://ror.org/01pv73b02"},{"id":"https://openalex.org/F4320321181","display_name":"Austrian Science Fund","ror":"https://ror.org/013tf3c58"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7212119070.pdf","grobid_xml":"https://content.openalex.org/works/W7212119070.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2971373133","https://openalex.org/W2914210239","https://openalex.org/W2807609887","https://openalex.org/W3114927938","https://openalex.org/W2047242736","https://openalex.org/W3152096110","https://openalex.org/W6977374176","https://openalex.org/W3173804809","https://openalex.org/W4293161885","https://openalex.org/W4411230250"],"abstract_inverted_index":{"Single":[0],"crystals":[1,27],"of":[2,57,67,99],"the":[3,29,58,82,97,100,105],"ionic":[4],"MOF":[5],"{[Zn":[6],"2":[7,9,12],"(BDC)":[8],"(OAc)]":[10],"-}":[11],"[Zn(DMSO)":[13],"6":[14],"]":[15],"2+":[16],"have":[17],"been":[18],"grown":[19],"and":[20,34,93],"their":[21],"photoluminescence":[22],"recorded":[23],"as":[24,102],"excitation-emission":[25],"maps.Solvated":[26],"in":[28,60],"mother":[30],"liquor,":[31],"dimethyl":[32],"sulfoxide,":[33],"1,2-dichloroethane":[35],"exhibit":[36],"broadband":[37],"visible":[38,73],"emission":[39,101],"centred":[40],"at":[41],"approximately":[42],"440":[43],"nm":[44],"under":[45],"a":[46,61,68],"narrow":[47],"excitation":[48,54,56],"band":[49],"near":[50],"300":[51],"nm.The":[52],"sharp":[53],"indicates":[55],"linker":[59],"well-defined":[62],"ground-state":[63],"geometry":[64],"rather":[65,107],"than":[66,108],"heterogeneous":[69],"defect":[70],"ensemble.The":[71],"featureless":[72],"envelope":[74],"is":[75,88],"attributed":[76],"to":[77,104],"subsequent":[78],"structural":[79],"relaxations":[80],"on":[81],"excited-state":[83],"potential-energy":[84],"surface.The":[85],"same":[86],"motif":[87],"observed":[89],"for":[90],"optically":[91],"clear":[92],"cloudy":[94],"crystals,":[95],"supporting":[96],"assignment":[98],"intrinsic":[103],"framework":[106],"defect-centred.":[109]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-09-11T00:00:00"}