{"id":"https://openalex.org/W7166345211","doi":"https://doi.org/10.1093/chemle/upag139","title":"Silyl radical\u2013mediated photocatalytic decyanation of \u03b1-monosubstituted malononitriles","display_name":"Silyl radical\u2013mediated photocatalytic decyanation of \u03b1-monosubstituted malononitriles","publication_year":2026,"publication_date":"2026-06-27","ids":{"openalex":"https://openalex.org/W7166345211","doi":"https://doi.org/10.1093/chemle/upag139"},"language":"en","primary_location":{"id":"doi:10.1093/chemle/upag139","doi":"https://doi.org/10.1093/chemle/upag139","is_oa":false,"landing_page_url":"https://doi.org/10.1093/chemle/upag139","pdf_url":null,"source":{"id":"https://openalex.org/S90825563","display_name":"Chemistry Letters","issn_l":"0366-7022","issn":["0366-7022","1348-0715"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310311648","host_organization_name":"Oxford University Press","host_organization_lineage":["https://openalex.org/P4310311648","https://openalex.org/P4310311647"],"host_organization_lineage_names":["Oxford University Press","University of Oxford"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry Letters","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102351719","display_name":"Yuto Yoshida","orcid":"https://orcid.org/0009-0005-3576-1859","observed_orcids":["https://orcid.org/0009-0005-3576-1859"]},"institutions":[{"id":"https://openalex.org/I197274945","display_name":"Nagoya Institute of Technology","ror":"https://ror.org/055yf1005","country_code":"JP","type":"education","lineage":["https://openalex.org/I197274945"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yuto Yoshida","raw_affiliation_strings":["Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555 ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555 ,","institution_ids":["https://openalex.org/I197274945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037788901","display_name":"Shuichi Nakamura","orcid":"https://orcid.org/0000-0001-5633-8367","observed_orcids":["https://orcid.org/0000-0001-5633-8367"]},"institutions":[{"id":"https://openalex.org/I197274945","display_name":"Nagoya Institute of Technology","ror":"https://ror.org/055yf1005","country_code":"JP","type":"education","lineage":["https://openalex.org/I197274945"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Shuichi Nakamura","raw_affiliation_strings":["Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555 ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555 ,","institution_ids":["https://openalex.org/I197274945"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5051068355","display_name":"Naoki Yasukawa","orcid":"https://orcid.org/0000-0002-7994-0470","observed_orcids":["https://orcid.org/0000-0002-7994-0470"]},"institutions":[{"id":"https://openalex.org/I197274945","display_name":"Nagoya Institute of Technology","ror":"https://ror.org/055yf1005","country_code":"JP","type":"education","lineage":["https://openalex.org/I197274945"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Naoki Yasukawa","raw_affiliation_strings":["Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555 ,"],"raw_orcid":"https://orcid.org/0000-0002-7994-0470","affiliations":[{"raw_affiliation_string":"Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555 ,","institution_ids":["https://openalex.org/I197274945"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5037788901","https://openalex.org/A5051068355"],"corresponding_institution_ids":["https://openalex.org/I197274945"],"apc_list":{"value":150000,"currency":"JPY","value_usd":1003},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.39078561,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"55","issue":"7","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silyl-radicals","display_name":"silyl radicals","score":0.9279999732971191},{"id":"https://openalex.org/keywords/aliphatic-nitriles","display_name":"aliphatic nitriles","score":0.9380000233650208}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9578999876976013},{"id":"https://openalex.org/C5304478","wikidata":"https://www.wikidata.org/wiki/Q502457","display_name":"Silylation","level":3,"score":0.9284999966621399},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.5286999940872192},{"id":"https://openalex.org/C2776730140","wikidata":"https://www.wikidata.org/wiki/Q421634","display_name":"Pinacol","level":3,"score":0.49410000443458557},{"id":"https://openalex.org/C2993420144","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen