{"id":"https://openalex.org/W7204855587","doi":"https://doi.org/10.1016/j.nxmate.2026.103327","title":"Ni-Bi-Mo/Al2O3 metal-oxide catalysts for CO2-mediated oxidative dehydrogenation of n-butane into buta-1,3-diene: Bismuth molybdate effect and mechanistic insights","display_name":"Ni-Bi-Mo/Al2O3 metal-oxide catalysts for CO2-mediated oxidative dehydrogenation of n-butane into buta-1,3-diene: Bismuth molybdate effect and mechanistic insights","publication_year":2026,"publication_date":"2026-09-01","ids":{"openalex":"https://openalex.org/W7204855587","doi":"https://doi.org/10.1016/j.nxmate.2026.103327"},"language":"en","primary_location":{"id":"doi:10.1016/j.nxmate.2026.103327","doi":"https://doi.org/10.1016/j.nxmate.2026.103327","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.nxmate.2026.103327","pdf_url":null,"source":{"id":"https://openalex.org/S4387287712","display_name":"Next Materials","issn_l":"2949-8228","issn":["2949-8228"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Next Materials","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.1016/j.nxmate.2026.103327","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5086537476","display_name":"Olga V. Larina","orcid":"https://orcid.org/0000-0001-6359-1512","observed_orcids":["https://orcid.org/0000-0001-6359-1512"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I4210154421","display_name":"L.V. Pisarzhevskii Institute of Physical Chemistry","ror":"https://ror.org/05cfz8m13","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}],"countries":["UA"],"is_corresponding":true,"raw_author_name":"Olga V. Larina","raw_affiliation_strings":["Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine"],"raw_orcid":"https://orcid.org/0000-0001-6359-1512","affiliations":[{"raw_affiliation_string":"Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057085991","display_name":"Olexandra P. Pertko","orcid":"https://orcid.org/0000-0003-3539-7688","observed_orcids":["https://orcid.org/0000-0003-3539-7688"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I4210117011","display_name":"Institute of Bioorganic Chemistry and Petrochemistry V.P. Kukhar","ror":"https://ror.org/02tb8n028","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210117011"]},{"id":"https://openalex.org/I4210154421","display_name":"L.V. Pisarzhevskii Institute of Physical Chemistry","ror":"https://ror.org/05cfz8m13","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}],"countries":["UA"],"is_corresponding":false,"raw_author_name":"Oleksandra P. Pertko","raw_affiliation_strings":["Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","Department of \u0421atalytic Synthesis, V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine, 1 Vulytsia Akademika Kukharia, Kyiv 02094, Ukraine"],"raw_orcid":"https://orcid.org/0000-0003-3539-7688","affiliations":[{"raw_affiliation_string":"Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]},{"raw_affiliation_string":"Department of \u0421atalytic Synthesis, V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine, 1 Vulytsia Akademika Kukharia, Kyiv 02094, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210117011"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007827144","display_name":"Oksana V. Zikrata","orcid":"https://orcid.org/0000-0003-1429-951X","observed_orcids":["https://orcid.org/0000-0003-1429-951X"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I4210154421","display_name":"L.V. Pisarzhevskii Institute of Physical Chemistry","ror":"https://ror.org/05cfz8m13","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}],"countries":["UA"],"is_corresponding":false,"raw_author_name":"Oksana V. Zikrata","raw_affiliation_strings":["Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine"],"raw_orcid":"https://orcid.org/0000-0003-1429-951X","affiliations":[{"raw_affiliation_string":"Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067906461","display_name":"Ivan