{"id":"https://openalex.org/W7203733706","doi":"https://doi.org/10.1002/anie.5252700","title":"Light\u2010Driven Out\u2010of\u2010Equilibrium Helicity Control in a Diarylethene\u2013Helicene Photosystem","display_name":"Light\u2010Driven Out\u2010of\u2010Equilibrium Helicity Control in a Diarylethene\u2013Helicene Photosystem","publication_year":2026,"publication_date":"2026-08-19","ids":{"openalex":"https://openalex.org/W7203733706","doi":"https://doi.org/10.1002/anie.5252700","pmid":"https://pubmed.ncbi.nlm.nih.gov/42615262"},"language":"en","primary_location":{"id":"doi:10.1002/anie.5252700","doi":"https://doi.org/10.1002/anie.5252700","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.5252700","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.5252700","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.5252700","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5081935805","display_name":"Eric Sidler","orcid":"https://orcid.org/0000-0001-7740-3869","observed_orcids":["https://orcid.org/0000-0001-7740-3869"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]},{"id":"https://openalex.org/I202697423","display_name":"University of Zurich","ror":"https://ror.org/02crff812","country_code":"CH","type":"education","lineage":["https://openalex.org/I202697423"]}],"countries":["CH","NL"],"is_corresponding":true,"raw_author_name":"Eric Sidler","raw_affiliation_strings":["Department of Chemistry University of Zurich  Z\u00fcrich Switzerland","Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands"],"raw_orcid":"https://orcid.org/0000-0001-7740-3869","affiliations":[{"raw_affiliation_string":"Department of Chemistry University of Zurich  Z\u00fcrich Switzerland","institution_ids":["https://openalex.org/I202697423"]},{"raw_affiliation_string":"Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands","institution_ids":["https://openalex.org/I169381384"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056554644","display_name":"Jinghao Wang","orcid":"https://orcid.org/0000-0001-8696-6911","observed_orcids":["https://orcid.org/0000-0001-8696-6911"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Jinghao Wang","raw_affiliation_strings":["Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands","institution_ids":["https://openalex.org/I169381384"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5147563582","display_name":"Christina Vallina","orcid":"https://orcid.org/0009-0009-2805-1495","observed_orcids":["https://orcid.org/0009-0009-2805-1495"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Christina Vallina","raw_affiliation_strings":["Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands"],"raw_orcid":"https://orcid.org/0009-0009-2805-1495","affiliations":[{"raw_affiliation_string":"Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands","institution_ids":["https://openalex.org/I169381384"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5087713906","display_name":"Ben L. Feringa","orcid":"https://orcid.org/0000-0003-0588-8435","observed_orcids":["https://orcid.org/0000-0003-0588-8435"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":true,"raw_author_name":"Ben L. Feringa","raw_affiliation_strings":["Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands"],"raw_orcid":"https://orcid.org/0000-0003-0588-8435","affiliations":[{"raw_affiliation_string":"Stratingh Institute for Chemistry University of Groningen  Groningen the Netherlands","institution_ids":["https://openalex.org/I169381384"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5081935805","https://openalex.org/A5087713906"],"corresponding_institution_ids":["https://openalex.org/I169381384","https://openalex.org/I202697423"],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":{"value":5510,"currency":"USD","value_usd":5510},"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.44346911,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"65","issue":"45","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.9458000063896179,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.9458000063896179,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.027000000700354576,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11298","display_name":"Synthesis and Properties of Aromatic