{"id":"https://openalex.org/W7202060656","doi":"https://doi.org/10.36120/2587-3644.v21i1.29-38","title":"Template synthesis, crystal and electronic structure of trinuclear Co(II) complex based on new 15-dentate macrocyclic Schiff base ligand","display_name":"Template synthesis, crystal and electronic structure of trinuclear Co(II) complex based on new 15-dentate macrocyclic Schiff base ligand","publication_year":2026,"publication_date":"2026-07-01","ids":{"openalex":"https://openalex.org/W7202060656","doi":"https://doi.org/10.36120/2587-3644.v21i1.29-38"},"language":"en","primary_location":{"id":"pmh:oai:doaj.org/article:217eda78b0174e36a42f9897d9ee37e1","doi":"https://doi.org/10.36120/2587-3644.v21i1.29-38","is_oa":false,"landing_page_url":"https://doaj.org/article/217eda78b0174e36a42f9897d9ee37e1","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Acta et Commentationes: \u015etiin\u0163e Exacte \u015fi ale Naturii, Vol 21, Iss 1 (2026)","raw_type":"article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["doaj"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5084566907","display_name":"Olga Danilescu","orcid":"https://orcid.org/0000-0001-9090-7164","observed_orcids":["https://orcid.org/0000-0001-9090-7164"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Olga Danilescu","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082329733","display_name":"Ion I. Bulhac","orcid":"https://orcid.org/0000-0002-2437-2875","observed_orcids":["https://orcid.org/0000-0002-2437-2875"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Ion Bulhac","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033092828","display_name":"Paulina Bourosh","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Paulina Bourosh","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007330592","display_name":"Maria Cocu","orcid":"https://orcid.org/0000-0001-8572-0258","observed_orcids":["https://orcid.org/0000-0001-8572-0258"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Maria Cocu","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5058669324","display_name":"Yurii M. Chumakov","orcid":"https://orcid.org/0000-0003-2582-2871","observed_orcids":["https://orcid.org/0000-0003-2582-2871","https://orcid.org/0000-0003-0525-992X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Yurii Chumakov","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.4672999978065491,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.4672999978065491,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.3456999957561493,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.10019999742507935,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/macrocyclic-ligands","display_name":"macrocyclic ligands","score":0.8849999904632568},{"id":"https://openalex.org/keywords/schiff-base","display_name":"Schiff base","score":0.597000002861023},{"id":"https://openalex.org/keywords/2-6-diacetylpyridine","display_name":"2,6-diacetylpyridine","score":0.9440000057220459},{"id":"https://openalex.org/keywords/templated-synthesis","display_name":"template synthesis","score":0.8889999985694885},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.8100000023841858},{"id":"https://openalex.org/keywords/electronic-structure","display_name":"electronic structure","score":0.984000027179718},{"id":"https://openalex.org/keywords/exchange-coupling","display_name":"exchange coupling","score":0.703000009059906},{"id":"https://openalex.org/keywords/coordination-compounds","display_name":"metal complexes","score":0.6179999709129333}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.43619999289512634},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3937999904155731},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.3476000130176544},{"id":"https://openalex.org/C2777904410","wikidata":"https://www.wikidata.org/wiki/Q7397","display_name":"Software","level":2,"score":0.2881999909877777},{"id":"https://openalex.org/C12713177","wikidata":"https://www.wikidata.org/wiki/Q1900281","display_name":"Perspective (graphical)","level":2,"score":0.2847000062465668},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2838999927043915},{"id":"https://openalex.org/C182306322","wikidata":"https://www.wikidata.org/wiki/Q1779371","display_name":"Order (exchange)","level":2,"score":0.2770000100135803},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.2759000062942505},{"id":"https://openalex.org/C2778355321","wikidata":"https://www.wikidata.org/wiki/Q17079427","display_name":"Identity (music)","level":2,"score":0.26159998774528503},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.2468000054359436}],"mesh":[],"locations_count":1,"locations":[{"id":"pmh:oai:doaj.org/article:217eda78b0174e36a42f9897d9ee37e1","doi":"https://doi.org/10.36120/2587-3644.v21i1.29-38","is_oa":false,"landing_page_url":"https://doaj.org/article/217eda78b0174e36a42f9897d9ee37e1","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Acta et Commentationes: \u015etiin\u0163e Exacte \u015fi ale Naturii, Vol 21, Iss 1 (2026)","raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W7202236357","https://openalex.org/W7128790912","https://openalex.org/W6987603335","https://openalex.org/W2125093453","https://openalex.org/W7067740750","https://openalex.org/W2022110849","https://openalex.org/W2053650846","https://openalex.org/W1499969318","https://openalex.org/W2091990909","https://openalex.org/W2061359948"],"abstract_inverted_index":{"The":[0,21,50,74],"new":[1],"15-dentate":[2],"macrocyclic":[3,27,48,91],"Schiff":[4,28],"base":[5,29],"ligand,":[6],"derived":[7],"from":[8],"2,6-diacetylpyridine":[9],"and":[10,36,53,71,78],"malonic":[11],"acid":[12],"dihydrazide,":[13],"was":[14,34],"synthesized":[15],"using":[16],"a":[17,39,45],"template":[18],"condensation":[19],"approach.":[20],"deprotonation-protonation":[22],"behaviour":[23],"of":[24,44,56],"this":[25],"polydentate":[26],"in":[30,89,94],"Co(II)":[31,92],"coordination":[32],"compounds":[33],"investigated":[35],"exploited":[37],"as":[38],"strategy":[40],"for":[41],"the":[42,57,85,95],"assembly":[43],"novel":[46],"trinuclear":[47,90],"complex.":[49],"chemical":[51],"composition":[52],"crystal":[54],"structure":[55],"resulting":[58],"complex":[59,93],"[Co\u2083(H\u2086L)(H\u2082O)\u2086](ClO\u2084)\u2086":[60],"\u00b7":[61],"8H\u2082O":[62],"were":[63,81],"elucidated":[64],"by":[65],"single-crystal":[66],"X-ray":[67],"diffraction,":[68],"infrared":[69],"spectroscopy,":[70],"elemental":[72],"analysis.":[73],"TB2J":[75],"python":[76],"package":[77],"SIESTA":[79],"code":[80],"used":[82],"to":[83],"analyse":[84],"magnetic":[86],"exchange":[87],"interactions":[88],"crystal.":[96]},"counts_by_year":[],"updated_date":"2026-11-13T13:42:25.865203","created_date":"2026-08-10T00:00:00"}