M. Remezovskyi","orcid":"https://orcid.org/0000-0001-9812-9117","observed_orcids":["https://orcid.org/0000-0001-9812-9117"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I4210154421","display_name":"L.V. Pisarzhevskii Institute of Physical Chemistry","ror":"https://ror.org/05cfz8m13","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}],"countries":["UA"],"is_corresponding":false,"raw_author_name":"Ivan M. Remezovskyi","raw_affiliation_strings":["Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine"],"raw_orcid":"https://orcid.org/0000-0001-9812-9117","affiliations":[{"raw_affiliation_string":"Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001515343","display_name":"Dmytro Yu. Balakin","orcid":"https://orcid.org/0000-0003-1327-6172","observed_orcids":["https://orcid.org/0000-0003-1327-6172"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I21250087","display_name":"Charles University","ror":"https://ror.org/024d6js02","country_code":"CZ","type":"education","lineage":["https://openalex.org/I21250087"]},{"id":"https://openalex.org/I75705878","display_name":"Institute of Physics","ror":"https://ror.org/02we6hx96","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I75705878"]}],"countries":["CZ","UA"],"is_corresponding":false,"raw_author_name":"Dmytro Yu. Balakin","raw_affiliation_strings":["Department of Adsorption Phenomena, Institute of Physics of the National Academy of Sciences of Ukraine, 46 Prosp. Nauky, Kyiv 03028, Ukraine","Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holesovickach 2, Prague 18000, Czech Republic"],"raw_orcid":"https://orcid.org/0000-0003-1327-6172","affiliations":[{"raw_affiliation_string":"Department of Adsorption Phenomena, Institute of Physics of the National Academy of Sciences of Ukraine, 46 Prosp. Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I75705878"]},{"raw_affiliation_string":"Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holesovickach 2, Prague 18000, Czech Republic","institution_ids":["https://openalex.org/I21250087"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036187229","display_name":"Pavlo I. Kyriienko","orcid":"https://orcid.org/0000-0003-1533-3492","observed_orcids":["https://orcid.org/0000-0003-1533-3492"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I4210154421","display_name":"L.V. Pisarzhevskii Institute of Physical Chemistry","ror":"https://ror.org/05cfz8m13","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}],"countries":["UA"],"is_corresponding":false,"raw_author_name":"Pavlo I. Kyriienko","raw_affiliation_strings":["Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5041127502","display_name":"Sergiy O. Soloviev","orcid":"https://orcid.org/0000-0001-9271-7495","observed_orcids":["https://orcid.org/0000-0001-9271-7495"]},"institutions":[{"id":"https://openalex.org/I149851306","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102","country_code":"UA","type":"government","lineage":["https://openalex.org/I149851306"]},{"id":"https://openalex.org/I4210154421","display_name":"L.V. Pisarzhevskii Institute of Physical Chemistry","ror":"https://ror.org/05cfz8m13","country_code":"UA","type":"facility","lineage":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}],"countries":["UA"],"is_corresponding":false,"raw_author_name":"Sergiy O. Soloviev","raw_affiliation_strings":["Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine"],"raw_orcid":"https://orcid.org/0000-0001-9271-7495","affiliations":[{"raw_affiliation_string":"Department of Catalytic Tandem Processes, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 Prospekt Nauky, Kyiv 03028, Ukraine","institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5086537476"],"corresponding_institution_ids":["https://openalex.org/I149851306","https://openalex.org/I4210154421"],"apc_list":{"value":1280,"currency":"USD","value_usd":1280},"apc_paid":{"value":1280,"currency":"USD","value_usd":1280},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"13","issue":null,"first_page":"103327","last_page":"103327"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/butane","display_name":"butane","score":0.9580000042915344},{"id":"https://openalex.org/keywords/buta-1-3-diene","display_name":"buta-1,3-diene","score":0.9890000224113464},{"id":"https://openalex.org/keywords/bi2moo6","display_name":"bismuth