{"id":"https://openalex.org/W7196948623","doi":"https://doi.org/10.1039/d6sc05617b","title":"The crystalline radical anion salt of a free N-heterocyclic carbene","display_name":"The crystalline radical anion salt of a free N-heterocyclic carbene","publication_year":2026,"publication_date":"2026-01-01","ids":{"openalex":"https://openalex.org/W7196948623","doi":"https://doi.org/10.1039/d6sc05617b","pmid":"https://pubmed.ncbi.nlm.nih.gov/42689232","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/13537185"},"language":"en","primary_location":{"id":"doi:10.1039/d6sc05617b","doi":"https://doi.org/10.1039/d6sc05617b","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d6sc05617b","pdf_url":null,"source":{"id":"https://openalex.org/S184645833","display_name":"Chemical Science","issn_l":"2041-6520","issn":["2041-6520","2041-6539"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-3","ki-jl-2","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Science","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://doi.org/10.1039/d6sc05617b","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5071142877","display_name":"Preslav Smits","orcid":"https://orcid.org/0009-0000-9267-4018","observed_orcids":["https://orcid.org/0009-0000-9267-4018"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I899635006","display_name":"Universit\u00e9 Grenoble Alpes","ror":"https://ror.org/02rx3b187","country_code":"FR","type":"education","lineage":["https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Preslav Smits","raw_affiliation_strings":["Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France"],"raw_orcid":"https://orcid.org/0009-0000-9267-4018","affiliations":[{"raw_affiliation_string":"Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I899635006"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023111046","display_name":"Jacques P\u00e9caut","orcid":"https://orcid.org/0000-0001-9666-3105","observed_orcids":["https://orcid.org/0000-0001-9666-3105"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I3020098449","display_name":"CEA Grenoble","ror":"https://ror.org/02mg6n827","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I3020098449"]},{"id":"https://openalex.org/I4210124948","display_name":"Institut Nanosciences et Cryog\u00e9nie","ror":"https://ror.org/02w3v0826","country_code":"FR","type":"facility","lineage":["https://openalex.org/I2738703131","https://openalex.org/I4210113668","https://openalex.org/I4210124948"]},{"id":"https://openalex.org/I4400600907","display_name":"Syst\u00e8mes Mol\u00e9culaires et nanoMat\u00e9riaux pour l'\u00c9nergie et la Sant\u00e9","ror":"https://ror.org/0535cbn94","country_code":"FR","type":"education","lineage":["https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210091409","https://openalex.org/I4210113668","https://openalex.org/I4400600907","https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Jacques Pecaut","raw_affiliation_strings":["CEA, CNRS, INAC-SyMMES, UMR 5819, 38000 Grenoble, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, CNRS, INAC-SyMMES, UMR 5819, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I3020098449","https://openalex.org/I4210124948","https://openalex.org/I4400600907"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5105786016","display_name":"Christian Philouze","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I899635006","display_name":"Universit\u00e9 Grenoble Alpes","ror":"https://ror.org/02rx3b187","country_code":"FR","type":"education","lineage":["https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Christian Philouze","raw_affiliation_strings":["Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I899635006"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022562421","display_name":"J\u00e9r\u00f4me Fortage","orcid":"https://orcid.org/0000-0003-2673-0610","observed_orcids":["https://orcid.org/0000-0003-2673-0610"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I899635006","display_name":"Universit\u00e9 Grenoble Alpes","ror":"https://ror.org/02rx3b187","country_code":"FR","type":"education","lineage":["https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"J\u00e9rome Fortage","raw_affiliation_strings":["Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France"],"raw_orcid":"https://orcid.org/0000-0003-2673-0610","affiliations":[{"raw_affiliation_string":"Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I899635006"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025100690","display_name":"Eder Tom\u00e1s\u2010Mendivil","orcid":"https://orcid.org/0000-0002-4247-6731","observed_orcids":["https://orcid.org/0000-0002-4247-6731"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I899635006","display_name":"Universit\u00e9 Grenoble Alpes","ror":"https://ror.org/02rx3b187","country_code":"FR","type":"education","lineage":["https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Eder Tom\u00e1s-Mendivil","raw_affiliation_strings":["Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France"],"raw_orcid":"https://orcid.org/0000-0002-4247-6731","affiliations":[{"raw_affiliation_string":"Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I899635006"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5009617769","display_name":"David Mart\u00edn","orcid":"https://orcid.org/0000-0002-3257-9876","observed_orcids":["https://orcid.org/0000-0002-3257-9876"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210099103","display_name":"D\u00e9partement