Compounds","score":0.01979999989271164,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/diarylethene","display_name":"diarylethene","score":0.8529999852180481},{"id":"https://openalex.org/keywords/helicenes","display_name":"helicenes","score":0.9610000252723694},{"id":"https://openalex.org/keywords/photoswitches","display_name":"photoswitches","score":0.7379999756813049},{"id":"https://openalex.org/keywords/helicity-control","display_name":"helicity control","score":0.921999990940094},{"id":"https://openalex.org/keywords/non-equilibrium-systems","display_name":"nonequilibrium systems","score":0.7059999704360962},{"id":"https://openalex.org/keywords/photochemical-ring-opening","display_name":"photochemical ring opening","score":0.5820000171661377},{"id":"https://openalex.org/keywords/kinetic-trapping","display_name":"kinetic trapping","score":0.7509999871253967},{"id":"https://openalex.org/keywords/helix-inversion","display_name":"helix inversion","score":0.6620000004768372},{"id":"https://openalex.org/keywords/dynamic-chirality","display_name":"dynamic chirality","score":0.6169999837875366},{"id":"https://openalex.org/keywords/molecular-helicity","display_name":"molecular helicity","score":0.3479999899864197}],"concepts":[{"id":"https://openalex.org/C2775859700","wikidata":"https://www.wikidata.org/wiki/Q568855","display_name":"Helicity","level":2,"score":0.7613999843597412},{"id":"https://openalex.org/C2777694918","wikidata":"https://www.wikidata.org/wiki/Q11171014","display_name":"Ratchet","level":3,"score":0.6822999715805054},{"id":"https://openalex.org/C2776663404","wikidata":"https://www.wikidata.org/wiki/Q5479379","display_name":"Photoswitch","level":2,"score":0.6481999754905701},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5450999736785889},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.4611999988555908},{"id":"https://openalex.org/C62752575","wikidata":"https://www.wikidata.org/wiki/Q6822487","display_name":"Metadynamics","level":3,"score":0.45010000467300415},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.4472000002861023},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.44699999690055847},{"id":"https://openalex.org/C2991957519","wikidata":"https://www.wikidata.org/wiki/Q2469857","display_name":"Kinetic control","level":3,"score":0.4140999913215637},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.40720000863075256},{"id":"https://openalex.org/C38976095","wikidata":"https://www.wikidata.org/wiki/Q752641","display_name":"Asymmetry","level":2,"score":0.3986999988555908},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.3544999957084656},{"id":"https://openalex.org/C84551667","wikidata":"https://www.wikidata.org/wiki/Q155640","display_name":"Potential energy","level":2,"score":0.3138999938964844},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.289000004529953},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.28060001134872437},{"id":"https://openalex.org/C22547674","wikidata":"https://www.wikidata.org/wiki/Q582668","display_name":"Chemical energy","level":2,"score":0.27570000290870667},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.25589999556541443},{"id":"https://openalex.org/C18705241","wikidata":"https://www.wikidata.org/wiki/Q1128023","display_name":"Conformational isomerism","level":3,"score":0.2531999945640564},{"id":"https://openalex.org/C119621388","wikidata":"https://www.wikidata.org/wiki/Q5377166","display_name":"Energy landscape","level":2,"score":0.2526000142097473},{"id":"https://openalex.org/C130787639","wikidata":"https://www.wikidata.org/wiki/Q5645293","display_name":"Hamiltonian (control theory)","level":2,"score":0.25040000677108765}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/anie.5252700","doi":"https://doi.org/10.1002/anie.5252700","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.5252700","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.5252700","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:42615262","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42615262","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:13725563","doi":null,"is_oa":true,"landing_page_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC13725563/","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angew Chem Int Ed