molybdate","score":0.9980000257492065},{"id":"https://openalex.org/keywords/acid-base-sites","display_name":"acid-base sites","score":0.640999972820282},{"id":"https://openalex.org/keywords/hydrogen-abstraction","display_name":"hydrogen abstraction","score":0.6790000200271606},{"id":"https://openalex.org/keywords/reverse-water-gas-shift-reaction","display_name":"reverse water-gas shift reaction","score":0.8009999990463257},{"id":"https://openalex.org/keywords/coordinatively-unsaturated-sites","display_name":"coordinatively unsaturated sites","score":0.7929999828338623},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.6850000023841858}],"concepts":[{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7264999747276306},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6906999945640564},{"id":"https://openalex.org/C119889771","wikidata":"https://www.wikidata.org/wiki/Q898262","display_name":"Dehydrogenation","level":3,"score":0.6482999920845032},{"id":"https://openalex.org/C533668322","wikidata":"https://www.wikidata.org/wiki/Q942","display_name":"Bismuth","level":2,"score":0.6383000016212463},{"id":"https://openalex.org/C2775981058","wikidata":"https://www.wikidata.org/wiki/Q3273039","display_name":"Molybdate","level":2,"score":0.501800000667572},{"id":"https://openalex.org/C57600042","wikidata":"https://www.wikidata.org/wiki/Q227564","display_name":"Oxidative phosphorylation","level":2,"score":0.46650001406669617},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.42719998955726624},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.31769999861717224},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.25859999656677246},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.2547999918460846},{"id":"https://openalex.org/C511782168","wikidata":"https://www.wikidata.org/wiki/Q725","display_name":"Chromium","level":2,"score":0.25040000677108765}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1016/j.nxmate.2026.103327","doi":"https://doi.org/10.1016/j.nxmate.2026.103327","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.nxmate.2026.103327","pdf_url":null,"source":{"id":"https://openalex.org/S4387287712","display_name":"Next Materials","issn_l":"2949-8228","issn":["2949-8228"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Next Materials","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1016/j.nxmate.2026.103327","doi":"https://doi.org/10.1016/j.nxmate.2026.103327","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.nxmate.2026.103327","pdf_url":null,"source":{"id":"https://openalex.org/S4387287712","display_name":"Next Materials","issn_l":"2949-8228","issn":["2949-8228"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Next Materials","raw_type":"journal-article"},"sustainable_development_goals":[{"score":0.5690000057220459,"display_name":"Affordable and clean energy","id":"https://metadata.un.org/sdg/7"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G4127489079","display_name":null,"funder_award_id":"2021.01/0017","funder_id":"https://openalex.org/F4320325308","funder_display_name":"State Fund for Fundamental Research of Ukraine"},{"id":"https://openalex.org/G5107396631","display_name":null,"funder_award_id":"\u041a\u041f\u041a\u0412\u041a 6541030","funder_id":"https://openalex.org/F4320322850","funder_display_name":"National Academy of Sciences of Ukraine"},{"id":"https://openalex.org/G6534303266","display_name":null,"funder_award_id":"0126U001704","funder_id":"https://openalex.org/F4320322850","funder_display_name":"National Academy of Sciences of Ukraine"}],"funders":[{"id":"https://openalex.org/F3194090993","display_name":"Central European Research Infrastructure