{"id":"https://openalex.org/W7204921855","doi":"https://doi.org/10.48550/arxiv.2608.30464","title":"Viscoelastic interfacial structures in undersaturated calcium solutions under nanoconfinement","display_name":"Viscoelastic interfacial structures in undersaturated calcium solutions under nanoconfinement","publication_year":2026,"publication_date":"2026-08-31","ids":{"openalex":"https://openalex.org/W7204921855","doi":"https://doi.org/10.48550/arxiv.2608.30464"},"language":"en","primary_location":{"id":"pmh:oai:arXiv.org:2608.30464","doi":null,"is_oa":true,"landing_page_url":"https://arxiv.org/abs/2608.30464","pdf_url":"https://arxiv.org/pdf/2608.30464","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},"volume":null,"type":"preprint","indexed_in":["arxiv","datacite"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://arxiv.org/pdf/2608.30464","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5084933799","display_name":"Shurui Miao","orcid":"https://orcid.org/0000-0002-1840-3866","observed_orcids":["https://orcid.org/0000-0002-1840-3866"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Miao, Shurui","raw_affiliation_strings":["Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom","institution_ids":["https://openalex.org/I40120149"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102722153","display_name":"T. Groves","orcid":"https://orcid.org/0000-0003-2168-2437","observed_orcids":["https://orcid.org/0000-0003-2168-2437"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Groves, Timothy S.","raw_affiliation_strings":["Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom","institution_ids":["https://openalex.org/I40120149"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005824436","display_name":"Kieran J. Agg","orcid":"https://orcid.org/0000-0001-5096-0083","observed_orcids":["https://orcid.org/0000-0001-5096-0083"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Agg, Kieran J.","raw_affiliation_strings":["Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom","institution_ids":["https://openalex.org/I40120149"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5015798358","display_name":"Susan Perkin","orcid":"https://orcid.org/0000-0002-5875-5217","observed_orcids":["https://orcid.org/0000-0002-5875-5217"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Perkin, Susan","raw_affiliation_strings":["Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry , Physical & Theoretical Chemistry Laboratory , University of Oxford , United Kingdom","institution_ids":["https://openalex.org/I40120149"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I40120149"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11278","display_name":"Calcium Carbonate Crystallization and Inhibition","score":0.9829000234603882,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11278","display_name":"Calcium Carbonate Crystallization and Inhibition","score":0.9829000234603882,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.0044999998062849045,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11881","display_name":"Crystallization and Solubility Studies","score":0.00430000014603138,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/calcium-carbonate-nucleation","display_name":"calcium carbonate nucleation","score":0.8050000071525574},{"id":"https://openalex.org/keywords/nanoconfinement","display_name":"nanoconfinement","score":0.9490000009536743},{"id":"https://openalex.org/keywords/mineral-interfaces","display_name":"mineral interfaces","score":0.7900000214576721},{"id":"https://openalex.org/keywords/surface-force-measurement","display_name":"surface force measurement","score":0.699999988079071},{"id":"https://openalex.org/keywords/biomineralization","display_name":"biomineralization","score":0.6840000152587891},{"id":"https://openalex.org/keywords/carbon-storage","display_name":"carbon storage","score":0.8130000233650208}],"concepts":[{"id":"https://openalex.org/C61048295","wikidata":"https://www.wikidata.org/wiki/Q909022","display_name":"Nucleation","level":2,"score":0.7928000092506409},{"id":"https://openalex.org/C2778039128","wikidata":"https://www.wikidata.org/wiki/Q23767","display_name":"Calcium carbonate","level":2,"score":0.6772000193595886},{"id":"https://openalex.org/C2776432453","wikidata":"https://www.wikidata.org/wiki/Q7946","display_name":"Mineral","level":2,"score":0.5741000175476074},{"id":"https://openalex.org/C519063684","wikidata":"https://www.wikidata.org/wiki/Q706","display_name":"Calcium","level":2,"score":0.5663999915122986},{"id":"https://openalex.org/C45206210","wikidata":"https://www.wikidata.org/wiki/Q2415817","display_name":"Nanoscopic