de Chimie Mol\u00e9culaire","ror":"https://ror.org/010rs2a38","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I4210128300","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I899635006","display_name":"Universit\u00e9 Grenoble Alpes","ror":"https://ror.org/02rx3b187","country_code":"FR","type":"education","lineage":["https://openalex.org/I899635006"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"David Martin","raw_affiliation_strings":["Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France"],"raw_orcid":"https://orcid.org/0000-0002-3257-9876","affiliations":[{"raw_affiliation_string":"Department of Molecular Chemistry Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I899635006"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":7,"corresponding_author_ids":["https://openalex.org/A5009617769"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210099103","https://openalex.org/I899635006"],"apc_list":null,"apc_paid":null,"fwci":1.6011,"has_fulltext":true,"cited_by_count":1,"citation_normalized_percentile":{"value":0.85781552,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":91,"max":95},"biblio":{"volume":"17","issue":"40","first_page":"19220","last_page":"19226"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbenes","display_name":"N-heterocyclic carbenes","score":0.9549999833106995},{"id":"https://openalex.org/keywords/radical-anions","display_name":"radical anions","score":0.9480000138282776},{"id":"https://openalex.org/keywords/crystalline-salts","display_name":"crystalline salts","score":0.515999972820282},{"id":"https://openalex.org/keywords/proton-coupled-electron-transfer","display_name":"proton-coupled electron transfer","score":0.8889999985694885},{"id":"https://openalex.org/keywords/radical-intermediates","display_name":"radical intermediates","score":0.3479999899864197}],"concepts":[{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.9218999743461609},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.7450000047683716},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7401000261306763},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.7365999817848206},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.512499988079071},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4975000023841858},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.4542999863624573},{"id":"https://openalex.org/C96444392","wikidata":"https://www.wikidata.org/wiki/Q1993452","display_name":"Radical ion","level":3,"score":0.36039999127388},{"id":"https://openalex.org/C169749651","wikidata":"https://www.wikidata.org/wiki/Q902198","display_name":"Radical substitution","level":3,"score":0.3398999869823456},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.31200000643730164},{"id":"https://openalex.org/C147120987","wikidata":"https://www.wikidata.org/wiki/Q2225","display_name":"Electron","level":2,"score":0.30889999866485596},{"id":"https://openalex.org/C105768512","wikidata":"https://www.wikidata.org/wiki/Q7458208","display_name":"Reaction intermediate","level":3,"score":0.26589998602867126}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1039/d6sc05617b","doi":"https://doi.org/10.1039/d6sc05617b","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d6sc05617b","pdf_url":null,"source":{"id":"https://openalex.org/S184645833","display_name":"Chemical Science","issn_l":"2041-6520","issn":["2041-6520","2041-6539"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-3","ki-jl-2","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Science","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv.15002791/v1","doi":"https://doi.org/10.26434/chemrxiv.15002791/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15002791/v1","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15002791/v1","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmh:oai:pubmedcentral.nih.gov:13537185","doi":null,"is_oa":true,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42689232/","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC13537185/pdf/SC-OLF-D6SC05617B.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chem Sci","raw_type":"Text"},{"id":"pmid:42689232","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42689232","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical science","raw_type":"Journal Article"},{"id":"pmh:oai:HAL:hal-05759926v1","doi":null,"is_oa":true,"landing_page_url":"https://hal.science/hal-05759926","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemical Science, 2026, &#x27E8;10.1039/d6sc05617b&#x27E9;","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.1039/d6sc05617b","doi":"https://doi.org/10.1039/d6sc05617b","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d6sc05617b","pdf_url":null,"source":{"id":"https://openalex.org/S184645833","display_name":"Chemical Science","issn_l":"2041-6520","issn":["2041-6520","2041-6539"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-3","ki-jl-2","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Science","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1513157868","display_name":"CBH-EUR-GS","funder_award_id":"ANR-17-EURE-0003","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G2238372359","display_name":"Carbene-catalyzed super-reductions through direct photoactivation of