atom","level":3,"score":0.4180000126361847},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.40070000290870667},{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.3765000104904175},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3700999915599823},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.366100013256073},{"id":"https://openalex.org/C2776308844","wikidata":"https://www.wikidata.org/wiki/Q47192","display_name":"Ethyl acetoacetate","level":3,"score":0.3499999940395355},{"id":"https://openalex.org/C2777332933","wikidata":"https://www.wikidata.org/wiki/Q170409","display_name":"Functional group","level":3,"score":0.3456000089645386},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3086000084877014},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.30730000138282776},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.29159998893737793},{"id":"https://openalex.org/C65667505","wikidata":"https://www.wikidata.org/wiki/Q5138702","display_name":"Cobalt-mediated radical polymerization","level":5,"score":0.27230000495910645},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.2685000002384186},{"id":"https://openalex.org/C2991944050","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Reaction conditions","level":3,"score":0.2667999863624573}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1093/chemle/upag139","doi":"https://doi.org/10.1093/chemle/upag139","is_oa":false,"landing_page_url":"https://doi.org/10.1093/chemle/upag139","pdf_url":null,"source":{"id":"https://openalex.org/S90825563","display_name":"Chemistry Letters","issn_l":"0366-7022","issn":["0366-7022","1348-0715"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310311648","host_organization_name":"Oxford University Press","host_organization_lineage":["https://openalex.org/P4310311648","https://openalex.org/P4310311647"],"host_organization_lineage_names":["Oxford University Press","University of Oxford"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry Letters","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G8937088531","display_name":"\u7cbe\u5bc6\u6709\u6a5f\u5408\u6210\u53cd\u5fdc\u306e\u958b\u767a\u306b\u5411\u3051\u305f\u30db\u30a6\u7d20\u30e9\u30b8\u30ab\u30eb\u5316\u5b66\u306e\u65b0\u5c55\u958b","funder_award_id":"24K17678","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W937394879","https://openalex.org/W1907114422","https://openalex.org/W1996941025","https://openalex.org/W2016133475","https://openalex.org/W2029817361","https://openalex.org/W2037424279","https://openalex.org/W2072624193","https://openalex.org/W2102605881","https://openalex.org/W2155604981","https://openalex.org/W2588944565","https://openalex.org/W2593538402","https://openalex.org/W2767598589","https://openalex.org/W2769797581","https://openalex.org/W2785632336","https://openalex.org/W2949424045","https://openalex.org/W2952962991","https://openalex.org/W2953067004","https://openalex.org/W2953294813","https://openalex.org/W3091854466","https://openalex.org/W3160334326","https://openalex.org/W3178147378","https://openalex.org/W3188096523","https://openalex.org/W3209064371","https://openalex.org/W4283021239","https://openalex.org/W4288051672","https://openalex.org/W4366090087","https://openalex.org/W4382011566","https://openalex.org/W4394819989","https://openalex.org/W4402393166","https://openalex.org/W4406259429","https://openalex.org/W4411580978","https://openalex.org/W7118864353"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"This":[1,49],"manuscript":[2],"represents":[3],"a":[4,11,18,29,34],"photocatalytic":[5],"decyanation":[6,82],"of":[7,36,63,77],"\u03b1-monosubstituted":[8],"malononitriles":[9],"using":[10,57],"silyl":[12,19,70],"boronic":[13],"acid":[14],"pinacol":[15],"ester":[16],"as":[17],"radical":[20,71,86],"precursor.":[21],"The":[22],"reaction":[23],"proceeds":[24],"under":[25],"mild":[26],"conditions":[27],"via":[28],"radical\u2013polar":[30],"crossover":[31],"mechanism,":[32],"affording":[33],"variety":[35],"aliphatic":[37],"nitriles":[38],"in":[39],"good":[40],"to":[41,54,73],"high":[42],"yields":[43],"with":[44],"broad":[45],"functional":[46],"group":[47,80],"tolerance.":[48],"protocol":[50],"can":[51],"be":[52],"extended":[53],"decyanative":[55],"deuteration":[56],"D2O,":[58],"enabling":[59],"the":[60,74,78],"site-selective":[61],"synthesis":[62],"deuterated":[64],"nitriles.":[65],"Mechanistic":[66],"studies":[67],"suggest":[68],"that":[69],"addition":[72],"nitrogen":[75],"atom":[76],"cyano":[79],"triggers":[81],"through":[83],"an":[84],"imidoyl":[85],"intermediate.":[87]},"counts_by_year":[],"updated_date":"2026-09-21T07:43:02.447757","created_date":"2026-06-28T00:00:00"}