scale","level":2,"score":0.5371000170707703},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5350000262260437},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5307999849319458},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.5184999704360962},{"id":"https://openalex.org/C186541917","wikidata":"https://www.wikidata.org/wiki/Q910483","display_name":"Viscoelasticity","level":2,"score":0.5041000247001648},{"id":"https://openalex.org/C203036418","wikidata":"https://www.wikidata.org/wiki/Q284256","display_name":"Crystallization","level":2,"score":0.4821000099182129},{"id":"https://openalex.org/C199289684","wikidata":"https://www.wikidata.org/wiki/Q83353","display_name":"Mineralogy","level":1,"score":0.4000999927520752},{"id":"https://openalex.org/C183586093","wikidata":"https://www.wikidata.org/wiki/Q610457","display_name":"Biomineralization","level":2,"score":0.38850000500679016},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3305000066757202},{"id":"https://openalex.org/C2780393986","wikidata":"https://www.wikidata.org/wiki/Q19892223","display_name":"Classical nucleation theory","level":3,"score":0.3208000063896179},{"id":"https://openalex.org/C2776799497","wikidata":"https://www.wikidata.org/wiki/Q484298","display_name":"Surface (topology)","level":2,"score":0.3165999948978424},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3109000027179718},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.26989999413490295},{"id":"https://openalex.org/C2780659211","wikidata":"https://www.wikidata.org/wiki/Q181699","display_name":"Carbonate","level":2,"score":0.2639000117778778}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:arXiv.org:2608.30464","doi":null,"is_oa":true,"landing_page_url":"https://arxiv.org/abs/2608.30464","pdf_url":"https://arxiv.org/pdf/2608.30464","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},{"id":"doi:10.48550/arxiv.2608.30464","doi":"https://doi.org/10.48550/arxiv.2608.30464","is_oa":true,"landing_page_url":"https://doi.org/10.48550/arxiv.2608.30464","pdf_url":null,"source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Preprint"}],"best_oa_location":{"id":"pmh:oai:arXiv.org:2608.30464","doi":null,"is_oa":true,"landing_page_url":"https://arxiv.org/abs/2608.30464","pdf_url":"https://arxiv.org/pdf/2608.30464","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7204921855.pdf","grobid_xml":"https://content.openalex.org/works/W7204921855.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2531261395","https://openalex.org/W2952378799","https://openalex.org/W4232506779","https://openalex.org/W4402581128","https://openalex.org/W2321225884","https://openalex.org/W3094367808","https://openalex.org/W4406405172","https://openalex.org/W3001666125","https://openalex.org/W2792413265","https://openalex.org/W4396720605"],"abstract_inverted_index":{"Calcium":[0],"mineralisation":[1],"underpins":[2],"processes":[3],"ranging":[4],"from":[5,70],"biomineralisation":[6],"to":[7,32,50,56,121],"scalable":[8],"carbon":[9],"storage,":[10],"yet":[11],"the":[12,71,110,135],"earliest":[13],"stages":[14],"of":[15,130,138],"nucleation":[16,132],"remain":[17],"unresolved.":[18],"Here":[19],"we":[20,42,54],"investigate":[21],"calcium-containing":[22],"solutions":[23],"under":[24,106],"nanoscopic":[25],"confinement":[26,115,141],"while":[27],"remaining":[28],"undersaturated":[29,107],"with":[30,87],"respect":[31],"bulk":[33,72],"calcium":[34,51],"carbonate":[35],"precipitation.":[36],"Using":[37],"sensitive":[38],"surface":[39,89],"force":[40],"measurements,":[41],"identify":[43],"a":[44,76],"long-range":[45],"non-DLVO":[46],"repulsive":[47],"interaction":[48],"specific":[49],"solutions,":[52],"which":[53],"attribute":[55],"hydrated":[57,98],"ion":[58,99,118],"networks":[59,65,100],"at":[60,103],"mineral":[61,104,131],"interfaces.":[62],"These":[63,123],"interfacial":[64],"exhibit":[66],"viscoelastic":[67],"behaviour":[68],"distinct":[69],"solution,":[73],"persist":[74],"across":[75],"broad":[77],"pH":[78],"range,":[79],"and":[80,114,127,133,140],"can":[81,101],"be":[82],"disrupted":[83],"by":[84],"competing":[85],"ions":[86],"strong":[88],"affinity.":[90],"Our":[91],"findings":[92],"provide":[93],"experimental":[94],"evidence":[95],"that":[96,112],"stable":[97],"emerge":[102],"interfaces":[105,113,139],"conditions,":[108],"supporting":[109],"possibility":[111],"stabilise":[116],"intermediate":[117],"assemblies":[119],"prior":[120],"nucleation.":[122],"results":[124],"bridge":[125],"classical":[126],"nonclassical":[128],"descriptions":[129],"highlight":[134],"central":[136],"role":[137],"in":[142],"directing":[143],"crystallisation":[144],"pathways.":[145]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2026-09-02T00:00:00"}