Consortium","ror":"https://ror.org/01h2v3d55"},{"id":"https://openalex.org/F4320318013","display_name":"National Research Foundation of Ukraine","ror":"https://ror.org/02gmp5156"},{"id":"https://openalex.org/F4320322850","display_name":"National Academy of Sciences of Ukraine","ror":"https://ror.org/00je4t102"},{"id":"https://openalex.org/F4320325308","display_name":"State Fund for Fundamental Research of Ukraine","ror":"https://ror.org/05k0zzt52"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":119,"referenced_works":["https://openalex.org/W330947506","https://openalex.org/W843007777","https://openalex.org/W1523013182","https://openalex.org/W1565531522","https://openalex.org/W1964848787","https://openalex.org/W1969199282","https://openalex.org/W1972616434","https://openalex.org/W1974577058","https://openalex.org/W1977461311","https://openalex.org/W1981353018","https://openalex.org/W1983087916","https://openalex.org/W1989430780","https://openalex.org/W1990525737","https://openalex.org/W1993853241","https://openalex.org/W1994028694","https://openalex.org/W1994301903","https://openalex.org/W1994368911","https://openalex.org/W1994406425","https://openalex.org/W1995323708","https://openalex.org/W1995481575","https://openalex.org/W1995734656","https://openalex.org/W1996923858","https://openalex.org/W1998135879","https://openalex.org/W2006832405","https://openalex.org/W2007173814","https://openalex.org/W2009197346","https://openalex.org/W2017226416","https://openalex.org/W2019656675","https://openalex.org/W2022141993","https://openalex.org/W2022730294","https://openalex.org/W2022876965","https://openalex.org/W2025053815","https://openalex.org/W2032459821","https://openalex.org/W2033549660","https://openalex.org/W2037187763","https://openalex.org/W2041004291","https://openalex.org/W2044453567","https://openalex.org/W2044687817","https://openalex.org/W2048438201","https://openalex.org/W2049819714","https://openalex.org/W2052426124","https://openalex.org/W2055044300","https://openalex.org/W2057436659","https://openalex.org/W2059429000","https://openalex.org/W2061221675","https://openalex.org/W2062049711","https://openalex.org/W2063138605","https://openalex.org/W2065051207","https://openalex.org/W2066750900","https://openalex.org/W2068222155","https://openalex.org/W2069395067","https://openalex.org/W2069604286","https://openalex.org/W2070484460","https://openalex.org/W2070993377","https://openalex.org/W2071060954","https://openalex.org/W2075922577","https://openalex.org/W2076838266","https://openalex.org/W2082703652","https://openalex.org/W2086574254","https://openalex.org/W2108953022","https://openalex.org/W2116698048","https://openalex.org/W2143092464","https://openalex.org/W2171583835","https://openalex.org/W2293070692","https://openalex.org/W2318713233","https://openalex.org/W2345364483","https://openalex.org/W2478185284","https://openalex.org/W2520033914","https://openalex.org/W2546301623","https://openalex.org/W2606998605","https://openalex.org/W2626378709","https://openalex.org/W2683582219","https://openalex.org/W2735139576","https://openalex.org/W2790336878","https://openalex.org/W2793229345","https://openalex.org/W2806251429","https://openalex.org/W2883211566","https://openalex.org/W2893802640","https://openalex.org/W2899283097","https://openalex.org/W2903562458","https://openalex.org/W2907695380","https://openalex.org/W2913020355","https://openalex.org/W2922832091","https://openalex.org/W2943511124","https://openalex.org/W2950801504","https://openalex.org/W2954938957","https://openalex.org/W2973574869","https://openalex.org/W2990410433","https://openalex.org/W3000476907","https://openalex.org/W3013587066","https://openalex.org/W3042167767","https://openalex.org/W3044232881","https://openalex.org/W3047663495","https://openalex.org/W3095290319","https://openalex.org/W3121338555","https://openalex.org/W3128843566","https://openalex.org/W3129981786","https://openalex.org/W3176567374","https://openalex.org/W3177302286","https://openalex.org