intermediates","funder_award_id":"ANR-25-CE07-0501","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G2389725886","display_name":null,"funder_award_id":"ANR\u201017\u2010EURE\u20100003","funder_id":"https://openalex.org/F4320314200","funder_display_name":"LABoratoires d\u2019EXcellence ARCANE"},{"id":"https://openalex.org/G2659019386","display_name":null,"funder_award_id":"ANR-17-EURE-","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"},{"id":"https://openalex.org/G6803667113","display_name":null,"funder_award_id":"ANR-17","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"}],"funders":[{"id":"https://openalex.org/F4320314200","display_name":"LABoratoires d\u2019EXcellence ARCANE","ror":null},{"id":"https://openalex.org/F4320320883","display_name":"Agence Nationale de la Recherche","ror":"https://ror.org/00rbzpz17"},{"id":"https://openalex.org/F4320338463","display_name":"CHIST-ERA","ror":"https://ror.org/00rbzpz17"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7196948623.pdf","grobid_xml":"https://content.openalex.org/works/W7196948623.grobid-xml"},"referenced_works_count":77,"referenced_works":["https://openalex.org/W1537192859","https://openalex.org/W1755120593","https://openalex.org/W1971080513","https://openalex.org/W1974348769","https://openalex.org/W1995596954","https://openalex.org/W2003555872","https://openalex.org/W2006185263","https://openalex.org/W2006545498","https://openalex.org/W2010117753","https://openalex.org/W2017023377","https://openalex.org/W2018702845","https://openalex.org/W2020399678","https://openalex.org/W2025519202","https://openalex.org/W2034392569","https://openalex.org/W2038092103","https://openalex.org/W2046286719","https://openalex.org/W2048828341","https://openalex.org/W2066635731","https://openalex.org/W2077959742","https://openalex.org/W2078370450","https://openalex.org/W2078798686","https://openalex.org/W2085841955","https://openalex.org/W2094014427","https://openalex.org/W2103362663","https://openalex.org/W2122031375","https://openalex.org/W2128434357","https://openalex.org/W2146051607","https://openalex.org/W2171524143","https://openalex.org/W2288760809","https://openalex.org/W2299637886","https://openalex.org/W2320050688","https://openalex.org/W2320163706","https://openalex.org/W2324402477","https://openalex.org/W2462518070","https://openalex.org/W2511837465","https://openalex.org/W2527541422","https://openalex.org/W2567033104","https://openalex.org/W2626738381","https://openalex.org/W2808515502","https://openalex.org/W3015824199","https://openalex.org/W3015897809","https://openalex.org/W3020209089","https://openalex.org/W3025153687","https://openalex.org/W3121438936","https://openalex.org/W3198264957","https://openalex.org/W3207871969","https://openalex.org/W4210960216","https://openalex.org/W4220694265","https://openalex.org/W4251485118","https://openalex.org/W4284890507","https://openalex.org/W4285730196","https://openalex.org/W4288063837","https://openalex.org/W4309289763","https://openalex.org/W4310732516","https://openalex.org/W4311240439","https://openalex.org/W4315752767","https://openalex.org/W4361002584","https://openalex.org/W4388013796","https://openalex.org/W4391090462","https://openalex.org/W4400362730","https://openalex.org/W4404250636","https://openalex.org/W4407382670","https://openalex.org/W4407478041","https://openalex.org/W4408885584","https://openalex.org/W4411675878","https://openalex.org/W4415353134","https://openalex.org/W7122774731","https://openalex.org/W7141689885","https://openalex.org/W7154749988","https://openalex.org/W7157992731","https://openalex.org/W7164140820","https://openalex.org/W7164145980","https://openalex.org/W7164181938","https://openalex.org/W7164183012","https://openalex.org/W7164183126","https://openalex.org/W7164184771","https://openalex.org/W7164187436"],"related_works":["https://openalex.org/W7160388707","https://openalex.org/W2885371647","https://openalex.org/W2961760112","https://openalex.org/W4319844847","https://openalex.org/W4309289763","https://openalex.org/W4413984466","https://openalex.org/W4313397513","https://openalex.org/W4389784394","https://openalex.org/W4319834863","https://openalex.org/W4309288328"],"abstract_inverted_index":{"Free":[0],"N-heterocyclic":[1],"Carbene":[2],"(NHC)":[3],"radical":[4,32,53],"ions":[5],"have":[6],"remained":[7],"short-lived,":[8],"mostly":[9],"elusive,":[10],"intermediates":[11],"so":[12],"far.":[13],"We":[14,28],"probed":[15],"the":[16,37,46,72],"square":[17],"schemes":[18],"for":[19],"proton-coupled":[20],"electron":[21],"transfers":[22],"of":[23,48,76],"representative":[24],"redox-active":[25],"free":[26],"NHC.":[27],"found":[29],"that":[30],"NHC":[31,34],"anions":[33],"\u2022\u2013":[35],"and/or":[36],"conjugated":[38],"acid":[39],"NHC\u2022H":[40],"\u2022":[41],"could":[42],"be":[43],"persistent.":[44],"In":[45],"case":[47],"a":[49],"benzoquinone-based":[50],"NHC,":[51],"both":[52],"forms":[54],"were":[55,69],"isolated":[56],"as":[57],"stable":[58],"crystalline":[59],"compounds,":[60],"characterized,":[61],"including":[62],"with":[63],"single-crystal":[64],"X-ray":[65],"diffraction":[66],"studies,":[67],"and":[68],"engaged":[70],"in":[71],"straighKorward":[73],"divergent":[74],"syntheses":[75],"NHC-based":[77],"radicals.":[78]},"counts_by_year":[{"year":2026,"cited_by_count":1}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-08-07T00:00:00"}