Engl","raw_type":"Text"}],"best_oa_location":{"id":"doi:10.1002/anie.5252700","doi":"https://doi.org/10.1002/anie.5252700","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.5252700","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.5252700","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G7535225800","display_name":"Helicene-based molecular motors and switches","funder_award_id":"214313","funder_id":"https://openalex.org/F4320320924","funder_display_name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320320924","display_name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung","ror":"https://ror.org/00yjd3n13"},{"id":"https://openalex.org/F4320320933","display_name":"Rijksuniversiteit Groningen","ror":"https://ror.org/012p63287"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7203733706.pdf","grobid_xml":"https://content.openalex.org/works/W7203733706.grobid-xml"},"referenced_works_count":35,"referenced_works":["https://openalex.org/W1559264985","https://openalex.org/W1986883628","https://openalex.org/W1989122618","https://openalex.org/W2000798385","https://openalex.org/W2012206068","https://openalex.org/W2017931896","https://openalex.org/W2058848030","https://openalex.org/W2087634138","https://openalex.org/W2090329067","https://openalex.org/W2108241347","https://openalex.org/W2162915475","https://openalex.org/W2321077391","https://openalex.org/W2469713039","https://openalex.org/W2481980415","https://openalex.org/W2605768989","https://openalex.org/W2729995910","https://openalex.org/W2737449748","https://openalex.org/W2741722526","https://openalex.org/W2752522940","https://openalex.org/W2989020725","https://openalex.org/W3129018228","https://openalex.org/W3206776443","https://openalex.org/W4229009502","https://openalex.org/W4229022276","https://openalex.org/W4281702960","https://openalex.org/W4385634496","https://openalex.org/W4387033224","https://openalex.org/W4390639870","https://openalex.org/W4391923457","https://openalex.org/W4393871098","https://openalex.org/W4404228163","https://openalex.org/W4412995533","https://openalex.org/W7117975191","https://openalex.org/W7119488626","https://openalex.org/W7140336536"],"related_works":["https://openalex.org/W7220736939","https://openalex.org/W2062105664","https://openalex.org/W2554243023","https://openalex.org/W2344505921","https://openalex.org/W2168400166","https://openalex.org/W2910015779","https://openalex.org/W4404228164","https://openalex.org/W2124560289","https://openalex.org/W2117818573","https://openalex.org/W7165178165"],"abstract_inverted_index":{"Molecular":[0],"photoswitches":[1],"are":[2],"key":[3],"tools":[4],"to":[5,10],"control":[6,27,132,143],"responsive":[7,37],"functions":[8],"and":[9,20,59,103],"drive":[11],"systems":[12],"away":[13],"from":[14],"equilibrium":[15],"by":[16,75],"enabling":[17,130],"kinetic":[18],"asymmetry":[19],"energy":[21,50,78,120],"ratchet":[22,121],"mechanisms.":[23],"Incorporating":[24],"dynamic":[25],"chirality":[26],"within":[28,124],"such":[29],"non-equilibrium":[30],"frameworks,":[31],"however,":[32],"remains":[33],"challenging.":[34],"Here,":[35],"the":[36,53,57,63,69,80,87,94,98,107],"behavior":[38],"of":[39,62],"a":[40,76,111,118,125,138],"diarylethene-[5]helicene":[41],"photoswitch":[42],"comprising":[43],"multiple":[44],"interconverting":[45],"diastereomers":[46],"is":[47,72,101],"investigated.":[48],"Distinct":[49],"profiles":[51],"govern":[52],"helicity":[54,95,142],"dynamics":[55],"in":[56,68,97,106,144],"open":[58,70,108],"closed":[60,81,99],"forms":[61],"switch.":[64],"While":[65],"helix":[66],"inversion":[67],"state":[71,82,100],"kinetically":[73,104],"hindered":[74],"high":[77],"barrier,":[79],"allows":[83],"rapid":[84],"equilibration":[85],"toward":[86],"thermodynamically":[88],"favored":[89],"diastereomer.":[90],"Upon":[91],"photochemical":[92],"ring-opening,":[93],"acquired":[96],"transferred":[102],"trapped":[105],"form,":[109],"generating":[110],"persistent":[112],"out-of-equilibrium":[113],"configuration.":[114],"This":[115],"sequence":[116],"constitutes":[117],"rare":[119],"mechanism":[122],"operating":[123],"single":[126],"covalently":[127],"linked":[128],"molecule,":[129],"directional":[131],"over":[133],"helicity.":[134],"These":[135],"findings":[136],"provide":[137],"concept":[139],"for":[140],"light-driven":[141],"adaptive":[145],"chiral":[146],"systems.":[147]},"counts_by_year":[],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2026-08-20T00:00:00"}