/W4220871769","https://openalex.org/W4230926534","https://openalex.org/W4238924556","https://openalex.org/W4281865480","https://openalex.org/W4284963272","https://openalex.org/W4366606904","https://openalex.org/W4382655212","https://openalex.org/W4383755519","https://openalex.org/W4385782481","https://openalex.org/W4393011083","https://openalex.org/W4395467373","https://openalex.org/W4398190894","https://openalex.org/W4399438029","https://openalex.org/W4399986092","https://openalex.org/W4400284566","https://openalex.org/W4401966979","https://openalex.org/W4402408229","https://openalex.org/W4405519914","https://openalex.org/W4412050174","https://openalex.org/W7203465057"],"related_works":["https://openalex.org/W4412050174","https://openalex.org/W1983503423","https://openalex.org/W1979870281","https://openalex.org/W2039017102","https://openalex.org/W2022141993","https://openalex.org/W1965975910","https://openalex.org/W2038777494","https://openalex.org/W1994406425","https://openalex.org/W7203465057","https://openalex.org/W2055044300"],"abstract_inverted_index":{"Ni-Bi-Mo/Al":[0],"2":[1,17,21,26,37,137,156,159,169,222],"O":[2],"3":[3,24,171],"metal-oxide":[4],"systems":[5],"were":[6,33,128],"prepared":[7],"via":[8],"co-impregnation":[9],"and":[10,28,46,63,67,92,130,161],"characterized":[11],"using":[12],"XRD,":[13],"low-temperature":[14],"(\u2212196\u2103)":[15],"N":[16],"adsorption\u2013desorption,":[18],"SEM-EDX,":[19],"H":[20],"-TPR,":[22],"NH":[23],"/CO":[25],"-TPD,":[27],"XPS.":[29],"Their":[30],"catalytic":[31,121],"properties":[32],"investigated":[34],"in":[35,123,177],"CO":[36,136,170,221],"-mediated":[38,138],"oxidative":[39,139],"dehydrogenation":[40,109,140,195,225],"of":[41,53,77,83,87,98,141,181],"n":[42,107,142],"-butane.":[43],"Increasing":[44],"Bi":[45,162],"Mo":[47,158],"loadings":[48],"leads":[49],"to":[50,216],"the":[51,59,65,80,102,120,124,144,178,182,200,207,237],"accumulation":[52],"crystalline":[54,154],"bismuth":[55,151],"molybdates,":[56],"thereby":[57],"reducing":[58],"specific":[60],"surface":[61,146,172],"area":[62],"redistributing":[64],"acidic":[66,90],"basic":[68],"sites":[69,91,96,229],"by":[70,74,119,220],"strength.":[71],"As":[72],"evidenced":[73],"TPSR-MS":[75],"profiles":[76],"pre-adsorbed":[78],"butenes,":[79],"increased":[81],"number":[82],"acid-base":[84],"pairs":[85],"composed":[86],"moderate-strength":[88],"butene-retaining":[89],"adjacent":[93],"lattice":[94],"oxygen":[95],"capable":[97],"hydrogen":[99],"abstraction":[100],"from":[101],"adsorbed":[103],"olefin":[104],"intermediates":[105],"enables":[106],"-butane":[108],"toward":[110],"buta-1,3-diene":[111],"with":[112,165,236],"a":[113,166,189,231],"67%":[114],"selectivity.":[115],"Structural":[116],"changes":[117],"induced":[118],"reaction":[122],"most":[125],"selective":[126,193],"catalyst":[127,145],"studied,":[129],"mechanistic":[131],"insights":[132],"are":[133],"discussed.":[134],"During":[135],"-butane,":[143],"undergoes":[147],"progressive":[148],"reduction,":[149],"transforming":[150],"molybdates":[152],"into":[153],"MoO":[155],",":[157,164,223],"C,":[160],"0":[163],"thin":[167],"(BiO)":[168],"shell.":[173],"This":[174],"process":[175],"results":[176],"concurrent":[179],"operation":[180],"initial,":[183],"rapid":[184],"Mars-van":[185],"Krevelen":[186],"cycle":[187],"alongside":[188],"slower":[190],"but":[191],"more":[192],"direct":[194,224],"pathway":[196],"that":[197],"emerges":[198],"on":[199,226],"newly":[201],"formed":[202],"coordinatively":[203,227],"unsaturated":[204,228],"sites.":[205],"Because":[206],"bulk":[208],"Bi\u2013Mo":[209],"oxide":[210],"phases":[211],"cannot":[212],"be":[213],"fully":[214],"re-oxidized":[215],"their":[217],"initial":[218],"state":[219],"becomes":[230],"prominent":[232],"pathway,":[233],"operating":[234],"concurrently":[235],"Reverse":[238],"Water-Gas":[239],"Shift":[240],"reaction.":[241]},"counts_by_year":[],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2026-09-01T00:00:00"}